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PUBLICATION

2012 2011 2010 2009 2008 2007 2006 2005 2004 2003 2002 2001 2000

2012

Journal

  1. Efficient [WO4]2--Catalyzed Chemical Fixation of Carbon Dioxide with 2-Aminobenzonitriles to Quinazoline-2,4(1H,3H)-diones
    T. Kimura, H. Sunaba, K. Kamata, N. Mizuno,
    Inorg. Chem., 51, 13001-13008 (2012).
    DOI: 10.1021/ic302110a Publication Date: 2012/11/13
  2. Synthesis and Reversible Transformation of Cun -Bridged (n = 1, 2, or 4) Silicodecatungstate Dimers
    K. Suzuki, M. Shinoe, N. Mizuno,
    Inorg. Chem., 51, 11574-11581 (2012).
    DOI: 10.1021/ic301488a Publication Date: 2012/10/19
  3. Facile synthesis of nitriles via manganese oxide promoted oxidative dehydrosulfurization of primary thioamides
    K. Yamaguchi, K. Yajima, N. Mizuno,
    Chem. Commun., 48, 11247-11249 (2012).
    DOI: 10.1039/C2CC36635E Publication Date: 2012/10/03
  4. Oxygen rocking aqueous batteries utilizing reversible topotactic oxygen insertion/extraction in iron-based perovskite oxides Ca1-xLaxFeO3-δ
    M. Hibino, T. Kimura, Y. Suga, T. Kudo, N. Mizuno,
    Sci. Rep. 2, 601 (2012).
    DOI: 10.1038/srep00601 Publication Date: 2012/08/24
  5. Rhodium acetate/base-catalyzed N-silylation of indole derivatives with hydrosilanes
    S. Itagaki, K. Kamata, K. Yamaguchi, N. Mizuno,
    Chem. Commun., 48, 9269-9271 (2012).
    DOI: 10.1039/c2cc34381a Publication Date: 2012/07/26
  6. A Green Synthetic Route to Imides from Terminal Alkynes and Amides by Simple Solid Catalysts
    X. Jin, K. Yamaguchi, N. Mizuno,
    Chem. Lett., 41, 866-867 (2012).
    DOI: 10.1246/cl.2012.866 Publication Date: 2012/08/11
  7. Highly Selective Sorption and Separation of CO2 from a Gas Mixture of CO2 and CH4 at Room Temperature by a Zeolitic Organic-Inorganic Ionic Crystal and Investigation of the Interaction with CO2
    R. Eguchi, S. Uchida, N. Mizuno,
    J. Phys. Chem. C, 116, 16105-16110 (2012).
    DOI: 10.1021/jp305890s Publication Date: 2012/07/10
  8. Structural and Dynamical Aspects of Alkylammonium Salts of a Silicodecatungstate as Heterogeneous Epoxidation Catalysts
    S. Uchida, K. Kamata, Y. Ogasawara, M. Fujita, N. Mizuno,
    Dalton Trans., 41, 9979-9983 (2012)
    DOI: 10.1039/C2DT30492A Publication Date: 2012/04/30
  9. A Highly Negatively Charged γ-Keggin Germanodecatungstate Efficient for Knoevenagel Condensation
    K. Sugahara, T. Kimura, K. Kamata, K. Yamaguchi, N. Mizuno,
    Chem. Commun., 48, 8422-8424 (2012)
    DOI: 10.1039/C2CC33839D Publication Date: 2012/07/02
  10. Reactive N-Protonated Isocyanate Species Stabilized by Bis(μ-hydroxo)divanadium(IV)-Substituted Polyoxometalates
    K. Uehara, K. Fukaya, N. Mizuno,
    Angew. Chem. Int. Ed., 51, 7715-7718 (2012)
    DOI: 10.1002/anie.201108205 Publication Date: 2012/06/26
  11. Reversible Deprotonation and Protonation Behaviors of a Tetra-protonated γ-Keggin Silicodecatungstate
    K. Sugahara, S. Kuzuya, T. Hirano, K. Kamata, N. Mizuno,
    Inorg. Chem., 51, 7932-7939 (2012)
    DOI: 10.1021/ic3010773 Publication Date: 2012/07/05
  12. Chemo- and Regioselective Direct Hydroxylation of Aromatics to Phenols with Hydrogen Peroxide Catalyzed by a Divanadium-Substituted Phosphotungstate
    K. Kamata, T. Yamaura, N. Mizuno,
    Angew. Chem. Int. Ed., 51, 7275-7279 (2012)
    DOI: 10.1002/anie.201201605 Publication Date: 2012/06/08
  13. Manganese Oxides Promoted Liquid-Phase Aerobic Oxidative Amidation of Methylarenes to Monoamides Using Ammonia Surrogates
    Y. Wang, K. Yamaguchi, N. Mizuno,
    Angew. Chem. Int. Ed., 51, 7250-7254 (2012)
    DOI: 10.1002/anie.201203098 Publication Date: 2012/06/12
  14. Strategic Design and Refinement of Lewis Acid-Base Catalysis by Rare-Earth-Metal-Containing Polyoxometalates
    K. Suzuki, M. Sugawa, Y. Kikukawa, K. Kamata, K. Yamaguchi, N. Mizuno,
    Inorg. Chem., 51, 6953-6961 (2012)
    DOI: 10.1021/ic3008365 Publication Date: 2012/06/06
  15. Bifunctional Tungstate Catalyst for Chemical Fixation of CO2 at Atmospheric Pressure
    T. Kimura, K. Kamata, N. Mizuno,
    Angew. Chem. Int. Ed., 51, 6700-6703 (2012)
    DOI: 10.1002/anie.201203189 Publication Date: 2012/06/05
