Publications (Prof. Nozaki)
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Exceptionally Short Tetracoordinated Carbon–Halogen Bonds in Hexafluorodihalocubanes
M. Sugiyama, Y. Uetake, N. Miyagi, M. Yoshida, K. Nozaki, T. Okazoe, M. Akiyama
J. Am. Chem. Soc. 2024, 146, 30686–30697. 10.1021/jacs.4c12732 Highlighted in ChemistryViews.
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Sequence-Controlled Copolymerization of Structurally Well-Defined Multinuclear Zinc Acrylate Complexes and Styrene
T. Iwasaki, G. Suehisa, R. Mandai, K. Nozaki
Macromol. Rapid Commun. accepted.
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Crystallization of Strictly Linear Poly(ethylene-ran-acrylic acid) Copolymer: Impacts of Pendant Group Insertion and Hydrogen Bonding
J. Zhou, K. Takahashi, K. Nozaki, Y. Yamamoto, T. Katashima, N. Yoshie, S. Nakagawa
Macromolecules in press. acs.macromol.4c01250
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Synthesis, Structure, and Optical Property of Tris(biaryldiyl)metal Complexes Consisting of Group 9 Elements
M. Hara, Y. Hirooka, T. Iwasaki, K. Nozaki
Inorg. Chem. in press. 10.1021/acs.inorgchem.4c03514
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Fully Conjugated Tetraborylethylene: Selenium Mediated C–C Double Bond Formation from Diborylcarbenoid
Y. Shibutani, S. Kusumoto, K. Nozaki
Chem. Sci. 2024, 15, 17912–17917. 10.1039/D4SC05928J
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Synthesis, Structure, and Optical Property of [6]Cyclo-1,2-naphthylene
M. Hara, N. Toriumi, M. Uchiyama, K. Nozaki
Chem. Eur. J. 2024, e202402323. 10.1002/chem.202402323 Highlighted in ChemistryViews.
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Bimetallic Synergy in Ru−Pt Alloy Catalyst for Polyethylene Hydrogenolysis
Y. Yamazaki, X. Jin, W. Sun, K. Nomoto, K. Takahashi, H. Miura, T. Shishido, A. Nakayama, K. Nozaki
ChemRxiv 2024 (preprint) 10.26434/chemrxiv-2024-sm1lp
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Polyethylene Materials with Tunable Degradability by Incorporating In-chain Mechanophores
X. Zhang, Y. Zhao, M. Chen, M. Ji, Y. Sha, K. Nozaki, S. Tang
J. Am. Chem. Soc. 2024, 146, 24024–24032. 10.1021/jacs.4c07445
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Pd-Catalyzed Thiotritylation Cross-Coupling of Aryl Bromides and Iodides to Access Sulfur Functional Groups
Y. Liu, T. Okazoe, T. Gatzenmeier, K. Nozaki
ChemistryEurope 2024, e202400053. 10.1002/ceur.202400053
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Chemoselective Hydrogenolysis of Urethanes to Formamides and Alcohols in the Presence of More Electrophilic Carbonyl Compounds
T. Iwasaki, Y. Yamada, N. Naito, K. Nozaki
J. Am. Chem. Soc. 2024, 146, 25562–25568. 10.1021/jacs.4c06553 Highlighted in Press Release, 日刊工業新聞, 日本経済新聞, ニュースイッチ, fabcross forエンジニア, Chem-Stationスポットライトリサーチ, マイナビニュース, Mapion, Science Portal. Featured on the supplementary cover.
ChemRxiv 2024 (preprint) 10.26434/chemrxiv-2024-69jc4
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Aliphatic Polyketones from Alternating Copolymerization of CO and Olefins: Phosphinoamidate Nickel Catalyst, Polymerization Study, Mechanical Properties and Degradations.
L. Zhu, J. Li, W. -Y. Chen, C. Ziegler, K. Takahashi, K. Nozaki, L. Jia
ACS Appl. Polym. Mater. 2024, 6, 9829–9836. 10.1021/acsapm.4c01691
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Stability of Medium-Ring Cyclic Unsaturated Carbonyl Compounds. Direct Access to Unsaturated Ketones with C−C Double Bond at Distal Positions via Transfer Dehydrogenation of Alicyclic Ketones.
M. Iwasaki, S. Kusumoto, K. Nozaki
Org. Lett. 2024, 26, 6540–6545. 10.1021/acs.orglett.4c01971
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Synthesis of Long-Chain Polyamides via Main-Chain Modification of Polyethyleneketones
Y. Lu, K. Takahashi, J. Zhou, R. Nontarin, S. Nakagawa, N. Yoshie, K. Nozaki
Angew. Chem. Int. Ed. 2024, 63, e202410849. 10.1002/anie.202410849
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Mild Catalytic Degradation of Crystalline Polyethylene Units in Solid State Assisted by Carboxylic Acid Groups
B. Lu, K. Takahashi, J. Zhou, S. Nakagawa, Y. Yamamoto, T. Katashima, N. Yoshie, K. Nozaki
J. Am. Chem. Soc. 2024, 146, 19599–19608. 10.1021/jacs.4c07458 Highlighted in Press Release, 日本経済新聞.
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Hydrogenolysis of epoxy resins by a reusable CeO2-supported Ni−Pd bimetallic catalyst toward recycling of epoxy thermosets
Y. Huang, Y. Yamazaki, K. Nomoto, H. Miura, T. Shishido, X. Jin, K. Nozaki
ChemRxiv 2024 (preprint) 10.26434/chemrxiv-2024-lncxh
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Synthesis of novel polymers with biodegradability by main-chain editing of chiral polyketones
H. Yuan, K. Takahashi, S. Hayashi, M. Suzuki, N. Fujikake, K. Kasuya, J. Zhou, S. Nakagawa, N. Yoshie, C. Li, K. Yamaguchi, K. Nozaki
J. Am. Chem. Soc. 2024, 146, 13658–13665. 10.1021/jacs.4c04389 Highlighted in Press Release.
ChemRxiv 2023 (preprint) 10.26434/chemrxiv-2023-wj0p6
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Hydrogenolysis of Urethanes and Ureas Catalyzed by Manganese Complex Supported by Bidentate PN Ligand
T. Iwasaki, N. Saito, Y. Yamada, S. Ajiro, K. Nozaki
Organometallics 2024, 43, 924–928. 10.1021/acs.organomet.4c00032
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Tetrakispyrazolylethene: Protonation-Induced Emission
Y. Takemasa, K. Nozaki
J. Org. Chem. 2024, 89, 7156–7162. 10.1021/acs.joc.4c00538
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Linear, Planar, Orbicular, and Macrocyclic Multinuclear Zinc (Meth)acrylate Complexes
T. Iwasaki, G. Suehisa, H. Tadaoka, K. Shiga, K. Nozaki
Chem. Eur. J. 2024, 30, e202400586. 10.1002/chem.202400586
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Selective Hydrogenation of Aldehydes Under Syngas Using CeO2-Supported Au Nanoparticle Catalyst
K. Shirayama, X. Jin, K. Nozaki
J. Am. Chem. Soc. 2024, 146, 14086–14094. 10.1021/jacs.4c02531 Featured on the supplementary cover.
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Hydrogen-induced formation of surface acid sites on Pt/Al(PO3)3 enables remarkably efficient hydrogenolysis of C−O bonds in alcohols and ethers
K. Oshida, K. Yuan, Y. Yamazaki, R. Tsukimura, H. Nishio, K. Nomoto, H. Miura, T. Shishido, X. Jin, K. Nozaki
Angew. Chem. Int. Ed. 2024, 63, e202403092. 10.1002/anie.202403092 Highlighted in Synfacts.
ChemRxiv 2023 (preprint) 10.26434/chemrxiv-2023-vjn0d
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Hexakispyrazolylethane: New Strategy for Stabilization of Hexaarylethane
Y. Takemasa, K. Nozaki
Chem. Eur. J. 2024, 30, e202303575. 10.1002/chem.202303575 Highlighted in Synfacts.
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Hydrogenative Degradation of PEG-Functionalized Lignin
S. Kusumoto, T. Higashi, Y. Matsumoto, T. Yamada, K. Nozaki
Polym. J. 2024, 56, 353–357. 10.1038/s41428-023-00867-5
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Nickel-Catalyzed C(sp3)−O Hydrogenolysis via a Remote Concerted Oxidative Addition and its Application to Degradation of a Bisphenol A-Based Epoxy Resin
Y. Liao, K. Takahashi, K. Nozaki
J. Am. Chem. Soc. 2024, 146, 2419–2425. 10.1021/jacs.3c09061 Featured on the cover. Highlighted in OPR&D.
ChemRxiv 2023 (preprint) 10.26434/chemrxiv-2023-dz9v9-v2
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Fluoroalkylated Hypervalent Sulfur Fluorides: Radical Addition of Arylchlorotetrafluoro-λ6-sulfanes to Tetrafluoroethylene
E. Yasuo, K. Aikawa, K. Nozaki, T. Okazoe
Chem. Sci. 2023, 14, 12379–12385. 10.1039/D3SC04837C
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Boron Polycation Supported by Cyclic Bis(carbodiphosphorane)
K. Saito, S. Kusumoto, K. Nozaki
Chem. Eur. J. 2023, 29, e202302060. 10.1002/chem.202302060
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A Dinuclear Rh(-I)/Rh(I) Complex Bridged by Biphilic Phosphinine Ligands
K. Masada, K. Okabe, S. Kusumoto, K. Nozaki
Chem. Sci. 2023, 14, 8524–8530. 10.1039/D3SC02292G
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Synthesis, Characterization and Trapping of a Cyclic Diborylcarbene, an Electrophilic Carbene
Y. Shibutani, S. Kusumoto, K. Nozaki
J. Am. Chem. Soc. 2023, 145, 16186–16192. 10.1021/jacs.3c04933 Featured on the cover. Highlighted in Chem-Station.
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N-Fluorobenzenesulfonimide (NFSI) analogs with deprotectable substituents: synthesis of β-fluoroamines via catalytic aminofluorination of styrenes
Y. Ito, A. Adachi, K. Aikawa, K. Nozaki, T. Okazoe
Chem. Commun. 2023, 59, 9195–9198. 10.1039/D3CC02292G
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Palladium-catalyzed copolymerization of ethylene or propylene with norbornene carboxylic acids and their esters
K. Tsuge, K. Lau, Y. Hirooka, T. Iwasaki, K. Yokomizo, K. Nozaki
Polymer 2023, 281, 126116. 10.1016/j.polymer.2023.126116
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Chemoselectivity Change in Catalytic Hydrogenolysis enabling Urea-reduction to Formamide/Amine over More Reactive Carbonyl Compounds
T. Iwasaki, K. Tsuge, N. Naito, K. Nozaki
Nat. Commun. 2023, 14, 3279. 10.1038/s41467-023-38997-2 Highlighted in 日本経済新聞, 化学工業日報, Press Release, ASCII, Science Portal, Yahoo!ニュース.
ChemRxiv 2023 (preprint) 10.26434/chemrxiv-2023-z49zw
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Nickel-Catalyzed Selective Incorporation of Isolated In-Chain Carbonyls into Ethylene/Carbon Monoxide Copolymer Using Metal Carbonyls as a Carbonyl Source
G. Yonezaki, F. Seidel, K. Takahashi, K. Nozaki
Bull. Chem. Soc. Jpn. 2023, 96, 545–549. 10.1246/bcsj.20230073 Selected as a Selected Paper. Featured on Back Cover Picture.
