Publications (Dr. Iwasaki)

  1. Sequence-Controlled Copolymerization of Structurally Well-Defined Multinuclear Zinc Acrylate Complexes and Styrene
    T. Iwasaki, G. Suehisa, R. Mandai, K. Nozaki
    Macromol. Rapid Commun. 2024, 2400742. 10.1002/marc.202400742
  2. Synthesis, Structure, and Optical Property of Tris(biaryldiyl)metal Complexes Consisting of Group 9 Elements
    M. Hara, Y. Hirooka, T. Iwasaki, K. Nozaki
    Inorg. Chem. 2024, 63, 21474–21487. 10.1021/acs.inorgchem.4c03514
  3. Chemoselective Hydrogenolysis of Urethanes to Formamides and Alcohols in the Presence of More Electrophilic Carbonyl Compounds
    T. Iwasaki, Y. Yamada, N. Naito, K. Nozaki
    J. Am. Chem. Soc. 2024, 146, 25562–25568. 10.1021/jacs.4c06553 Highlighted in Press Release, 日刊工業新聞, 日本経済新聞, ニュースイッチ, fabcross forエンジニア, Chem-Stationスポットライトリサーチ, マイナビニュース, Mapion, Science Portal. Featured on the supplementary cover.
    ChemRxiv 2024 (preprint) 10.26434/chemrxiv-2024-69jc4
  4. Hydrogenolysis of Urethanes and Ureas Catalyzed by Manganese Complex Supported by Bidentate PN Ligand
    T. Iwasaki, N. Saito, Y. Yamada, S. Ajiro, K. Nozaki
    Organometallics 2024, 43, 924–928. 10.1021/acs.organomet.4c00032
  5. Linear, Planar, Orbicular, and Macrocyclic Multinuclear Zinc (Meth)acrylate Complexes
    T. Iwasaki, G. Suehisa, H. Tadaoka, K. Shiga, K. Nozaki
    Chem. Eur. J. 2024, 30, e202400586. 10.1002/chem.202400586 Featured on inside cover.
  6. Palladium-catalyzed copolymerization of ethylene or propylene with norbornene carboxylic acids and their esters
    K. Tsuge, K. Lau, Y. Hirooka, T. Iwasaki, K. Yokomizo, K. Nozaki
    Polymer 2023, 281, 126116. 10.1016/j.polymer.2023.126116
  7. Chemoselectivity Change in Catalytic Hydrogenolysis enabling Urea-reduction to Formamide/Amine over More Reactive Carbonyl Compounds
    T. Iwasaki, K. Tsuge, N. Naito, K. Nozaki
    Nat. Commun. 2023, 14, 3279. 10.1038/s41467-023-38997-2 Highlighted in 日本経済新聞, 化学工業日報, Press Release, ASCII, Science Portal, Yahoo!ニュース.
    ChemRxiv 2023 (preprint) 10.26434/chemrxiv-2023-z49zw
  8. Chain Transfer Approach for Terminal Functionalization of Alternating Copolymerization of CO2 and Epoxide by Using Active Methylene Compounds as Chain Transfer Agents
    H. Nagae, S. Akebi, S. Matsushiro, K. Sakamoto, T. Iwasaki, K. Nozaki, K. Mashima
    Macromolecules 2022, 55, 9066–9073.10.1021/acs.macromol.2c01761
  9. Mechanistic Insight into Rh-Catalyzed C(sp2)–O Bond Cleavage Applied to Cross-Coupling Reaction of Benzofurans with Aryl Grignard Reagents
    T. Iwasaki, W. Ishiga, S. Pal, K. Nozaki, N. Kambe
    ACS Catal. 2022, 12, 7936–7949. 10.1021/acscatal.2c01974
  10. Bio-Inspired Asymmetric Aldehyde Arylations Catalyzed by Rhodium-Cyclodextrin Self-Inclusion Complexes
    S. Tsuda, K. Asahi, R. Takahashi, H. Yamauchi, R. Ueda, T. Iwasaki, S. Fujiwara, N. Kambe
    Org. Biomol. Chem. 2022, 20, 801–807. 10.1039/d1ob02014e Featured on the cover.
