Publications (Dr. Takahashi)

  1. Nickel-Catalyzed C(sp3)−O Hydrogenolysis via a Remote Concerted Oxidative Addition and its Application to Degradation of a Bisphenol A-Based Epoxy Resin
    Y. Liao, K. Takahashi, K. Nozaki
    J. Am. Chem. Soc. in press. 10.1021/jacs.3c09061
    ChemRxiv 2023 (preprint) 10.26434/chemrxiv-2023-dz9v9-v2
  2. Synthesis of novel polymers with biodegradability from propylene and carbon monoxide
    H. Yuan, K. Takahashi, S. Hayashi, M. Suzuki, N. Fujikake, K. Kasuya, J. Zhou, S. Nakagawa, N. Yoshie, C. Li, K. Yamaguchi, K. Nozaki
    ChemRxiv 2023 (preprint) 10.26434/chemrxiv-2023-wj0p6
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  4. Nickel-Catalyzed Selective Incorporation of Isolated In-Chain Carbonyls into Ethylene/Carbon Monoxide Copolymer Using Metal Carbonyls as a Carbonyl Source
    G. Yonezaki, F. Seidel, K. Takahashi, K. Nozaki
    Bull. Chem. Soc. Jpn. 2023, 96, 545–549. 10.1246/bcsj.20230073 Selected as a Selected Paper. Featured on Back Cover Picture.
  5. Catalytic Synthesis of a Methylmalonate Salt from Ethylene and Carbon Dioxide through Photoinduced Activation and Photoredox-Catalyzed Reduction of Nickelalactones
    K. Takahashi, Y. Sakurazawa, A. Iwai, N. Iwasawa
    ACS Catal. 2022, 12, 3776–3781. 10.1021/acscatal.2c01053
  6. 2-Quinolyl Benzodiazaborine: A Tunable Platform for Aggregation‐Induced Emission Luminogens via Formation of Dimeric Borate Crystals with Acid Additives
    S. Shimo, T. Nakamura, K. Takahashi, N. Toriumi, N. Iwasawa
    ChemPhotoChem 2022, 6, e202100195. 10.1002/cptc.202100195
  7. Reversible C–C Double Bond Cleavage to Form a Metal Carbene and an Alkene Enabled on an Iridium Complex Bearing a Pincer-type Alkoxycarbene Ligand
    K. Takahashi, N. Iwasawa
    Organometallics 2021, 40, 3926–3934. 10.1021/acs.organomet.1c00498
  8. Supramolecular Photocatalysis by Utilizing the Host-Guest Charge-Transfer Interaction: Visible-Light-Induced Generation of Triplet Anthracenes for [4+2] Cycloaddition Reactions
    T. Uchikura, M. Oshima, M. Kawasaki, K. Takahashi, N. Iwasawa
    Angew. Chem. Int. Ed. 2020, 59, 7403–7408. 10.1002/anie.201916732
  9. Mechanistic Investigations of the Ruthenium-Catalyzed Synthesis of Acrylate Salt from Ethylene and CO2
    K. Takahashi, Y. Hirataka, T. Ito, N. Iwasawa
    Organometallics 2020, 39, 1561–1572. 10.1021/acs.organomet.9b00659
  10. Development of N-Phosphinomethyl-Substituted NHC-Nickel(0) Complexes as Robust Catalysts for Acrylate Salt Synthesis from Ethylene and CO2
    K. Takahashi, K. Cho, A. Iwai, T. Ito, N. Iwasawa
    Chem. Eur. J. 2019, 25, 13504–13508. 10.1002/chem.201903625
  11. Self-Assembly of Macrocyclic Boronic Esters Bearing Tellurophene Moieties and Their Guest-Responsive Phosphorescence
    K. Takahashi, S. Shimo, E. Hupf, J. Ochiai, C. A. Brau, W. Delgado, L. Xu, G. He, E. Rivard, N. Iwasawa
    Chem. Eur. J. 2019, 25, 8479–8483. 10.1002/chem.201901319
  12. 1,2-Dihydro-1-hydroxy-2,3,1-benzodiazaborine Bearing an Acridine Moiety as a Circular Dichroism Probe for Determination of Absolute Configuration of Mono-Alcohols
    S. Shimo, K. Takahashi, N. Iwasawa
    Chem. Eur. J. 2019, 25, 3790–3794. 10.1002/chem.201900350
  13. Reactivity of a Ruthenium(0) Complex Bearing a Tetradentate Phosphine Ligand: Applications to Catalytic Acrylate Salt Synthesis from Ethylene and CO2
    T. Ito, K. Takahashi, N. Iwasawa
    Organometallics 2018, 38, 205–209. 10.1021/acs.organomet.8b00789
  14. Dynamic Interconversion between Boroxine Cages Based on Pyridine Ligation
    K. Ono, S. Shimo, K. Takahashi, N. Yasuda, H. Uekusa, N. Iwasawa
    Angew. Chem. Int. Ed. 2018, 57, 3113–3117. 10.1002/anie.201713221
  15. Utilization of Donor–Acceptor Interactions for the Catalytic Acceleration of Nucleophilic Additions to Aromatic Carbonyl Compounds
    T. Uchikura. K. Ono, K. Takahashi, N. Iwasawa
    Angew. Chem. Int. Ed. 2018, 57, 2130–2133. 10.1002/anie.201711726
  16. Ruthenium Catalyzed Hydrogenation of Aldehyde with Synthesis Gas
    K. Takahashi, K. Nozaki
    Org. Lett. 2014, 16, 5846–5849. 10.1021/ol502681y
  17. Tandem Isomerization/Hydroformylation/Hydrogenation of Internal Alkenes to normal-Alcohols Using Rh/Ru Dual or Ternary Catalyst Systems
    Y. Yuki, K. Takahashi, Y. Tanaka, K. Nozaki
    J. Am. Chem. Soc. 2013, 135, 17393–17400. 10.1021/ja407523j
  18. Tandem Hydroformylation/Hydrogenation of Alkenes to normal-Alcohols Using Rh/Ru Dual Catalyst or Ru Single Component Catalyst
    K. Takahashi, M. Yamashita, K. Nozaki
    J. Am. Chem. Soc. 2012, 134, 18746–18757. 10.1021/ja307998h
  19. CpRu/C5Me5/Bisphosphine- or Bisphosphite-Based Catalysts for normal-Selective Hydroformylation
    K. Takahashi, M. Yamashita, Y. Tanaka, K. Nozaki
    Angew. Chem. Int. Ed. 2012, 51, 4283–4387. 10.1002/anie.201108396
  20. High-Yielding Tandem Hydroformylation/Hydrogenation of a Terminal Olefin to Produce a Linear Alcohol Using a Rh/Ru Dual Catalyst System
    K. Takahashi, M. Yamashita, T. Ichihara, K. Nakano, K. Nozaki
    Angew. Chem. Int. Ed. 2010, 49, 4488–4490. 10.1002/anie.201001327 selected as an outside cover, highlighted in ChemCatChem, highlighted at the following blogs, NNNS chemistry blog, ユーキの有機化学Hot Topics

Review articles

  1. パラジウム触媒を用いた芳香族のC–H結合亜鉛化反応
    K. Takahashi
    月刊化学, 化学同人, 2021.
  2. 一酸化炭素のC–O結合の開裂を伴うボロン酸エステルの合成法
    K. Takahashi
    Organometallic News, 近畿化学協会有機金属部会, 2021.
  3. オレフィンのヒドロホルミル化
    K. Takahashi, K. Nozaki
    有機合成のための新触媒反応101, 有機合成化学協会, 2021.
  4. パラジウムによるアミナールのC–N結合切断とアルケン類からの触媒的アミン合成への応用
    K. Takahashi
    有機合成化学協会誌, 有機合成化学協会, 75, 1055–1056 (2017).
  5. Hydroformylation of Epoxides
    K. Takahashi, K. Nozaki
    C-1 Building Blocks in Organic Synthesis 2, Science of Synthesis, Thieme, 207–217 (2014).
  6. ヒドロホルミル化
    K. Takahashi, K. Nozaki
    触媒調製ハンドブック, NTS出版, 370–374 (2011).