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Cyclopentadienone Vanadium(I) Complex; Synthesis, Red-Ox Activity and Application to Catalytic Transfer Hydrogenation
T. Higashi, S. Kusumoto, K. Nozaki
Organometallics 2023, 42, 865–870. 10.1021/acs.organomet.3c00135
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Structure and Reactivity of Ag(I) Complexes Bearing Tridentate Phosphinine Ligands
K. Masada, S. Kusumoto, K. Nozaki
Organometallics 2023, 42, 971–981. 10.1021/acs.organomet.3c00143
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Multifunctional WO3−ZrO2-supported Platinum Catalyst for Remarkably Efficient Hydrogenolysis of Esters to Alkanes
K. Yuan, Y. Yamazaki, X. Jin, K. Nozaki
J. Am. Chem. Soc. 2023, 145, 3454–3461. 10.1021/jacs.2c11145 Featured on the supplementary cover.
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Chain Transfer Approach for Terminal Functionalization of Alternating Copolymerization of CO2 and Epoxide by Using Active Methylene Compounds as Chain Transfer Agents
H. Nagae, S. Akebi, S. Matsushiro, K. Sakamoto, T. Iwasaki, K. Nozaki, K. Mashima
Macromolecules 2022, 55, 9066–9073. 10.1021/acs.macromol.2c01761
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TEMPO as a Hydrogen Atom Transfer Catalyst for Aerobic Dehydrogenation of Activated Alkanes to Alkenes
T. Ito, F. Seidel, X. Jin, K. Nozaki
J. Org. Chem. 2022, 87, 12733–12740. 10.1021/acs.joc.2c01302 Selected as Most Read Articles in September 2022.
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Electron in a cube: Synthesis and characterization of perfluorocubane as an electron acceptor
M. Sugiyama, M. Akiyama, Y. Yonezawa, K. Komaguchi, M. Higashi, K. Nozaki, T. Okazoe
Science 2022, 377, 756–759. 10.1126/science.abq0516
Press release from AGC Inc. and UTokyo,
Highlighted in C&EN, MarketScreener, Tech+, Chem-Station
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Pincer-Supported Perfluororhodacyclopentanes: High Nucleophilicity of M–CF Bond
S. Hayashi, T. Murayama, S. Kusumoto, K. Nozaki
Angew. Chem. Int. Ed. 2022, 61, e202207760. 10.1002/anie.202207760
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Mechanistic Insight into Rh-Catalyzed C(sp2)–O Bond Cleavage Applied to Cross-Coupling Reaction of Benzofurans with Aryl Grignard Reagents
T. Iwasaki, W. Ishiga, S. Pal, K. Nozaki, N. Kambe
ACS Catal. 2022, 12, 7936–7949. 10.1021/acscatal.2c01974
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Cationic and Neutral Iridium(III) Hydride Complexes Supported by a Rigid, Bidentate Boryl/Phosphine Ligand
F. Seidel, K. Nozaki
Organometallics 2022, 41, 1063–1066. 10.1021/acs.organomet.2c00126
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Incorporation of CO2-derived Bicyclic Lactone into Conventional Vinyl Polymers
M. Hill, S. Tang, K. Masada, Y. Hirooka, K. Nozaki
Macromolecules 2022, 55, 3311–3316. 10.1021/acs.macromol.1c02503
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Statistical Analysis of Catalytic Performance in Ethylene/Methyl Acrylate Copolymerization Using Palladium/Phosphine–Sulfonate Catalysts
S. Akita, J -Y. Guo, F. Seidel, M. Sigman, K. Nozaki
Organometallics 2022, 41, 3185–3196. 10.1021/acs.organomet.2c00066
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Synthesis of Crystalline CF3-Rich Perfluoropolyethers from Hexafluoropropylene Oxide and (Trifluoromethyl)Trimethylsilane
M. Koyama. M. Akiyama, K. Kashiwagi, K. Nozaki, T. Okazoe
Macromol. Rapid Commun. 2022, 43, 2200038. 10.1002/marc.202200038
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Synthesis and Reactivity of PC(sp3)P-pincer Iridium Complexes Bearing Diborylmethyl Anion
M. Kishino, S. Takaoka, Y. Shibutani, S. Kusumoto, K. Nozaki
Dalton Trans. 2022, 51, 5009–5015. 10.1039/D2DT00513A
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Atom Swapping on Aromatic Rings: Conversion from Phosphinine Pincer Metal Complexes to Metallabenzenes Triggered by O2 Oxidation
K. Masada, S. Kusumoto, K. Nozaki
Angew. Chem. Int. Ed. 2022, 61, e202117096. 10.1002/anie.202117096 Featured on the cover.
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Cleavage of Si–H, Si–C Bonds by Metal–Ligand Cooperation: Formation of Silyl Anion and Silylene Equivalents from Tertiary Silanes
T. Higashi, S. Kusumoto, K. Nozaki
Organometallics 2022, 41, 659–665. 10.1021/acs.organomet.2c00037 Selected as ACS Editors' Choice. Selected as Most Read Articles in 2022.
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A Ni0 σ-Borane Complex Bearing a Rigid Bidentate Borane/Phosphine Ligand: Boryl Complex Formation by Oxidative Dehydrochloroborylation and Catalytic Activity for Ethylene Polymerization
F. W. Seidel, K. Nozaki
Angew. Chem. Int. Ed. 2022, 62, e202111691. 10.1002/anie.202111691
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Synthesis of Triptycenemonohydroquinonedibenzoquinone by Comproportionation
Y. Takemasa, K. Nozaki
J. Org. Chem. 2022, 87, 1502–1506. 10.1021/acs.joc.1c01683 Featured on the cover.
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Highly Active Cross Metathesis of Tetrafluoroethylene with a Seven-membered NHC-Ruthenium Catalyst
K. Mori, M. Akiyama, K. Inada, Y. Imamura, Y. Ishibashi, Y. Takahira, K. Nozaki, T. Okazoe
J. Am. Chem. Soc. 2021, 143, 20980–20987. 10.1021/jacs.1c10574 J. Am. Chem. Soc. 2021, 143, 20980–20987. 10.1021/jacs.1c10574 Highlighted in Synfact.
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Bench-Stable Electrophilic Fluorinating Reagents for Highly Selective Mono- and Difluorination of Silyl Enol Ethers
A. Adachi, K. Aikawa, Y. Ishibashi, K. Nozaki, T. Okazoe
Chem. Eur, J. 2021, 27, 11919–11925. 10.1002/chem.202101499
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One-Pot Synthesis of Polyethylene-Based Block Copolymers via a Dual Polymerization Pathway
Y. Zhao, J. Jung, K. Nozaki
J. Am. Chem. Soc. 2021, 143, 18832–18837. 10.1021/jacs.1c08512
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Accessing Divergent Main-Chain-Functionalized Polyethylenes via Copolymerization of Ethylene with a CO2/Butadiene-Derived Lactone
S. Tang, Y. Zhao, K. Nozaki
J. Am. Chem. Soc. 2021, 143, 17953–17957. 10.1021/jacs.1c08578
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High Density Polyethylenes Bearing Isolated In-Chain Carbonyls
S. Tang, F. W. Seidel, K. Nozaki
Angew. Chem. Int. Ed. 2021, 60, 26506–26510. 10.1002/anie.202110957
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Heterolytic Oxidative Addition of sp2 and sp3 C–H Bonds by Metal–Ligand Cooperation with an Electron-deficient Cyclopentadienone Iridium Complex
T. Higashi, S. Kusumoto, K. Nozaki
J. Am. Chem. Soc. 2021, 143, 12999–13004. 10.1021/jacs.1c06714 Featured on the cover.
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Lithium Hexaphenylrhodate(III) and –Iridate(III): Structure in the Solid State and in Solution
T. Iwasaki, Y. Hirooka, H. Takaya, T. Honma, K. Nozaki
Organometallics 2021, 40, 2489–2495. 10.1021/acs.organomet.1c00248
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Metal-Ligand Cooperative κ1-N-pyrazolate Cp*RhIII-Catalysts for Dehydrogenation of Dimethylamine-borane at Room Temperature
S. Pal, T. Iwasaki, K. Nozaki
Dalton Trans. 2021, 50, 7938–7943. 10.1039/D1DT01705E
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Copolymerization of Ethylene and Methyl Acrylate by Palladium Catalysts Bearing IzQO Ligand Containing Methoxyethyl Ether Moiety and Salt Effect for the Polymerization
S. Akita, K. Nozaki
Polym. J. 2021, 53, 1057–1060. 10.1038/s41428-021-00500-3
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Metal-Support Cooperation in Al(PO3)3-Supported Pt Nanoparticles for the Selective Hydrogenolysis of Phenols to Arenes
X. Jin, R. Tsukimura, T. Aihara, H. Miura, T. Shishido, K. Nozaki
Nat. Catal. 2021, 4, 312–321. 10.1038/s41929-021-00598-x
See the article.
Featured on the cover. Highlighted in UTokyo FOCUS, EurekAlart!, AlphaGalileo, ScienceDaily, Phys.org, ScienMag, Science Bulletin, Mirage News, Laboratory Equipment.
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Synthesis and Properties of Spiro-double Sila[7]helicene: The LUMO Spiro-conjugation
N. Terada, K. Uematsu, R. Higuchi, Y. Tokimaru, Y. Sato, K. Nakano, K. Nozaki
Chem. Eur. J. 2021, 27, 9342–9349. 10.1002/chem.202100385 Selected as Top Downloaded Article published in 2021.
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Reversible PtII-CH3 Deuteration without Methane Loss: Metal-Ligand Cooperation vs Ligand-Assisted PtII-Protonation
S. Pal, K. Nozaki, A. Vedernikov, J. Love
Chem. Sci. 2021, 12, 2960–2969. 10.1039/D0SC06518H
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Umpolung of B–H Bonds by Metal–Ligand Cooperation with Cyclopentadienone Iridium Complexes
T. Higashi, S. Kusumoto, K. Nozaki
Angew. Chem. Int. Ed. 2021, 60, 2844–2848. 10.1002/anie.202011322
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Expedient Synthetic Identification of a Novel P-stereogenic Ligand Motif for the Palladium-Catalyzed Preparation of Isotactic Polar Polypropylenes
F. W. Seidel, I. Tomizawa, K. Nozaki
Angew. Chem. Int. Ed. 2020, 59, 22591–22601. 10.1002/anie.202009027 Highlighted in Press Release
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Synthesis of and Structural Insights into Contact Ion Pair and Solvent-Separated Ion Pair Diphenyliridate Complexes
T. Iwasaki, T. Akaiwa, Y. Hirooka, S. Pal, K. Nozaki, N. Kambe
Organometallics 2020, 39, 3077–3081. 10.1021/acs.organomet.0c00446
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Heavy Metal-Free Fischer-Tropsch Type Reaction: Sequential Homologation of Alkylborane Using a Combination of CO and Hydrides as Methylene Source
A. Phanopoulos, S. Pal, T. Kawakami, K. Nozaki
J. Am. Chem. Soc. 2020, 142, 14064–14068. 10.1021/jacs.0c06580
Highlighted in Hokkaido Shimbun Press, Science, UTokyo FOCUS, Synfact, and Asian Scientist
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Alternating Copolymerization of CO2 and Cyclohexene Oxide Catalyzed by Cobalt-Lanthanide Mixed Multinuclear Complexes
H. Asaba, T. Iwasaki, M. Hatazawa, J. Deng, H. Nagae, K. Mashima, K. Nozaki
Inorg. Chem. 2020, 59, 7928–7933. 10.1021/acs.inorgchem.0c01156
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Aluminum Porphyrins with Quaternary Ammonium Halides as Catalysts for Copolymerization of Cyclohexene Oxide and CO2: Metal–Ligand Cooperative Catalysis
J. Deng, M. Ratanasak, Y. Sako, H. Tokuda, C. Maeda, J. Hasegawa, K. Nozaki, T. Ema
Chem. Sci. 2020, 11, 5669–5675. 10.1039/D0SC01609H
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Metal–Metal Cooperative Bond Activation by Heterobimetallic Alkyl, Aryl, and Acetylide PtII/CuI Complexes
S. Deolka, O. Rivada, S. L. Aristizábal, R. R. Fayzullin, S. Pal, K. Nozaki, E. Khaskin, J. R. Khusnutdinova
Chem. Sci. 2020, 11, 5494–5502. 10.1039/D0SC00646G
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Reductive Coupling of Carbon Dioxide and an Aldehyde Mediated by a Copper(I) Complex toward the Synthesis of α-Hydroxycarboxylic Acids
K. Masada, S. Kusumoto, K. Nozaki
Org. Lett. 2020, 22, 4922–4926. 10.1021/acs.orglett.0c00995 Featured on the cover
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Copolymerization of Nonpolar Olefins and Allyl Acetate Using Nickel Catalysts Bearing a Methylene-bridged Bisphosphine Monoxide Ligand
J. Jung, H. Yasuda, K. Nozaki
Macromolecules 2020, 53, 2547–2556. 10.1021/acs.macromol.0c00183
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Synthesis of unsymmetrically substituted triarylamines via acceptorless dehydrogenative aromatization using a Pd/C and p-toluenesulfonic acid hybrid relay catalyst
S. Takayama, T. Yatabe, Y. Koizumi, X. Jin, K. Nozaki, N. Mizuno, K. Yamaguchi
Chem. Sci. 2020, 11, 4074–4084. 10.1039/C9SC06442G
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An Endergonic Synthesis of Single Sondheimer-Wong Diyne by Local Probe Chemistry
S. Kawai, H. Sang, L. Kantorovich, K. Takahashi, K. Nozaki, S. Ito
Angew. Chem. Int. Ed. 2020, 59, 10842–10847. 10.1002/anie.202001268
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Cleavage of C–C and C–O bonds in β-O-4 Linkage of Lignin Model Compound by Cyclopentadienone Group 8 and 9 Metals Complexes
S. Kusumoto, M. Kishino, K. Nozaki
Chem. Lett. 2020, 49, 477–480. 10.1246/cl.200037
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Synthesis of Fluorinated Dialkyl Carbonates from Carbon Dioxide as a Carbonyl Source
M. Sugiyama, M. Akiyama, K. Nishiyama, T. Okazoe, K. Nozaki
ChemSusChem 2020, 13, 1775–1784. 10.1002/cssc.202000090
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Single-molecule single-electron transistor (SM-SET) based on π-conjugated quinoidal-fused oligosilole and heteroepitaxial spherical Au/Pt nanogap electrodes
S. Lee, J. Kim, T. Tsuda, R. Takano, R. Shintani, K. Nozaki, Y. Majima
Appl. Phys. Express 2019, 12, 125007. 10.7567/1882-0786/ab56e5
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Synthesis of Polyethylene with in-chain α,β-Unsaturated Ketone and Isolated Ketone Units by Pd-catalyzed Ring-opening Copolymerization of Cyclopropenones with Ethylene
X. Wang, F. W. Seidel, K. Nozaki
Angew. Chem. Int. Ed. 2019, 58, 12955–12959. 10.1002/anie.201906990
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Reversible Polymer-Chain Modification: Ring-Opening and Closing of Polylactone
S. Moon, K. Masada, K. Nozaki
J. Am. Chem. Soc. 2019, 141, 10938–10942. 10.1021/jacs.9b03205
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Stepwise Reduction of Azapentabenzocorannulene
Z. Zhou, Z. Wei, Y. Tokimaru, S. Ito, K. Nozaki, M. A. Petrukhina
Angew. Chem. Int. Ed. 2019, 58, 12107–12111. 10.1002/anie.201906748
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Selective Synthesis of Primary Anilines from NH3 and Cyclohexanones by Utilizing Preferential Adsorption of Styrene on the Pd Nanoparticle Surface
Y. Koizumi, X. Jin, T. Yatabe, R. Miyazaki, J. Hasegawa, K. Nozaki, N. Mizuno, K. Yamaguchi
Angew. Chem. Int. Ed. 2019, 58, 10893–10897. 10.1002/anie.201903841
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Cyanide Free One-pot Synthesis of Methacrylic Esters from Acetone
M. Koyama, T. Kawakami, T. Okazoe, K. Nozaki
Chem. Eur. J. 2019, 25, 10913–10917. 10.1002/chem.201901933
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Metal–Ligand Cooperative C–H Bond Formation by Cyclopentadienone Platinum Complexes
T. Higashi, H. Ando, S. Kusumoto, K. Nozaki
J. Am. Chem. Soc. 2019, 141, 2247–2250. 10.1021/jacs.8b13829
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Synthesis of carbonyl-bridged dibenzofulvalenes and related compounds by rhodium-catalyzed stitching reaction
R. Shintani, S. Kishikawa, K. Nakamura, T. Tsuda, K. Nozaki
Chem. Commun. 2019, 55, 1072–1075. 10.1039/C8CC09943J
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Selective Chain-end Functionalization of Polar Polyethylenes: Orthogonal Reactivity of Carbene and Polar Vinyl Monomers in Their Copolymerization with Ethylene
X. Wang, K. Nozaki
J. Am. Chem. Soc. 2018, 140, 15635–15640. 10.1021/jacs.8b10335
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Palladium Complexes Bearing an N-Heterocyclic Carbene–Sulfonamide Ligand for Cooligomerization of Ethylene and Polar Monomers
W. Tao, X. Wang, S. Ito, K. Nozaki
J. Polym. Sci. Part A: Polym. Chem. 2019, 57, 474–477. 10.1002/pola.29270
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Functionalization of Azapentabenzocorannulenes via Five-fold C-H Borylation and Cross-Coupling Arylation: Application to Columnar Liquid Crystalline Materials
T. Nagano, K. Nakamura, Y. Tokimaru, S. Ito, D. Miyajima, T. Aida, K. Nozaki
Chem. Eur. J. 2018, 53, 14075–14078. 10.1002/chem.201803676
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Hydrogenation of Carbon Dioxide with Organic Base by PC(II)P-Ir Catalysts
S. Takaoka, A. Eizawa, S. Kusumoto, K. Nakajima, Y. Nishibayashi, K. Nozaki
Organometallics 2018, 37, 3001-3009. 10.1021/acs.organomet.8b00377 Featured on the cover
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Single-step construction of the anti-deoxypropionate motif from propylene: Formal total synthesis of the cuticular hydrocarbons isolated from Antitrogus parvulus
T. Murayama, K. Nozaki
Angew. Chem. Int. Ed. 2018, 57, 11394–11398. 10.1002/anie.201804711
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Synthesis and Reactivity of Methylpalladium Complexes Bearing a Partially Saturated IzQO Ligand
S. Akita, R. Nakano, S. Ito, K. Nozaki
Organometallics 2018, 37, 2286–2296. 10.1021/acs.organomet.8b00263
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Hybrid of Corannulene and Azacorannulene: Synthesis of a Highly Curved Nitrogen-Containing Buckybowl
Y. Tokimaru, S. Ito, K. Nozaki
Angew. Chem. Int. Ed. 2018, 57, 9818–9822. 10.1002/anie.201805678
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Palladium-Catalyzed Intramolecular C–H Arylation vs. 1,5-Palladium Migration: Theoretical Investigation
N. Misawa, T. Tsuda, R. Shintani, K. Yamashita, K. Nozaki
Chem. Asian. J. 2018, 13, 2566–2572. 10.1002/asia.201800603
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Phosphorescence Resulting from Interaction between Two Non-equivalent Metals on a Helical π-Conjugated Surface
M. Akiyama, Y. Tsuchiya, A. Ishii, M. Hasegawa, Y. Kurashige, K. Nozaki
Chem. Asian. J. 2018, 13, 1902-1905. 10.1002/asia.201800780
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Branched-Selective Hydroformylation of Non-Activated Olefins Using a N-Triphos/Rh Catalyst
A. Phanopoulos, K. Nozaki
ACS Catal. 2018, 8, 5799–5809. 10.1021/acscatal.8b00566
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Dehydrogenation of dimethylamine-borane catalyzed by half-sandwich Ir and Rh complexes: Mechanism and the role of Cp* non-innocence
S. Pal, S. Kusumoto, K. Nozaki
Organometallics 2018, 37, 906–914. 10.1021/acs.organomet.7b00889
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Methylene-Bridged Bisphosphine Monoxide Ligands for Palladium-Catalyzed Copolymerization of Ethylene and Polar Monomers
Y. Mitsushige, H. Yasuda, B. Carrow, S. Ito, M. Kobayashi, T. Tayano, Y. Watanabe, Y. Okuno, S. Hayashi, J. Kuroda, Y. Okumura, K. Nozaki
ACS Macro Lett. 2018, 7, 305–311. 10.1021/acsmacrolett.8b00034
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Nickel-Catalyzed Propylene/Polar Monomer Copolymerization
Y. Konishi, W. Tao, H. Yasuda, S. Ito, Y. Oishi, H. Ohtaki, A. Tanna, T. Tayano, K. Nozaki
ACS Macro Lett. 2018, 7, 213–217. 10.1021/acsmacrolett.7b00904
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Palladium/IzQO-Catalyzed Coordination–Insertion Copolymerization of Ethylene and 1,1-Disubstituted Ethylenes Bearing a Polar Functional Group
H. Yasuda, R. Nakano, S. Ito, K. Nozaki
J. Am. Chem. Soc. 2018, 140, 1876–1883. 10.1021/jacs.7b12593
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Synthesis of Pyrrole-Fused Corannulenes: 1,3-Dipolar Cycloaddition of Azomethine Ylides to Corannulene
Y. Tokimaru, S. Ito, K. Nozaki
Angew. Chem. Int. Ed. 2017, 56, 15560–15564. 10.1002/anie.201707087
Highlighted in Synfacts
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Cationic Co-Salphen Complexes Bisligated by DMAP as Catalysts for the Copolymerization of Cyclohexene Oxide with Phthalic Anhydride or Carbon Dioxide
M. Hatazawa, R. Takahashi, J. Deng, H. Houjou, K. Nozaki
Macromolecules 2017, 50, 7895–7900. 10.1021/acs.macromol.7b01130
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Selective Synthesis of Primary Anilines from Cyclohexanone Oximes by the Concerted Catalysis of a Mg−Al Layered Double Hydroxide Supported Pd Catalyst
X. Jin, Y. Koizumi, K. Yamaguchi, K. Nozaki, N. Mizuno
J. Am. Chem. Soc. 2017, 139, 13821-13829. 10.1021/jacs.7b07347
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Formal arylation of NH3 to produce diphenylamines over supported Pd catalysts
Y. Koizumi, K. Taniguchi, X. Jin, K. Yamaguchi, K. Nozaki, N. Mizuno
Chem. Commun. 2017, 53, 10827–10830. 10.1039/C7CC06737B
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Competing Annulene and Radialene Structures in a Single Anti-Aromatic Molecule Studied by High-Resolution Atomic Force Microscopy
S. Kawai, K. Takahashi, S. Ito, R. Pawlak, T. Meier, P. Spijker, F. F. Canova, J. Tracey, K. Nozaki, A. S. Foster, E. Meyer
ACS Nano 2017, 11, 8122–8130. 10.1021/acsnano.7b02973
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Palladium-Catalyzed Asymmetric Synthesis of Silicon-Stereogenic 5,10-Dihydrophenazasilines via Enantioselective 1,5-Palladium Migration
Y. Sato, C. Takagi, R. Shintani, K. Nozaki
Angew. Chem. Int. Ed. 2017, 31, 9211–9216. 10.1002/anie.201705500
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Cp*Ir-catalyzed Acceptorless Dehydrogenation of Carbon–Carbon Single Bonds
H. Ando, S. Kusumoto, W. Wu, K. Nozaki
Organometallics 2017, 36, 2317–2322. 10.1021/acs.organomet.7b00245
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Structures and Physical Properties of Chemically Reduced Diindenosiloles and Their π-Extended Derivatives
R. Takano, R. Shintani, A. Fukazawa, S. Yamaguchi, K. Nakabayashi, S. Ohkoshi, K. Nozaki
Organometallics 2017, 36, 2646–2653. 10.1021/acs.organomet.7b00260
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A Ni-Mg-Al layered triple hydroxide-supported Pd catalyst for heterogeneous acceptorless dehydrogenative aromitization
X. Jin, K. Taniguchi, K. Yamaguchi, K. Nozaki, N. Mizuno
Chem. Commun. 2017, 53, 5267–5270. 10.1039/C7CC01182B
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Synthesis of Quinoidal Fused Oligosiloles by Rhodium-Catalyzed Stitching Reaction and Theoretical Investigation of Their Properties
R. Shintani, N. Misawa, T. Tsuda, R. Iino, M. Fujii, K. Yamashita, K. Nozaki
J. Am. Chem. Soc. 2017, 139, 3861–3867. 10.1021/jacs.7b00344 Highlited in Synfacts
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Copolymerisation of Ethylene with Polar Monomers by Palladium Catalysts Bearing an N-Heterocyclic Carbene–Phosphine Oxide Bidentate Ligand
W. Tao, S. Akita, R. Nakano, S. Ito, Y. Hoshimoto, S. Ogoshi, K. Nozaki
Chem. Commun. 2017, 53, 2630–2633. 10.1039/C7CC00002B
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Facile styrene formation from ethylene and a phenylplatinum(II) complex leading to an observable platinum(II)-hydride
S. Pal, S. Kusumoto, K.Nozaki
Organometallics 2017, 36, 502–505. 10.1021/acs.organomet.6b00892
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Synthesis of Optically Pure Helicene Metallocenes
M. Akiyama, K. Nozaki
Angew. Chem. Int. Ed. 2017, 56, 2040–2044. 10.1002/anie.201611488
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Rhodium-Catalyzed Synthesis and Optical Properties of Silicon-Bridged Arylpyridines
R. Shintani, N. Misawa, R. Takano, K. Nozaki
Chem. Eur. J. 2017, 23, 2660–2665. 10.1002/chem.201605000
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Versatile routes for synthesis of diarylamines through acceptorless dehydrogenative aromatization catalysis over supported gold–palladium bimetallic nanoparticles
K. Taniguchi, X. Jin, K. Yamaguchi, K. Nozaki, N. Mizuno
Chem. Sci. 2017, 8, 2131–2142. 10.1039/C6SC04455G
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Selective Synthesis of Unsymmetric Dibenzo[a,e]pentalenes by Rhodium-Catalysed Stitching Reaction
K. Takahashi, S. Ito, R. Shintani, K. Nozaki
Chem. Sci. 2017, 8, 101–107. 10.1039/C6SC04560J Featured on the back cover. Highlighted in Synfacts
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A Potassium Diboryllithate: Synthesis, Bonding Properties, and the Deprotonation of Benzene
T. Ohsato, Y. Okuno, S. Ishida, T. Iwamoto, K.-H. Lee, Z. Lin, M. Yamashita, K. Nozaki
Angew. Chem. Int. Ed. 2016, 55, 11426–11430. 10.1002/anie.201605005
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Elucidating the Key Role of Phosphine–Sulfonate Ligands in Palladium-Catalyzed Ethylene Polymerization: Effect of Ligand Structure on the Molecular Weight and Linearity of Polyethylene
R. Nakano, L. W. Chung, Y. Watanabe, Y. Okuno, Y. Okumura, S. Ito, K. Morokuma, K. Nozaki
ACS Catal. 2016, 6, 6101–6113. 10.1021/acscatal.6b00911
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Synthesis and Properties of [7]Helicene-like Compounds Fused with a Fluorene Unit
H. Oyama, M. Akiyama, K. Nakano, M. Naito, K. Nobusawa, K. Nozaki
Org. Lett. 2016, 18, 3654–3657. 10.1021/acs.orglett.6b01708
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In Situ Generation of Salen/Co(III) Complexes for Copolymerization of Propylene Oxide and CO2
M. Hatazawa, K. Nakabayashi, S. Ohkoshi, K. Nozaki
Chem. Eur. J. 2016, 22, 13677–13681. 10.1002/chem.201602546
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Reactions of 2-Methyltetrahydropyran on Silica-Supported Nickel Phosphide in Comparison with 2-Methyltetrahydrofuran
P. P. Bui, S. T. Oyama, A. Takagaki, B. P. Carrow, K. Nozaki
ACS Catal. 2016, 6, 4549–4558. 10.1021/acscatal.6b01033
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Intermolecular Three-Component Arylsilylation of Alkynes under Palladium/Copper Cooperative Catalysis
R. Shintani, H. Kurata, K. Nozaki
J. Org. Chem. 2016, 81, 3065–3069. 10.1021/acs.joc.6b00587
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Crystalline Isotactic Polar Polypropylene from the Palladium-Catalyzed Copolymerization of Propylene and Polar Monomers
Y. Ota, S. Ito, M. Kobayashi, S. Kitade, K. Sakata, T. Tayano, K. Nozaki
Angew. Chem. Int. Ed. 2016, 55, 7505–7509. 10.1002/anie.201600819
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Rhodium-Catalyzed Stitching Reaction: Convergent Synthesis of Quinoidal Fused Oligosiloles
R. Shintani, R. Iino, K. Nozaki
J. Am. Chem. Soc. 2016, 138, 3635–3638. 10.1021/jacs.6b00082 highlighted in Synfacts
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A Qualitative Analysis of a “Bora-Brook Rearrangement”: the Ambident Reactivity of Boryl-Substituted Alkoxide Including the Carbon-to-Oxygen Migration of a Boryl Group
H. Kisu, H. Sakaino, F. Ito, M. Yamashita, K. Nozaki
J. Am. Chem. Soc. 2016, 138, 3548–3552. 10.1021/jacs.6b00283
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One-step catalytic asymmetric synthesis of all-syn deoxypropionate motif from propylene: Total synthesis of (2R,4R,6R,8R)-2,4,6,8-tetramethyldecanoic acid
Y. Ota, T. Murayama, K. Nozaki
Proc. Natl. Acad. Sci. USA 2016, 113, 2857–2861. 10.1073/pnas.1518898113 highlighted in UTokyo Research (Japanese), UTokyo Research (English), and Synform
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Pyrazole Supported Zinc(II) Benzoates as Catalysts for the Ring Opening Copolymerization of Cyclohexene Oxide and Carbon Dioxide
M. L. Lephoto, K. Nakano, D. Appavoo, B. O. Owaga, K. Nozaki, J. Darkwa
Catalysts 2016, 6, 17. 10.3390/catal6010017
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Copolymerization of Ethylene and Polar Monomers Using Ni/IzQO Catalysts
W. Tao, R. Nakano, S. Ito, K. Nozaki
Angew. Chem. Int. Ed. 2016, 55, 2835–2839. 10.1002/anie.201510077
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Rhodium-Catalyzed Asymmetric Synthesis of Silicon-Stereogenic Silicon-Bridged Arylpyridinones
R. Shintani, R. Takano, K. Nozaki
Chem. Sci. 2016, 7, 1205–1211. 10.1039/C5SC03767K highlighted in Synfacts
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Ligand-Controlled Insertion Regioselectivity Accelerates Copolymerisation of Ethylene with Methyl Acrylate by Cationic Bisphosphine Monoxide-Palladium Catalysts
Y. Mitsushige, B. P. Carrow, S. Ito, K. Nozaki
Chem. Sci. 2016, 7, 737–744. 10.1039/C5SC03361F
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Iron-Catalyzed Homo- and Copolymerization of Propylene: Steric Influence of Bis(imino)pyridine Ligands
T. Kawakami, S. Ito, K. Nozaki
Dalton Trans. 2015, 44, 20745–20752. 10.1039/C5DT03551A
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Development of Highly Active Ir–PNP Catalysts for Hydrogenation of Carbon Dioxide with Organic Bases
W. Aoki, N. Wattanabinin, S. Kusumoto, K. Nozaki
Bull. Chem. Soc. Jpn. 2016, 89, 113–124. 10.1246/bcsj.20150311 highlighted as BCSJ Selected Papers
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Copolymerization of Propylene and Polar Monomers Using Pd/IzQO Catalysts
R. Nakano, K. Nozaki
J. Am. Chem. Soc. 2015, 137, 10934–10937. 10.1021/jacs.5b06948 highlighted in ACS Selects Virtual Issue
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Rhodium-Catalyzed Intramolecular Alkynylsilylation of Alkynes
R. Shintani, H. Kurata, K. Nozaki
Chem. Commun. 2015, 51, 11378–11381. 10.1039/C5CC04172D highlighted in Chemistry World
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The Retro-Hydroformylation Reaction
S. Kusumoto, T. Tatsuki, K. Nozaki
Angew. Chem. Int. Ed. 2015, 54, 8458–8461. 10.1002/anie.201503620 highlighted in Front cover, Wiley-Japan Science Cafe, and 現代化学
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Benzene-Fused Azacorannulene Bearing an Internal Nitrogen Atom
S. Ito, Y. Tokimaru, K. Nozaki
Angew. Chem. Int. Ed. 2015, 54, 7256–7260. 10.1002/anie.201502599 highlighted in Frontispiece and Synfacts
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Formal Aryne/Carbon Monoxide Copolymerization to Form Aromatic Polyketones/Polyketals
S. Ito, W. Wang, K. Nishimura, K. Nozaki
Macromolecules 2015, 48, 1959–1962. 10.1021/acs.macromol.5b00315
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Synthesis and Properties of Benzophospholo[3,2-b]benzofuran Derivatives
M. Takahashi, K. Nakano, K. Nozaki
J. Org. Chem. 2015, 80, 3790–3797. 10.1021/jo502889r highlighted in Synfacts
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Formal Aryne/Ethylene Copolymerization to Form Polyethylene Containing o-Arylene Units in the Main Chain
S. Ito, W. Wang, K. Nozaki
Polym. J. 2015, 47, 474–480. 10.1038/pj.2015.27
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Direct and Selective Hydrogenolysis of Arenols and Aryl Methyl Ethers
S. Kusumoto, K. Nozaki
Nat. Commun. 2015, 6, 6296. 10.1038/ncomms7296 highlighted in C&E News and UTokyo Research.
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Rhodium-Catalyzed Asymmetric Synthesis of Silicon-Stereogenic Dibenzosiloles via Enantioselective [2+2+2] Cycloaddition
R. Shintani, C. Takagi, T. Ito, M. Naito, K. Nozaki
Angew. Chem. Int. Ed. 2015, 54, 1616–1620. 10.1002/anie.201409733
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Isoquinolino[4,3,2-de]phenanthridine: Synthesis and Its Use in 1,3-Dipolar Cycloadditions to Form Nitrogen-Containing Polyaromatic Hydrocarbons
S. Ito, Y. Tokimaru, K. Nozaki
Chem. Commun. 2015, 51, 221–224. 10.1039/C4CC06643J
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Ruthenium Catalyzed Hydrogenation of Aldehyde with Synthesis Gas
K. Takahashi, K. Nozaki
Org. Lett. 2014, 16, 5846–5849. 10.1021/ol502681y
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Quantification of the Steric Influence of Alkylphosphine–Sulfonate Ligands on Polymerization, Leading to High-Molecular-Weight Copolymers of Ethylene and Polar Monomers
Y. Ota, S. Ito, J. Kuroda, Y. Okumura, K. Nozaki
J. Am. Chem. Soc. 2014, 136, 11898–11901. 10.1021/ja505558e
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Facile Estimation of Catalytic Activity and Selectivities in Copolymerization of Propylene Oxide with Carbon Dioxide Mediated by Metal Complexes with Planer Tetradentate Ligand
T. Ohkawara, K. Suzuki, K. Nakano, S. Mori, K. Nozaki
J. Am. Chem. Soc. 2014, 136, 10728–10735. 10.1021/ja5046814 highlighted in JACS Spotlight.
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Rhodium-Catalyzed Polymerization of 3,3-Diarylcyclopropenes Involving a 1,4-Rhodium Migration
R. Shintani, R. Iino, K. Nozaki
J. Am. Chem. Soc. 2014, 136, 7849–7852. 10.1021/ja5032002 highlighted in Synfacts.
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Formal Aryne Polymerization: Use of [2.2.1]Oxabicyclic Alkenes as Aryne Equivalents
S. Ito, K. Takahashi, K. Nozaki
J. Am. Chem. Soc. 2014, 136, 7547–7550. 10.1021/ja502073k highlighted in Synfacts.
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Silylative Cyclopropanation of Allyl Phosphates with Silylboronates
R. Shintani, R. Fujie, M. Takeda, K. Nozaki
Angew. Chem. Int. Ed. 2014, 53, 6546–6549. 10.1002/anie.201403726 highlighted in Synfacts.
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Assessing the Brønsted Basicity of Diaminoboryl Anions: Reactivity toward Methylated Benzenes and Dihydrogen
N. Dettenrieder, Y. Aramaki, B. Wolf, C. Maichle-Mössmer, X. Zhao, M. Yamashita, K. Nozaki, R. Anwander
Angew. Chem. Int. Ed. 2014, 53, 6259–6262. 10.1002/anie.201402175
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Copolymerization of Carbon Dioxide and Butadiene via a Lactone Intermediate
R. Nakano, S. Ito, K. Nozaki
Nature Chem. 2014, 6, 325–331. 10.1038/nchem.1882 highlighted in Nature Chemistry, Chemistry World, C&E News, Chemical Enginnering, Chem-Station, Angew. Chem. Int. Ed..
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Manganese-Corrole Complex as a Versatile Catalyst for Ring-Opening Homo- and Co-polymerization of Epoxide
C. Robert, T. Ohkawara, K. Nozaki
Chem. Eur. J. 2014, 20, 4789–4795. 10.1002/chem.201303703
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Solvent and Co-catalyst Dependent Pyrazolylpyridinamine and Pyrazolylpyrroleamine Nickel(II) Catalyzed Oligomerization and Polymerization of Ethylene
C. Obuah, B. Omondi, K. Nozaki, J. Darkwa
J. Mol. Catal. A: Chem. 2014, 382, 31–40. 10.1016/j.molcata.2013.10.024
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Acceptorless Dehydrogenation of C–C Single Bonds Adjacent to Functional Groups by Metal-Ligand Cooperation
S. Kusumoto, M. Akiyama, K. Nozaki
J. Am. Chem. Soc. 2013, 135, 18726–18729. 10.1021/ja409672w
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Tandem Isomerization/Hydroformylation/Hydrogenation of Internal Alkenes to normal-Alcohols Using Rh/Ru Dual or Ternary Catalyst Systems
Y. Yuki, K. Takahashi, Y. Tanaka, K. Nozaki
J. Am. Chem. Soc. 2013, 135, 17393–17400. 10.1021/ja407523j
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Direct Aldol Polymerization of Acetaldehyde with Organocatalyst/Brønsted Acid Systems
S. Kusumoto, S. Ito, K. Nozaki
Asian J. Org. Chem. 2013, 2, 977–982. 10.1002/ajoc.201300134 This paper will be listed in a special issue on the Mukaiyama aldol reaction.
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Efficient Catalyst Removal and Recycling in Copolymerization of Epoxides with Carbon Dioxide via Simple Liquid–Liquid Phase Separation
K. Nakano, R. Fujie, R. Shintani, K. Nozaki
Chem. Commun. 2013, 49, 9332–9334. 10.1039/C3CC45622F
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Copolymerization of Epoxides with Carbon Dioxide Catalyzed by Iron–Corrole Complexes: Synthesis of a Crystalline Copolymer
K. Nakano, K. Kobayashi, T. Ohkawara, H. Imoto, K. Nozaki
J. Am. Chem. Soc. 2013, 135, 8456–8459. 10.1021/ja4028633
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Oxidative Addition of a Strained C–C Bond onto Electron-Rich Rhodium(I) at Room Temperature
Y. Masuda, M. Hasegawa, M. Yamashita, K. Nozaki, N. Ishida, M. Murakami
J. Am. Chem. Soc. 2013, 135, 7142–7145. 10.1021/ja403461f
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Facile Synthetic Route to Highly Luminescent Sila[7]helicene
H. Oyama, K. Nakano, T. Harada, R. Kuroda, M. Naito, K. Nobusawa, K. Nozaki
Org. Lett. 2013, 15, 2104–2107. 10.1021/ol4005036 highlighted in Noteworthy Chemistry
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Copper-Catalyzed Hydroboration of Carbon Dioxide
R. Shintani, K. Nozaki
Organometallics 2013, 32, 2459–2462. 10.1021/om400175h
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Ethylene and Styrene Carbon Monoxide Copolymerization Catalyzed by Pyrazolyl Palladium(II) Complexes
C. Obuah, M. K. Ainooson, S. Boltina, I. A. Guzei, K. Nozaki, J. Darkwa
Organometallics 2013, 32, 980–988. 10.1021/om300798y
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Synthesis and Characterization of B-Heterocyclic π-Radical and Its Reactivity as a Boryl Radical
Y. Aramaki, H. Omiya, M. Yamashita, K. Nakabayashi, S.-i. Ohkoshi, K. Nozaki
J. Am. Chem. Soc. 2012, 134, 19989–19992. 10.1021/ja3094372
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Tandem Hydroformylation/Hydrogenation of Alkenes to normal-Alcohols Using Rh/Ru Dual Catalyst or Ru Single Component Catalyst
K. Takahashi, M. Yamashita, K. Nozaki
J. Am. Chem. Soc. 2012, 134, 18746–18757. 10.1021/ja307998h
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Ethylene/Allyl Monomer Cooligomerization by Nickel/Phosphine–Sulfonate Catalysts
S. Ito, Y. Ota, K. Nozaki
Dalton Trans. 2012, 41, 13807–13809. 10.1039/C2DT31771K
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Ping-Pong Polymerization by Allylation and Hydroformylation for Alternating Vinyl Alcohol-Vinyl Monomer Copolymers
S. Ito, M. Noguchi, K. Nozaki
Chem. Commun. 2012, 48, 10481–10483. 10.1039/C2CC34980A Featured in the front cover
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P-Chiral Phosphine–Sulfonate/Palladium-Catalyzed Asymmetric Copolymerization of Vinyl Acetate with Carbon Monoxide
A. Nakamura, T. Kageyama, H. Goto, B. P. Carrow, S. Ito, K. Nozaki
J. Am. Chem. Soc. 2012, 134, 12366–12369. 10.1021/ja3044344
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Synthesis of Functional Polyolefins Using Cationic Bisphosphine Monoxide-Palladium Complexes
B. P. Carrow, K. Nozaki
J. Am. Chem. Soc. 2012, 134, 8802–8805. 10.1021/ja303507t
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Isolation of PBP-Pincer Rhodium Complex Stabilized by an Intermolecular C-H sigma-Coordination as the Fourth Ligand
M. Hasegawa, Y. Segawa, M. Yamashita, K. Nozaki
Angew. Chem. Int. Ed. 2012, 51, 6956–6960. 10.1002/anie.201201916
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CpRu/C5Me5/Bisphosphine- or Bisphosphite-Based Catalysts for normal-Selective Hydroformylation
K. Takahashi, M. Yamashita, Y. Tanaka, K. Nozaki
Angew. Chem. Int. Ed. 2012, 51, 4283–4387. 10.1002/anie.201108396
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Syntheses and Thermolysis of Arylpalladium Hydroxide Complexes: Implications for C(sp2)–OH Bond-Forming Reductive Elimination to Generate Phenol Derivatives
Y. Hayashi, S. Wada, M. Yamashita, K. Nozaki
Organometallics 2012, 31, 1073–1081. 10.1021/om201142s
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Mechanistic Studies on the Reversible Hydrogenation of Carbon Dioxide Catalyzed by an Ir-PNP Complex
R. Tanaka, M. Yamashita, L. W. Chung, K. Morokuma, K. Nozaki
Organometallics 2011, 30, 6742–6750. 10.1021/om2010172
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Phosphora[7]helicenes: Synthesis, Properties, and Columnar Aggregation with One-Way Chirality
K. Nakano, H. Oyama, Y. Nishimura, S. Nakasako, K. Nozaki
Angew. Chem. Int. Ed. 2012, 51, 695–699. 10.1002/anie.201106157
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Ethylene Polymerization by Palladium/Phosphine–Sulfonate Catalysts in the Presence and Absence of Protic Solvents: Structural and Mechanistic Differences
M. Kanazawa, S. Ito, K. Nozaki
Organometallics 2011, 30, 6049–6052. 10.1021/om2004207
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Tetravalent Metal Complexes as a New Family of Catalysts for Copolymerization of Epoxides with Carbon Dioxide
K. Nakano, K. Kobayashi, K. Nozaki
J. Am. Chem. Soc. 2011, 133, 10720–10723. 10.1021/ja203382q
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One-Pot Carboboration of Alkynes Using Lithium Borylcyanocuprate and the Subsequent Suzuki-Miyaura Cross-Coupling Reaction of Resulting Tetrasubstituted Alkenylborane
Y. Okuno, M. Yamashita, K. Nozaki
Eur. J. Org. Chem. 2011, 3951–3958. 10.1002/ejoc.201100373 The picture of Prof. Kyoko Nozaki appeared on the cover picture of this Special Issue: Women in Chemistry
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Pd-Catalyzed Copolymerization of Methyl Acrylate with Carbon Monoxide: Structures, Properties and Mechanistic Aspects toward Ligand Design
A. Nakamura, K. Munakata, S. Ito, T. Kochi, L. W. Chung, K. Morokuma, K. Nozaki
J. Am. Chem. Soc. 2011, 133, 6761–6779. 10.1021/ja2003268
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Syntheses and Properties of Triborane(5) Possessing Bulky Diamino Substituents on Terminal Boron Atoms
Y. Hayashi, Y. Segawa, M. Yamashita, K. Nozaki
Chem. Commun. 2011, 47, 5888–5890. 10.1039/C1CC11334H
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Stereocomplex of Poly(propylene carbonate): Synthesis of Stereogradient Poly(propylene carbonate) via Stereo- and Enantioselective Copolymerization of Propylene Oxide with Carbon Dioxide
K. Nakano, S. Hashimoto, M. Nakamura, T. Kamada, K. Nozaki
Angew. Chem. Int. Ed. 2011, 50, 4868–4871. 10.1002/anie.201007958 selected as VIP, highlighted in Nature Chemistry
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Coordination-Insertion Copolymerization of Allyl Monomers with Ethylene
S. Ito, M. Kanazawa, K. Munakata, J. Kuroda, Y. Okumura, K. Nozaki
J. Am. Chem. Soc. 2011, 133, 1232–1235. 10.1021/ja1092216
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Vinylarene/CO Copolymerization and Vinylarene/Polar Vinyl Monomer/CO Terpolymerization Using Palladium/Phosphine-Sulfonate Catalysts
T. Kageyama, S. Ito, K. Nozaki
Chem. Asian J. 2011, 6, 690–697. 10.1002/asia.201000668
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Borylcyanocuprate in a One-Pot Carboboration by a Sequential Reaction with an Electron-Deficient Alkyne and an Organic Carbon Electrophile
Y. Okuno, M. Yamashita, K. Nozaki
Angew. Chem. Int. Ed. 2011, 50, 920–923. 10.1002/anie.201005667
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Why Did Incorporation of Acrylonitrile to a Linear Polyethylene Become Possible? Comparison of Phosphine-Sulfonate Ligand with Diphosphine and Imine-Phenolate Ligands in the Pd-Catalyzed Ethylene/Acrylonitrile Copolymerization
K. Nozaki, S. Kusumoto, S. Noda, T. Kochi, L. W. Chung, K. Morokuma
J. Am. Chem. Soc. 2010, 132, 16030–16042. 10.1021/ja104837h
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A Catalytic Synthesis of Dialkylamines from Alkylamines Using Neopentyl-Substituted PNP Pincer Iridium Complex
M. Yamashita, Y. Moroe, T. Yano, K. Nozaki
Inorg. Chim. Acta 2011, 369, 15–18. 10.1016/j.ica.2010.08.034
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New Class of Catalysts for Alternating Copolymerization of Alkylene Oxide and Carbon Dioxide
A. Okada, S. Kikuchi, K. Nakano, K. Nishioka, K. Nozaki, T. Yamada
Chem. Lett. 2010, 39, 1066–1068. 10.1246/cl.2010.1066
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Boryltrihydroborate:Synthesis, Structure, and Reactivity as a Reductant in Ionic, Organometallic and Radical Reactions
K. Nozaki, Y. Aramaki, M. Yamashita, S.-H. Ueng, M. Malacria, E. Lacote, D. Curran
J. Am. Chem. Soc. 2010, 132, 11449–11451. 10.1021/ja105277u
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Reduction of Base-Stabilized Difluoroboranes to Induce Rearrangement Reactions
M. Yamashita, Y. Aramaki, K. Nozaki
New J. Chem. 2010, 34, 1774–1782. 10.1039/C0NJ00363H
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New Low Temperature NMR Studies Establish the Presence of a Second Equatorial-Apical Isomer of [(R,S)-Binaphos](CO)2RhH
D. A. Castillo Molina, C. P. Casey, I. Müller, K. Nozaki, C. Jäkel
Organometallics 2010, 29, 3362–3367. 10.1021/om100323q
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Bimetallic mechanism operating in the copolymerization of propylene oxide with carbon dioxide catalyzed by cobalt-salen complexes
K. Nakano, S. Hashimoto, K. Nozaki
Chem. Sci. 2010, 1, 369–373. 10.1039/c0sc00220h
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High-Yielding Tandem Hydroformylation/Hydrogenation of a Terminal Olefin to Produce a Linear Alcohol Using a Rh/Ru Dual Catalyst System
K. Takahashi, M. Yamashita, T. Ichihara, K. Nakano, K. Nozaki
Angew. Chem. Int. Ed. 2010, 49, 4488–4490. 10.1002/anie.201001327 selected as an outside cover, highlighted in ChemCatChem, highlighted at the following blogs, NNNS chemistry blog, ユーキの有機化学Hot Topics
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Regioselective Synthesis of Halohydrin Esters from Epoxides: Reaction with Acyl Halides and Rhodium-catalyzed Three-component Coupling Reaction with Alkyl Halides and Carbon Monoxide
K. Nakano, S. Kodama, Y. Permana, K. Nozaki
Chem. Commun. 2009, 6970–6972. 10.1039/b912907c
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Diphenylphosphino- or Dicyclohexylphosphino-Tethered Boryl Pincer Ligands: Syntheses of PBP Iridium(III) Complexes and Their Conversion to Iridium–Ethylene Complexes
Y. Segawa, M. Yamashita, K. Nozaki
Organometallics 2009, 28, 6234–6242. 10.1021/om9006455
- Synthesis of N-Heterocyclic Carbene-Sulfonate Palladium Complexes
Y. Nagai, T. Kochi, K. Nozaki
Organometallics 2009, 28, 6131–6134. 10.1021/om9004252
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Copolymerization of Vinyl Acetate with Ethylene by Palladium/Alkylphosphine–Sulfonate Catalysts
S. Ito, K. Munakata, A. Nakamura, K. Nozaki
J. Am. Chem. Soc. 2009, 131, 14606–14607. 10.1021/ja9050839
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Group 4 Transition Metal Boryl Complexes: Syntheses, Structures, Boron–Metal Bonding Properties, and Application as a Polymerization Catalyst
T. Terabayashi, T. Kajiwara, M. Yamashita, K. Nozaki
J. Am. Chem. Soc. 2009, 131, 14162–14163. 10.1021/ja905950g
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Catalytic Hydrogenation of Carbon Dioxide Using Ir(III)-Pincer Complexes
R. Tanaka, M. Yamashita, K. Nozaki
J. Am. Chem. Soc. 2009, 131, 14168–14169. 10.1021/ja903574e highlighted in Angewandte Chemie
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Mechanistic Studies on the Formation of Linear Polyethylene Chain Catalyzed by Palladium Phosphine–Sulfonate Complexes: Experiment and Theoretical Studies
S. Noda, A. Nakamura, T. Kochi, L. W. Chung, K. Morokuma, K. Nozaki
J. Am. Chem. Soc. 2009, 131, 14088–14100. 10.1021/ja9047398
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Alternating Copolymerization of Cyclohexene Oxide with Carbon Dioxide Catalyzed by (salalen)CrCl Complexes
K. Nakano, M. Nakamura, K. Nozaki
Macromolecules, 2009, 42, 6972–6980. 10.1021/ma9012626
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Syntheses of PBP Pincer Iridium Complexes: A Supporting Boryl Ligand
Y. Segawa, M. Yamashita, K. Nozaki
J. Am. Chem. Soc. 2009, 131, 9201–9203. 10.1021/ja9037092 highlighted in Angewandte Chemie
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Rhodium Catalysts Bearing Mixed Thioether-Phosphine Ligands for Carbonylation of Methanol
K. Sakakibara, K. Nozaki
Bull. Chem. Soc. Jpn. 2009, 82, 1009–1011. 10.1246/bcsj.82.1009
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Sulfide-Bearing Phosphine Ligands: Their Pd Complexes and Application to Copolymerizations of Olefins and CO
K. Sakakibara, K. Nozaki
Bull. Chem. Soc. Jpn. 2009, 82, 1006–1008. 10.1246/bcsj.82.1006
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Synthesis of p-Conjugated Copolymer with Dibenzo[d,d']benzo[1,2-b:4,5-b']difuran Unit in the Main Chain
K. Nakano, M. Takahashi, K. Kawaguchi, K. Nozaki
Synthetic Metals 2009, 159, 939–942. 10.1016/j.synthmet.2009.02.001
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Synthesis of Allylnickel Complexes with Phosphine–Sulfonate Ligands and Their Application for Olefin Polymerization without Activators
S. Noda, T. Kochi, K. Nozaki
Organometallics 2009, 28, 656–658. 10.1021/om800781b
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Ring-opening reaction of Bus- and SES-protected aziridines using lithiated dithianes
K. Sakakibara, K. Nozaki
Org. Biomol. Chem. 2009, 7, 502–507. 10.1039/b814413c
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Neopentyl-Substituted PNP-Pincer Ligand: Complexation with Iridium to Form an Iridacycle via Alkyl C-H Activation
T. Yano, Y. Moroe, M. Yamashita, K. Nozaki
Chem. Lett. 2008, 37, 1300–1301. 10.1246/cl.2008.1300
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Chemistry of Boryllithium: Synthesis, Structure, and Reactivity
Y. Segawa, Y. Suzuki, M. Yamashita, K. Nozaki
J. Am. Chem. Soc. 2008, 130, 16069–16079. 10.1021/ja8057919
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Syntheses of Ester-Substituted Norbornyl Palladium Complexes Ligated with tBu3P: Studies on the Insertion of exo- and endo-Monomers in the Ester-Substituted Norbornene Polymerization
I. Takamiya, M. Yamashita, K. Nozaki
Organometallics 2008, 27, 5347–5352. 10.1021/om800566j
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Tandem Hydroformylation-Hydrogenation of 1-Decene Catalyzed by Rh-Bidentate Bis(trialkylphosphine)s
T. Ichihara, K. Nakano, M. Katayama, K. Nozaki
Chem. Asian J. 2008, 3, 1722–1728. 10.1002/asia.200800163
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Regiocontrolled Copolymerization of Methyl Acrylate with Carbon Monoxide.
A. Nakamura, K. Munakata, T. Kochi, K. Nozaki
J. Am. Chem. Soc. 2008, 130, 8128–8129. 10.1021/ja802161n
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Syntheses, Structures, and Reactivities of Borylcopper and -zinc Compounds: 1,4-Silaboration of An α,β-Unsaturated Ketone to Form A γ-Siloxyallylborane.
T. Kajiwara, T. Terabayashi, M. Yamashita, K. Nozaki
Angew. Chem. Int. Ed. 2008, 47, 6606–6610. 10.1002/anie.200801728
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Crystal Structure of Boryllithium with Two THF Molecules and DFT Analysis of Its Property as a Boryl Anion.
M. Yamashita, Y. Suzuki, Y. Segawa, K. Nozaki
Chem. Lett. 2008, 37, 802–803. 10.1246/cl.2008.802
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Polymerization of Norbornene with a Pendent Sulfonyl Fluoride Group Catalyzed by Palladium Complex Bearing tBu3P Ligand.
I. Takamiya, M. Yamashita, E, Murotani, Y. Morizawa, K. Nozaki
J. Polym. Sci., Part A: Polym. Chem. 2008, 46, 5133–5141. 10.1002/pola.22841
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Synthesis, Structures, and Properties of Unsymmetrical Heteroacenes Containing both Pyrrole and Furan Rings
K. Kawaguchi, K. Nakano, K. Nozaki
Org. Lett. 2008, 10, 1199–1202. 10.1021/ol703110g
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Carbonylative Polymerization of Oxetanes Initiated by Acetylcobalt Complexes
Y. Permana, K. Nakano, M. Yamashita, D. Watanabe, K. Nozaki
Chem. Asian J. 2008, 3, 710–718. 10.1002/asia.200700339
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Synthesis of Sulfur-Rich Polymers: Copolymerization of Episulfide with Carbon Disulfide by Using [PPN]Cl/(salph)Cr(III)Cl System
K. Nakano, G. Tatsumi, K. Nozaki
J. Am. Chem. Soc. 2007, 129, 15116–15117. 10.1021/ja076056b
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Synthesis, Structure of Borylmagnesium, and Its Reaction with Benzaldehyde to Form Benzoylborane
M. Yamashita, Y. Suzuki, Y. Segawa, K. Nozaki
J. Am. Chem. Soc. 2007, 129, 9570–9571. 10.1021/ja073037t highlighted in Nachrichten aus der Chemie
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Synthesis of alpha-Heteroarylpropanoic Acid via Asymmetric Hydroformylation Catalyzed by Rh(I)-(R,S)-BINAPHOS and the Subsequent Oxidation
R. Tanaka, K. Nakano, K. Nozaki
J. Org. Chem. 2007, 72, 8671–8676. 10.1021/jo0712190
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Boryl Anion Attacks Transition Metal Chlorides to Form Boryl Complexes: Syntheses, Spectroscopic and Structural Studies on Group 11 Borylmetal Complexes
Y. Segawa, M. Yamashita, K. Nozaki
Angew. Chem. Int. Ed. 2007, 46, 6710–6713. 10.1002/anie.200702369 highlighted in Nachrichten aus der Chemie
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Formation of linear copolymers of ethylene and acrylonitrile catalyzed by phosphine-sulfonate palladium complexes
T. Kochi, S. Noda, K. Yoshimura, K. Nozaki
J. Am. Chem. Soc. 2007, 129, 8948–8949. 10.1021/ja0725504 highlighted in Angewandte Chemie.
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Alternating Copolymerization of Vinyl Acetate with Carbon Monoxide
T. Kochi, A. Nakamura, H. Ida, K. Nozaki
J. Am. Chem. Soc. 2007, 129, 7770–7771. 10.1021/ja072859n highlighted in Angewandte Chemie.
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Regio-Regular Polymerization of Fluorine-Containing Epoxides
K. Sakakibara, K. Nakano, K. Nozaki
Macromolecules 2007, 40, 6136–6142. 10.1021/ma070428j
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Synthesis of Ladder-Type π-Conjugated Heteroacenes via Palladium-Catalyzed Double N-Arylation and Intramolecular O-Arylation.
K. Kawaguchi, K. Nakano, K. Nozaki
J. Org. Chem. 2007, 72, 5119–5128. 10.1021/jo070427p
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Boryllithium: Isolation, Characterization, and Reactivity as a Boryl Anion.
Y. Segawa, M. Yamashita, K. Nozaki
Science 2006, 314, 113–115. 10.1126/science.1131914 [full text] [abstract] highlighted in Science, Chemistry World, C&EN, Angewandte Chemie, Kagaku to Kogyo, and Nachrichten aus der Chemie
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Selective Formation of Polycarbonate over Cyclic Carbonate: Copolymerization of Epoxides with Carbon Dioxide Catalyzed by Cobalt(III) Complex with Piperidinium End-Capping Arm.
K. Nakano, T. Kamada, K. Nozaki
Angew. Chem. Int. Ed. 2006, 45, 7274–7277. 10.1002/anie.200603132
highlighted in Chemical & Engineering (2007, Nov. 16, pp 16).
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Syntheses and Structures of Bulky Monophosphine-ligated Methylpalladium Complexes - Application to Homo- and Co-Polymerization of Norbornene and/or Methoxycarbonylnorbornene.
M. Yamashita, I. Takamiya, K. Jin, K. Nozaki
Organometallics 2006, 25, 4588–4595. 10.1021/om060347w
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Asymmetric Hydroformylation of Vinylfurans Catalyzed by {(11bS)-4-{[(1R)-2'-Phosphino[1,1'-binaphthalen]-2-yl]oxy}dinaphtho[2,1-d:1',2'-f]-[1,3,2]dioxaphosphepin}rhodium(I) [RhI{(R,S)-binaphos}] Derivatives
K. Nakano, R. Tanaka, and K. Nozaki
Helv. Chim. Acta 2006, 89, 1681–1686. 10.1002/hlca.200690166
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Regio-Contorlled Ring-Opening Polymerization of Perfluoroalkyl-Substituted Epoxides
K. Sakakibara, K. Nakano, K. Nozaki
Chem. Commun. 2006, 3334–3336. 10.1039/b606693c
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Syntheses and Characterizations of Methylpalladium Complexes Bearing a Biphenyl-Based Bulky Phosphine Ligand: Weak Interactions Suggested by NBO and QTAIM Analyses
M. Yamashita, I. Takamiya, K. Jin, K. Nozaki
J. Organomet. Chem. 2006, 691, 3189–3195. 10.1016/j.jorganchem.2006.02.001
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Alternating Copolymerization of Fluoroalkenes with Carbon Monoxide
T. Fujita, K. Nakano, M. Yamashita, K. Nozaki
J. Am. Chem. Soc. 2006, 128, 1968–1975. 10.1021/ja055862k
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Synthesis of anionic methylpalladium complexes with phosphine–sulfonate ligands and their activities for olefin polymerization
T. Kochi, K. Yoshimura, K. Nozaki
Dalton Trans. 2006, 25–27. 10.1039/b512452m
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Stereospecific Synthesis of Hetero[7]helicenes via the Palladium-Catalyzed Double N-Arylation and Intramolecular O-Arylation
K. Nakano, Y. Hidehira, K. Takahashi, T. Hiyama, K. Nozaki
Angew. Chem. Int. Ed. 2005, 44, 7136–7138. 10.1002/anie.200502855
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Comparison of two preparative methods: a polymer-supported catalyst by metal-complexation with a polymeric ligand or by polymerization of a metal complex
S. Kinoshita, F. Shibahara, K. Nozaki
Green Chem. 2005, 7, 256–258. 10.1039/b418264b
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Asymmetric amplification in asymmetric alternating copolymerization of cyclohexene oxide and carbon dioxide
K. Nakano, T. Hiyama, K. Nozaki
Chem. Commun. 2005, 1871–1873. 10.1039/b417973k
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An Efficient Pd(II)-Based Catalyst System for Carboxylation of Aromatic C-H bond by Addition of a Phosphenium Salt.
K. Sakakibara, M. Yamashita, K. Nozaki
Tetrahedron Lett. 2005, 46, 959–962. 10.1016/j.tetlet.2004.12.027
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The Double N-Arylation of Primary Amines: Carbazole Synthesis from 2,2'-biphenyldiols.
A. Kuwahara, K. Nakano, K. Nozaki
J. Org. Chem. 2005, 70, 413–419. 10.1021/jo048472+
Selected as the most accessed article in 2005.
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A novel mild deprotection method for phosphine-boranes.
M. Schroeder, K. Nozaki, T. Hiyama
Bull. Chem. Soc. Jpn. 2004, 77, 1931–1932. 10.1246/bcsj.77.1931
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Synthesis of a polyester macromonomer via the cobalt-catalyzed alternating copolymerization of propylene oxide and carbon monoxide.
K. Nakano, F. Kondo, K. Nozaki
J. Polym. Sci., Part A: Polym. Chem. 2004, 42, 4666–4670. 10.1002/pola.20383
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Baeyer-Villiger Oxidation of an Optically Active 1,4-Polyketone.
N. Kosaka, T. Hiyama, K. Nozaki
Macromolecules 2004, 37, 4484–4487. 10.1021/ma0359638
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An alternative route to protected aldols: Cobalt-catalyzed hydroformylationof epoxides and in situ protection of β-hydroxyaldehydes by HC(OMe)3.
K. Nakano, M. Katayama, S. Ishihara, T. Hiyama, K. Nozaki
Synlett 2004, 1367–1370. 10.1055/s-2004-825620
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Palladium(II)-Catalyzed Sequential Hydroxylation-Carboxylation of Biphenyl Using Formic Acid as a Carbonyl Source.
F. Shibahara, S. Kinoshita, K. Nozaki
Org. Lett. 2004, 6, 2437–2439. 10.1021/ol049166l
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Synthesis and Photoisomerization of Optically Active 1,4-Polyketones Substituted by Azobenzene Side Chains.
N. Kosaka, T. Oda, T. Hiyama, K. Nozaki
Macromolecules 2004, 37, 4484–4487. 10.1021/ma0359638
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Hydroesterification of vinylarenes catalyzed by palladium complexes of dialkylmonoaryl- and monoalkyldiarylphosphines.
Y. Kawashima, K. Okano, K. Nozaki, T. Hiyama
Bull. Chem. Soc. Jpn. 2004, 77, 347–355. 10.1246/bcsj.77.347
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High-Pressure NMR Studies on the Alternating Copolymerization of Styrene with Carbon Monoxide Catalyzed by a Palladium(II)-(R,S)-BINAPHOS Complex.
J. A. Iggo, Y. Kawashima, J. Liu, T. Hiyama, K. Nozaki
Organometallics 2003, 22, 5418–5422. 10.1021/om0304917
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Liquid-crystalline Stereoregular Polyketone Prepared from a Mesogenic Vinylarene and Carbon Monoxide.
Y. Kawashima, K. Nozaki, T. Hiyama, M Yoshio, K. Kanie, T. Kato
J. Polym. Sci., Part A: Polym. Chem. 2003, 41, 3556–3563. 10.1002/pola.10843
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Conformational Studies on an Optically Active 1,4-Polyketone in Solution.
N. Kosaka, K. Nozaki, T. Hiyama
Macromolecules 2003, 36, 6884–6887. 10.1021/ma025979i
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Solvent-Free Asymmetric Olefin Hydroformylation Catalyzed by Highly Crosslinked Polystyrene-Supported (R,S)-BINAPHOS-Rh(I) Complex.
F. Shibahara, K. Nozaki, T. Hiyama
J. Am. Chem. Soc. 2003, 125, 8555–8560. 10.1021/ja034447u
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The Double N-arylation of Primary Amines: A New Synthetic Strategy toward Carbazoles with Unique Optical Properties.
K. Nozaki, K. Takahashi, K. Nakano, T. Hiyama, H.-Z. Tang, M. Fujiki, S. Yamaguchi, K. Tamao
Angew. Chem. Int. Ed. 2003, 42, 2051–2053. 10.1002/anie.200250648
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Asymmetric Alternating Copolymerization of Cyclohezene Oxide and CO2 with Dimeric Zinc Complexes.
K. Nakano, K. Nozaki, T. Hiyama
J. Am. Chem. Soc. 2003, 125, 5501–5510. 10.1021/ja028666b
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Asymmetric Terpolymerization of Styrene or Its Derivative and Aliphatic 1-Alkenes with CO Catalyzed by Pd-(R,S)-BINAPHOS.
Y. Kawashima, K. Nozaki, T. Hiyama
Inorg. Chim. Acta 2003, 350, 577–582. 10.1016/S0020-1693(02)01542-6
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High Pressure IR Studies on the Asymmetric Hydroformylation of Styrene Catalyzed by Rh(I)-(R,S)-BINAPHOS'es.
K. Nozaki, T. Matsuo, F. Shibahara, T. Hiyama
Organometallics 2003, 22, 594–600. 10.1021/om020245f
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Carbon-Monoxide Free Aminocarbonylation of Organic Halides Using DMF as an Amide Source.
K. Hosoi, K. Nozaki, T. Hiyama
Org. Lett. 2002, 4, 2849–2851. 10.1021/ol026236k
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Palladium-catalyzed cross-coupling reaction using alkenyldimethyl(2-thienyl)silanes.
K. Hosoi, K. Nozaki, T. Hiyama
Proc. Jpn. Acad., Ser. B 2002, 78, 154–160.
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Asymmetric Hydroformylation with Highly Crosslinked Polystyrene-Supported (R,S)-BINAPHOS-Rh(I) Complexes: The Effect of Immobilization Positions.
F. Shibahara, K. Nozaki, T. Matsuo, T. Hiyama
Bioorg. Med. Chem. Lett. 2002, 12, 1825–1827. 10.1016/S0020-1693(02)01542-6
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Methylenation of Optically Active γ-Polyketones.
K. Nozaki, N. Kosaka, V. M. Graubner, T. Hiyama
Polymer J. 2002, 34, 376–382. 10.1295/polymj.34.376
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Alkenyldimethyl(2-thienyl)silanes, Excellent Coupling Partner for the Palladium-Catalyzed Cross-Coupling Reaction.
K. Hosoi, K. Nozaki, T. Hiyama
Chem. Lett 2002, 138–139. 10.1246/cl.2002.138
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Synthesis and Liquid Crystalline Behavior of Stereoregular Polyketones with Mesogenic Side Chains.
K. Nozaki, Y. Kawashima, T. Oda, T. Hiyama, K. Kanie, T. Kato
Macromolecules 2002, 35, 1140–1142. 10.1021/ma0113125
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Asymmetric Synthesis of Optically Active Polymers with Main-Chain Chirality.
Kyoko Nozaki
Kobunshironbunshu 2001, 58, 375–381.
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Spectral Assignment of Poly[Cyclohexene Oxide-alt-Carbon Dioxide].
K. Nakano, K. Nozaki, T. Hiyama
Macromolecules 2001, 34, 6325–6332. 10.1021/ma010732r
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Methylenation of an Optically Active γ-Polyketone: Synthesis of a New Class of Hydrocarbon Polymers with Main-Chain Chirality.
K. Nozaki, N. Kosaka, V. M. Graubner, T. Hiyama
Macromolecules 2001, 34, 6167–6168. 10.1021/ma0107713
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Alternating Copolymerization of ω-Perfluoroalkyl-1-alkenes with Carbon Monoxide Catalyzed by Homogeneous and Polymer-Supported Pd-Complexes.
K. Nozaki, F. Shibahara, S. Elzner, T. Hiyama
Can. J. Chem. 2001, 593–597. 10.1139/v01-073
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Solid Phase Cross-coupling Reaction of Aryl(halo)silanes with 4-Iodobenzoic Acid.
F. Homsi, K. Hosoi, K. Nozaki, T. Hiyama
J. Organomet. Chem. 2001, 624, 208–216. 10.1016/S0022-328X(01)00664-7
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Substituent Effect in Asymmetric Hydroformylation of Olefins Catalyzed by Rhodium(I) Complexes of (R,S)-BINAPHOS Derivatives: A Protocol for Improvement of Regio- and Enantioselectivities.
K. Nozaki, T. Matsuo, F. Shibahara, T. Hiyama
Adv. Syn. Catal. 2001, 343, 61–63. 10.1002/1615-4169(20010129)343:1%3C61::AID-ADSC61%3E3.0.CO;2-L
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Predominant 1,2-Insertion of Styrene in the Pd-Catalyzed Alternating Copolymerization with Carbon Monoxide.
K. Nozaki, H. Komaki, Y. Kawashima, T. Hiyama, T. Matsubara
J. Am. Chem. Soc. 2001, 123, 534–544. 10.1021/ja001395p
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Asymmetric Reduction of an Enantiomerically pure γ-polyketone.
K .Nozaki, N. Kosaka, S. Muguruma, T. Hiyama
Macromolecules 2000, 33, 5340–5346. 10.1021/ma000424d
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Solid Phase Cross-Coupling Reactions of Aryl(fluoro)silanes with 4-iodobenzoic acid.
F. Homsi, K. Nozaki, T. Hiyama
Tetrahedron Lett. 2000, 41, 5869–5872. 10.1016/S0040-4039(00)00789-9
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Vapor-Phase Asymmetric Hydroformylation.
K. Nozaki, F. Shibahara, T. Hiyama
Chem. Lett. 2000, 694–695. 10.1246/cl.2000.694
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High Pressure NMR Studies on the Alternating Copolymerization of Propene with Carbon Monoxide Catalyzed by a Palladium(II) Complex of an Unsymmetrical Phosphine-Phosphite.
K. Nozaki, T. Hiyama, S. Kacker, I. T. Horvah
Organometallics 2000, 19, 2031–2035. 10.1021/om990985x
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Practical Stereoselective Synthesis of (2,3,4,5-Tetrahydro-1H-Benzo[b]azepin-5-yl)acetic Acid.
T. Shinohara, K. Kondo, H. Ogawa, T. Mori, K. Nozaki, T. Hiyama
Chirality 2000, 12, 425–430. 10.1002/(SICI)1520-636X(2000)12:5/6%3C425::AID-CHIR23%3E3.0.CO;2-E
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Optically Active Polycarbonates: Asymmetric Alternating Copolymerization of Cyclohexene Oxide with Carbon Dioxide.
K. Nozaki, K. Nakano, T. Hiyama
J. Am. Chem. Soc. 1999, 121, 11008–11009. 10.1021/ja992433b
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Alternating Copolymerization of Various Alkenes with Carbon Monoxide Using a Cationic Pd(II) Complexes of (R,S)-BINAPHOS as an Initiator.
K. Nozaki, Y. Kawashima, K. Nakamoto, T. Hiyama
Polymer J. 1999, 31, 1057–1060. 10.1295/polymj.31.1057
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Asymmetric Hydroformylation of Olefins in Highly Crosslinked Polymer Matrixes.
K. Nozaki, F. Shibahara, Y. Itoi, T. Ohta, H. Takaya, T. Hiyama
Bull Chem. Soc. Jpn. 1999, 72, 1911–1918. 10.1246/bcsj.72.1911
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Asymmetric Terpolymerization of Propene, Vinylarene, and Carbon Monoxide.
K. Nozaki, Y. Kawashima, K. Nakamoto, T. Hiyama
Macromolecules 1999, 32, 5168–5170. 10.1021/ma9902807
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A Chiral Bometallic Lewis Acid as a Reaction Template. Asymmetric Reduction of Unsymmetric Ketones with LiBH4.
K. Nozaki, K. Kobori, T. Uemura, T. Tsutsumi, H. Takaya, T. Hiyama
Bull. Chem. Soc. Jpn. 1999, 72, 1109–1113. 10.1246/bcsj.72.1109
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Asymmetric Hydroformylation of Olefins in a Highly Crosslinked Polymer Matrix.
K. Nozaki, Y. Itoi, F. Shibahara, E. Shirakawa, T. Ohta, H. Takaya, T. Hiyama
J. Am. Chem. Soc. 1998, 120, 4051–4052. 10.1021/ja973408d
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Double Helical Oligo Esters: Chiral Twist of Two Aromatic Ester Chains.
K. Nozaki, T. Terakawa, H. Takaya, T. Hiyama
Angew. Chem., Int. Ed. Engl. 1998, 37, 131–133. 10.1002/(SICI)1521-3773(19980202)37:1/2<131::AID-ANIE131>3.0.CO;2-K
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Chiral and achiral phosphine phosphite ligands in Pd(II)-catalyzed alternating copolymerization of propene with CO.
K. Nozaki, M. Yasutomi, K. Nakamoto, T. Hiyama
Polyhedron 1998, 17, 1159–1164. 10.1016/S0277-5387(97)00503-2
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Mechanistic Aspects of the Alternating Copolymerization of Propylene with Carbon Monoxide Catalyzed by Pd(II) Complexes of Unsymmetrical Phosphine-phosphite Ligands.
K. Nozaki, N. Sato, Y. Tonomura, M. Yasutomi, H. Takaya, T. Hiyama
J. Am. Chem. Soc. 1997, 119, 12779–12793. 10.1021/ja973199x
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Cyclic Polyamides Consisting of 1,1'-Binaphthyls. "Chiral Twist" of Glycine Residues.
K. Nozaki, T. Terakawa, H. Takaya, T. Hiyama
Tetrahedron: Asymmetry 1997, 8, 3430–3436. 10.1016/S0957-4166(97)00460-6
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Asymmetric Hydroformylation of Allylic Alcohols Catalyzed by Rh(I) (R,S)-BINAPHOS.
K. Nozaki, W. G. Li, T. Horiuchi, H. Takaya
Tetrahedron Lett. 1997, 38, 4611–4614. 10.1016/S0040-4039(97)00988-X
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Asymmetric Hydroformylation of Hetrocyclic Olefins Catalyzed by Chiral Phosphine Phosphite Rh(I) Complex.
T. Horiuchi, T. Ohta, E. Shirakawa, K. Nozaki, H. Takaya
J. Org. Chem. 1997, 62, 4285–4292. 10.1021/jo9624051
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Mechanistic Aspects of Asymmetric Hydroformylation of Olefins Catalyzed by Chiral Phosphine-Phosphite Rh(I) Complexes.
T. Horiuchi, E. Shirakawa, K. Nozaki, H. Takaya
Organometallics 1997, 16, 2981–2986. 10.1021/om970134u
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Asymmetric Hydroformylation of Conjugated Dienes Catalyzed by Chiral Phosphine Phosphite Rh(I) Complex.
T. Horiuchi, T. Ohta, E. Shirakawa, K. Nozaki, H. Takaya
Tetrahedron 1997, 53, 7795–7804. 10.1016/S0040-4020(97)00471-7
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Highly Enantioselective Hydroformylation of Olefins Catalyzed by Rhodium(I) Complexes of New Chiral Phosphine-Phosphite Ligands.
K. Nozaki, N. Sakai, T. Higashijima, S. Mano, T. Horiuchi, H. Takaya
J. Am. Chem. Soc. 1997, 119, 4413–4423. 10.1021/ja970049d
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Hydroestrification of Styrene Catalyzed by Montmorillonite diphenylphosphinepalladium(II) Chloride in the Presence of Chiral Phosphines.
K. Nozaki, M. L. Kantam, T. Horiuchi, H. Takaya
J. Mol. Catal. A. 1997, 118, 247–253. 10.1016/S1381-1169(96)00385-8
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Cyclocopolymerization of α,ω-Dienes with Carbon Monoxide Catalyzed by (R,S)-BINAPHOS Pd(II).
K. Nozaki, N. Sato, K. Nakamoto, H. Takaya
Bull. Chem. Soc. Jpn. 1997, 70, 659–664. 10.1246/bcsj.70.659
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Synthesis of (R)-2-diphenylphosphino-2'-diphenylphosphinomethyl-1,1'-binaphthyl and its use for asymmetric hydrogenation of α-alkylstyrenes.
K. Inagaki, T. Ohta, K. Nozaki, H. Takaya
J. Organomet. Chem. 1997, 531, 159–163. 10.1016/S0022-328X(96)06712-5
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Asymmetric Michael Reaction of α-Cyano Esters by Chiral Rh(I) Complex with a New Optically Active Bisphosphine Ligand.
K. Inagaki, K. Nozaki, H. Takaya
Synlett 1997, 119–120. 10.1055/s-1997-712
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Asymmetric Hydroformylation Catalyzed by a Rh(I) (R,S)-BINAPHOS Complex: Substituent Effects in Olefins on the Regioselectivity.
K. Nozaki, T. Nanno, H. Takaya
J. Organomet. Chem. 1997, 527, 103–108. 10.1016/S0022-328X(96)06620-X
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(R,S)-BINAPHOS Ni(0) and Pd(0) Complexes: Characterization and Their Use for Asymmetric Hydrocyanation of Norbornene.
T. Horiuchi, E. Shirakawa, K. Nozaki, H. Takaya
Tetrahedron: Asymmetry 1997, 8, 57–63. 10.1016/S0957-4166(96)00483-1
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New Stereocontrolled Approach to 1β-Methylcarbapenem: Asymmetric Hydroformylation of 4-Vinyl-β-lactams Catalyzed by Rh(I) Complexes of Chiral Phosphine-phosphites and Phosphine-phosphinites.
K. Nozaki, W.-g. Li, T. Horiuchi, H. Takaya, T. Saito, A, Yoshida, K. Matsumura, Y. Kato, T. Imai, T. Miura, H. Kumobayashi
J. Org. Chem. 1996, 61, 7658–7659. 10.1021/jo961689m
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Highly Efficient Enantioselective Synthesis of Optically Active Carboxylic Acids by Ru(OCOCH3)2[(S)-H8-BINAP].
T. Uemura, X. Zhang, K. Matsumura, N. Sayo, H. Kumobayashi, T. Ohta, K. Nozaki, H. Takaya
J. Org. Chem. 1996, 61, 5510–5516. 10.1021/jo960426p
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Synthesis of Highly Functionalized γ-Butyrolactones from Activated Carbonyl Compounds and Dimethyl Acetylenedicarboxylate.
K. Nozaki, N. Sato, K. Ikeda, H. Takaya
J. Org. Chem. 1996, 61, 4516–4519. 10.1021/jo951828k
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Chiral Bimetallic Boronic Esters: A Donor Acceptor Coexisting Receptor for Amines.
K. Nozaki, M. Yoshida, H. Takaya
Bull. Chem. Soc. Jpn. 1996, 69, 2043–2052. 10.1246/bcsj.69.2043
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Palladium-Catalyzed Acylcyanation of Terminal Arylacetylenes. Synthesis of 1,3-Diaryl-3-cyano-2-propen-1-ones and Tetrasubstituted Furans.
K. Nozaki, N. Sato, H. Takaya
Bull. Chem. Soc. Jpn. 1996, 69, 1629–1637. 10.1246/bcsj.69.1629
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Anionic Dinuclear BINAP-Ru(II) Complex: Crystal Structure of [NH2Et2][{RuCl(R)-p-MeO-binap)}2(μ-Cl)3]and Its Use for Asymmetric Hydrogenation.
T. Ohta, Y. Tonomura, K. Nozaki, H. Takaya
Organometallics 1996, 15, 1521–1523. 10.1021/om9508905
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Asymmetric Hydroformylation of Conjugated Dienes Catalyzed by [(R)-2-diphenylphosphino-1,1'-dinaphthalen-2'-yl][(S)-1,1'-dinaphthalene-2,2'-diyl]phosphite-rhodium(I).
T. Horiuchi, T. Ohta, K. Nozaki, H. Takaya
Chem. Commun. 1996, 155–156. 10.1039/CC9960000155
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Asymmetric Hydroformylation of Sulfur-Containing Olefins Catalyzed by BINAPHOS-Rh(I) Complexes.
T. Nanno, N. Sakai, K. Nozaki, H. Takaya
Tetrahedron: Asymmetry 1995, 6, 2583–2591. 10.1016/0957-4166(95)00339-Q
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Selective Binding of Diamines to a Chiral Lewis Acid with Two Boron Centers.
K. Nozaki, T. Tsutsumi, H. Takaya
J. Org. Chem. 1995, 60, 6668–6669. 10.1021/jo00126a009
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Highly Enantioselective Alternating Copolymerization of Propene with Carbon Monoxide Catalyzed by a Chiral Phosphine-Phosphite Complex of Palladium(II).
K. Nozaki, N. Sato, H. Takaya
J. Am. Chem. Soc. 1995, 117, 9911–9912. 10.1021/ja00144a018
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A Chiral Lewis Acid with Two "Metal" Centers: Cooperative Binding of Two Amine Molecules to a Chiral Diboronic Ester.
K. Nozaki, M. Yoshida, H. Takaya
Angew. Chem., Int. Ed. Engl. 1994, 33, 2452–2454. 10.1002/anie.199424521
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Cationic BINAP-Ru(II) Halide Complexes: Highly Efficient Catalysts for Stereoselective Asymmetric Hydrogenation of a- and b-Functionalized Ketones.
K. Mashima, K. Kusano, Y. Matsumura, N. Sato, K. Nozaki, H. Kumobayashi, N. Sayo, Y. Hori, T. Ishizaki, S. Akutagawa, H. Takaya
J. Org. Chem. 1994, 59, 3064–3076. 10.1021/jo00090a026
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Acylcyanation of Terminal Acetylenes: Palladium Catalyzed Addition of Aryloyl Cyanides to Arylacetylenes
K. Nozaki, N. Sato, H. Takaya
J. Org. Chem. 1994, 59, 2679–2681. 10.1021/jo00089a006
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Reaction Rate Enhancement by Addition of Anionic Surfactant SDS in the Ruthenium Catalyzed Hydrogen Transfer from a 1,4-Diols to 4-Phenyl-3-buten-2-one.
K. Nozaki, M. Yoshida, H. Takaya
J. Organomet. Chem. 1994, 473, 253–256. 10.1016/0022-328X(94)80125-8
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Synthesis of New Chiral Phosphinephosphites Having 2-Diphenyl-phosphinobiphenyl-2'-yl Backbone and Their Use in Rh(I) Catalyzed Asymmetric Hydroformylations.
T. Higashijima, N. Sakai, K. Nozaki, H. Takaya
Tetrahedron Lett. 1994, 35, 2023–2026. 10.1016/S0040-4039(00)73039-5
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Asymmetric Hydroformylation of 1,2-Di-substituted Olefins Catalyzed by Chiral Phosphinephosphite-Rh(I) Complexes.
N. Sakai, K. Nozaki and H. Takaya
J. Chem. Soc., Chem. Commun. 1994, 395–396. 10.1039/C39940000395
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Enantioselective Synthesis of L- and D-Isoserine via Asymmetric Hydrogenation of Methyl N-Phthaloyl-3-amino-2-oxopropanoate.
K. Nozaki, N. Sato, H. Takaya
Tetrahedron: Asymmetry 1993, 4, 2179–2182. 10.1016/S0957-4166(00)80068-3
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Highly Enantioselective Hydroformylation of Olefins Catalyzed by New Phosphinephosphite-Rh(I) Complexes.
N. Sakai, S. Mano, K. Nozaki, H. Takaya
J. Am. Chem. Soc. 1993, 115, 7033–7034. 10.1021/ja00068a095
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Asymmetric Hydroformylation of Vinyl Acetate By Use of Chiral Bis(triarylphosphite)-Rhodium(I) Complexes.
N. Sakai, K. Nozaki, K. Mashima, H. Takaya
Tetrahedron: Asymmetry 1992, 3, 583–586. 10.1016/S0957-4166(00)82286-7
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Isomerization of Olefins by Means of R3SnH-Et3B and Stereochemical Study on Reduction of Alkenyl Iodides.
M. Taniguchi, K. Nozaki, K. Miura, K. Oshima and K. Utimoto
Bull. Chem. Soc. Jpn. 1992, 65, 349–353. 10.1246/bcsj.65.349
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Triethylborane Induced 1,4-Reduction of α,β-Unsaturated Carbonyl Compounds with Triphenyltin Hydride or Tributyltin Hydride.
K. Nozaki, K. Oshima, K. Utimoto
Bull. Chem. Soc. Jpn. 1991, 64, 2585–2587. 10.1246/bcsj.64.2585
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Palladium Catalyzed Reaction of Silacyclobutanes with Acetylenes.
Y. Takeyama, K. Nozaki, K. Matsumoto, K. Oshima, K. Utimoto
Bull. Chem. Soc. Jpn. 1991, 64, 1461–1466. 10.1246/bcsj.64.1461
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Trialkylborane as an Initiator and Terminator of Free Radical Reactions: Facile Routs to Boron Enolates via a-Carbonyl Radicals and Aldol Reaction of Boron Enolates.
K. Nozaki, K. Oshima, K. Utimoto
Bull. Chem. Soc. Jpn. 1991, 64, 403–409. 10.1246/bcsj.64.403
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On the Mechanism of Lewis Acid Mediated Nucleophilic Substitution Reactions of Acetals.
I. Mori, K. Ishihara, L. A. Flippin, K. Nozaki, H. Yamamoto, P. A. Bartlett, C. H. Heathcock
J. Org. Chem. 1990, 55, 6107–6115. 10.1021/jo00312a015
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Triethylborane Induced Perfluoroalkylation of Silyl Enol Ethers or Germyl Enol Ethers with Perfluoroalkyl Iodides.
K. Miura, M. Taniguchi, K. Nozaki, K. Oshima, K. Utimoto
Tetrahedron Lett. 1990, 31, 6391–6394. 10.1016/S0040-4039(00)97073-4
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Facile Reduction of Dithiocarbonates Derived from Secondary Alcohols with n-Bu3SnH-Et3B and Synthesis of 2-Furanthiones and 2-Furanones by Intramolecular Addition of Alkoxythiocarbonyl Free Radicals to Acetylenic Lincages.
K. Nozaki, K. Oshima, K. Utimoto
Bull. Chem. Soc. Jpn. 1990, 63, 2578–2583. 10.1246/bcsj.63.2578
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Et3B-Induced Stereoselective Radical Addition of Ph3GeH to Carbon-Carbon Multiple Bonds and Its Application to Isomerization of Olefins.
K. Nozaki, Y. Ichinose, K. Wakamatsu, K. Oshima, K. Utimoto
Bull. Chem. Soc. Jpn. 1990, 63, 2268–2272. 10.1246/bcsj.63.2268
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Et3B-Induced Radical Addition of Ph3SnH to Acetylenes and Its Application to Cyclization Reaction.
K. Nozaki, K. Oshima, K. Utimoto
Tetrahedron 1989, 45, 923–933. 10.1016/0040-4020(89)80004-3
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Et3B-Induced Hydrodehalogenation of Organic Halides by Tin Hydrides.
K. Miura, Y. Ichinose, K. Nozaki, K. Fugami, K. Oshima, K. Utimoto
Bull. Chem. Soc. Jpn. 1989, 62, 143–147. 10.1246/bcsj.62.143
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Synthesis of Lactones by Intramolecular Addition of Alkoxythiocarbonyl Free Radicals to Acetylenes.
K. Nozaki, K. Oshima, K. Utimoto
Tetrahedron Lett. 1988, 29, 6127–6128. 10.1016/S0040-4039(00)82284-4
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Facile Reduction of Dithiocarbonates with n-Bu3SnH-Et3B: Easy Access to Hydrocarbons from Secondary Alcohols.
K. Nozaki, K. Oshima, K. Utimoto
Tetrahedron Lett. 1988, 29, 6125–6126. 10.1016/S0040-4039(00)82283-2
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Facile Routes to Boron Enolates: Et3B-Mediated Reformatsky Type Reaction and Three-Component Coupling Reaction of Alkyl Iodides, Methyl Vinyl Ketone, and Carbonyl Compounds.
K. Nozaki, K. Oshima, K. Utimoto
Tetrahedron Lett. 1988, 29, 1041–1044. 10.1016/0040-4039(88)85330-9
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Synthesis of α-Methylene-γ-butyrolactones via Addition of Tin Hydride to Enynes Induced by Triethylborane.
K. Nozaki, K. Oshima, K. Utimoto
Bull. Chem. Soc. Jpn. 1987, 60, 3465–3467. 10.1246/bcsj.60.3465
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Et3B-Induced Radical Addition of Thiols to Acetylenes.
Y. Ichinose, K. Wakamatsu, K. Nozaki, J.-L. Birbaum, K. Oshima, K. Utimoto
Chem. Lett. 1987, 1647–1650. 10.1246/cl.1987.1647
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Et3B-Induced Stereoselective Radical Addition of Ph3GeH to Carbon-Carbon Multiple Bonds and Its Application to Isomerization of Olefins.
Y. Ichinose, K. Nozaki, K. Wakamatsu, K. Oshima, K. Utimoto
Tetrahedron Lett. 1987, 28, 3709–3712. 10.1016/S0040-4039(00)96363-9
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Et3B-Induced Radical Addition of R3SnH to Acetylenes and Its Application to Cyclization Reaction.
K. Nozaki, K. Oshima, K. Utimoto
J. Am. Chem. Soc. 1987, 109, 2547–2549. 10.1021/ja00242a068
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Transition-Metal Catalyzed Regioselective Addition of PhMe2SiBEt3Li and Bu3SnBEt3Li to Acetylenic Compounds in the Presence of Methanol.
K. Nozaki, K. Wakamatsu, T. Nonaka, W. Tukmantel, K. Oshima, K. Utimoto
Tetrahedron Lett. 1986, 27, 2007–2010. 10.1016/S0040-4039(00)84434-2