    This article is part of the themed collections: 2021 Organic & Biomolecular Chemistry HOT article collection and Supramolecular chemistry in OBC
  11. 2-Aryl-Perfluorobenzoxazoles: Synthesis, Fluorescence Properties and Synthetic Application in Cubic Platinum Nanoparticles
    R. Wang, M. Yan, M. Li, X. Lyu, H. Huang, A. Ghaderi, T. Iwasaki, N. Kambe, A. Abdukadera, R. Qiu
    J. Mater. Chem. C 2021, 9, 12545–12549. 10.1039/D1TC03338G
  12. Lithium Hexaphenylrhodate(III) and –Iridate(III): Structure in the Solid State and in Solution
    T. Iwasaki, Y. Hirooka, H. Takaya, T. Honma, K. Nozaki
    Organometallics 2021, 40, 2489–2495. 10.1021/acs.organomet.1c00248
  13. Metal-Ligand Cooperative κ1-N-pyrazolate Cp*RhIII-Catalysts for Dehydrogenation of Dimethylamine-borane at Room Temperature
    S. Pal, T. Iwasaki, K. Nozaki
    Dalton Trans. 2021, 50, 7938–7943. 10.1039/D1DT01705E
  14. Synthesis of and Structural Insights into Contact Ion Pair and Solvent-Separated Ion Pair Diphenyliridate Complexes
    T. Iwasaki, T. Akaiwa, Y. Hirooka, S. Pal, K. Nozaki, N. Kambe
    Organometallics 2020, 39, 3077–3081. 10.1021/acs.organomet.0c00446
  15. Alternating Copolymerization of CO2 and Cyclohexene Oxide Catalyzed by Cobalt-Lanthanide Mixed Multinuclear Complexes
    H. Asaba, T. Iwasaki, M. Hatazawa, J. Deng, H. Nagae, K. Mashima, K. Nozaki
    Inorg. Chem. 2020, 59, 7928–7933. 10.1021/acs.inorgchem.0c01156
  16. Effect of Alkyl Groups in Pyrene Chromophore on Mechanical Response of Pyrene-Octafluoronaphthalene Co-Crystals
    T. Iwasaki, S. Murakami, Y. Takeda, N. Tohnai, and N. Kambe
    Chem. Asian J. 2020, 15, 1349–1354. 10.1002/asia.202000138
  17. Copper-catalyzed Amination of C(sp3)–H Bonds: From Anilides to Indolines
    J. Long, L. Le, T. Iwasaki, R. Qiu, and N. Kambe
    J. Org. Chem. 2020, 85, 482–492. 10.1021/acs.joc.9b02404
  18. Molecular Packing and Solid-state Photophysical Properties of 1,3,6,8-Tetraalkylpyrenes
    T. Iwasaki, S. Murakami, Y. Takeda, G. Fukuhara, N. Tohnai, Y. Yakiyama, H. Sakurai, N. Kambe
    Chem. Eur. J. 2019, 25, 14817–14825. 10.1002/chem.201903224 selected as Cover Picture.
  19. Structure of the Complex Ni(C8H12)(L) and Its Reactivity toward Organometallic Reagents
    T. Iwasaki, W. Yokoyama, N. Kambe
    Organometallics 2019, 38, 2701–2704. 10.1021/acs.organomet.9b00296 selected as Cover Picture.
  20. Pivalic Acid-Assisted Rh(III)-Catalyzed C-H Functionalization of 2-Arylpyridine Derivatives Using Arylsilanes
    A. Ghaderi, T. Iwasaki, N. Kambe
    Asian J. Org. Chem. 2019, 8, 1344–1347. 10.1002/ajoc.201900362
  21. Synthesis of Imidazolium Salts Bearing Two Cyclodextrins
    S. Tsuda, Y. Minami, R. Ueda, T. Iwasaki, S.-i. Fujiwara, H. Kuniyasu, N. Kambe
    Heterocycles 2018, 96, 2111–2118. 10.3987/COM-18-13993
  22. Synthesis of Cyclopropane Fatty Acids by C(sp3)–C(sp3) Cross-coupling Reaction and Formal Synthesis of α-Mycolic Acid