  16. Manganese Oxide-catalyzed Additive- and Solvent-free Aerobic Oxidative Synthesis of Primary Amides from Primary Amines
    K. Yamaguchi, Y. Wang, N. Mizuno,
    Chem. Lett., 41, 633-635 (2012)
    DOI: 10.1246/cl.2012.633 Publication Date: 2012/05/02
  17. Efficient Hydration of Nitriles Promoted by Simple Amorphous Manganese Oxide Using Reduced Amounts of Water
    K. Yamaguchi, Y. Wang, H. Kobayashi, N. Mizuno,
    Chem. Lett., 41, 574-576 (2012)
    DOI: 10.1246/cl.2012.574 Publication Date: 2012/05/12
  18. Polyoxotungstate-Surfactant Layered Crystal toward Conductive Inorganic-Organic Hybrid,
    T. Ito, N. Fujimoto, S. Uchida, J. Iijima, H. Naruke, N. Mizuno
    Crystals, 2, 362-373 (2012)
    DOI: 10.3390/cryst2020362 Publication Date: 2012/05/03
  19. Heterogeneously catalyzed selective aerobic oxidative cross-coupling of terminal alkynes and amides with simple copper(II) hydroxide
    X. Jin, K. Yamaguchi, N. Mizuno,
    Chem. Commun., 48, 4974-4976 (2012)
    DOI: 10.1039/C2CC31159C Publication Date: 2012/03/23
  20. A Highly Active Protonated Tetranuclear Peroxotungstate for Oxidation with Hydrogen Peroxide,
    R. Ishimoto, K. Kamata, N. Mizuno
    Angew. Chem. Int. Ed., 51, 4662-4665 (2012)
    DOI: 10.1002/anie.201201049 Publication Date: 2012/04/04
  21. Oxidative functional group transformations with hydrogen peroxide catalyzed by a divanadium-substituted phosphotungstate
    N. Mizuno, K. Kamata, K. Yamaguchi,
    Catal. Today, 185, 157-161 (2012).
    (Proceedings of 13th Korea-Japan Symposium on Catalysis)
    DOI: 10.1016/j.cattod.2011.07.007 Publication Date: 2011/08/09
  22. Palladium(II) Containing γ-Keggin Silicodecatungstate That Efficiently Catalyzes Hydration of Nitriles
    T. Hirano, K. Uehara, K. Kamata, N. Mizuno,
    J. Am. Chem. Soc., 134, 6425-6433 (2012).
    DOI: 10.1021/ja3006012 Publication Date: 2012/03/19
  23. Cyanosilylation of Carbonyl Compounds with Trimethylsilyl Cyanide by Yttrium-Pillared Silicotungstate Dimer
    Y. Kikukawa, K. Suzuki, M. Sugawa, T. Hirano, K. Kamata, K. Yamaguchi, N. Mizuno,
    Angew. Chem. Int. Ed., 51, 3686-3690 (2012)
    DOI: 10.1002/anie.201200486 Publication Date: 2012/02/29
  24. Diamond-Shaped [Ag4]4+ Cluster Encapsulated with Silicotungstate Ligands: Synthesis and the Catalysis for Hydrolytic Oxidation of Silanes
    Y. Kikukawa, Y. Kuroda, K. Yamaguchi, N. Mizuno,
    Angew. Chem. Int. Ed., 51, 2434-2437 (2012)
    DOI: 10.1002/anie.201108372 Publication Date: 2012/01/19
  25. Manganese oxide-catalyzed transformation of primary amines to primary amides through the sequence of oxidative dehydrogenation and successive hydration
    Y. Wang, H. Kobayashi, K. Yamaguchi, N. Mizuno,
    Chem. Commun., 48, 2642-2644 (2012)
    DOI: 10.1039/C2CC17499E Publication Date: 2012/01/16
  26. Three-Dimensional Ordered Arrays of 58 x 58 x 58 A3 Hollow Frameworks in Ionic Crystals of M2Zn2-Substituted Polyoxometallates
    K. Suzuki, Y. Kikukawa, S. Uchida, H. Tokoro, K. Imoto, S. Ohkoshi, N. Mizuno,
    Angew. Chem. Int. Ed., 51, 1597-1601 (2012)
    DOI: 10.1002/anie.201107041 Publication Date: 2012/01/10
  27. Inverse and High CO2/C2H2 Sorption Selectivity in Flexible Organic-Inorganic Ionic Crystals
    R. Eguchi, S. Uchida, N. Mizuno,
    Angew. Chem. Int. Ed., 51, 1635-1640 (2012)
    DOI: 10.1002/anie.201107906 Publication Date: 2012/01/03
  28. Selective Sorption of Olefins by Halogen-Substituted Macrocation-Polyoxometalate Porous Ionic Crystals
    S. Uchida, R. Eguchi, S. Nakamura, Y. Ogasawara, N. Kurosawa, N. Mizuno,
    Chem. Mater., 24, 325-330 (2012)
    DOI: 10.1021/cm202976e Publication Date: 2011/11/30
  29. Ionic Crystals [M3O(OOCC6H5)6(H2O)3]4[α-SiW12O40] (M = Cr, Fe) as Heterogeneous Catalysts for Pinacol Rearrangement
    S. Uchida, A. Lesbani, Y. Ogasawara, N. Mizuno,
    Inorg. Chem., 51, 775-777 (2012)
    DOI: 10.1021/ic2025186 Publication Date: 2011/12/27
  30. Heterogeneously Catalyzed Synthesis of Primary Amides Directly from Primary Alcohols and Aqueous Ammonia
    K. Yamaguchi, H. Kobayashi, T. Oishi, N. Mizuno,
    Angew. Chem. Int. Ed., 51, 544-547 (2012)
    DOI: 10.1002/anie.201107110 Publication Date: 2011/11/23

Review

  1. 金属酸化物クラスターを用いた多孔質材料
    水野 哲孝,
    セラミックス, 47, 627 (2012).
  2. 二酸化炭素を見分ける!-多孔性イオン結晶の構築と機能開発
    水野 哲孝, 内田さやか,
    化学, 67(6), 64-65 (2012).

2011

Journal

  1. Resonant Photoemission Spectroscopy of the Cathode Material LixFePO4 for Lithium-Ion Battery
    S. Kurosumi, N. Nagamura, S. Toyoda, K. Horiba, H. Kumigashira, M.Oshima, S. Furutsuki, S. Nishimura, A. Yamada, N. Mizuno,
    J. Phys. Chem. C, 115, 25519-25522 (2011)
    DOI: 10.1021/jp208069m Publication Date: 2011/11/21
  2. Layered Assemblies of Dialuminum-Substituted Silicotungstate Trimer and the Reversible Interlayer Cation-Exchange Properties
    Y. Kikukawa, K. Yamaguchi, M. Hibino, N. Mizuno
    Inorg. Chem., 50, 12411-12413 (2011)
    DOI: 10.1021/ic202264 Publication Date: 2011/11/17
  3. Efficient Heterogeneous Epoxidation of Alkenes by Supported Tungsten Oxide Catalyst
    K. Kamata, K. Yonehara, Y. Sumida, K. Hirata, S. Nojima, N. Mizuno,
    Angew. Chem. Int. Ed., 50, 12062-12066 (2011)
    DOI: 10.1002/anie.201106064 Publication Date: 2011/10/25
  4. Heteropoly Acid-Based Materials for Reversible H2 Storage as Protons and Electrons under Mild Conditions
    S. Itagaki, K. Yamaguchi, N. Mizuno,
    Chem. Mater., 23, 4102-4104 (2011).
    DOI: 10.1021/cm2016627 Publication Date: 2011/08/19
  5. Conceptual Design of Heterogeneous Oxidation Catalyst: Copper Hydroxide on Manganese Oxide-Based Octahedral Molecular Sieve for Aerobic Oxidative Alkyne Homocoupling
    T. Oishi, K. Yamaguchi, N. Mizuno,
    ACS Catal., 1, 1351-1354 (2011).
    DOI: 10.1021/cs200388v Publication Date: 2011/09/05
  6. Efficient Epoxidation of Electron-deficient Alkenes with Hydrogen Peroxide Catalyzed by [γ-PW10O38V2(μ-OH)2]3-
    K. Kamata, K. Sugahara, K. Yonehara, R. Ishimoto, N. Mizuno,
    Chem. Eur. J., 17, 7549-7559 (2011).
    DOI: 10.1002/chem.201101001 Publication Date: 2011/06/06
  7. Aerobic Oxidative Transformation of Primary Azides to Nitriles by Ruthenium Hydroxide Catalyst
    J. L. He, K. Yamaguchi, N. Mizuno,
    J. Org. Chem., 76, 4606-4610 (2011).
    DOI: 10.1021/jo2004956 Publication Date: 2011/04/20
  8. Tin-Tungsten Mixed Oxide as Efficient Heterogeneous Catalyst for Conversion of Saccharides to Furan Derivatives
    K. Yamaguchi, T. Sakurada, Y. Ogasawara, N. Mizuno,
    Chem. Lett., 40, 542-543 (2011).
    DOI: 10.1246/cl.2011.542 Publication Date: 2011/04/23
  9. Saccharification of Natural Lignocellulose and Polysaccharides by Highly Negatively Charged Heteropoly Acids in the Concentrated Aqueous Solution
    Y. Ogasawara, S. Itagaki, K. Yamaguchi, N. Mizuno,
    ChemSusChem, 4, 519-525 (2011).
    DOI: 10.1002/cssc.201100025 Publication Date: 2011/03/14
  10. An Efficient, Ligand-free, Heterogeneous Supported Copper Hydroxide Catalyst for the Synthesis of N,N-bicyclic Pyrazolidinone Derivatives
    K. Yoshimura, T. Oishi, K. Yamaguchi, N. Mizuno,
    Chem. Eur. J., 17, 3827-3831 (2011).
    DOI: 10.1002/chem.201002793 Publication Date: 2011/02/24
  11. An Efficient H2O2-based Oxidative Bromination of Alkenes, Alkynes, and Aromatics by a Divanadium-substituted Phosphotungstate
    K. Yonehara, K. Kamata, K. Yamaguchi, N. Mizuno,
    Chem. Commun., 47, 1692-1694 (2011).
    DOI: 10.1039/C0CC04889E Publication Date: 2011/01/05
  12. Heterolytic Dissociation of Water Demonstrated by Crystal-to-Crystal Core Interconversion from (μ-Oxo)divanadium to Bis(μ-hydroxo)divanadium Substituted Polyoxometalates
    K. Uehara, N. Mizuno,
    J. Am. Chem. Soc., 133, 1622-1625 (2011).
    DOI: 10.1021/ja108245g Publication Date: 2011/01/07
  13. Heterogeneously Catalyzed Efficient Hydration of Alkynes to Ketones by Tin−Tungsten Mixed Oxides
    X. Jin, T. Oishi, K. Yamaguchi, N. Mizuno,
    Chem. Eur. J., 17, 1261-1267 (2011).
    DOI: 10.1002/chem.201002761 Publication Date: 2010/12/01

Review

  1. スズ-タングステン複合酸化物固体酸触媒の液相有機合成反応への応用
    小笠原 義之, 山口 和也, 水野 哲孝,
    触媒, 53, 346-351 (2011).
  2. Catalytic Oxidation of Hydrocarbons with Hydrogen Peroxide by Vanadium-Based Polyoxometalates
    N, Mizuno, K. Kamata,
    Coord. Chem. Rev., 255, 2358-2370 (2011). (special issue V7 Symposium)
    DOI: 10.1016/j.ccr.2011.01.041 Publication Date: 2011/01/31
  3. Molecular Design of Polyoxometalate-Based Compounds for Environmentally-Friendly Functional Group Transformations −From Molecular Catalysts to Heterogeneous Catalysts−
    N. Mizuno, K. Yamaguchi, K. Kamata,
    Catal. Surv. Asia, 15, 68-79 (2011). (special issue TOCAT6)
    DOI: 10.1007/s10563-011-9111-2 Publication Date: 2011/02/15

Book

  1. Liquid-Phase Selective Oxidation by Multimetallic Active Sites of Polyoxometalate-Based Molecular Catalysts
    N. Mizuno, K. Kamata, K. Yamaguchi,
    Topics in Organometallic Chemistry-Chemistry of Bifunctional Molecular Catalysis (ed. by T. Ikariya and M. Shibasaki), Springer, 37, 127-160 (2011).
  2. 担持水酸化ルテニウム触媒の調製
    水野 哲孝, 山口 和也,
    触媒調製ハンドブック (岩本正和 監修), エヌ・ティー・エス, p.16-17 (2011).
  3. Ag2[Cr3O(OOC2H5)6(H2O)3]2[α-SiW12O40]・nH2Oの調製
    水野 哲孝, 内田 さやか,
    触媒調製ハンドブック (岩本正和 監修), エヌ・ティー・エス, p.252-253 (2011).

2010

Journal

  1. Flexible Non-porous Heterogeneous Catalyst for Size-selective Oxidation
    N. Mizuno, S. Uchida, K. Kamata, R. Ishimoto, S. Nojima, K. Yonehara, Y. Sumida,
    Angew. Chem. Int. Ed., 49, 9972-9976 (2010).
    DOI: 10.1002/anie.201005275 Publication Date: 2010/12/17
  2. Zeotype Organic-Inorganic Ionic Crystals by Facile Cation-Exchange and the Cotrollable Sorption Properties
    S. Uchida, R. Eguchi, N. Mizuno,
    Angew. Chem. Int. Ed., 49, 9930-9934 (2010).
    DOI: 10.1002/anie.201005176 Publication Date: 2010/12/17
  3. Scope and reaction mechanism of an aerobic oxidative alkyne homocoupling catalyzed by a di-copper-substituted silicotungstate
    N. Mizuno, K. Kamata, Y. Nakagawa, T. Oishi, K. Yamaguchi,
    Catal. Today, 157, 359-363 (2010).
    DOI: 10.1016/j.cattod.2010.02.073 Publication Date: 2010/11/17
  4. Selective Synthesis of Secondary Amines via N-Alkylation of Primary Amines and Ammonia with Alcohols by Supported Copper Hydroxide Catalysts
    J. He, K. Yamaguchi, N. Mizuno,
    Chem. Lett., 39, 1182-1183 (2010).
    DOI: 10.1246/cl.2010.1182 Publication Date: 2010/10/16
  5. Sandwich-Type Zinc-Containing Polyoxometalates with a Hexaprismane Core [{Zn2W(O)O3}2]4+ Synthesized by Thermally Induced Isomerization of a Metastable Polyoxometalate
    Y. Kikukawa, K. Yamaguchi, N. Mizuno,
    Inorg. Chem., 49, 8194-8196 (2010).
    DOI: 10.1021/ic101419a Publication Date: 2010/08/17
  6. An Efficient Copper-mediated 1,3-Dipolar Cycloaddition of Pyrazolidinone-based Dipoles to Terminal Alkynes to Produce N,N-Bicyclic Pyrazolidinone Derivatives
    T. Oishi, K. Yoshimura, K. Yamaguchi, N. Mizuno,
    Chem. Lett., 39, 1086-1087 (2010).
    DOI: 10.1246/cl.2010.1086 Publication Date: 2010/09/04
  7. Zinc(II) Containing γ-Keggin Sandwich-Type Silicotungstate: Synthesis in Organic Media and Oxidation Catalysis
    Y. Kikukawa, K. Yamaguchi, N. Mizuno,
    Angew. Chem. Int. Ed., 49, 6096-6100 (2010).
    DOI: 10.1002/anie.201001468 Publication Date: 2010/07/15
  8. Theoretical and Experimental Studies on Reaction Mechanism for Aerobic Alcohol Oxidation by Supported Ruthenium Hydroxide Catalysts
    F. Nikaidou, H. Ushiyama, K. Yamaguchi, K. Yamashita, N. Mizuno,
    J. Phys. Chem. C, 114, 10873-10880 (2010).
    DOI: 10.1021/jp101692j Publication Date: 2010/07/01
  9. The "Borrowing Hydrogen Strategy" by Supported Ruthenium Hydroxide Catalysts: Synthetic Scope of Symmetrically and Unsymmetrically Substituted Amines
    K. Yamaguchi, J. He, T. Oishi, N. Mizuno,
    Chem. Eur. J., 16, 7199-7207 (2010).
    DOI: 10.1002/chem.201000149 Publication Date: 2010/06/25
  10. Sulfoxidation with Hydrogen Peroxide Catalyzed by [SeO4{WO(O2)2}2]2- and The Mechanism
    K. Kamata, T. Hirano, R. Ishimoto, N. Mizuno,
    Dalton Trans., 39, 5509-5518 (2010).
    DOI: 10.1039/C002318C Publication Date: 2010/05/07
  11. Cyclopropanation of Olefins with Diazo Compounds Catalyzed by a Dicopper-substituted Silicotungstate [γ-H2SiW10O36Cu2(μ-1,1-N3)2]4-
    K. Kamata, T. Kimura, N. Mizuno,
    Chem. Lett., 39, 702-703 (2010).
    DOI: 10.1246/cl.2010.702 Publication Date: 2010/05/29
  12. Efficient stereo- and regioselective hydroxylation of alkanes catalyzed by a bulky polyoxometalate,
    K. Kamata, K. Yonehara, Y. Nakagawa, K. Uehara, N. Mizuno
    Nature Chem., 2, 478-483 (2010).
    DOI: 10.1038/nchem.648 Publication Date: 2010/05/02
  13. An Efficient One-Pot Synthesis of Nitriles from Alcohols or Aldehydes with NH3 Catalyzed by a Supported Ruthenium Hydroxide
    T. Oishi, K. Yamaguchi, N. Mizuno,
    Top. Catal., 53, 479-486 (2010). (Special Issue The 12th Japan-Korea Symposium on Catalysis)
    DOI: 10.1007/s11244-010-9475-y Publication Date: 2010/04/01
  14. Epoxidation of Alkenes with Hydrogen Peroxide Catalyzed by Selenium-Containing Dinuclear Peroxotungstate and Kinetic, Spectroscopic, and Theoretical Investigation of Mechanism
    K. Kamata, R. Ishimoto, T. Hirano, S. Kuzuya, K. Uehara, N. Mizuno,
    Inorg. Chem., 49, 2471-2478 (2010).
    DOI: 10.1021/ic902381b Publication Date: 2010/02/02
  15. Synthetic and Computational Studies on Factors Controlling Structures of Molecular Triangles and Squares and the Equilibrium in Solutions
    K. Uehara, K. Kasai, N. Mizuno,
    Inorg. Chem., 49, 2008-2015 (2010).
    DOI: 10.1021/ic100011a Publication Date: 2010/01/22

Review

  1. Green Functional Group Transformations by Supported Ruthenium Hydroxide Catalysts
    K. Yamaguchi, N. Mizuno,
    Synlett, 2365-2382 (2010).
    DOI: 10.1055/s-0030-1258565 Publication Date: 2010/10/09
  2. Green Oxidation Reactions by Polyoxometalate-Based Catalysts: From Molecular to Solid Catalysts
    N. Mizuno, K. Kamata, K. Yamaguchi,
    Top. Catal., 53, 876-893 (2010).
    DOI: 10.1007/s11244-010-9520-x Publication Date: 2010/05/11

Book

  1. カーボンアロイ材料の化学合成用貴金属フリー触媒としての応用展開の可能性
    山口和也, 水野哲孝,
    白金代替カーボンアロイ触媒 (宮田清蔵 監修), シーエムシー出版, p.172-184 (2010).

2009

Journal

  1. Efficient Catalytic Synthesis of Tertiary and Secondary Amines from Alcohols and Urea
    J. L. He, J. W. Kim, K. Yamaguchi, N. Mizuno,
    Angew. Chem. Int. Ed., 48, 9888-9891 (2009).
    DOI: 10.1002/anie.200905385 Publication Date: 2009/11/26
  2. Aerobic alcohol oxidation catalyzed by supported ruthenium hydroxides
    K. Yamaguchi, J. W. Kim, J. L. He, N. Mizuno,
    J. Catal., 268, 343-349 (2009).
    DOI: 10.1016/j.jcat.2009.10.004 Publication Date: 2009/12/10
  3. Highly Selective Oxidation of Organosilanes to Silanols with Hydrogen Peroxide Catalyzed by Lacunary Polyoxotungstate
    R. Ishimoto, K. Kamata, N. Mizuno,
    Angew. Chem. Int. Ed., 48, 8900-8904 (2009).(Hot paper)
    DOI: 10.1002/anie.200904694 Publication Date: 2009/10/21
  4. Micelles and Vesicles Formed by Polyoxometalate-Block Copolymer Composites
    W. Bu, S. Uchida, N. Mizuno,
    Angew. Chem. Int. Ed., 48, 8281-8284 (2009).
    DOI: 10.1002/anie.200904116 Publication Date: 2009/09/24
  5. A Supported Copper Hydroxide on Titanium Oxide as Efficient Reusable Heterogeneous Catalyst for 1,3-Dipolar Cycloaddition of Organic Azides to Terminal Alkynes
    K. Yamaguchi, T. Oishi, T. Katayama, N. Mizuno,
    Chem. Eur. J., 15, 10464-10472 (2009).
    DOI: 10.1002/chem.200901444 Publication Date: 2009/08/28
  6. Heterogeneously Catalyzed One-pot Synthesis of Aldimines from Primary Alcohols and Amines by Supported Ruthenium Hydroxides
    J. W. Kim, J. He, K. Yamaguchi, N. Mizuno,
    Chem. Lett., 920-921 (2009).
    DOI: 10.1246/cl.2009.920 Publication Date: 2009/08/22
  7. Inorganic Cryptand: Size-selective Strong Metallic Cation Encapsulation by Disilicoicosatungstate (Si2W20) Polyoxometalate
    A. Yoshida, Y. Nakagawa, K. Uehara, S. Hikichi, N. Mizuno,
    Angew. Chem. Int. Ed., 48, 7055-7058 (2009).
    DOI: 10.1002/anie.200903275 Publication Date: 2009/08/24
  8. Catalytic Oxidative Synthesis of Nitriles Directly from Primary Alcohols and Ammonia
    T. Oishi, K. Yamaguchi, N. Mizuno,
    Angew. Chem. Int. Ed., 48, 6286-6288 (2009). (Hot paper)
    DOI: 10.1002/anie.200900418 Publication Date: 2009/03/30
  9. Heterogeneously Catalyzed Efficient Alkyne-Alkyne Homocoupling by a Supported Copper Hydroxide on Titanium Oxide
    T. Oishi, T. Katayama, K. Yamaguchi, N. Mizuno,
    Chem. Eur. J., 15, 7539-7542 (2009).
    DOI: 10.1002/chem.200901080 Publication Date: 2009/06/30
  10. Size-Selective Sorption of Small Organic Molecules in One-Dimensional Channel of Organic-Inorganic Hybrid Ionic Crystal Stabilized by π-π Interaction
    H. Tagami, S. Uchida, N. Mizuno,
    Angew. Chem. Int. Ed., 48, 6160-6164 (2009).
    DOI: 10.1002/anie.200902681 Publication Date: 2009/07/11
  11. Highly Efficient Oxidation of Sulfide with Hydrogen Peroxide Catalyzed by [SeO4{WO(O2)2}2]2-
    K. Kamata, T. Hirano, N. Mizuno,
    Chem. Commun., 3958-3960 (2009).
    DOI: 10.1039/B907952A Publication Date: 2009/06/02
  12. An Efficient Solvent-Free Route to Silyl Esters and Silyl Ethers
    Y. Ojima, K. Yamaguchi, N. Mizuno,
    Adv. Synth. Catal., 351, 1405-1411 (2009).
    DOI: 10.1002/adsc.200900230 Publication Date: 2009/06/03
  13. Design, Synthesis, and Catalysts of Bio-inspired Immobilized Metallocomplex Catalyst
    S. Hikichi, M. Kaneko, Y. Miyoshi, N. Mizuno, K. Fujita, M. Akita,
    Top. in Catal., 52, 845-851 (2009).
    DOI: 10.1007/s11244-009-9232-2 Publication Date: 2009/04/14
  14. Hydrogen-Bond-Assisted Epoxidation of Homoallylic and Allylic Alcohols with Hydrogen Peroxide Catalyzed by Selenium-Containing Dinuclear Peroxotungstate
    K. Kamata, T. Hirano, S. Kuzuya, N. Mizuno,
    J. Am. Chem. Soc., 131, 6997-7004 (2009).
    DOI: 10.1021/ja901289r Publication Date: 2009/05/01
  15. A Tin-Tungsten Mixed Oxide as an Efficient Heterogeneous Catalyst for C-C Bond-Forming Reactions
    Y. Ogasawara, S. Uchida, K. Yamaguchi, N. Mizuno,
    Chem. Eur. J., 15, 4343-4349 (2009).
    DOI: 10.1002/chem.200802536 Publication Date: 2009/03/13
  16. Heterogeneously Catalyzed Selective N-alkylation of Aromatic and Heteroaroatic Amines with Alcohols by a Supported Ruthenium Hydroxide
    J. W. Kim, K. Yamaguchi, N. Mizuno,
    J. Catal., 263, 205-208 (2009).
    DOI: 10.1016/j.jcat.2009.01.020 Publication Date: 2009/04/01
  17. Cucurbit[n]uril-Polyoxoanion Hybrids
    X. Fang, P. Kögerler, L. Isaacs, S. Uchida, N. Mizuno,
    J. Am. Chem. Soc., 131, 432-433 (2009).
    DOI: 10.1021/ja807751b Publication Date: 2008/12/29
  18. A Supported Copper Hydroxide as an Efficient, Ligand-Free, and Heterogeneous Precatalyst for 1,3-Dipolar Cycloaddition of Organic Azides to Terminal Alkynes
    T. Katayama, K. Kamata, K. Yamaguchi, N. Mizuno,
    ChemSusChem, 2, 59-62 (2009).
    DOI: 10.1002/cssc.200800202 Publication Date: 2009/01/08

Review

  1. Hierarchical Design of Nano-Structured Materials based on Polyoxometalates
    N. Mizuno, S. Uchida, K. Uehara,
    Pure. Appl. Chem., 81, 2369-2376 (2009).(Special Issue NMS-IV and FCFP-XVIII)
    DOI: 10.1351/PAC-CON-08-11-26 Publication Date: 2009/11/29
  2. Preface
    M. Iwamoto, Y. Iwasawa, F. Ozawa, T. Tanaka, N. Mizuno, T. Deguchi, T. Muroi,
    Top. in Catal., 52, 543 (2009).
    DOI: 10.1007/s11244-009-9189-1 Publication Date: 2009/04/08
  3. 多金属の協奏機能による選択酸化反応
    水野哲孝,
    化学と工業, 62, p.1168-1170 (2009).
  4. 高機能触媒開発-私の研究理念
    水野哲孝,
    化学, 64, p.24-28 (2009).
  5. 担持金属水酸化物触媒による高効率官能基変換反応系の開発
    山口和也, 水野哲孝,
    化学工業, 60 p.506-510 (2009).

Book

  1. “細孔性ポリオキソメタレート集積体”
    内田さやか, 水野哲孝,
    錯体化学選書7「超分子錯体」(藤田誠、塩谷光彦 監修), 三共出版, p.28-35 (2009).
  2. ”多孔性無機錯体の合成”
    内田さやか, 水野哲孝,
    配位空間の化学-最新技術と応用- (北川進 監修), シーエムシー出版, p.333-343 (2009).
  3. Liquid-Phase Oxidations with Hydrogen Peroxide and Molecular Oxygen Catalyzed by Polyoxometalate-Based Compounds
    N. Mizuno, K. Kamata, S. Uchida, K. Yamaguchi,
    Modern Heterogeneous Oxidation Catalysis(ed. by N. Mizuno), Wiley-VCH, p.185-216 (2009).

2008

Journal

  1. Efficient Oxidative Alkyne-Alkyne Homocoupling by a Monomeric Dicopper-Substituted Silicotungstate
    K. Kamata, S. Yamaguchi, M. Kotani, K. Yamaguchi, N. Mizuno,
    Angew. Chem. Int. Ed., 47, 2407-2410 (2008).
    DOI: 10.1002/anie.200705126 Publication Date: 2008/02/19
  2. Heterogeneously Catalyzed Efficient Oxygenation of Primary Amines to Amides by a Supported Ruthenium Hydroxide Catalyst
    J. W. Kim, K. Yamaguchi, N. Mizuno,
    Angew. Chem. Int. Ed., 47, 9249-9251 (2008).
    DOI: 10.1002/anie.200802464 Publication Date: 2008/07/18
  3. Highly Selective Sorption of Small Unsaturated Hydrocarbons by Non-Porous Flexible Framework with Silver Ion
    S. Uchida, R. Kawamoto, H. Tagami, Y. Nakagawa, N. Mizuno,
    J. Am. Chem. Soc., 130, 12370-12376 (2008).
    DOI: 10.1021/ja801453c Publication Date: 2008/08/23
  4. 1,3-Dipolar Cycloaddition of Organic Azides to Alkynes by a Dicopper-Substituted Silicotungstate
    K. Kamata, Y. Nakagawa, K. Yamaguchi, N. Mizuno,
    J. Am. Chem. Soc., 130, 15304-15310 (2008).
    DOI: 10.1021/ja806249n Publication Date: 2008/10/24
  5. Synthesis of a Dialuminum-Substituted Silicotungstate and the Diastereoselective Cyclization of Citronellal Derivatives
    Y. Kikukawa, S. Yamaguchi, Y. Nakagawa, K. Uehara, S. Uchida, K. Yamaguchi, N. Mizuno,
    J. Am. Chem. Soc., 130, 15872-15878 (2008).
    DOI: 10.1021/ja8014154 Publication Date: 2008/10/31
  6. Synthesis and Catalysis of Di- and Tetra-nuclear Metal Sandwich-type Silicotungstates [(γ-SiW10O36)2M2(μ-OH)2]10- and [(γ-SiW10O36)2M44-O)(μ-OH)6]8- (M = Zr or Hf)
    Y. Kikukawa, S. Yamaguchi, K. Tsuchida, Y. Nakagawa, K. Uehara, K. Yamaguchi, N. Mizuno,
    J. Am. Chem. Soc., 130, 5472-5478 (2008).
    DOI: 10.1021/ja078313i Publication Date: 2008/03/28
  7. Synthesis and Structural Characterization of a Monomeric Di-copper-substituted Silicotungstate [γ-H2SiW10O36Cu2(μ-1,1-N3)2]4- and the Catalysis of Oxidative Homocoupling of Alkynes
    K. Yamaguchi, K. Kamata, S. Yamaguchi, M. Kotani, N. Mizuno,
    J. Catal., 258, 121-130 (2008).
    DOI: 10.1016/j.jcat.2008.06.004 Publication Date: 2008/08/15
  8. Control of Structures and Sorption Properties of Ionic Crystals of A2[Cr3O(OOCC2H5)6(H2O)3]2[α-SiW12O40] (A = Na, K, Rb, NH4, Cs, TMA)
    A. Lesbani, R. Kawamoto, S. Uchida, N. Mizuno,
    Inorg. Chem., 47, 3349-3357 (2008).
    DOI: 10.1021/ic702333w Publication Date: 2008/02/27
  9. Highly Dispersed Ruthenium Hydroxide Supported on Titanium Oxide Effective for Liquid-Phase Hydrogen-Transfer Reactions
    K. Yamaguchi, T. Koike, J. W. Kim, Y. Ogasawara, N. Mizuno,
    Chem. Eur. J., 14, 11480-11487 (2008).
    DOI: 10.1002/chem.200801655 Publication Date: 2008/11/19
  10. Synthetic Scope of Ru(OH)x/Al2O3-Catalyzed Hydrogen-Transfer Reactions: An Application to Reduction of Allylic Alcohols via a Sequential Process of Isomerization/Meerwein-Ponndorf-Verley-Type Reduction
    J. W. Kim, M. Kotani, K. Yamaguchi, N. Mizuno,
    Chem. Eur. J., 14, 4104-4109 (2008).
    DOI: 10.1002/chem.200701917 Publication Date: 2008/03/13
  11. A Supported Rhodium Hydroxide Catalyst: Preparation, Characterization, and Scope of the Synthesis of Primary Amides from Aldoximes or Aldehydes
    H. Fujiwara, Y. Ogasawara, M. Kotani, K. Yamaguchi, N. Mizuno,
    Chem. Asian J., 3, 1715-1721 (2008). (Special Issue in Honor of the 70th Birthday of Professor Ryoji Noyori)
    DOI: 10.1002/asia.200800067 Publication Date: 2008/06/09
  12. Selective Aerobic Oxidations by Supported Ruthenium Hydroxide Catalysts
    N. Mizuno, K. Yamaguchi,
    Catal. Today, 132, 18-26 (2008).
    DOI: 10.1016/j.cattod.2007.12.026 Publication Date: 2008/05/21
  13. A γ-Keggin-type Dimeric Silicotungstate Sandwiching an Adamantanoid Tetra-nuclear Ruthenium-oxygen Cluster Core
    S. Yamaguchi, K. Uehara, K. Kamata, K. Yamaguchi, N. Mizuno,
    Chem. Lett., 37, 328-329 (2008).
    DOI: 10.1246/cl.2008.328 Publication Date: 2008/03/28
  14. An Efficient One-pot Three-component Reaction to Produce 1,4-Disubstituted-1,2,3-triazoles Catalyzed by a Dicopper-substituted Silicotungstate
    K. Yamaguchi, M. Kotani, K. Kamata, N. Mizuno,
    Chem. Lett., 37, 1258-1259 (2008).
    DOI: 10.1246/cl.2008.1258 Publication Date: 2008/02/19

Review

  1. 分子の貯蔵・分離,変換場となる機能性物質の創製
    水野哲孝, 内田さやか,
    化学, 63, p.76-77 (2008).
  2. 多核遷移金属活性点と反応場の制御による選択酸化触媒の開発
    水野哲孝,
    学術月報, 61, p.17-23 (2008).
  3. 精密制御された金属酸化物クラスター触媒によるグリーン酸化反応系の開発
    水野哲孝,
    月刊ファインケミカル, 37, p.20-28 (2008).
  4. Activation of Hydrogen Peroxide by Polyoxometalates
    N. Mizuno, K. Yamaguchi, K. Kamata, Y. Nakagawa,
    Mechanism in Homogeneous and Heterogeneous Catalytic Epoxidation, Elsevier, p.155-176 (2008).

Book

  1. III. 触媒編 12.2.3 ポリ酸
    水野哲孝, 鎌田慶吾,
    触媒便覧, 講談社サイエンティフィク, p.374-382 (2008).

2007

Journal

  1. Self-Organization of All-Inorganic Dodecatungstophosphate Nanocrystallites
    K. Okamoto, S. Uchida, T. Ito, N. Mizuno,
    J. Am. Chem. Soc., 129, 7378-7384 (2007).
    DOI: 10.1021/ja070694c Publication Date: 2007/05/17
  2. A Tungsten-Tin Mixed Hydroxide as an Efficient Heterogeneous Catalyst for Dehydration of Aldoximes to Nitriles
    K. Yamaguchi, H. Fujiwara, Y. Ogasawara, M. Kotani, N. Mizuno,
    Angew. Chem. Int. Ed., 46, 3922-3925 (2007).
    DOI: 10.1002/anie.200605004 Publication Date: 2007/04/11
  3. A One-Pot Synthesis of Primary Amides from Aldoximes or Aldehydes in Water in the Presence of a Supported Rhodium Catalyst
    H. Fujiwara, Y. Ogasawara, K. Yamaguchi, N. Mizuno,
    Angew. Chem. