Publications (Prof. Nozaki)

  1. Degradation of Epoxy Resins in Water for Recovery of Small Organic Molecules: The Use of Platinum Catalyst under Hydrothermal Conditions
    K. Nozaki, Y. Liao, S. Hosokawa, K. Takahashi, S. Nakagawa, N. Yoshie, Y. Yamasaki
    Research Square 2024 (preprint) 10.21203/rs.3.rs-5298299/v1
  2. Exceptionally Short Tetracoordinated Carbon–Halogen Bonds in Hexafluorodihalocubanes
    M. Sugiyama, Y. Uetake, N. Miyagi, M. Yoshida, K. Nozaki, T. Okazoe, M. Akiyama
    J. Am. Chem. Soc. 2024, 146, 30686–30697. 10.1021/jacs.4c12732 Highlighted in ChemistryViews.
  3. Sequence-Controlled Copolymerization of Structurally Well-Defined Multinuclear Zinc Acrylate Complexes and Styrene
    T. Iwasaki, G. Suehisa, R. Mandai, K. Nozaki
    Macromol. Rapid Commun. 2024, 2400742. 10.1002/marc.202400742
  4. Crystallization of Strictly Linear Poly(ethylene-ran-acrylic acid) Copolymer: Impacts of Pendant Group Insertion and Hydrogen Bonding
    J. Zhou, K. Takahashi, K. Nozaki, Y. Yamamoto, T. Katashima, N. Yoshie, S. Nakagawa
    Macromolecules 2024, 57, 10176–10191. acs.macromol.4c01250
  5. Synthesis, Structure, and Optical Property of Tris(biaryldiyl)metal Complexes Consisting of Group 9 Elements
    M. Hara, Y. Hirooka, T. Iwasaki, K. Nozaki
    Inorg. Chem. 2024, 63, 21474–21487. 10.1021/acs.inorgchem.4c03514
  6. Fully Conjugated Tetraborylethylene: Selenium Mediated C–C Double Bond Formation from Diborylcarbenoid
    Y. Shibutani, S. Kusumoto, K. Nozaki
    Chem. Sci. 2024, 15, 17912–17917. 10.1039/D4SC05928J
  7. Synthesis, Structure, and Optical Property of [6]Cyclo-1,2-naphthylene
    M. Hara, N. Toriumi, M. Uchiyama, K. Nozaki
    Chem. Eur. J. 2024, e202402323. 10.1002/chem.202402323 Highlighted in ChemistryViews.
  8. Bimetallic Synergy in Ru−Pt Alloy Catalyst for Polyethylene Hydrogenolysis
    Y. Yamazaki, X. Jin, W. Sun, K. Nomoto, K. Takahashi, H. Miura, T. Shishido, A. Nakayama, K. Nozaki
    ChemRxiv 2024 (preprint) 10.26434/chemrxiv-2024-sm1lp
  9. Polyethylene Materials with Tunable Degradability by Incorporating In-chain Mechanophores
    X. Zhang, Y. Zhao, M. Chen, M. Ji, Y. Sha, K. Nozaki, S. Tang
    J. Am. Chem. Soc. 2024, 146, 24024–24032. 10.1021/jacs.4c07445
  10. Pd-Catalyzed Thiotritylation Cross-Coupling of Aryl Bromides and Iodides to Access Sulfur Functional Groups
    Y. Liu, T. Okazoe, T. Gatzenmeier, K. Nozaki
    ChemistryEurope 2024, 2, e202400053. 10.1002/ceur.202400053
  11. Chemoselective Hydrogenolysis of Urethanes to Formamides and Alcohols in the Presence of More Electrophilic Carbonyl Compounds
    T. Iwasaki, Y. Yamada, N. Naito, K. Nozaki
    J. Am. Chem. Soc. 2024, 146, 25562–25568. 10.1021/jacs.4c06553 Highlighted in Press Release, 日刊工業新聞, 日本経済新聞, ニュースイッチ, fabcross forエンジニア, Chem-Stationスポットライトリサーチ, マイナビニュース, Mapion, Science Portal. Featured on the supplementary cover.
    ChemRxiv 2024 (preprint) 10.26434/chemrxiv-2024-69jc4
  12. Aliphatic Polyketones from Alternating Copolymerization of CO and Olefins: Phosphinoamidate Nickel Catalyst, Polymerization Study, Mechanical Properties and Degradations.
    L. Zhu, J. Li, W. -Y. Chen, C. Ziegler, K. Takahashi, K. Nozaki, L. Jia
    ACS Appl. Polym. Mater. 2024, 6, 9829–9836. 10.1021/acsapm.4c01691
  13. Stability of Medium-Ring Cyclic Unsaturated Carbonyl Compounds. Direct Access to Unsaturated Ketones with C−C Double Bond at Distal Positions via Transfer Dehydrogenation of Alicyclic Ketones.
    M. Iwasaki, S. Kusumoto, K. Nozaki
    Org. Lett. 2024, 26, 6540–6545. 10.1021/acs.orglett.4c01971
  14. Synthesis of Long-Chain Polyamides via Main-Chain Modification of Polyethyleneketones
    Y. Lu, K. Takahashi, J. Zhou, R. Nontarin, S. Nakagawa, N. Yoshie, K. Nozaki
    Angew. Chem. Int. Ed. 2024, 63, e202410849. 10.1002/anie.202410849
  15. Mild Catalytic Degradation of Crystalline Polyethylene Units in Solid State Assisted by Carboxylic Acid Groups
    B. Lu, K. Takahashi, J. Zhou, S. Nakagawa, Y. Yamamoto, T. Katashima, N. Yoshie, K. Nozaki
    J. Am. Chem. Soc. 2024, 146, 19599–19608. 10.1021/jacs.4c07458 Highlighted in Press Release, 日本経済新聞.
  16. Hydrogenolysis of epoxy resins by a reusable CeO2-supported Ni−Pd bimetallic catalyst toward recycling of epoxy thermosets
    Y. Huang, Y. Yamazaki, K. Nomoto, H. Miura, T. Shishido, X. Jin, K. Nozaki
    ChemRxiv 2024 (preprint) 10.26434/chemrxiv-2024-lncxh
  17. Synthesis of novel polymers with biodegradability by main-chain editing of chiral polyketones
    H. Yuan, K. Takahashi, S. Hayashi, M. Suzuki, N. Fujikake, K. Kasuya, J. Zhou, S. Nakagawa, N. Yoshie, C. Li, K. Yamaguchi, K. Nozaki
    J. Am. Chem. Soc. 2024, 146, 13658–13665. 10.1021/jacs.4c04389 Highlighted in Press Release.
    ChemRxiv 2023 (preprint) 10.26434/chemrxiv-2023-wj0p6
  18. Hydrogenolysis of Urethanes and Ureas Catalyzed by Manganese Complex Supported by Bidentate PN Ligand
    T. Iwasaki, N. Saito, Y. Yamada, S. Ajiro, K. Nozaki
    Organometallics 2024, 43, 924–928. 10.1021/acs.organomet.4c00032
  19. Tetrakispyrazolylethene: Protonation-Induced Emission
    Y. Takemasa, K. Nozaki
    J. Org. Chem. 2024, 89, 7156–7162. 10.1021/acs.joc.4c00538
  20. Linear, Planar, Orbicular, and Macrocyclic Multinuclear Zinc (Meth)acrylate Complexes
    T. Iwasaki, G. Suehisa, H. Tadaoka, K. Shiga, K. Nozaki
    Chem. Eur. J. 2024, 30, e202400586. 10.1002/chem.202400586
  21. Selective Hydrogenation of Aldehydes Under Syngas Using CeO2-Supported Au Nanoparticle Catalyst
    K. Shirayama, X. Jin, K. Nozaki
    J. Am. Chem. Soc. 2024, 146, 14086–14094. 10.1021/jacs.4c02531 Featured on the supplementary cover.
  22. Hydrogen-induced formation of surface acid sites on Pt/Al(PO3)3 enables remarkably efficient hydrogenolysis of C−O bonds in alcohols and ethers
    K. Oshida, K. Yuan, Y. Yamazaki, R. Tsukimura, H. Nishio, K. Nomoto, H. Miura, T. Shishido, X. Jin, K. Nozaki
    Angew. Chem. Int. Ed. 2024, 63, e202403092. 10.1002/anie.202403092 Highlighted in Synfacts.
    ChemRxiv 2023 (preprint) 10.26434/chemrxiv-2023-vjn0d
  23. Hexakispyrazolylethane: New Strategy for Stabilization of Hexaarylethane
    Y. Takemasa, K. Nozaki
    Chem. Eur. J. 2024, 30, e202303575. 10.1002/chem.202303575 Highlighted in Synfacts.
  24. Hydrogenative Degradation of PEG-Functionalized Lignin
    S. Kusumoto, T. Higashi, Y. Matsumoto, T. Yamada, K. Nozaki
    Polym. J. 2024, 56, 353–357. 10.1038/s41428-023-00867-5
  25. Nickel-Catalyzed C(sp3)−O Hydrogenolysis via a Remote Concerted Oxidative Addition and its Application to Degradation of a Bisphenol A-Based Epoxy Resin
    Y. Liao, K. Takahashi, K. Nozaki
    J. Am. Chem. Soc. 2024, 146, 2419–2425. 10.1021/jacs.3c09061 Featured on the cover. Highlighted in OPR&D.
    ChemRxiv 2023 (preprint) 10.26434/chemrxiv-2023-dz9v9-v2
  26. Fluoroalkylated Hypervalent Sulfur Fluorides: Radical Addition of Arylchlorotetrafluoro-λ6-sulfanes to Tetrafluoroethylene
    E. Yasuo, K. Aikawa, K. Nozaki, T. Okazoe
    Chem. Sci. 2023, 14, 12379–12385. 10.1039/D3SC04837C
  27. Difluorination of Heterobenzylic C–H Bonds with N-Fluoro-N-(fluorosulfonyl)carbamate (NFC)
    A. Adachi, T. Hashimoto, K. Aikawa, K. Nozaki, T. Okazoe
    Org. Chem. Front. 2023, 10, 5362–5368. 10.1039/D3QO01162C
  28. Boron Polycation Supported by Cyclic Bis(carbodiphosphorane)
    K. Saito, S. Kusumoto, K. Nozaki
    Chem. Eur. J. 2023, 29, e202302060. 10.1002/chem.202302060
  29. A Dinuclear Rh(-I)/Rh(I) Complex Bridged by Biphilic Phosphinine Ligands
    K. Masada, K. Okabe, S. Kusumoto, K. Nozaki
    Chem. Sci. 2023, 14, 8524–8530. 10.1039/D3SC02292G
  30. Synthesis, Characterization and Trapping of a Cyclic Diborylcarbene, an Electrophilic Carbene
    Y. Shibutani, S. Kusumoto, K. Nozaki
    J. Am. Chem. Soc. 2023, 145, 16186–16192. 10.1021/jacs.3c04933 Featured on the cover. Highlighted in Chem-Station.
  31. N-Fluorobenzenesulfonimide (NFSI) analogs with deprotectable substituents: synthesis of β-fluoroamines via catalytic aminofluorination of styrenes
    Y. Ito, A. Adachi, K. Aikawa, K. Nozaki, T. Okazoe
    Chem. Commun. 2023, 59, 9195–9198. 10.1039/D3CC02292G
  32. Palladium-catalyzed copolymerization of ethylene or propylene with norbornene carboxylic acids and their esters
    K. Tsuge, K. Lau, Y. Hirooka, T. Iwasaki, K. Yokomizo, K. Nozaki
    Polymer 2023, 281, 126116. 10.1016/j.polymer.2023.126116
  33. Chemoselectivity Change in Catalytic Hydrogenolysis enabling Urea-reduction to Formamide/Amine over More Reactive Carbonyl Compounds
    T. Iwasaki, K. Tsuge, N. Naito, K. Nozaki
    Nat. Commun. 2023, 14, 3279. 10.1038/s41467-023-38997-2 Highlighted in 日本経済新聞, 化学工業日報, Press Release, ASCII, Science Portal, Yahoo!ニュース.
    ChemRxiv 2023 (preprint) 10.26434/chemrxiv-2023-z49zw
  34. Nickel-Catalyzed Selective Incorporation of Isolated In-Chain Carbonyls into Ethylene/Carbon Monoxide Copolymer Using Metal Carbonyls as a Carbonyl Source
    G. Yonezaki, F. Seidel, K. Takahashi, K. Nozaki
    Bull. Chem. Soc. Jpn. 2023, 96, 545–549. 10.1246/bcsj.20230073 Selected as a Selected Paper. Featured on Back Cover Picture.
  35. Cyclopentadienone Vanadium(I) Complex; Synthesis, Red-Ox Activity and Application to Catalytic Transfer Hydrogenation
    T. Higashi, S. Kusumoto, K. Nozaki
    Organometallics 2023, 42, 865–870. 10.1021/acs.organomet.3c00135
  36. Structure and Reactivity of Ag(I) Complexes Bearing Tridentate Phosphinine Ligands
    K. Masada, S. Kusumoto, K. Nozaki
    Organometallics 2023, 42, 971–981. 10.1021/acs.organomet.3c00143
  37. Multifunctional WO3−ZrO2-supported Platinum Catalyst for Remarkably Efficient Hydrogenolysis of Esters to Alkanes
    K. Yuan, Y. Yamazaki, X. Jin, K. Nozaki
    J. Am. Chem. Soc. 2023, 145, 3454–3461. 10.1021/jacs.2c11145 Featured on the supplementary cover.
  38. Chain Transfer Approach for Terminal Functionalization of Alternating Copolymerization of CO2 and Epoxide by Using Active Methylene Compounds as Chain Transfer Agents
    H. Nagae, S. Akebi, S. Matsushiro, K. Sakamoto, T. Iwasaki, K. Nozaki, K. Mashima
    Macromolecules 2022, 55, 9066–9073. 10.1021/acs.macromol.2c01761
  39. TEMPO as a Hydrogen Atom Transfer Catalyst for Aerobic Dehydrogenation of Activated Alkanes to Alkenes
    T. Ito, F. Seidel, X. Jin, K. Nozaki
    J. Org. Chem. 2022, 87, 12733–12740. 10.1021/acs.joc.2c01302 Selected as Most Read Articles in September 2022.
  40. Electron in a cube: Synthesis and characterization of perfluorocubane as an electron acceptor
    M. Sugiyama, M. Akiyama, Y. Yonezawa, K. Komaguchi, M. Higashi, K. Nozaki, T. Okazoe
    Science 2022, 377, 756–759. 10.1126/science.abq0516
    Press release from AGC Inc. and UTokyo, Highlighted in C&EN, MarketScreener, Tech+, Chem-Station
  41. Pincer-Supported Perfluororhodacyclopentanes: High Nucleophilicity of M–CF Bond
    S. Hayashi, T. Murayama, S. Kusumoto, K. Nozaki
    Angew. Chem. Int. Ed. 2022, 61, e202207760. 10.1002/anie.202207760
  42. Mechanistic Insight into Rh-Catalyzed C(sp2)–O Bond Cleavage Applied to Cross-Coupling Reaction of Benzofurans with Aryl Grignard Reagents
    T. Iwasaki, W. Ishiga, S. Pal, K. Nozaki, N. Kambe
    ACS Catal. 2022, 12, 7936–7949. 10.1021/acscatal.2c01974
  43. Cationic and Neutral Iridium(III) Hydride Complexes Supported by a Rigid, Bidentate Boryl/Phosphine Ligand
    F. Seidel, K. Nozaki
    Organometallics 2022, 41, 1063–1066. 10.1021/acs.organomet.2c00126
  44. Incorporation of CO2-derived Bicyclic Lactone into Conventional Vinyl Polymers
    M. Hill, S. Tang, K. Masada, Y. Hirooka, K. Nozaki
    Macromolecules 2022, 55, 3311–3316. 10.1021/acs.macromol.1c02503
  45. Statistical Analysis of Catalytic Performance in Ethylene/Methyl Acrylate Copolymerization Using Palladium/Phosphine–Sulfonate Catalysts
    S. Akita, J -Y. Guo, F. Seidel, M. Sigman, K. Nozaki
    Organometallics 2022, 41, 3185–3196. 10.1021/acs.organomet.2c00066
  46. Synthesis of Crystalline CF3-Rich Perfluoropolyethers from Hexafluoropropylene Oxide and (Trifluoromethyl)Trimethylsilane
    M. Koyama. M. Akiyama, K. Kashiwagi, K. Nozaki, T. Okazoe
    Macromol. Rapid Commun. 2022, 43, 2200038. 10.1002/marc.202200038
  47. Synthesis and Reactivity of PC(sp3)P-pincer Iridium Complexes Bearing Diborylmethyl Anion
    M. Kishino, S. Takaoka, Y. Shibutani, S. Kusumoto, K. Nozaki
    Dalton Trans. 2022, 51, 5009–5015. 10.1039/D2DT00513A
  48. Atom Swapping on Aromatic Rings: Conversion from Phosphinine Pincer Metal Complexes to Metallabenzenes Triggered by O2 Oxidation
    K. Masada, S. Kusumoto, K. Nozaki
    Angew. Chem. Int. Ed. 2022, 61, e202117096. 10.1002/anie.202117096 Featured on the cover.
  49. Cleavage of Si–H, Si–C Bonds by Metal–Ligand Cooperation: Formation of Silyl Anion and Silylene Equivalents from Tertiary Silanes
    T. Higashi, S. Kusumoto, K. Nozaki
    Organometallics 2022, 41, 659–665. 10.1021/acs.organomet.2c00037 Selected as ACS Editors' Choice. Selected as Most Read Articles in 2022.
  50. A Ni0 σ-Borane Complex Bearing a Rigid Bidentate Borane/Phosphine Ligand: Boryl Complex Formation by Oxidative Dehydrochloroborylation and Catalytic Activity for Ethylene Polymerization
    F. W. Seidel, K. Nozaki
    Angew. Chem. Int. Ed. 2022, 62, e202111691. 10.1002/anie.202111691
  51. Synthesis of Triptycenemonohydroquinonedibenzoquinone by Comproportionation
    Y. Takemasa, K. Nozaki
    J. Org. Chem. 2022, 87, 1502–1506. 10.1021/acs.joc.1c01683 Featured on the cover.
  52. Highly Active Cross Metathesis of Tetrafluoroethylene with a Seven-membered NHC-Ruthenium Catalyst
    K. Mori, M. Akiyama, K. Inada, Y. Imamura, Y. Ishibashi, Y. Takahira, K. Nozaki, T. Okazoe
    J. Am. Chem. Soc. 2021, 143, 20980–20987. 10.1021/jacs.1c10574 J. Am. Chem. Soc. 2021, 143, 20980–20987. 10.1021/jacs.1c10574 Highlighted in Synfact.
  53. Bench-Stable Electrophilic Fluorinating Reagents for Highly Selective Mono- and Difluorination of Silyl Enol Ethers
    A. Adachi, K. Aikawa, Y. Ishibashi, K. Nozaki, T. Okazoe
    Chem. Eur, J. 2021, 27, 11919–11925. 10.1002/chem.202101499
  54. One-Pot Synthesis of Polyethylene-Based Block Copolymers via a Dual Polymerization Pathway
    Y. Zhao, J. Jung, K. Nozaki
    J. Am. Chem. Soc. 2021, 143, 18832–18837. 10.1021/jacs.1c08512
  55. Accessing Divergent Main-Chain-Functionalized Polyethylenes via Copolymerization of Ethylene with a CO2/Butadiene-Derived Lactone
    S. Tang, Y. Zhao, K. Nozaki
    J. Am. Chem. Soc. 2021, 143, 17953–17957. 10.1021/jacs.1c08578
  56. High Density Polyethylenes Bearing Isolated In-Chain Carbonyls
    S. Tang, F. W. Seidel, K. Nozaki
    Angew. Chem. Int. Ed. 2021, 60, 26506–26510. 10.1002/anie.202110957
  57. Heterolytic Oxidative Addition of sp2 and sp3 C–H Bonds by Metal–Ligand Cooperation with an Electron-deficient Cyclopentadienone Iridium Complex
    T. Higashi, S. Kusumoto, K. Nozaki
    J. Am. Chem. Soc. 2021, 143, 12999–13004. 10.1021/jacs.1c06714 Featured on the cover.
  58. Lithium Hexaphenylrhodate(III) and –Iridate(III): Structure in the Solid State and in Solution
    T. Iwasaki, Y. Hirooka, H. Takaya, T. Honma, K. Nozaki
    Organometallics 2021, 40, 2489–2495. 10.1021/acs.organomet.1c00248
  59. Metal-Ligand Cooperative κ1-N-pyrazolate Cp*RhIII-Catalysts for Dehydrogenation of Dimethylamine-borane at Room Temperature
    S. Pal, T. Iwasaki, K. Nozaki
    Dalton Trans. 2021, 50, 7938–7943. 10.1039/D1DT01705E
  60. Copolymerization of Ethylene and Methyl Acrylate by Palladium Catalysts Bearing IzQO Ligand Containing Methoxyethyl Ether Moiety and Salt Effect for the Polymerization
    S. Akita, K. Nozaki
    Polym. J. 2021, 53, 1057–1060. 10.1038/s41428-021-00500-3
  61. Metal-Support Cooperation in Al(PO3)3-Supported Pt Nanoparticles for the Selective Hydrogenolysis of Phenols to Arenes
    X. Jin, R. Tsukimura, T. Aihara, H. Miura, T. Shishido, K. Nozaki
    Nat. Catal. 2021, 4, 312–321. 10.1038/s41929-021-00598-x See the article.
    Featured on the cover. Highlighted in UTokyo FOCUS, EurekAlart!, AlphaGalileo, ScienceDaily, Phys.org, ScienMag, Science Bulletin, Mirage News, Laboratory Equipment.
  62. Synthesis and Properties of Spiro-double Sila[7]helicene: The LUMO Spiro-conjugation
    N. Terada, K. Uematsu, R. Higuchi, Y. Tokimaru, Y. Sato, K. Nakano, K. Nozaki
    Chem. Eur. J. 2021, 27, 9342–9349. 10.1002/chem.202100385 Selected as Top Downloaded Article published in 2021.
  63. Reversible PtII-CH3 Deuteration without Methane Loss: Metal-Ligand Cooperation vs Ligand-Assisted PtII-Protonation
    S. Pal, K. Nozaki, A. Vedernikov, J. Love
    Chem. Sci. 2021, 12, 2960–2969. 10.1039/D0SC06518H
  64. Umpolung of B–H Bonds by Metal–Ligand Cooperation with Cyclopentadienone Iridium Complexes
    T. Higashi, S. Kusumoto, K. Nozaki
    Angew. Chem. Int. Ed. 2021, 60, 2844–2848. 10.1002/anie.202011322
  65. Expedient Synthetic Identification of a Novel P-stereogenic Ligand Motif for the Palladium-Catalyzed Preparation of Isotactic Polar Polypropylenes
    F. W. Seidel, I. Tomizawa, K. Nozaki
    Angew. Chem. Int. Ed. 2020, 59, 22591–22601. 10.1002/anie.202009027 Highlighted in Press Release
  66. Synthesis of and Structural Insights into Contact Ion Pair and Solvent-Separated Ion Pair Diphenyliridate Complexes
    T. Iwasaki, T. Akaiwa, Y. Hirooka, S. Pal, K. Nozaki, N. Kambe
    Organometallics 2020, 39, 3077–3081. 10.1021/acs.organomet.0c00446
  67. Heavy Metal-Free Fischer-Tropsch Type Reaction: Sequential Homologation of Alkylborane Using a Combination of CO and Hydrides as Methylene Source
    A. Phanopoulos, S. Pal, T. Kawakami, K. Nozaki
    J. Am. Chem. Soc. 2020, 142, 14064–14068. 10.1021/jacs.0c06580 Highlighted in Hokkaido Shimbun Press, Science, UTokyo FOCUS, Synfact, and Asian Scientist
  68. Alternating Copolymerization of CO2 and Cyclohexene Oxide Catalyzed by Cobalt-Lanthanide Mixed Multinuclear Complexes
    H. Asaba, T. Iwasaki, M. Hatazawa, J. Deng, H. Nagae, K. Mashima, K. Nozaki
    Inorg. Chem. 2020, 59, 7928–7933. 10.1021/acs.inorgchem.0c01156
  69. Aluminum Porphyrins with Quaternary Ammonium Halides as Catalysts for Copolymerization of Cyclohexene Oxide and CO2: Metal–Ligand Cooperative Catalysis
    J. Deng, M. Ratanasak, Y. Sako, H. Tokuda, C. Maeda, J. Hasegawa, K. Nozaki, T. Ema
    Chem. Sci. 2020, 11, 5669–5675. 10.1039/D0SC01609H
  70. Metal–Metal Cooperative Bond Activation by Heterobimetallic Alkyl, Aryl, and Acetylide PtII/CuI Complexes
    S. Deolka, O. Rivada, S. L. Aristizábal, R. R. Fayzullin, S. Pal, K. Nozaki, E. Khaskin, J. R. Khusnutdinova
    Chem. Sci. 2020, 11, 5494–5502. 10.1039/D0SC00646G
  71. Reductive Coupling of Carbon Dioxide and an Aldehyde Mediated by a Copper(I) Complex toward the Synthesis of α-Hydroxycarboxylic Acids
    K. Masada, S. Kusumoto, K. Nozaki
    Org. Lett. 2020, 22, 4922–4926. 10.1021/acs.orglett.0c00995 Featured on the cover
  72. Copolymerization of Nonpolar Olefins and Allyl Acetate Using Nickel Catalysts Bearing a Methylene-bridged Bisphosphine Monoxide Ligand
    J. Jung, H. Yasuda, K. Nozaki
    Macromolecules 2020, 53, 2547–2556. 10.1021/acs.macromol.0c00183
  73. Synthesis of unsymmetrically substituted triarylamines via acceptorless dehydrogenative aromatization using a Pd/C and p-toluenesulfonic acid hybrid relay catalyst
    S. Takayama, T. Yatabe, Y. Koizumi, X. Jin, K. Nozaki, N. Mizuno, K. Yamaguchi
    Chem. Sci. 2020, 11, 4074–4084. 10.1039/C9SC06442G
  74. An Endergonic Synthesis of Single Sondheimer-Wong Diyne by Local Probe Chemistry
    S. Kawai, H. Sang, L. Kantorovich, K. Takahashi, K. Nozaki, S. Ito
    Angew. Chem. Int. Ed. 2020, 59, 10842–10847. 10.1002/anie.202001268
  75. Cleavage of C–C and C–O bonds in β-O-4 Linkage of Lignin Model Compound by Cyclopentadienone Group 8 and 9 Metals Complexes
    S. Kusumoto, M. Kishino, K. Nozaki
    Chem. Lett. 2020, 49, 477–480. 10.1246/cl.200037
  76. Synthesis of Fluorinated Dialkyl Carbonates from Carbon Dioxide as a Carbonyl Source
    M. Sugiyama, M. Akiyama, K. Nishiyama, T. Okazoe, K. Nozaki
    ChemSusChem 2020, 13, 1775–1784. 10.1002/cssc.202000090
  77. Single-molecule single-electron transistor (SM-SET) based on π-conjugated quinoidal-fused oligosilole and heteroepitaxial spherical Au/Pt nanogap electrodes
    S. Lee, J. Kim, T. Tsuda, R. Takano, R. Shintani, K. Nozaki, Y. Majima
    Appl. Phys. Express 2019, 12, 125007. 10.7567/1882-0786/ab56e5
  78. Synthesis of Polyethylene with in-chain α,β-Unsaturated Ketone and Isolated Ketone Units by Pd-catalyzed Ring-opening Copolymerization of Cyclopropenones with Ethylene
    X. Wang, F. W. Seidel, K. Nozaki
    Angew. Chem. Int. Ed. 2019, 58, 12955–12959. 10.1002/anie.201906990
  79. Reversible Polymer-Chain Modification: Ring-Opening and Closing of Polylactone
    S. Moon, K. Masada, K. Nozaki
    J. Am. Chem. Soc. 2019, 141, 10938–10942. 10.1021/jacs.9b03205
  80. Stepwise Reduction of Azapentabenzocorannulene
    Z. Zhou, Z. Wei, Y. Tokimaru, S. Ito, K. Nozaki, M. A. Petrukhina
    Angew. Chem. Int. Ed. 2019, 58, 12107–12111. 10.1002/anie.201906748
  81. Selective Synthesis of Primary Anilines from NH3 and Cyclohexanones by Utilizing Preferential Adsorption of Styrene on the Pd Nanoparticle Surface
    Y. Koizumi, X. Jin, T. Yatabe, R. Miyazaki, J. Hasegawa, K. Nozaki, N. Mizuno, K. Yamaguchi
    Angew. Chem. Int. Ed. 2019, 58, 10893–10897. 10.1002/anie.201903841
  82. Cyanide Free One-pot Synthesis of Methacrylic Esters from Acetone
    M. Koyama, T. Kawakami, T. Okazoe, K. Nozaki
    Chem. Eur. J. 2019, 25, 10913–10917. 10.1002/chem.201901933
  83. Metal–Ligand Cooperative C–H Bond Formation by Cyclopentadienone Platinum Complexes
    T. Higashi, H. Ando, S. Kusumoto, K. Nozaki
    J. Am. Chem. Soc. 2019, 141, 2247–2250. 10.1021/jacs.8b13829
  84. Synthesis of carbonyl-bridged dibenzofulvalenes and related compounds by rhodium-catalyzed stitching reaction
    R. Shintani, S. Kishikawa, K. Nakamura, T. Tsuda, K. Nozaki
    Chem. Commun. 2019, 55, 1072–1075. 10.1039/C8CC09943J
  85. Selective Chain-end Functionalization of Polar Polyethylenes: Orthogonal Reactivity of Carbene and Polar Vinyl Monomers in Their Copolymerization with Ethylene
    X. Wang, K. Nozaki
    J. Am. Chem. Soc. 2018, 140, 15635–15640. 10.1021/jacs.8b10335
  86. Palladium Complexes Bearing an N-Heterocyclic Carbene–Sulfonamide Ligand for Cooligomerization of Ethylene and Polar Monomers
    W. Tao, X. Wang, S. Ito, K. Nozaki
    J. Polym. Sci. Part A: Polym. Chem. 2019, 57, 474–477. 10.1002/pola.29270
  87. Functionalization of Azapentabenzocorannulenes via Five-fold C-H Borylation and Cross-Coupling Arylation: Application to Columnar Liquid Crystalline Materials
    T. Nagano, K. Nakamura, Y. Tokimaru, S. Ito, D. Miyajima, T. Aida, K. Nozaki
    Chem. Eur. J. 2018, 53, 14075–14078. 10.1002/chem.201803676
  88. Hydrogenation of Carbon Dioxide with Organic Base by PC(II)P-Ir Catalysts
    S. Takaoka, A. Eizawa, S. Kusumoto, K. Nakajima, Y. Nishibayashi, K. Nozaki
    Organometallics 2018, 37, 3001-3009. 10.1021/acs.organomet.8b00377 Featured on the cover
  89. Single-step construction of the anti-deoxypropionate motif from propylene: Formal total synthesis of the cuticular hydrocarbons isolated from Antitrogus parvulus
    T. Murayama, K. Nozaki
    Angew. Chem. Int. Ed. 2018, 57, 11394–11398. 10.1002/anie.201804711
  90. Synthesis and Reactivity of Methylpalladium Complexes Bearing a Partially Saturated IzQO Ligand
    S. Akita, R. Nakano, S. Ito, K. Nozaki
    Organometallics 2018, 37, 2286–2296. 10.1021/acs.organomet.8b00263
  91. Hybrid of Corannulene and Azacorannulene: Synthesis of a Highly Curved Nitrogen-Containing Buckybowl
    Y. Tokimaru, S. Ito, K. Nozaki
    Angew. Chem. Int. Ed. 2018, 57, 9818–9822. 10.1002/anie.201805678
  92. Palladium-Catalyzed Intramolecular C–H Arylation vs. 1,5-Palladium Migration: Theoretical Investigation
    N. Misawa, T. Tsuda, R. Shintani, K. Yamashita, K. Nozaki
    Chem. Asian. J. 2018, 13, 2566–2572. 10.1002/asia.201800603
  93. Phosphorescence Resulting from Interaction between Two Non-equivalent Metals on a Helical π-Conjugated Surface
    M. Akiyama, Y. Tsuchiya, A. Ishii, M. Hasegawa, Y. Kurashige, K. Nozaki
    Chem. Asian. J. 2018, 13, 1902-1905. 10.1002/asia.201800780
  94. Branched-Selective Hydroformylation of Non-Activated Olefins Using a N-Triphos/Rh Catalyst
    A. Phanopoulos, K. Nozaki
    ACS Catal. 2018, 8, 5799–5809. 10.1021/acscatal.8b00566
  95. Dehydrogenation of dimethylamine-borane catalyzed by half-sandwich Ir and Rh complexes: Mechanism and the role of Cp* non-innocence
    S. Pal, S. Kusumoto, K. Nozaki
    Organometallics 2018, 37, 906–914. 10.1021/acs.organomet.7b00889
  96. Methylene-Bridged Bisphosphine Monoxide Ligands for Palladium-Catalyzed Copolymerization of Ethylene and Polar Monomers
    Y. Mitsushige, H. Yasuda, B. Carrow, S. Ito, M. Kobayashi, T. Tayano, Y. Watanabe, Y. Okuno, S. Hayashi, J. Kuroda, Y. Okumura, K. Nozaki
    ACS Macro Lett. 2018, 7, 305–311. 10.1021/acsmacrolett.8b00034
  97. Nickel-Catalyzed Propylene/Polar Monomer Copolymerization
    Y. Konishi, W. Tao, H. Yasuda, S. Ito, Y. Oishi, H. Ohtaki, A. Tanna, T. Tayano, K. Nozaki
    ACS Macro Lett. 2018, 7, 213–217. 10.1021/acsmacrolett.7b00904
  98. Palladium/IzQO-Catalyzed Coordination–Insertion Copolymerization of Ethylene and 1,1-Disubstituted Ethylenes Bearing a Polar Functional Group
    H. Yasuda, R. Nakano, S. Ito, K. Nozaki
    J. Am. Chem. Soc. 2018, 140, 1876–1883. 10.1021/jacs.7b12593
  99. Synthesis of Pyrrole-Fused Corannulenes: 1,3-Dipolar Cycloaddition of Azomethine Ylides to Corannulene
    Y. Tokimaru, S. Ito, K. Nozaki
    Angew. Chem. Int. Ed. 2017, 56, 15560–15564. 10.1002/anie.201707087 Highlighted in Synfacts
  100. Cationic Co-Salphen Complexes Bisligated by DMAP as Catalysts for the Copolymerization of Cyclohexene Oxide with Phthalic Anhydride or Carbon Dioxide
    M. Hatazawa, R. Takahashi, J. Deng, H. Houjou, K. Nozaki
    Macromolecules 2017, 50, 7895–7900. 10.1021/acs.macromol.7b01130
  101. Selective Synthesis of Primary Anilines from Cyclohexanone Oximes by the Concerted Catalysis of a Mg−Al Layered Double Hydroxide Supported Pd Catalyst
    X. Jin, Y. Koizumi, K. Yamaguchi, K. Nozaki, N. Mizuno
    J. Am. Chem. Soc. 2017, 139, 13821-13829. 10.1021/jacs.7b07347
  102. Formal arylation of NH3 to produce diphenylamines over supported Pd catalysts
    Y. Koizumi, K. Taniguchi, X. Jin, K. Yamaguchi, K. Nozaki, N. Mizuno
    Chem. Commun. 2017, 53, 10827–10830. 10.1039/C7CC06737B
  103. Competing Annulene and Radialene Structures in a Single Anti-Aromatic Molecule Studied by High-Resolution Atomic Force Microscopy
    S. Kawai, K. Takahashi, S. Ito, R. Pawlak, T. Meier, P. Spijker, F. F. Canova, J. Tracey, K. Nozaki, A. S. Foster, E. Meyer
    ACS Nano 2017, 11, 8122–8130. 10.1021/acsnano.7b02973
  104. Palladium-Catalyzed Asymmetric Synthesis of Silicon-Stereogenic 5,10-Dihydrophenazasilines via Enantioselective 1,5-Palladium Migration
    Y. Sato, C. Takagi, R. Shintani, K. Nozaki
    Angew. Chem. Int. Ed. 2017, 31, 9211–9216. 10.1002/anie.201705500
  105. Cp*Ir-catalyzed Acceptorless Dehydrogenation of Carbon–Carbon Single Bonds
    H. Ando, S. Kusumoto, W. Wu, K. Nozaki
    Organometallics 2017, 36, 2317–2322. 10.1021/acs.organomet.7b00245
  106. Structures and Physical Properties of Chemically Reduced Diindenosiloles and Their π-Extended Derivatives
    R. Takano, R. Shintani, A. Fukazawa, S. Yamaguchi, K. Nakabayashi, S. Ohkoshi, K. Nozaki
    Organometallics 2017, 36, 2646–2653. 10.1021/acs.organomet.7b00260
  107. A Ni-Mg-Al layered triple hydroxide-supported Pd catalyst for heterogeneous acceptorless dehydrogenative aromitization
    X. Jin, K. Taniguchi, K. Yamaguchi, K. Nozaki, N. Mizuno
    Chem. Commun. 2017, 53, 5267–5270. 10.1039/C7CC01182B
  108. Synthesis of Quinoidal Fused Oligosiloles by Rhodium-Catalyzed Stitching Reaction and Theoretical Investigation of Their Properties
    R. Shintani, N. Misawa, T. Tsuda, R. Iino, M. Fujii, K. Yamashita, K. Nozaki
    J. Am. Chem. Soc. 2017, 139, 3861–3867. 10.1021/jacs.7b00344 Highlited in Synfacts
  109. Copolymerisation of Ethylene with Polar Monomers by Palladium Catalysts Bearing an N-Heterocyclic Carbene–Phosphine Oxide Bidentate Ligand
    W. Tao, S. Akita, R. Nakano, S. Ito, Y. Hoshimoto, S. Ogoshi, K. Nozaki
    Chem. Commun. 2017, 53, 2630–2633. 10.1039/C7CC00002B
  110. Facile styrene formation from ethylene and a phenylplatinum(II) complex leading to an observable platinum(II)-hydride
    S. Pal, S. Kusumoto, K.Nozaki
    Organometallics 2017, 36, 502–505. 10.1021/acs.organomet.6b00892
  111. Synthesis of Optically Pure Helicene Metallocenes
    M. Akiyama, K. Nozaki
    Angew. Chem. Int. Ed. 2017, 56, 2040–2044. 10.1002/anie.201611488
  112. Rhodium-Catalyzed Synthesis and Optical Properties of Silicon-Bridged Arylpyridines
    R. Shintani, N. Misawa, R. Takano, K. Nozaki
    Chem. Eur. J. 2017, 23, 2660–2665. 10.1002/chem.201605000
  113. Versatile routes for synthesis of diarylamines through acceptorless dehydrogenative aromatization catalysis over supported gold–palladium bimetallic nanoparticles
    K. Taniguchi, X. Jin, K. Yamaguchi, K. Nozaki, N. Mizuno
    Chem. Sci. 2017, 8, 2131–2142. 10.1039/C6SC04455G
  114. Selective Synthesis of Unsymmetric Dibenzo[a,e]pentalenes by Rhodium-Catalysed Stitching Reaction
    K. Takahashi, S. Ito, R. Shintani, K. Nozaki
    Chem. Sci. 2017, 8, 101–107. 10.1039/C6SC04560J Featured on the back cover. Highlighted in Synfacts
  115. A Potassium Diboryllithate: Synthesis, Bonding Properties, and the Deprotonation of Benzene
    T. Ohsato, Y. Okuno, S. Ishida, T. Iwamoto, K.-H. Lee, Z. Lin, M. Yamashita, K. Nozaki
    Angew. Chem. Int. Ed. 2016, 55, 11426–11430. 10.1002/anie.201605005
  116. Elucidating the Key Role of Phosphine–Sulfonate Ligands in Palladium-Catalyzed Ethylene Polymerization: Effect of Ligand Structure on the Molecular Weight and Linearity of Polyethylene
    R. Nakano, L. W. Chung, Y. Watanabe, Y. Okuno, Y. Okumura, S. Ito, K. Morokuma, K. Nozaki
    ACS Catal. 2016, 6, 6101–6113. 10.1021/acscatal.6b00911
  117. Synthesis and Properties of [7]Helicene-like Compounds Fused with a Fluorene Unit
    H. Oyama, M. Akiyama, K. Nakano, M. Naito, K. Nobusawa, K. Nozaki
    Org. Lett. 2016, 18, 3654–3657. 10.1021/acs.orglett.6b01708
  118. In Situ Generation of Salen/Co(III) Complexes for Copolymerization of Propylene Oxide and CO2
    M. Hatazawa, K. Nakabayashi, S. Ohkoshi, K. Nozaki
    Chem. Eur. J. 2016, 22, 13677–13681. 10.1002/chem.201602546
  119. Reactions of 2-Methyltetrahydropyran on Silica-Supported Nickel Phosphide in Comparison with 2-Methyltetrahydrofuran
    P. P. Bui, S. T. Oyama, A. Takagaki, B. P. Carrow, K. Nozaki
    ACS Catal. 2016, 6, 4549–4558. 10.1021/acscatal.6b01033
  120. Intermolecular Three-Component Arylsilylation of Alkynes under Palladium/Copper Cooperative Catalysis
    R. Shintani, H. Kurata, K. Nozaki
    J. Org. Chem. 2016, 81, 3065–3069. 10.1021/acs.joc.6b00587
  121. Crystalline Isotactic Polar Polypropylene from the Palladium-Catalyzed Copolymerization of Propylene and Polar Monomers
    Y. Ota, S. Ito, M. Kobayashi, S. Kitade, K. Sakata, T. Tayano, K. Nozaki
    Angew. Chem. Int. Ed. 2016, 55, 7505–7509. 10.1002/anie.201600819
  122. Rhodium-Catalyzed Stitching Reaction: Convergent Synthesis of Quinoidal Fused Oligosiloles
    R. Shintani, R. Iino, K. Nozaki
    J. Am. Chem. Soc. 2016, 138, 3635–3638. 10.1021/jacs.6b00082 highlighted in Synfacts
  123. A Qualitative Analysis of a “Bora-Brook Rearrangement”: the Ambident Reactivity of Boryl-Substituted Alkoxide Including the Carbon-to-Oxygen Migration of a Boryl Group
    H. Kisu, H. Sakaino, F. Ito, M. Yamashita, K. Nozaki
    J. Am. Chem. Soc. 2016, 138, 3548–3552. 10.1021/jacs.6b00283
  124. One-step catalytic asymmetric synthesis of all-syn deoxypropionate motif from propylene: Total synthesis of (2R,4R,6R,8R)-2,4,6,8-tetramethyldecanoic acid
    Y. Ota, T. Murayama, K. Nozaki
    Proc. Natl. Acad. Sci. USA 2016, 113, 2857–2861. 10.1073/pnas.1518898113 highlighted in UTokyo Research (Japanese), UTokyo Research (English), and Synform
  125. Pyrazole Supported Zinc(II) Benzoates as Catalysts for the Ring Opening Copolymerization of Cyclohexene Oxide and Carbon Dioxide
    M. L. Lephoto, K. Nakano, D. Appavoo, B. O. Owaga, K. Nozaki, J. Darkwa
    Catalysts 2016, 6, 17. 10.3390/catal6010017
  126. Copolymerization of Ethylene and Polar Monomers Using Ni/IzQO Catalysts
    W. Tao, R. Nakano, S. Ito, K. Nozaki
    Angew. Chem. Int. Ed. 2016, 55, 2835–2839. 10.1002/anie.201510077
  127. Rhodium-Catalyzed Asymmetric Synthesis of Silicon-Stereogenic Silicon-Bridged Arylpyridinones
    R. Shintani, R. Takano, K. Nozaki
    Chem. Sci. 2016, 7, 1205–1211. 10.1039/C5SC03767K highlighted in Synfacts
  128. Ligand-Controlled Insertion Regioselectivity Accelerates Copolymerisation of Ethylene with Methyl Acrylate by Cationic Bisphosphine Monoxide-Palladium Catalysts
    Y. Mitsushige, B. P. Carrow, S. Ito, K. Nozaki
    Chem. Sci. 2016, 7, 737–744. 10.1039/C5SC03361F
  129. Iron-Catalyzed Homo- and Copolymerization of Propylene: Steric Influence of Bis(imino)pyridine Ligands
    T. Kawakami, S. Ito, K. Nozaki
    Dalton Trans. 2015, 44, 20745–20752. 10.1039/C5DT03551A
  130. Development of Highly Active Ir–PNP Catalysts for Hydrogenation of Carbon Dioxide with Organic Bases
    W. Aoki, N. Wattanabinin, S. Kusumoto, K. Nozaki
    Bull. Chem. Soc. Jpn. 2016, 89, 113–124. 10.1246/bcsj.20150311 highlighted as BCSJ Selected Papers
  131. Copolymerization of Propylene and Polar Monomers Using Pd/IzQO Catalysts
    R. Nakano, K. Nozaki
    J. Am. Chem. Soc. 2015, 137, 10934–10937. 10.1021/jacs.5b06948 highlighted in ACS Selects Virtual Issue
  132. Rhodium-Catalyzed Intramolecular Alkynylsilylation of Alkynes
    R. Shintani, H. Kurata, K. Nozaki
    Chem. Commun. 2015, 51, 11378–11381. 10.1039/C5CC04172D highlighted in Chemistry World
  133. The Retro-Hydroformylation Reaction
    S. Kusumoto, T. Tatsuki, K. Nozaki
    Angew. Chem. Int. Ed. 2015, 54, 8458–8461. 10.1002/anie.201503620 highlighted in Front cover, Wiley-Japan Science Cafe, and 現代化学
  134. Benzene-Fused Azacorannulene Bearing an Internal Nitrogen Atom
    S. Ito, Y. Tokimaru, K. Nozaki
    Angew. Chem. Int. Ed. 2015, 54, 7256–7260. 10.1002/anie.201502599 highlighted in Frontispiece and Synfacts
  135. Formal Aryne/Carbon Monoxide Copolymerization to Form Aromatic Polyketones/Polyketals
    S. Ito, W. Wang, K. Nishimura, K. Nozaki
    Macromolecules 2015, 48, 1959–1962. 10.1021/acs.macromol.5b00315
  136. Synthesis and Properties of Benzophospholo[3,2-b]benzofuran Derivatives
    M. Takahashi, K. Nakano, K. Nozaki
    J. Org. Chem. 2015, 80, 3790–3797. 10.1021/jo502889r highlighted in Synfacts
  137. Formal Aryne/Ethylene Copolymerization to Form Polyethylene Containing o-Arylene Units in the Main Chain
    S. Ito, W. Wang, K. Nozaki
    Polym. J. 2015, 47, 474–480. 10.1038/pj.2015.27
  138. Direct and Selective Hydrogenolysis of Arenols and Aryl Methyl Ethers
    S. Kusumoto, K. Nozaki
    Nat. Commun. 2015, 6, 6296. 10.1038/ncomms7296 highlighted in C&E News and UTokyo Research.
  139. Rhodium-Catalyzed Asymmetric Synthesis of Silicon-Stereogenic Dibenzosiloles via Enantioselective [2+2+2] Cycloaddition
    R. Shintani, C. Takagi, T. Ito, M. Naito, K. Nozaki
    Angew. Chem. Int. Ed. 2015, 54, 1616–1620. 10.1002/anie.201409733
  140. Isoquinolino[4,3,2-de]phenanthridine: Synthesis and Its Use in 1,3-Dipolar Cycloadditions to Form Nitrogen-Containing Polyaromatic Hydrocarbons
    S. Ito, Y. Tokimaru, K. Nozaki
    Chem. Commun. 2015, 51, 221–224. 10.1039/C4CC06643J
  141. Ruthenium Catalyzed Hydrogenation of Aldehyde with Synthesis Gas
    K. Takahashi, K. Nozaki
    Org. Lett. 2014, 16, 5846–5849. 10.1021/ol502681y
  142. Quantification of the Steric Influence of Alkylphosphine–Sulfonate Ligands on Polymerization, Leading to High-Molecular-Weight Copolymers of Ethylene and Polar Monomers
    Y. Ota, S. Ito, J. Kuroda, Y. Okumura, K. Nozaki
    J. Am. Chem. Soc. 2014, 136, 11898–11901. 10.1021/ja505558e
  143. Facile Estimation of Catalytic Activity and Selectivities in Copolymerization of Propylene Oxide with Carbon Dioxide Mediated by Metal Complexes with Planer Tetradentate Ligand
    T. Ohkawara, K. Suzuki, K. Nakano, S. Mori, K. Nozaki
    J. Am. Chem. Soc. 2014, 136, 10728–10735. 10.1021/ja5046814 highlighted in JACS Spotlight.
  144. Rhodium-Catalyzed Polymerization of 3,3-Diarylcyclopropenes Involving a 1,4-Rhodium Migration
    R. Shintani, R. Iino, K. Nozaki
    J. Am. Chem. Soc. 2014, 136, 7849–7852. 10.1021/ja5032002 highlighted in Synfacts.
  145. Formal Aryne Polymerization: Use of [2.2.1]Oxabicyclic Alkenes as Aryne Equivalents
    S. Ito, K. Takahashi, K. Nozaki
    J. Am. Chem. Soc. 2014, 136, 7547–7550. 10.1021/ja502073k highlighted in Synfacts.
  146. Silylative Cyclopropanation of Allyl Phosphates with Silylboronates
    R. Shintani, R. Fujie, M. Takeda, K. Nozaki
    Angew. Chem. Int. Ed. 2014, 53, 6546–6549. 10.1002/anie.201403726 highlighted in Synfacts.
  147. Assessing the Brønsted Basicity of Diaminoboryl Anions: Reactivity toward Methylated Benzenes and Dihydrogen
    N. Dettenrieder, Y. Aramaki, B. Wolf, C. Maichle-Mössmer, X. Zhao, M. Yamashita, K. Nozaki, R. Anwander
    Angew. Chem. Int. Ed. 2014, 53, 6259–6262. 10.1002/anie.201402175
  148. Copolymerization of Carbon Dioxide and Butadiene via a Lactone Intermediate
    R. Nakano, S. Ito, K. Nozaki
    Nature Chem. 2014, 6, 325–331. 10.1038/nchem.1882 highlighted in Nature Chemistry, Chemistry World, C&E News, Chemical Enginnering, Chem-Station, Angew. Chem. Int. Ed..
  149. Manganese-Corrole Complex as a Versatile Catalyst for Ring-Opening Homo- and Co-polymerization of Epoxide
    C. Robert, T. Ohkawara, K. Nozaki
    Chem. Eur. J. 2014, 20, 4789–4795. 10.1002/chem.201303703
  150. Solvent and Co-catalyst Dependent Pyrazolylpyridinamine and Pyrazolylpyrroleamine Nickel(II) Catalyzed Oligomerization and Polymerization of Ethylene
    C. Obuah, B. Omondi, K. Nozaki, J. Darkwa
    J. Mol. Catal. A: Chem. 2014, 382, 31–40. 10.1016/j.molcata.2013.10.024
  151. Acceptorless Dehydrogenation of C–C Single Bonds Adjacent to Functional Groups by Metal-Ligand Cooperation
    S. Kusumoto, M. Akiyama, K. Nozaki
    J. Am. Chem. Soc. 2013, 135, 18726–18729. 10.1021/ja409672w
  152. Tandem Isomerization/Hydroformylation/Hydrogenation of Internal Alkenes to normal-Alcohols Using Rh/Ru Dual or Ternary Catalyst Systems
    Y. Yuki, K. Takahashi, Y. Tanaka, K. Nozaki
    J. Am. Chem. Soc. 2013, 135, 17393–17400. 10.1021/ja407523j
  153. Direct Aldol Polymerization of Acetaldehyde with Organocatalyst/Brønsted Acid Systems
    S. Kusumoto, S. Ito, K. Nozaki
    Asian J. Org. Chem. 2013, 2, 977–982. 10.1002/ajoc.201300134 This paper will be listed in a special issue on the Mukaiyama aldol reaction.
  154. Efficient Catalyst Removal and Recycling in Copolymerization of Epoxides with Carbon Dioxide via Simple Liquid–Liquid Phase Separation
    K. Nakano, R. Fujie, R. Shintani, K. Nozaki
    Chem. Commun. 2013, 49, 9332–9334. 10.1039/C3CC45622F
  155. Copolymerization of Epoxides with Carbon Dioxide Catalyzed by Iron–Corrole Complexes: Synthesis of a Crystalline Copolymer
    K. Nakano, K. Kobayashi, T. Ohkawara, H. Imoto, K. Nozaki
    J. Am. Chem. Soc. 2013, 135, 8456–8459. 10.1021/ja4028633
  156. Oxidative Addition of a Strained C–C Bond onto Electron-Rich Rhodium(I) at Room Temperature
    Y. Masuda, M. Hasegawa, M. Yamashita, K. Nozaki, N. Ishida, M. Murakami
    J. Am. Chem. Soc. 2013, 135, 7142–7145. 10.1021/ja403461f
  157. Facile Synthetic Route to Highly Luminescent Sila[7]helicene
    H. Oyama, K. Nakano, T. Harada, R. Kuroda, M. Naito, K. Nobusawa, K. Nozaki
    Org. Lett. 2013, 15, 2104–2107. 10.1021/ol4005036 highlighted in Noteworthy Chemistry
  158. Copper-Catalyzed Hydroboration of Carbon Dioxide
    R. Shintani, K. Nozaki
    Organometallics 2013, 32, 2459–2462. 10.1021/om400175h
  159. Ethylene and Styrene Carbon Monoxide Copolymerization Catalyzed by Pyrazolyl Palladium(II) Complexes
    C. Obuah, M. K. Ainooson, S. Boltina, I. A. Guzei, K. Nozaki, J. Darkwa
    Organometallics 2013, 32, 980–988. 10.1021/om300798y
  160. Synthesis and Characterization of B-Heterocyclic π-Radical and Its Reactivity as a Boryl Radical
    Y. Aramaki, H. Omiya, M. Yamashita, K. Nakabayashi, S.-i. Ohkoshi, K. Nozaki
    J. Am. Chem. Soc. 2012, 134, 19989–19992. 10.1021/ja3094372
  161. Tandem Hydroformylation/Hydrogenation of Alkenes to normal-Alcohols Using Rh/Ru Dual Catalyst or Ru Single Component Catalyst
    K. Takahashi, M. Yamashita, K. Nozaki
    J. Am. Chem. Soc. 2012, 134, 18746–18757. 10.1021/ja307998h
  162. Ethylene/Allyl Monomer Cooligomerization by Nickel/Phosphine–Sulfonate Catalysts
    S. Ito, Y. Ota, K. Nozaki
    Dalton Trans. 2012, 41, 13807–13809. 10.1039/C2DT31771K
  163. Ping-Pong Polymerization by Allylation and Hydroformylation for Alternating Vinyl Alcohol-Vinyl Monomer Copolymers
    S. Ito, M. Noguchi, K. Nozaki
    Chem. Commun. 2012, 48, 10481–10483. 10.1039/C2CC34980A Featured in the front cover
  164. P-Chiral Phosphine–Sulfonate/Palladium-Catalyzed Asymmetric Copolymerization of Vinyl Acetate with Carbon Monoxide
    A. Nakamura, T. Kageyama, H. Goto, B. P. Carrow, S. Ito, K. Nozaki
    J. Am. Chem. Soc. 2012, 134, 12366–12369. 10.1021/ja3044344
  165. Synthesis of Functional Polyolefins Using Cationic Bisphosphine Monoxide-Palladium Complexes
    B. P. Carrow, K. Nozaki
    J. Am. Chem. Soc. 2012, 134, 8802–8805. 10.1021/ja303507t
  166. Isolation of PBP-Pincer Rhodium Complex Stabilized by an Intermolecular C-H sigma-Coordination as the Fourth Ligand
    M. Hasegawa, Y. Segawa, M. Yamashita, K. Nozaki
    Angew. Chem. Int. Ed. 2012, 51, 6956–6960. 10.1002/anie.201201916
  167. CpRu/C5Me5/Bisphosphine- or Bisphosphite-Based Catalysts for normal-Selective Hydroformylation
    K. Takahashi, M. Yamashita, Y. Tanaka, K. Nozaki
    Angew. Chem. Int. Ed. 2012, 51, 4283–4387. 10.1002/anie.201108396
  168. Syntheses and Thermolysis of Arylpalladium Hydroxide Complexes: Implications for C(sp2)–OH Bond-Forming Reductive Elimination to Generate Phenol Derivatives
    Y. Hayashi, S. Wada, M. Yamashita, K. Nozaki
    Organometallics 2012, 31, 1073–1081. 10.1021/om201142s
  169. Mechanistic Studies on the Reversible Hydrogenation of Carbon Dioxide Catalyzed by an Ir-PNP Complex
    R. Tanaka, M. Yamashita, L. W. Chung, K. Morokuma, K. Nozaki
    Organometallics 2011, 30, 6742–6750. 10.1021/om2010172
  170. Phosphora[7]helicenes: Synthesis, Properties, and Columnar Aggregation with One-Way Chirality
    K. Nakano, H. Oyama, Y. Nishimura, S. Nakasako, K. Nozaki
    Angew. Chem. Int. Ed. 2012, 51, 695–699. 10.1002/anie.201106157
  171. Ethylene Polymerization by Palladium/Phosphine–Sulfonate Catalysts in the Presence and Absence of Protic Solvents: Structural and Mechanistic Differences
    M. Kanazawa, S. Ito, K. Nozaki
    Organometallics 2011, 30, 6049–6052. 10.1021/om2004207
  172. Tetravalent Metal Complexes as a New Family of Catalysts for Copolymerization of Epoxides with Carbon Dioxide
    K. Nakano, K. Kobayashi, K. Nozaki
    J. Am. Chem. Soc. 2011, 133, 10720–10723. 10.1021/ja203382q
  173. One-Pot Carboboration of Alkynes Using Lithium Borylcyanocuprate and the Subsequent Suzuki-Miyaura Cross-Coupling Reaction of Resulting Tetrasubstituted Alkenylborane
    Y. Okuno, M. Yamashita, K. Nozaki
    Eur. J. Org. Chem. 2011, 3951–3958. 10.1002/ejoc.201100373 The picture of Prof. Kyoko Nozaki appeared on the cover picture of this Special Issue: Women in Chemistry
  174. Pd-Catalyzed Copolymerization of Methyl Acrylate with Carbon Monoxide: Structures, Properties and Mechanistic Aspects toward Ligand Design
    A. Nakamura, K. Munakata, S. Ito, T. Kochi, L. W. Chung, K. Morokuma, K. Nozaki
    J. Am. Chem. Soc. 2011, 133, 6761–6779. 10.1021/ja2003268
  175. Syntheses and Properties of Triborane(5) Possessing Bulky Diamino Substituents on Terminal Boron Atoms
    Y. Hayashi, Y. Segawa, M. Yamashita, K. Nozaki
    Chem. Commun. 2011, 47, 5888–5890. 10.1039/C1CC11334H
  176. Stereocomplex of Poly(propylene carbonate): Synthesis of Stereogradient Poly(propylene carbonate) via Stereo- and Enantioselective Copolymerization of Propylene Oxide with Carbon Dioxide
    K. Nakano, S. Hashimoto, M. Nakamura, T. Kamada, K. Nozaki
    Angew. Chem. Int. Ed. 2011, 50, 4868–4871. 10.1002/anie.201007958 selected as VIP, highlighted in Nature Chemistry
  177. Coordination-Insertion Copolymerization of Allyl Monomers with Ethylene
    S. Ito, M. Kanazawa, K. Munakata, J. Kuroda, Y. Okumura, K. Nozaki
    J. Am. Chem. Soc. 2011, 133, 1232–1235. 10.1021/ja1092216
  178. Vinylarene/CO Copolymerization and Vinylarene/Polar Vinyl Monomer/CO Terpolymerization Using Palladium/Phosphine-Sulfonate Catalysts
    T. Kageyama, S. Ito, K. Nozaki
    Chem. Asian J. 2011, 6, 690–697. 10.1002/asia.201000668
  179. Borylcyanocuprate in a One-Pot Carboboration by a Sequential Reaction with an Electron-Deficient Alkyne and an Organic Carbon Electrophile
    Y. Okuno, M. Yamashita, K. Nozaki
    Angew. Chem. Int. Ed. 2011, 50, 920–923. 10.1002/anie.201005667
  180. Why Did Incorporation of Acrylonitrile to a Linear Polyethylene Become Possible? Comparison of Phosphine-Sulfonate Ligand with Diphosphine and Imine-Phenolate Ligands in the Pd-Catalyzed Ethylene/Acrylonitrile Copolymerization
    K. Nozaki, S. Kusumoto, S. Noda, T. Kochi, L. W. Chung, K. Morokuma
    J. Am. Chem. Soc. 2010, 132, 16030–16042. 10.1021/ja104837h
  181. A Catalytic Synthesis of Dialkylamines from Alkylamines Using Neopentyl-Substituted PNP Pincer Iridium Complex
    M. Yamashita, Y. Moroe, T. Yano, K. Nozaki
    Inorg. Chim. Acta 2011, 369, 15–18. 10.1016/j.ica.2010.08.034
  182. New Class of Catalysts for Alternating Copolymerization of Alkylene Oxide and Carbon Dioxide
    A. Okada, S. Kikuchi, K. Nakano, K. Nishioka, K. Nozaki, T. Yamada
    Chem. Lett. 2010, 39, 1066–1068. 10.1246/cl.2010.1066
  183. Boryltrihydroborate:Synthesis, Structure, and Reactivity as a Reductant in Ionic, Organometallic and Radical Reactions
    K. Nozaki, Y. Aramaki, M. Yamashita, S.-H. Ueng, M. Malacria, E. Lacote, D. Curran
    J. Am. Chem. Soc. 2010, 132, 11449–11451. 10.1021/ja105277u
  184. Reduction of Base-Stabilized Difluoroboranes to Induce Rearrangement Reactions
    M. Yamashita, Y. Aramaki, K. Nozaki
    New J. Chem. 2010, 34, 1774–1782. 10.1039/C0NJ00363H
  185. New Low Temperature NMR Studies Establish the Presence of a Second Equatorial-Apical Isomer of [(R,S)-Binaphos](CO)2RhH
    D. A. Castillo Molina, C. P. Casey, I. Müller, K. Nozaki, C. Jäkel
    Organometallics 2010, 29, 3362–3367. 10.1021/om100323q
  186. Bimetallic mechanism operating in the copolymerization of propylene oxide with carbon dioxide catalyzed by cobalt-salen complexes
    K. Nakano, S. Hashimoto, K. Nozaki
    Chem. Sci. 2010, 1, 369–373. 10.1039/c0sc00220h
  187. High-Yielding Tandem Hydroformylation/Hydrogenation of a Terminal Olefin to Produce a Linear Alcohol Using a Rh/Ru Dual Catalyst System
    K. Takahashi, M. Yamashita, T. Ichihara, K. Nakano, K. Nozaki
    Angew. Chem. Int. Ed. 2010, 49, 4488–4490. 10.1002/anie.201001327 selected as an outside cover, highlighted in ChemCatChem, highlighted at the following blogs, NNNS chemistry blog, ユーキの有機化学Hot Topics
  188. Regioselective Synthesis of Halohydrin Esters from Epoxides: Reaction with Acyl Halides and Rhodium-catalyzed Three-component Coupling Reaction with Alkyl Halides and Carbon Monoxide
    K. Nakano, S. Kodama, Y. Permana, K. Nozaki
    Chem. Commun. 2009, 6970–6972. 10.1039/b912907c
  189. Diphenylphosphino- or Dicyclohexylphosphino-Tethered Boryl Pincer Ligands: Syntheses of PBP Iridium(III) Complexes and Their Conversion to Iridium–Ethylene Complexes
    Y. Segawa, M. Yamashita, K. Nozaki
    Organometallics 2009, 28, 6234–6242. 10.1021/om9006455
  190. Synthesis of N-Heterocyclic Carbene-Sulfonate Palladium Complexes
    Y. Nagai, T. Kochi, K. Nozaki
    Organometallics 2009, 28, 6131–6134. 10.1021/om9004252
  191. Copolymerization of Vinyl Acetate with Ethylene by Palladium/Alkylphosphine–Sulfonate Catalysts
    S. Ito, K. Munakata, A. Nakamura, K. Nozaki
    J. Am. Chem. Soc. 2009, 131, 14606–14607. 10.1021/ja9050839
  192. Group 4 Transition Metal Boryl Complexes: Syntheses, Structures, Boron–Metal Bonding Properties, and Application as a Polymerization Catalyst
    T. Terabayashi, T. Kajiwara, M. Yamashita, K. Nozaki
    J. Am. Chem. Soc. 2009, 131, 14162–14163. 10.1021/ja905950g
  193. Catalytic Hydrogenation of Carbon Dioxide Using Ir(III)-Pincer Complexes
    R. Tanaka, M. Yamashita, K. Nozaki
    J. Am. Chem. Soc. 2009, 131, 14168–14169. 10.1021/ja903574e highlighted in Angewandte Chemie
  194. Mechanistic Studies on the Formation of Linear Polyethylene Chain Catalyzed by Palladium Phosphine–Sulfonate Complexes: Experiment and Theoretical Studies
    S. Noda, A. Nakamura, T. Kochi, L. W. Chung, K. Morokuma, K. Nozaki
    J. Am. Chem. Soc. 2009, 131, 14088–14100. 10.1021/ja9047398
  195. Alternating Copolymerization of Cyclohexene Oxide with Carbon Dioxide Catalyzed by (salalen)CrCl Complexes
    K. Nakano, M. Nakamura, K. Nozaki
    Macromolecules, 2009, 42, 6972–6980. 10.1021/ma9012626
  196. Syntheses of PBP Pincer Iridium Complexes: A Supporting Boryl Ligand
    Y. Segawa, M. Yamashita, K. Nozaki
    J. Am. Chem. Soc. 2009, 131, 9201–9203. 10.1021/ja9037092 highlighted in Angewandte Chemie
  197. Rhodium Catalysts Bearing Mixed Thioether-Phosphine Ligands for Carbonylation of Methanol
    K. Sakakibara, K. Nozaki
    Bull. Chem. Soc. Jpn. 2009, 82, 1009–1011. 10.1246/bcsj.82.1009
  198. Sulfide-Bearing Phosphine Ligands: Their Pd Complexes and Application to Copolymerizations of Olefins and CO
    K. Sakakibara, K. Nozaki
    Bull. Chem. Soc. Jpn. 2009, 82, 1006–1008. 10.1246/bcsj.82.1006
  199. Synthesis of p-Conjugated Copolymer with Dibenzo[d,d']benzo[1,2-b:4,5-b']difuran Unit in the Main Chain
    K. Nakano, M. Takahashi, K. Kawaguchi, K. Nozaki
    Synthetic Metals 2009, 159, 939–942. 10.1016/j.synthmet.2009.02.001
  200. Synthesis of Allylnickel Complexes with Phosphine–Sulfonate Ligands and Their Application for Olefin Polymerization without Activators
    S. Noda, T. Kochi, K. Nozaki
    Organometallics 2009, 28, 656–658. 10.1021/om800781b
  201. Ring-opening reaction of Bus- and SES-protected aziridines using lithiated dithianes
    K. Sakakibara, K. Nozaki
    Org. Biomol. Chem. 2009, 7, 502–507. 10.1039/b814413c
  202. Neopentyl-Substituted PNP-Pincer Ligand: Complexation with Iridium to Form an Iridacycle via Alkyl C-H Activation
    T. Yano, Y. Moroe, M. Yamashita, K. Nozaki
    Chem. Lett. 2008, 37, 1300–1301. 10.1246/cl.2008.1300
  203. Chemistry of Boryllithium: Synthesis, Structure, and Reactivity
    Y. Segawa, Y. Suzuki, M. Yamashita, K. Nozaki
    J. Am. Chem. Soc. 2008, 130, 16069–16079. 10.1021/ja8057919
  204. Syntheses of Ester-Substituted Norbornyl Palladium Complexes Ligated with tBu3P: Studies on the Insertion of exo- and endo-Monomers in the Ester-Substituted Norbornene Polymerization
    I. Takamiya, M. Yamashita, K. Nozaki
    Organometallics 2008, 27, 5347–5352. 10.1021/om800566j
  205. Tandem Hydroformylation-Hydrogenation of 1-Decene Catalyzed by Rh-Bidentate Bis(trialkylphosphine)s
    T. Ichihara, K. Nakano, M. Katayama, K. Nozaki
    Chem. Asian J. 2008, 3, 1722–1728. 10.1002/asia.200800163
  206. Regiocontrolled Copolymerization of Methyl Acrylate with Carbon Monoxide.
    A. Nakamura, K. Munakata, T. Kochi, K. Nozaki
    J. Am. Chem. Soc. 2008, 130, 8128–8129. 10.1021/ja802161n
  207. Syntheses, Structures, and Reactivities of Borylcopper and -zinc Compounds: 1,4-Silaboration of An α,β-Unsaturated Ketone to Form A γ-Siloxyallylborane.
    T. Kajiwara, T. Terabayashi, M. Yamashita, K. Nozaki
    Angew. Chem. Int. Ed. 2008, 47, 6606–6610. 10.1002/anie.200801728
  208. Crystal Structure of Boryllithium with Two THF Molecules and DFT Analysis of Its Property as a Boryl Anion.
    M. Yamashita, Y. Suzuki, Y. Segawa, K. Nozaki
    Chem. Lett. 2008, 37, 802–803. 10.1246/cl.2008.802
  209. Polymerization of Norbornene with a Pendent Sulfonyl Fluoride Group Catalyzed by Palladium Complex Bearing tBu3P Ligand.
    I. Takamiya, M. Yamashita, E, Murotani, Y. Morizawa, K. Nozaki
    J. Polym. Sci., Part A: Polym. Chem. 2008, 46, 5133–5141. 10.1002/pola.22841
  210. Synthesis, Structures, and Properties of Unsymmetrical Heteroacenes Containing both Pyrrole and Furan Rings
    K. Kawaguchi, K. Nakano, K. Nozaki
    Org. Lett. 2008, 10, 1199–1202. 10.1021/ol703110g
  211. Carbonylative Polymerization of Oxetanes Initiated by Acetylcobalt Complexes
    Y. Permana, K. Nakano, M. Yamashita, D. Watanabe, K. Nozaki
    Chem. Asian J. 2008, 3, 710–718. 10.1002/asia.200700339
  212. Synthesis of Sulfur-Rich Polymers: Copolymerization of Episulfide with Carbon Disulfide by Using [PPN]Cl/(salph)Cr(III)Cl System
    K. Nakano, G. Tatsumi, K. Nozaki
    J. Am. Chem. Soc. 2007, 129, 15116–15117. 10.1021/ja076056b
  213. Synthesis, Structure of Borylmagnesium, and Its Reaction with Benzaldehyde to Form Benzoylborane
    M. Yamashita, Y. Suzuki, Y. Segawa, K. Nozaki
    J. Am. Chem. Soc. 2007, 129, 9570–9571. 10.1021/ja073037t highlighted in Nachrichten aus der Chemie
  214. Synthesis of alpha-Heteroarylpropanoic Acid via Asymmetric Hydroformylation Catalyzed by Rh(I)-(R,S)-BINAPHOS and the Subsequent Oxidation
    R. Tanaka, K. Nakano, K. Nozaki
    J. Org. Chem. 2007, 72, 8671–8676. 10.1021/jo0712190
  215. Boryl Anion Attacks Transition Metal Chlorides to Form Boryl Complexes: Syntheses, Spectroscopic and Structural Studies on Group 11 Borylmetal Complexes
    Y. Segawa, M. Yamashita, K. Nozaki
    Angew. Chem. Int. Ed. 2007, 46, 6710–6713. 10.1002/anie.200702369 highlighted in Nachrichten aus der Chemie
  216. Formation of linear copolymers of ethylene and acrylonitrile catalyzed by phosphine-sulfonate palladium complexes
    T. Kochi, S. Noda, K. Yoshimura, K. Nozaki
    J. Am. Chem. Soc. 2007, 129, 8948–8949. 10.1021/ja0725504 highlighted in Angewandte Chemie.
  217. Alternating Copolymerization of Vinyl Acetate with Carbon Monoxide
    T. Kochi, A. Nakamura, H. Ida, K. Nozaki
    J. Am. Chem. Soc. 2007, 129, 7770–7771. 10.1021/ja072859n highlighted in Angewandte Chemie.
  218. Regio-Regular Polymerization of Fluorine-Containing Epoxides
    K. Sakakibara, K. Nakano, K. Nozaki
    Macromolecules 2007, 40, 6136–6142. 10.1021/ma070428j
  219. Synthesis of Ladder-Type π-Conjugated Heteroacenes via Palladium-Catalyzed Double N-Arylation and Intramolecular O-Arylation.
    K. Kawaguchi, K. Nakano, K. Nozaki
    J. Org. Chem. 2007, 72, 5119–5128. 10.1021/jo070427p
  220. Boryllithium: Isolation, Characterization, and Reactivity as a Boryl Anion.
    Y. Segawa, M. Yamashita, K. Nozaki
    Science 2006, 314, 113–115. 10.1126/science.1131914 [full text] [abstract] highlighted in Science, Chemistry World, C&EN, Angewandte Chemie, Kagaku to Kogyo, and Nachrichten aus der Chemie
  221. Selective Formation of Polycarbonate over Cyclic Carbonate: Copolymerization of Epoxides with Carbon Dioxide Catalyzed by Cobalt(III) Complex with Piperidinium End-Capping Arm.
    K. Nakano, T. Kamada, K. Nozaki
    Angew. Chem. Int. Ed. 2006, 45, 7274–7277. 10.1002/anie.200603132
    highlighted in Chemical & Engineering (2007, Nov. 16, pp 16).
  222. Syntheses and Structures of Bulky Monophosphine-ligated Methylpalladium Complexes - Application to Homo- and Co-Polymerization of Norbornene and/or Methoxycarbonylnorbornene.
    M. Yamashita, I. Takamiya, K. Jin, K. Nozaki
    Organometallics 2006, 25, 4588–4595. 10.1021/om060347w
  223. Asymmetric Hydroformylation of Vinylfurans Catalyzed by {(11bS)-4-{[(1R)-2'-Phosphino[1,1'-binaphthalen]-2-yl]oxy}dinaphtho[2,1-d:1',2'-f]-[1,3,2]dioxaphosphepin}rhodium(I) [RhI{(R,S)-binaphos}] Derivatives
    K. Nakano, R. Tanaka, and K. Nozaki
    Helv. Chim. Acta 2006, 89, 1681–1686. 10.1002/hlca.200690166
  224. Regio-Contorlled Ring-Opening Polymerization of Perfluoroalkyl-Substituted Epoxides
    K. Sakakibara, K. Nakano, K. Nozaki
    Chem. Commun. 2006, 3334–3336. 10.1039/b606693c
  225. Syntheses and Characterizations of Methylpalladium Complexes Bearing a Biphenyl-Based Bulky Phosphine Ligand: Weak Interactions Suggested by NBO and QTAIM Analyses
    M. Yamashita, I. Takamiya, K. Jin, K. Nozaki
    J. Organomet. Chem. 2006, 691, 3189–3195. 10.1016/j.jorganchem.2006.02.001
  226. Alternating Copolymerization of Fluoroalkenes with Carbon Monoxide
    T. Fujita, K. Nakano, M. Yamashita, K. Nozaki
    J. Am. Chem. Soc. 2006, 128, 1968–1975. 10.1021/ja055862k
  227. Synthesis of anionic methylpalladium complexes with phosphine–sulfonate ligands and their activities for olefin polymerization
    T. Kochi, K. Yoshimura, K. Nozaki
    Dalton Trans. 2006, 25–27. 10.1039/b512452m
  228. Stereospecific Synthesis of Hetero[7]helicenes via the Palladium-Catalyzed Double N-Arylation and Intramolecular O-Arylation
    K. Nakano, Y. Hidehira, K. Takahashi, T. Hiyama, K. Nozaki
    Angew. Chem. Int. Ed. 2005, 44, 7136–7138. 10.1002/anie.200502855
  229. Comparison of two preparative methods: a polymer-supported catalyst by metal-complexation with a polymeric ligand or by polymerization of a metal complex
    S. Kinoshita, F. Shibahara, K. Nozaki
    Green Chem. 2005, 7, 256–258. 10.1039/b418264b
  230. Asymmetric amplification in asymmetric alternating copolymerization of cyclohexene oxide and carbon dioxide
    K. Nakano, T. Hiyama, K. Nozaki
    Chem. Commun. 2005, 1871–1873. 10.1039/b417973k
  231. An Efficient Pd(II)-Based Catalyst System for Carboxylation of Aromatic C-H bond by Addition of a Phosphenium Salt.
    K. Sakakibara, M. Yamashita, K. Nozaki
    Tetrahedron Lett. 2005, 46, 959–962. 10.1016/j.tetlet.2004.12.027
  232. The Double N-Arylation of Primary Amines: Carbazole Synthesis from 2,2'-biphenyldiols.
    A. Kuwahara, K. Nakano, K. Nozaki
    J. Org. Chem. 2005, 70, 413–419. 10.1021/jo048472+
    Selected as the most accessed article in 2005.
  233. A novel mild deprotection method for phosphine-boranes.
    M. Schroeder, K. Nozaki, T. Hiyama
    Bull. Chem. Soc. Jpn. 2004, 77, 1931–1932. 10.1246/bcsj.77.1931
  234. Synthesis of a polyester macromonomer via the cobalt-catalyzed alternating copolymerization of propylene oxide and carbon monoxide.
    K. Nakano, F. Kondo, K. Nozaki
    J. Polym. Sci., Part A: Polym. Chem. 2004, 42, 4666–4670. 10.1002/pola.20383
  235. Baeyer-Villiger Oxidation of an Optically Active 1,4-Polyketone.
    N. Kosaka, T. Hiyama, K. Nozaki
    Macromolecules 2004, 37, 4484–4487. 10.1021/ma0359638
  236. An alternative route to protected aldols: Cobalt-catalyzed hydroformylationof epoxides and in situ protection of β-hydroxyaldehydes by HC(OMe)3.
    K. Nakano, M. Katayama, S. Ishihara, T. Hiyama, K. Nozaki
    Synlett 2004, 1367–1370. 10.1055/s-2004-825620
  237. Palladium(II)-Catalyzed Sequential Hydroxylation-Carboxylation of Biphenyl Using Formic Acid as a Carbonyl Source.
    F. Shibahara, S. Kinoshita, K. Nozaki
    Org. Lett. 2004, 6, 2437–2439. 10.1021/ol049166l
  238. Synthesis and Photoisomerization of Optically Active 1,4-Polyketones Substituted by Azobenzene Side Chains.
    N. Kosaka, T. Oda, T. Hiyama, K. Nozaki
    Macromolecules 2004, 37, 4484–4487. 10.1021/ma0359638
  239. Hydroesterification of vinylarenes catalyzed by palladium complexes of dialkylmonoaryl- and monoalkyldiarylphosphines.
    Y. Kawashima, K. Okano, K. Nozaki, T. Hiyama
    Bull. Chem. Soc. Jpn. 2004, 77, 347–355. 10.1246/bcsj.77.347
  240. High-Pressure NMR Studies on the Alternating Copolymerization of Styrene with Carbon Monoxide Catalyzed by a Palladium(II)-(R,S)-BINAPHOS Complex.
    J. A. Iggo, Y. Kawashima, J. Liu, T. Hiyama, K. Nozaki
    Organometallics 2003, 22, 5418–5422. 10.1021/om0304917
  241. Liquid-crystalline Stereoregular Polyketone Prepared from a Mesogenic Vinylarene and Carbon Monoxide.
    Y. Kawashima, K. Nozaki, T. Hiyama, M Yoshio, K. Kanie, T. Kato
    J. Polym. Sci., Part A: Polym. Chem. 2003, 41, 3556–3563. 10.1002/pola.10843
  242. Conformational Studies on an Optically Active 1,4-Polyketone in Solution.
    N. Kosaka, K. Nozaki, T. Hiyama
    Macromolecules 2003, 36, 6884–6887. 10.1021/ma025979i
  243. Solvent-Free Asymmetric Olefin Hydroformylation Catalyzed by Highly Crosslinked Polystyrene-Supported (R,S)-BINAPHOS-Rh(I) Complex.
    F. Shibahara, K. Nozaki, T. Hiyama
    J. Am. Chem. Soc. 2003, 125, 8555–8560. 10.1021/ja034447u
  244. The Double N-arylation of Primary Amines: A New Synthetic Strategy toward Carbazoles with Unique Optical Properties.
    K. Nozaki, K. Takahashi, K. Nakano, T. Hiyama, H.-Z. Tang, M. Fujiki, S. Yamaguchi, K. Tamao
    Angew. Chem. Int. Ed. 2003, 42, 2051–2053. 10.1002/anie.200250648
  245. Asymmetric Alternating Copolymerization of Cyclohezene Oxide and CO2 with Dimeric Zinc Complexes.
    K. Nakano, K. Nozaki, T. Hiyama
    J. Am. Chem. Soc. 2003, 125, 5501–5510. 10.1021/ja028666b
  246. Asymmetric Terpolymerization of Styrene or Its Derivative and Aliphatic 1-Alkenes with CO Catalyzed by Pd-(R,S)-BINAPHOS.
    Y. Kawashima, K. Nozaki, T. Hiyama
    Inorg. Chim. Acta 2003, 350, 577–582. 10.1016/S0020-1693(02)01542-6
  247. High Pressure IR Studies on the Asymmetric Hydroformylation of Styrene Catalyzed by Rh(I)-(R,S)-BINAPHOS'es.
    K. Nozaki, T. Matsuo, F. Shibahara, T. Hiyama
    Organometallics 2003, 22, 594–600. 10.1021/om020245f
  248. Carbon-Monoxide Free Aminocarbonylation of Organic Halides Using DMF as an Amide Source.
    K. Hosoi, K. Nozaki, T. Hiyama
    Org. Lett. 2002, 4, 2849–2851. 10.1021/ol026236k
  249. Palladium-catalyzed cross-coupling reaction using alkenyldimethyl(2-thienyl)silanes.
    K. Hosoi, K. Nozaki, T. Hiyama
    Proc. Jpn. Acad., Ser. B 2002, 78, 154–160.
  250. Asymmetric Hydroformylation with Highly Crosslinked Polystyrene-Supported (R,S)-BINAPHOS-Rh(I) Complexes: The Effect of Immobilization Positions.
    F. Shibahara, K. Nozaki, T. Matsuo, T. Hiyama
    Bioorg. Med. Chem. Lett. 2002, 12, 1825–1827. 10.1016/S0020-1693(02)01542-6
  251. Methylenation of Optically Active γ-Polyketones.
    K. Nozaki, N. Kosaka, V. M. Graubner, T. Hiyama
    Polymer J. 2002, 34, 376–382. 10.1295/polymj.34.376
  252. Alkenyldimethyl(2-thienyl)silanes, Excellent Coupling Partner for the Palladium-Catalyzed Cross-Coupling Reaction.
    K. Hosoi, K. Nozaki, T. Hiyama
    Chem. Lett 2002, 138–139. 10.1246/cl.2002.138
  253. Synthesis and Liquid Crystalline Behavior of Stereoregular Polyketones with Mesogenic Side Chains.
    K. Nozaki, Y. Kawashima, T. Oda, T. Hiyama, K. Kanie, T. Kato
    Macromolecules 2002, 35, 1140–1142. 10.1021/ma0113125
  254. Asymmetric Synthesis of Optically Active Polymers with Main-Chain Chirality.
    Kyoko Nozaki
    Kobunshironbunshu 2001, 58, 375–381.
  255. Spectral Assignment of Poly[Cyclohexene Oxide-alt-Carbon Dioxide].
    K. Nakano, K. Nozaki, T. Hiyama
    Macromolecules 2001, 34, 6325–6332. 10.1021/ma010732r
  256. Methylenation of an Optically Active γ-Polyketone: Synthesis of a New Class of Hydrocarbon Polymers with Main-Chain Chirality.
    K. Nozaki, N. Kosaka, V. M. Graubner, T. Hiyama
    Macromolecules 2001, 34, 6167–6168. 10.1021/ma0107713
  257. Alternating Copolymerization of ω-Perfluoroalkyl-1-alkenes with Carbon Monoxide Catalyzed by Homogeneous and Polymer-Supported Pd-Complexes.
    K. Nozaki, F. Shibahara, S. Elzner, T. Hiyama
    Can. J. Chem. 2001, 593–597. 10.1139/v01-073
  258. Solid Phase Cross-coupling Reaction of Aryl(halo)silanes with 4-Iodobenzoic Acid.
    F. Homsi, K. Hosoi, K. Nozaki, T. Hiyama
    J. Organomet. Chem. 2001, 624, 208–216. 10.1016/S0022-328X(01)00664-7
  259. Substituent Effect in Asymmetric Hydroformylation of Olefins Catalyzed by Rhodium(I) Complexes of (R,S)-BINAPHOS Derivatives: A Protocol for Improvement of Regio- and Enantioselectivities.
    K. Nozaki, T. Matsuo, F. Shibahara, T. Hiyama
    Adv. Syn. Catal. 2001, 343, 61–63. 10.1002/1615-4169(20010129)343:1%3C61::AID-ADSC61%3E3.0.CO;2-L
  260. Predominant 1,2-Insertion of Styrene in the Pd-Catalyzed Alternating Copolymerization with Carbon Monoxide.
    K. Nozaki, H. Komaki, Y. Kawashima, T. Hiyama, T. Matsubara
    J. Am. Chem. Soc. 2001, 123, 534–544. 10.1021/ja001395p
  261. Asymmetric Reduction of an Enantiomerically pure γ-polyketone.
    K .Nozaki, N. Kosaka, S. Muguruma, T. Hiyama
    Macromolecules 2000, 33, 5340–5346. 10.1021/ma000424d
  262. Solid Phase Cross-Coupling Reactions of Aryl(fluoro)silanes with 4-iodobenzoic acid.
    F. Homsi, K. Nozaki, T. Hiyama
    Tetrahedron Lett. 2000, 41, 5869–5872. 10.1016/S0040-4039(00)00789-9
  263. Vapor-Phase Asymmetric Hydroformylation.
    K. Nozaki, F. Shibahara, T. Hiyama
    Chem. Lett. 2000, 694–695. 10.1246/cl.2000.694
  264. High Pressure NMR Studies on the Alternating Copolymerization of Propene with Carbon Monoxide Catalyzed by a Palladium(II) Complex of an Unsymmetrical Phosphine-Phosphite.
    K. Nozaki, T. Hiyama, S. Kacker, I. T. Horvah
    Organometallics 2000, 19, 2031–2035. 10.1021/om990985x
  265. Practical Stereoselective Synthesis of (2,3,4,5-Tetrahydro-1H-Benzo[b]azepin-5-yl)acetic Acid.
    T. Shinohara, K. Kondo, H. Ogawa, T. Mori, K. Nozaki, T. Hiyama
    Chirality 2000, 12, 425–430. 10.1002/(SICI)1520-636X(2000)12:5/6%3C425::AID-CHIR23%3E3.0.CO;2-E
  266. Optically Active Polycarbonates: Asymmetric Alternating Copolymerization of Cyclohexene Oxide with Carbon Dioxide.
    K. Nozaki, K. Nakano, T. Hiyama
    J. Am. Chem. Soc. 1999, 121, 11008–11009. 10.1021/ja992433b
  267. Alternating Copolymerization of Various Alkenes with Carbon Monoxide Using a Cationic Pd(II) Complexes of (R,S)-BINAPHOS as an Initiator.
    K. Nozaki, Y. Kawashima, K. Nakamoto, T. Hiyama
    Polymer J. 1999, 31, 1057–1060. 10.1295/polymj.31.1057
  268. Asymmetric Hydroformylation of Olefins in Highly Crosslinked Polymer Matrixes.
    K. Nozaki, F. Shibahara, Y. Itoi, T. Ohta, H. Takaya, T. Hiyama
    Bull Chem. Soc. Jpn. 1999, 72, 1911–1918. 10.1246/bcsj.72.1911
  269. Asymmetric Terpolymerization of Propene, Vinylarene, and Carbon Monoxide.
    K. Nozaki, Y. Kawashima, K. Nakamoto, T. Hiyama
    Macromolecules 1999, 32, 5168–5170. 10.1021/ma9902807
  270. A Chiral Bometallic Lewis Acid as a Reaction Template. Asymmetric Reduction of Unsymmetric Ketones with LiBH4.
    K. Nozaki, K. Kobori, T. Uemura, T. Tsutsumi, H. Takaya, T. Hiyama
    Bull. Chem. Soc. Jpn. 1999, 72, 1109–1113. 10.1246/bcsj.72.1109
  271. Asymmetric Hydroformylation of Olefins in a Highly Crosslinked Polymer Matrix.
    K. Nozaki, Y. Itoi, F. Shibahara, E. Shirakawa, T. Ohta, H. Takaya, T. Hiyama
    J. Am. Chem. Soc. 1998, 120, 4051–4052. 10.1021/ja973408d
  272. Double Helical Oligo Esters: Chiral Twist of Two Aromatic Ester Chains.
    K. Nozaki, T. Terakawa, H. Takaya, T. Hiyama
    Angew. Chem., Int. Ed. Engl. 1998, 37, 131–133. 10.1002/(SICI)1521-3773(19980202)37:1/2<131::AID-ANIE131>3.0.CO;2-K
  273. Chiral and achiral phosphine phosphite ligands in Pd(II)-catalyzed alternating copolymerization of propene with CO.
    K. Nozaki, M. Yasutomi, K. Nakamoto, T. Hiyama
    Polyhedron 1998, 17, 1159–1164. 10.1016/S0277-5387(97)00503-2
  274. Mechanistic Aspects of the Alternating Copolymerization of Propylene with Carbon Monoxide Catalyzed by Pd(II) Complexes of Unsymmetrical Phosphine-phosphite Ligands.
    K. Nozaki, N. Sato, Y. Tonomura, M. Yasutomi, H. Takaya, T. Hiyama
    J. Am. Chem. Soc. 1997, 119, 12779–12793. 10.1021/ja973199x
  275. Cyclic Polyamides Consisting of 1,1'-Binaphthyls. "Chiral Twist" of Glycine Residues.
    K. Nozaki, T. Terakawa, H. Takaya, T. Hiyama
    Tetrahedron: Asymmetry 1997, 8, 3430–3436. 10.1016/S0957-4166(97)00460-6
  276. Asymmetric Hydroformylation of Allylic Alcohols Catalyzed by Rh(I) (R,S)-BINAPHOS.
    K. Nozaki, W. G. Li, T. Horiuchi, H. Takaya
    Tetrahedron Lett. 1997, 38, 4611–4614. 10.1016/S0040-4039(97)00988-X
  277. Asymmetric Hydroformylation of Hetrocyclic Olefins Catalyzed by Chiral Phosphine Phosphite Rh(I) Complex.
    T. Horiuchi, T. Ohta, E. Shirakawa, K. Nozaki, H. Takaya
    J. Org. Chem. 1997, 62, 4285–4292. 10.1021/jo9624051
  278. Mechanistic Aspects of Asymmetric Hydroformylation of Olefins Catalyzed by Chiral Phosphine-Phosphite Rh(I) Complexes.
    T. Horiuchi, E. Shirakawa, K. Nozaki, H. Takaya
    Organometallics 1997, 16, 2981–2986. 10.1021/om970134u
  279. Asymmetric Hydroformylation of Conjugated Dienes Catalyzed by Chiral Phosphine Phosphite Rh(I) Complex.
    T. Horiuchi, T. Ohta, E. Shirakawa, K. Nozaki, H. Takaya
    Tetrahedron 1997, 53, 7795–7804. 10.1016/S0040-4020(97)00471-7
  280. Highly Enantioselective Hydroformylation of Olefins Catalyzed by Rhodium(I) Complexes of New Chiral Phosphine-Phosphite Ligands.
    K. Nozaki, N. Sakai, T. Higashijima, S. Mano, T. Horiuchi, H. Takaya
    J. Am. Chem. Soc. 1997, 119, 4413–4423. 10.1021/ja970049d
  281. Hydroestrification of Styrene Catalyzed by Montmorillonite diphenylphosphinepalladium(II) Chloride in the Presence of Chiral Phosphines.
    K. Nozaki, M. L. Kantam, T. Horiuchi, H. Takaya
    J. Mol. Catal. A. 1997, 118, 247–253. 10.1016/S1381-1169(96)00385-8
  282. Cyclocopolymerization of α,ω-Dienes with Carbon Monoxide Catalyzed by (R,S)-BINAPHOS Pd(II).
    K. Nozaki, N. Sato, K. Nakamoto, H. Takaya
    Bull. Chem. Soc. Jpn. 1997, 70, 659–664. 10.1246/bcsj.70.659
  283. Synthesis of (R)-2-diphenylphosphino-2'-diphenylphosphinomethyl-1,1'-binaphthyl and its use for asymmetric hydrogenation of α-alkylstyrenes.
    K. Inagaki, T. Ohta, K. Nozaki, H. Takaya
    J. Organomet. Chem. 1997, 531, 159–163. 10.1016/S0022-328X(96)06712-5
  284. Asymmetric Michael Reaction of α-Cyano Esters by Chiral Rh(I) Complex with a New Optically Active Bisphosphine Ligand.
    K. Inagaki, K. Nozaki, H. Takaya
    Synlett 1997, 119–120. 10.1055/s-1997-712
  285. Asymmetric Hydroformylation Catalyzed by a Rh(I) (R,S)-BINAPHOS Complex: Substituent Effects in Olefins on the Regioselectivity.
    K. Nozaki, T. Nanno, H. Takaya
    J. Organomet. Chem. 1997, 527, 103–108. 10.1016/S0022-328X(96)06620-X
  286. (R,S)-BINAPHOS Ni(0) and Pd(0) Complexes: Characterization and Their Use for Asymmetric Hydrocyanation of Norbornene.
    T. Horiuchi, E. Shirakawa, K. Nozaki, H. Takaya
    Tetrahedron: Asymmetry 1997, 8, 57–63. 10.1016/S0957-4166(96)00483-1
  287. New Stereocontrolled Approach to 1β-Methylcarbapenem: Asymmetric Hydroformylation of 4-Vinyl-β-lactams Catalyzed by Rh(I) Complexes of Chiral Phosphine-phosphites and Phosphine-phosphinites.
    K. Nozaki, W.-g. Li, T. Horiuchi, H. Takaya, T. Saito, A, Yoshida, K. Matsumura, Y. Kato, T. Imai, T. Miura, H. Kumobayashi
    J. Org. Chem. 1996, 61, 7658–7659. 10.1021/jo961689m
  288. Highly Efficient Enantioselective Synthesis of Optically Active Carboxylic Acids by Ru(OCOCH3)2[(S)-H8-BINAP].
    T. Uemura, X. Zhang, K. Matsumura, N. Sayo, H. Kumobayashi, T. Ohta, K. Nozaki, H. Takaya
    J. Org. Chem. 1996, 61, 5510–5516. 10.1021/jo960426p
  289. Synthesis of Highly Functionalized γ-Butyrolactones from Activated Carbonyl Compounds and Dimethyl Acetylenedicarboxylate.
    K. Nozaki, N. Sato, K. Ikeda, H. Takaya
    J. Org. Chem. 1996, 61, 4516–4519. 10.1021/jo951828k
  290. Chiral Bimetallic Boronic Esters: A Donor Acceptor Coexisting Receptor for Amines.
    K. Nozaki, M. Yoshida, H. Takaya
    Bull. Chem. Soc. Jpn. 1996, 69, 2043–2052. 10.1246/bcsj.69.2043
  291. Palladium-Catalyzed Acylcyanation of Terminal Arylacetylenes. Synthesis of 1,3-Diaryl-3-cyano-2-propen-1-ones and Tetrasubstituted Furans.
    K. Nozaki, N. Sato, H. Takaya
    Bull. Chem. Soc. Jpn. 1996, 69, 1629–1637. 10.1246/bcsj.69.1629
  292. Anionic Dinuclear BINAP-Ru(II) Complex: Crystal Structure of [NH2Et2][{RuCl(R)-p-MeO-binap)}2(μ-Cl)3]and Its Use for Asymmetric Hydrogenation.
    T. Ohta, Y. Tonomura, K. Nozaki, H. Takaya
    Organometallics 1996, 15, 1521–1523. 10.1021/om9508905
  293. Asymmetric Hydroformylation of Conjugated Dienes Catalyzed by [(R)-2-diphenylphosphino-1,1'-dinaphthalen-2'-yl][(S)-1,1'-dinaphthalene-2,2'-diyl]phosphite-rhodium(I).
    T. Horiuchi, T. Ohta, K. Nozaki, H. Takaya
    Chem. Commun. 1996, 155–156. 10.1039/CC9960000155
  294. Asymmetric Hydroformylation of Sulfur-Containing Olefins Catalyzed by BINAPHOS-Rh(I) Complexes.
    T. Nanno, N. Sakai, K. Nozaki, H. Takaya
    Tetrahedron: Asymmetry 1995, 6, 2583–2591. 10.1016/0957-4166(95)00339-Q
  295. Selective Binding of Diamines to a Chiral Lewis Acid with Two Boron Centers.
    K. Nozaki, T. Tsutsumi, H. Takaya
    J. Org. Chem. 1995, 60, 6668–6669. 10.1021/jo00126a009
  296. Highly Enantioselective Alternating Copolymerization of Propene with Carbon Monoxide Catalyzed by a Chiral Phosphine-Phosphite Complex of Palladium(II).
    K. Nozaki, N. Sato, H. Takaya
    J. Am. Chem. Soc. 1995, 117, 9911–9912. 10.1021/ja00144a018
  297. A Chiral Lewis Acid with Two "Metal" Centers: Cooperative Binding of Two Amine Molecules to a Chiral Diboronic Ester.
    K. Nozaki, M. Yoshida, H. Takaya
    Angew. Chem., Int. Ed. Engl. 1994, 33, 2452–2454. 10.1002/anie.199424521
  298. Cationic BINAP-Ru(II) Halide Complexes: Highly Efficient Catalysts for Stereoselective Asymmetric Hydrogenation of a- and b-Functionalized Ketones.
    K. Mashima, K. Kusano, Y. Matsumura, N. Sato, K. Nozaki, H. Kumobayashi, N. Sayo, Y. Hori, T. Ishizaki, S. Akutagawa, H. Takaya
    J. Org. Chem. 1994, 59, 3064–3076. 10.1021/jo00090a026
  299. Acylcyanation of Terminal Acetylenes: Palladium Catalyzed Addition of Aryloyl Cyanides to Arylacetylenes
    K. Nozaki, N. Sato, H. Takaya
    J. Org. Chem. 1994, 59, 2679–2681. 10.1021/jo00089a006
  300. Reaction Rate Enhancement by Addition of Anionic Surfactant SDS in the Ruthenium Catalyzed Hydrogen Transfer from a 1,4-Diols to 4-Phenyl-3-buten-2-one.
    K. Nozaki, M. Yoshida, H. Takaya
    J. Organomet. Chem. 1994, 473, 253–256. 10.1016/0022-328X(94)80125-8
  301. Synthesis of New Chiral Phosphinephosphites Having 2-Diphenyl-phosphinobiphenyl-2'-yl Backbone and Their Use in Rh(I) Catalyzed Asymmetric Hydroformylations.
    T. Higashijima, N. Sakai, K. Nozaki, H. Takaya
    Tetrahedron Lett. 1994, 35, 2023–2026. 10.1016/S0040-4039(00)73039-5
  302. Asymmetric Hydroformylation of 1,2-Di-substituted Olefins Catalyzed by Chiral Phosphinephosphite-Rh(I) Complexes.
    N. Sakai, K. Nozaki and H. Takaya
    J. Chem. Soc., Chem. Commun. 1994, 395–396. 10.1039/C39940000395
  303. Enantioselective Synthesis of L- and D-Isoserine via Asymmetric Hydrogenation of Methyl N-Phthaloyl-3-amino-2-oxopropanoate.
    K. Nozaki, N. Sato, H. Takaya
    Tetrahedron: Asymmetry 1993, 4, 2179–2182. 10.1016/S0957-4166(00)80068-3
  304. Highly Enantioselective Hydroformylation of Olefins Catalyzed by New Phosphinephosphite-Rh(I) Complexes.
    N. Sakai, S. Mano, K. Nozaki, H. Takaya
    J. Am. Chem. Soc. 1993, 115, 7033–7034. 10.1021/ja00068a095
  305. Asymmetric Hydroformylation of Vinyl Acetate By Use of Chiral Bis(triarylphosphite)-Rhodium(I) Complexes.
    N. Sakai, K. Nozaki, K. Mashima, H. Takaya
    Tetrahedron: Asymmetry 1992, 3, 583–586. 10.1016/S0957-4166(00)82286-7
  306. Isomerization of Olefins by Means of R3SnH-Et3B and Stereochemical Study on Reduction of Alkenyl Iodides.
    M. Taniguchi, K. Nozaki, K. Miura, K. Oshima and K. Utimoto
    Bull. Chem. Soc. Jpn. 1992, 65, 349–353. 10.1246/bcsj.65.349
  307. Triethylborane Induced 1,4-Reduction of α,β-Unsaturated Carbonyl Compounds with Triphenyltin Hydride or Tributyltin Hydride.
    K. Nozaki, K. Oshima, K. Utimoto
    Bull. Chem. Soc. Jpn. 1991, 64, 2585–2587. 10.1246/bcsj.64.2585
  308. Palladium Catalyzed Reaction of Silacyclobutanes with Acetylenes.
    Y. Takeyama, K. Nozaki, K. Matsumoto, K. Oshima, K. Utimoto
    Bull. Chem. Soc. Jpn. 1991, 64, 1461–1466. 10.1246/bcsj.64.1461
  309. Trialkylborane as an Initiator and Terminator of Free Radical Reactions: Facile Routs to Boron Enolates via a-Carbonyl Radicals and Aldol Reaction of Boron Enolates.
    K. Nozaki, K. Oshima, K. Utimoto
    Bull. Chem. Soc. Jpn. 1991, 64, 403–409. 10.1246/bcsj.64.403
  310. On the Mechanism of Lewis Acid Mediated Nucleophilic Substitution Reactions of Acetals.
    I. Mori, K. Ishihara, L. A. Flippin, K. Nozaki, H. Yamamoto, P. A. Bartlett, C. H. Heathcock
    J. Org. Chem. 1990, 55, 6107–6115. 10.1021/jo00312a015
  311. Triethylborane Induced Perfluoroalkylation of Silyl Enol Ethers or Germyl Enol Ethers with Perfluoroalkyl Iodides.
    K. Miura, M. Taniguchi, K. Nozaki, K. Oshima, K. Utimoto
    Tetrahedron Lett. 1990, 31, 6391–6394. 10.1016/S0040-4039(00)97073-4
  312. Facile Reduction of Dithiocarbonates Derived from Secondary Alcohols with n-Bu3SnH-Et3B and Synthesis of 2-Furanthiones and 2-Furanones by Intramolecular Addition of Alkoxythiocarbonyl Free Radicals to Acetylenic Lincages.
    K. Nozaki, K. Oshima, K. Utimoto
    Bull. Chem. Soc. Jpn. 1990, 63, 2578–2583. 10.1246/bcsj.63.2578
  313. Et3B-Induced Stereoselective Radical Addition of Ph3GeH to Carbon-Carbon Multiple Bonds and Its Application to Isomerization of Olefins.
    K. Nozaki, Y. Ichinose, K. Wakamatsu, K. Oshima, K. Utimoto
    Bull. Chem. Soc. Jpn. 1990, 63, 2268–2272. 10.1246/bcsj.63.2268
  314. Et3B-Induced Radical Addition of Ph3SnH to Acetylenes and Its Application to Cyclization Reaction.
    K. Nozaki, K. Oshima, K. Utimoto
    Tetrahedron 1989, 45, 923–933. 10.1016/0040-4020(89)80004-3
  315. Et3B-Induced Hydrodehalogenation of Organic Halides by Tin Hydrides.
    K. Miura, Y. Ichinose, K. Nozaki, K. Fugami, K. Oshima, K. Utimoto
    Bull. Chem. Soc. Jpn. 1989, 62, 143–147. 10.1246/bcsj.62.143
  316. Synthesis of Lactones by Intramolecular Addition of Alkoxythiocarbonyl Free Radicals to Acetylenes.
    K. Nozaki, K. Oshima, K. Utimoto
    Tetrahedron Lett. 1988, 29, 6127–6128. 10.1016/S0040-4039(00)82284-4
  317. Facile Reduction of Dithiocarbonates with n-Bu3SnH-Et3B: Easy Access to Hydrocarbons from Secondary Alcohols.
    K. Nozaki, K. Oshima, K. Utimoto
    Tetrahedron Lett. 1988, 29, 6125–6126. 10.1016/S0040-4039(00)82283-2
  318. Facile Routes to Boron Enolates: Et3B-Mediated Reformatsky Type Reaction and Three-Component Coupling Reaction of Alkyl Iodides, Methyl Vinyl Ketone, and Carbonyl Compounds.
    K. Nozaki, K. Oshima, K. Utimoto
    Tetrahedron Lett. 1988, 29, 1041–1044. 10.1016/0040-4039(88)85330-9
  319. Synthesis of α-Methylene-γ-butyrolactones via Addition of Tin Hydride to Enynes Induced by Triethylborane.
    K. Nozaki, K. Oshima, K. Utimoto
    Bull. Chem. Soc. Jpn. 1987, 60, 3465–3467. 10.1246/bcsj.60.3465
  320. Et3B-Induced Radical Addition of Thiols to Acetylenes.
    Y. Ichinose, K. Wakamatsu, K. Nozaki, J.-L. Birbaum, K. Oshima, K. Utimoto
    Chem. Lett. 1987, 1647–1650. 10.1246/cl.1987.1647
  321. Et3B-Induced Stereoselective Radical Addition of Ph3GeH to Carbon-Carbon Multiple Bonds and Its Application to Isomerization of Olefins.
    Y. Ichinose, K. Nozaki, K. Wakamatsu, K. Oshima, K. Utimoto
    Tetrahedron Lett. 1987, 28, 3709–3712. 10.1016/S0040-4039(00)96363-9
  322. Et3B-Induced Radical Addition of R3SnH to Acetylenes and Its Application to Cyclization Reaction.
    K. Nozaki, K. Oshima, K. Utimoto
    J. Am. Chem. Soc. 1987, 109, 2547–2549. 10.1021/ja00242a068
  323. Transition-Metal Catalyzed Regioselective Addition of PhMe2SiBEt3Li and Bu3SnBEt3Li to Acetylenic Compounds in the Presence of Methanol.
    K. Nozaki, K. Wakamatsu, T. Nonaka, W. Tukmantel, K. Oshima, K. Utimoto
    Tetrahedron Lett. 1986, 27, 2007–2010. 10.1016/S0040-4039(00)84434-2