    T. Iwasaki, S. Terahigashi, Y. Wang, A. Tanaka, H. Zhao, Y. Fujimoto, K. Fukase, N. Kambe
    Adv. Synth. Catal. 2018, 360, 3810–3817. 10.1002/adsc.201800901
  23. Ni-catalyzed Dimerization and Hydroperfluoroarylation of 1,3-Dienes
    T. Iwasaki, X. Min, A. Fukuoka, L. Zhu, R. Qiu, T. Yang, M. Ehara, A. Sudalai, N. Kambe
    J. Org. Chem. 2018, 83, 9267–9277. 10.1021/acs.joc.8b01266 highlighted in Synfacts 2018, 14, 968.
  24. Cross-Coupling Reaction of Alkyl Halides with Alkyl Grignard Reagents Catalyzed by Cp-Iron Complexes in the Presence of 1,3-Butadiene
    T. Iwasaki, R. Shimizu, R. Imanishi, H. Kuniyasu, N. Kambe
    Chem. Lett. 2018, 47, 763–766. 10.1246/cl.180201
  25. Nickel-Catalyzed Coupling Reaction of Alkyl Halides with Aryl Grignard Reagents in the Presence of 1,3-Butadiene: Mechanistic Studies of Four-Component Coupling and Competing Cross-Coupling Reactions
    T. Iwasaki, A. Fukuoka, W. Yokoyama, X. Min, I. Hisaki, T. Yang, M. Ehara, H. Kuniyasu, N. Kambe
    Chem. Sci. 2018, 9, 2195–2211. 10.1039/C7SC04675H highlighted in Synfacts 2018, 14, 303.
  26. Cu-Catalyzed Reductive Coupling of Perfluoroarenes with 1,3-Dienes
    T. Iwasaki, K. Okamoto, H. Kuniyasu, N. Kambe
    Chem. Lett. 2017, 46, 1504–1507. 10.1246/cl.170650
  27. Co-Catalyzed Cross-Coupling Reaction of Alkyl Fluorides with Alkyl Grignard Reagents
    T. Iwasaki, K. Yamashita, H. Kuniyasu, N. Kambe
    Org. Lett. 2017, 19, 3691–3694. 10.1021/acs.orglett.7b01370 highlighted in Synfacts 2017, 13, 1070.
  28. Nickel-Catalyzed Direct Alkylation of Thiophenes via Double C(sp3)-H/C(sp2)-H Bond Cleavage: The Importance of KH2PO4
    X. Wang, P. Xie, R. Qiu, L. Zhu, T. Liu, Y. Li, T. Iwasaki, C.-T. Au, X. Xu, Y. Xia, S.-F. Yin, N. Kambe
    Chem. Commun. 2017, 53, 8316–8319. 10.1039/C7CC04252C
  29. Intramolecular, Site-Selective, Iodine-Mediated, Amination of Unactivated (sp3)C-H Bonds for the Synthesis of Indoline Derivatives
    J. Long, X. Cao, L. Zhu, R. Qiu, C.-T. Au, S.-F. Yin, T. Iwasaki, N. Kambe
    Org. Lett. 2017, 19, 2793–2796. 10.1021/acs.orglett.7b00846
  30. Synthesis of Cyclic Nigerosylnigerose (CNN) Bis-Imidazolium Salts
    S. Tsuda, Y. Komatsu, Y. Minami, R. Ueda, S.-i. Fujiwara, T. Iwasaki, H. Kuniyasu, N. Kambe
    Heterocycles 2017, 95, 1197–1203. 10.3987/COM-16-S(S)69
  31. Multicomponent Coupling Reaction of Perfluoroarenes with 1,3-Butadiene and Aryl Grignard Reagents Promoted by an Anionic Ni(II) Complex
    T. Iwasaki, A. Fukuoka, X. Min, W. Yokoyama, H. Kuniyasu, N. Kambe
    Org. Lett. 2016, 18, 4868–4871. 10.1021/acs.orglett.6b02343
  32. Fe-Catalyzed Cross-Coupling Reaction of Vinylic Ethers with Aryl Grignard Reagents
    T. Iwasaki, R. Akimoto, H. Kuniyasu, N. Kambe
    Chem. Asian J. 2016, 11, 2834–2837. 10.1002/asia.201600972
  33. Regioselective Phosphorylation of myo-Inositol with BINOL-Derived Phosphoramidites, and Its Application for Protozoan Lysophosphatidylinositol
    T. Aiba, M. Sato, D. Umegaki, T. Iwasaki, N. Kambe, K. Fukase, Y. Fujimoto
    Org. Biomol. Chem. 2016, 14, 6672–6675. 10.1039/C6OB01062H
  34. Nickel-Catalyzed Dimerization and Alkylarylation of 1,3-Dienes with Alkyl Fluorides and Aryl Grignard Reagents
    T. Iwasaki, X. Min, A. Fukuoka, H. Kuniyasu, N. Kambe
    Angew. Chem. Int. Ed. 2016, 55, 5550–5554. 10.1002/anie.201601126 selected as Front Cover. highlighted in Synfacts 2016, 12, 523. 科学新聞4月15日付4面
  35. Cu-Catalyzed Regioselective Hydroalkylation of 1,3-Dienes with Alkyl Fluorides and Grignard Reagents
    T. Iwasaki, R. Shimizu, R. Imanishi, H. Kuniyasu, N. Kambe
    Angew. Chem. Int. Ed. 2015, 54, 9347–9350. 10.1002/anie.201503288 日経産業新聞７月１日付朝刊８面
  36. Nickel-catalyzed Synthesis of Diarylsulfides and Sulfones via C–H Bond Functionalization of Arylamides
    V. P. Reddy, R. Qiu, T. Iwasaki, N. Kambe
    Org. Biomol. Chem. 2015, 13, 6803–6813. 10.1039/C5OB00149H
  37. Copper-mediated Thiolation of Carbazole Derivatives and Related N-heterocycle Compounds
    L. Zhu, X. Cao, R. Qiu, T. Iwasaki, V. P. Reddy, X. Xu, S.-F. Yin, N. Kambe
    RSC Adv. 2015, 5, 39358–39365. 10.1039/C5RA04965B
  38. Regioselective Cis Insertion of DMAD into Au−P Bonds: Effect of Auxiliary Ligands on the Reaction Mechanism
    H. Kuniyasu, T. Nakajima, T. Tamaki, T. Iwasaki, N. Kambe
    Organometallics 2015, 34, 1373–1376. 10.1021/acs.organomet.5b00078
  39. AlCl3-catalyzed Insertion of Isocyanides into Nitrogen-sulfur Bonds of Sulfenamides
    D. Shiro, S.-i. Fujiwara, S. Tsuda, T. Iwasaki, H. Kuniyasu, N. Kambe
    Tetrahedron Lett. 2015, 56, 1531–1534. 10.1016/j.tetlet.2015.01.096
  40. Palladium-Catalyzed Insertion Reactions of Isocyanides into Thiocarbamates and Selenocarbamates
    D. Shiro, S.-i. Fujiwara, S. Tsuda, T. Iwasaki, H. Kuniyasu, N. Kambe
    Chem. Lett. 2015, 44, 465–467. 10.1246/cl.141141
  41. Palladium Catalyzed Intramolecular Vinylselenation and Vinylthiolation of Allenes
    S. Tsuda, M. Okuyama, S.-i. Fujiwara, T. Iwasaki, H. Kuniyasu, N. Kambe
    Heterocycles 2015, 90, 1323–1331. 10.3987/COM-14-S(K)80
  42. The Palladium-Catalyzed Intermolecular C–H Chalcogenation of Arenes
    R. Qiu, V. P. Reddy, T. Iwasaki, N. Kambe
    J. Org. Chem. 2015, 80, 367–374. 10.1021/jo502402d.
  43. Palladium-Catalyzed Decarbonylative Rearrangement of NI-Allenyl Seleno- and Tellurocarbamates
    D. Shiro, H. Nagai, S.-i. Fujiwara, S. Tsuda, T. Iwasaki, H. Kuniyasu, N. Kambe
    Heteroatom Chem. 2014, 25, 518–524. 10.1002/hc.21217
  44. Halogen Exchange by Reaction of CpRu(Cl)(PPh3)2 with MeC(O)X (X = Br, I) and its Mechanistic Study
    H. Kuniyasu, A. Sanagawa, T. Nakajima, T. Iwasaki, N. Kambe, K. Bobuatong, M. Ehara
    J. Organomet. Chem. 2014, 769, 34–37. 10.1016/j.jorganchem.2014.06.018
  45. Copper-Catalyzed Alkyl-Alkyl Cross-Coupling Reactions Using Hydrocarbon Additives: Efficiency of Catalyst and Roles of Additives
    T. Iwasaki, R. Imanishi, R. Shimizu, H. Kuniyasu, J. Terao, N. Kambe
    J. Org. Chem. (Featured Article) 2014, 79, 8522–8532. 10.1021/jo501006u selected as Cover picture and most read articles in month top 20.
  46. Diarylrhodates as Promising Active Catalysts for the Arylation of Vinyl Ethers with Grignard Reagents
    T. Iwasaki, Y. Miyata, R. Akimoto, Y. Fujii, H. Kuniyasu, N. Kambe
    J. Am. Chem. Soc. 2014, 136, 9260–9263. 10.1021/ja5043534
  47. The Cobalt-Catalyzed Cross-Coupling Reaction of Alkyl Halides with Alkyl Grignard Reagents: A New Route to Constructing Quaternary Carbon Centers
    T. Iwasaki, H. Takagawa, K. Okamoto, S. P. Singh, H. Kuniyasu, N. Kambe
    Synthesis 2014, 46, 1583–1592. 10.1055/s-0033-1341152
  48. Co-Catalyzed Cross-Coupling of Alkyl Halides with Tertiary Alkyl Grignard Reagents Using a 1,3-Butadiene Additive
    T. Iwasaki, H. Takagawa, S. P. Singh, H. Kuniyasu, N. Kambe
    J. Am. Chem. Soc. 2013, 135, 9604–9607. 10.1021/ja404285b highlighted in Synfacts 2013, 1002.
  49. Facile Halogen Exchange Method between Au(Cl)(L) and MeC(O)X (L = PPh3 and IPr; X = Br and I) via σ-Bond Metathesis Supported by DFT Calculation
    A. Sanagawa, H. Kuniyasu, T. Iwasaki, N. Kambe, K. Bobuatong, M. Ehara
    Chem. Lett. 2013, 42, 831–832. 10.1246/cl.130335
  50. σ-Bond Metathesis between M–X and RC(O)X’ (M = Pt, Pd; X, X’ = Cl, Br, I): Facile Determination of the Relative ΔG Values of the Oxidative Additions of RC(O)X to an M(0) Complex, Evidence by Density Functional Theory Calculations, and Synthetic Applications
    H. Kuniyasu, A. Sanagawa, D. Nakane, T. Iwasaki, N. Kambe, K. Bobuatong, Y. Lu, M. Ehara
    Organometallics 2013, 32, 2026–2032. 10.1021/om400157a
  51. Rhodium-Catalyzed Intermolecular Oxidative Cross-Coupling of (Hetero)Arenes with Chalcogenophenes
    V. P. Reddy, R. Qiu, T. Iwasaki, N. Kambe
    Org. Lett. 2013, 15, 1290–1293. 10.1021/ol400230y
  52. Synthesis of Imidazo and Benzimidazo[2,1-a]-isoquinolines by Rhodium-Catalyzed Intramolecular Double C-H Bond Activation
    V. P. Reddy, T. Iwasaki, N. Kambe
    Org. Biomol. Chem. 2013, 11, 2249–2253. 10.1039/c3ob27396b
  53. Ni-Butadiene Catalytic System for the Cross-Coupling of Bromoalkanoic Acids with Alkyl Grignard Reagents: A Practical and Versatile Method for Preparing Fatty Acids
    T. Iwasaki, K. Higashikawa, V. P. Reddy, W. W. S. Ho, Y. Fujimoto, K. Fukase, J. Terao, H. Kuniyasu, N. Kambe
    Chem. Eur. J. 2013, 19, 2956–2960. 10.1002/chem.201204222
  54. The Nickel-Catalyzed Coupling of Thiomethyl-Substituted 1,3-Benzothiazoles with Secondary Alkyl Grignard Reagents
    A. Ghaderi, T. Iwasaki, A. Fukuoka, J. Terao, N. Kambe
    Chem. Eur. J. 2013, 19, 2951–2955. 10.1002/chem.201203413
  55. Palladium-Catalyzed Vinylselenation of Allenes
    S.-i. Fujiwara, M. Okuyama, S. Tsuda, T. Iwasaki, H. Kuniyasu, N. Kambe
    Tetrahedron 2012, 68, 10523–20529. 10.1016/j.tet.2012.10.003
  56. A Computational Study of Lithium Cuprate Mixed Aggregates
    C. N. D. Khiem, L. N. Thach, T. Iwasaki, N. Kambe, A. A. Boguslavskiy, L. M. Pratt
    J. Phys. Chem. A 2012, 116, 9027–9032. 10.1021/jp3034424
  57. Copper-Catalyzed Coupling Reaction of Unactivated Secondary Alkyl Iodides with Alkyl Grignard Reagents in the Presence of 1,3-Butadiene as an Effective Additive
    R. Shen, T. Iwasaki, J. Terao, N. Kambe
    Chem. Commun. 2012, 48, 9313–9315. 10.1039/C2CC34847K
  58. Cross-coupling of Grignard reagents with Alkyl Halides or Tosylates by the Use of Nickel or Palladium Containing Perovskite
    S. P. Singh, T. Iwasaki, J. Terao, N. Kambe
    Tetrahedron Lett. 2011, 52, 774–776. 10.1016/j.tetlet.2010.12.011
  59. The First Example of Palladium-Catalyzed Intermolecular Allylaryloxylation of an Internal Alkyne by Allyl Aryl Ethers
    H. Kuniyasu, K. Takekawa, A. Sanagawa, T. Wakasa, T. Iwasaki, and N. Kambe
    Tetrahedron Lett. 2011, 52, 5501–5503. 10.1016/j.tetlet.2011.08.065
  60. Silver-Catalyzed Regioselective Carbomagnesiation of Alkynes with Alkyl Halides and Grignard Reagents
    N. Kambe, Y. Moriwaki, Y. Fujii, T. Iwasaki, J. Terao
    Org. Lett. 2011, 13, 4656–4659. 10.1021/ol2018664
  61. Additive Effect of N-Heteroaromatics on Transesterification Catalyzed by Tetranuclear Zinc Cluster
    Y. Maegawa, T. Ohshima, Y. Hayashi, K. Agura, T. Iwasaki, K. Mashima
    ACS Catal. 2011, 1, 1178–1182. 10.1021/cs200224b
  62. Kinetic Studies of the Ni-Catalyzed Cross-Coupling of Alkyl Halides and a Tosylate with Butyl Grignard Reagent in the Presence of 1,3-Butadiene
    T. Iwasaki, A. Tsumura, T. Omori, H. Kuniyasu, J. Terao, N. Kambe
    Chem. Lett. 2011, 40, 1024–1026. 10.1246/cl.2011.1024
  63. C1-Symmetric Rh-Phebox-Catalyzed Asymmetric Alkynylation of Keto Ester
    T. Ohshima, T. Kawabata, Y. Takeuchi, T. Kakinuma, T. Iwasaki, T. Yonezawa, H. Murakami, H. Nishiyama, K. Mashima
    Angew. Chem. Int. Ed. 2011, 50, 6296–6300. 10.1002/anie.201100252 selected as Synfact of the Month; Synfacts 2011, 967.
  64. A Tetranuclear-Zinc-Cluster-Catalyzed Practical and Versatile Deprotection of Acetates and Benzoates
    T. Iwasaki, K. Agura, Y. Maegawa, Y. Hayashi, T. Ohshima, K. Mashima
    Chem. Eur. J. 2010, 16, 11567–11571. 10.1002/chem.201000960
  65. Theoretical Study of Al(III)-Catalyzed Conversion of Glyoxal to Glycolic Acid: Dual Activated 1,2-Hydride Shift Mechanism by Protonated Al(OH)3 Species
    T. Ohshima, Y. Yamamoto, U. Takaki, Y. Inoue, T. Saeki, K. Itou, Y. Maegawa, T. Iwasaki, K. Mashima
    Chem. Commun. 2009, 2688-2690. 10.1039/B902729G
  66. A Simple, General, and Highly Chemoselective Acetylation of Alcohols Using Ethyl Acetate as the Acetyl Donor Catalyzed by a Tetranuclear Zinc Cluster
    T. Iwasaki, Y. Maegawa, Y. Hayashi, T. Ohshima, K. Mashima
    Synlett 2009, 1659-1663. 10.1055/s-0029-1217335
  67. Zinc-Catalyzed Cycloisomerizations. Synthesis of Substituted Furans and Furopyrimidine Nucleosides
    A. Sniady, A. Durham, M. S. Morreale, A. Marcinek, S. Szafert, T. Lis, K. R. Brzezinska, T. Iwasaki, T. Ohshima, K. Mashima, R. Dembinski
    J. Org. Chem. 2008, 73, 5881–5889. 10.1021/jo8007995 highlighted in Synfacts 2008, 1084.
  68. Transesterification of Various Methyl Esters Under Mild Conditions Catalyzed by Tetranuclear Zinc Cluster
    T. Iwasaki, Y. Maegawa, Y. Hayashi, T. Ohshima, K. Mashima
    J. Org. Chem. 2008, 73, 5147–5150. 10.1021/jo800625v highlighted in Synfacts 2008, 975.
  69. Enzyme-Like Chemoselective Acylation of Alcohol in the Presence of Amines Catalyzed by a Tetranuclear Zinc Cluster
    T. Ohshima, T. Iwasaki, Y. Maegawa, A. Yoshiyama, K. Mashima
    J. Am. Chem. Soc. 2008, 130, 2944-2945. 10.1021/ja711349r highlighted in Science 2008, 319, 1163, Nature 2008, 452, 415-416, Synfacts 2008, 627, 化学 2008, 63, 57–58.
  70. Direct Conversion of Esters, Lactones, and Carboxylic Acids to Oxazolines Catalyzed by Tetranuclear Zinc Cluster
    T. Ohshima, T. Iwasaki, K. Mashima
    Chem. Commun. 2006,2711-2713. 10.1039/B605066B

Review articles

  1. Counterintuitive chemoselectivity in the reduction of carbonyl compounds
    T. Iwasaki, K. Nozaki
    Nat. Rev. Chem. 2024, 8, 518–534. 10.1038/s41570-024-00608-z
  2. 水素を用いた難分解性プラスチックのケミカルリサイクル
    T. Iwasaki, K. Takahashi
    高分子, 73 (5), 201–202 (2024).
  3. Cross- and Multi-Coupling Reactions Using Monofluoroalkanes
    T. Iwasaki, N. Kambe
    Chem. Rec. 2023, 23, e202300033. 10.1002/tcr.202300033 Featured on Cover Picture.
  4. 複合金属錯体の特性に立脚した触媒的炭素骨格構築反応
    T. Iwasaki
    Bull. Jpn. Soc. Coord. Chem. 2021, 77, 11–25. 10.4019/bjscc.77.11
  5. Catalytic functionalization of 1,3-butadiene by carbon electrophiles
    T. Iwasaki
    J. Jpn. Petrol. Inst. 2020, 63, 123–132. 10.1627/jpi.63.123
  6. Catalytic Construction of Carbon Frameworks Employing Alkyl Fluorides as Electrophiles
    T. Iwasaki
    J. Synth. Org. Chem. Jpn., 78, 109–120 (2020). 10.5059/yukigoseikyokaishi.78.109
  7. アニオン性有機金属錯体触媒による1,3-ブタジエンへの選択的炭素官能基導入法の開発
    T. Iwasaki
    ペトロテック, 42, 708–712 (2019).
  8. カルボン酸とアミンとの触媒的縮合反応
    T. Iwasaki
    化学と工業, 71, 497 (2018).
  9. 極性転換が導く遷移金属の新機能−アニオン性有機金属化学種を活用する合成反応
    T. Iwasaki
    化学と工業, 69, 979–980 (2016).
  10. Ni-Catalyzed C–C Couplings Using Alkyl Electrophiles
    T. Iwasaki, N. Kambe
    Top. Curr. Chem. (Z), 374, article number 66 (2016). Part of the topical collection: Ni-Based and Fe-Based Cross-Coupling Reactions10.1007/s41061-016-0067-6
  11. 光を用いてNiの酸化状態を制御する-Ni触媒を用いたクロスカップリング反応の新展開
    T. Iwasaki, N. Kambe
    化学, 71, 70–71 (2016).
  12. 不斉アルキルーアルキルカップリング反応の新展開
    T. Iwasaki
    Organometallic News, 38, 38 (2015).
  13. Transition Metal Catalyzed Alkylation at sp3-, sp2-, and sp-Carbons
    N. Kambe, J. Terao, T. Iwasaki
    J. Synth. Org. Chem. Jpn., special issue in English, 69, 1271–1281 (2011). 10.5059/yukigoseikyokaishi.69.1271
  14. Pd-Catalyzed Cross-Coupling Reaction of Alkyl Halides
    N. Kambe, T. Iwasaki, J. Terao
    Chem. Soc. Rev., 40, 4937–4947 (2011). 10.1039/C1CS15129K
  15. 亜鉛四核クラスター触媒による環境調和型反応の開発
    T. Iwasaki, T. Ohshima, K. Mashima
    科学と工業, 84, 268–281 (2010).
  16. Development of Environmentally Benign Catalytic Reactions Using Tetranuclear Zinc Clusters
    T. Ohshima, T. Iwasaki, K. Mashima
    J. Synth. Org. Chem. Jpn., 67, 494–506 (2009). 10.5059/yukigoseikyokaishi.67.494

Book chapters

  1. Coupling Reactions Between sp3 Carbon Centers
    T. Iwasaki
    In Comprehensive Organic Synthesis, 3rd edition; N. Kiruthigadevi and N. Negi, Eds,; Elsevier: Oxford, in press. 10.1016/B978-0-323-96025-0.00030-2
  2. (Het)Arene/Alkane Cross-Dehydrogenative Coupling for C(sp2)—C(sp3) Bond Formation
    T. Iwasaki, N. Kambe
    In Science of Synthesis; Section 9, Cross-Dehydrogenative Coupling, Thieme, 201-228. 10.1055/sos-SD-240-00041
  3. Transition-Metal-Catalyzed Alkyl-Alkyl Cross-Coupling Reactions
    T. Iwasaki, N. Kambe
    In Organic Reactions; J. Montgomery and K. Shaughnessy, Eds, Wiley, Vol. 113, Chapter 1, 1–456 (2023). 10.1002/0471264180.or113.01
  4. 触媒総合辞典
    触媒学会編
    朝倉書店
    Chapter 8-23を担当
  5. クロスカップリング反応の新展開—sp3炭素上での結合形成反応—
    T. Iwasaki, N. Kambe
    触媒年鑑触媒技術の動向と展望, 26–36 (2017).
  6. 触媒化学　—基礎から応用まで (エキスパート応用化学テキストシリーズ)
    Y. Tanaka, H. Yamashita, A. Satsuma, M. Machida, T. Shishido, N. Kambe, T. Iwasaki, M. Ehara, H. Mori, D. Miura
    講談社サイエンティフィク
    ISBN-10: 4061568116
  7. Coupling Reactions Between sp3 Carbon Centers
    T. Iwasaki, N. Kambe
    In Comprehensive Organic Synthesis, 2nd edition; G. A. Molander, P. Knochel Eds., Elsevier, Oxford, Vol. 3, Chapter 07, 337–391 (2014). 10.1016/B978-0-08-097742-3.00311-6
  8. Esterification
    T. Iwasaki, Y. Maegawa, T. Ohshima, K. Mashima
    In Kirk-Othmer Encyclopedia of Chemical Technology, John Wiley & Sons, 1–33 (2012). 10.1002/0471238961.0519200501191201.a01.pub2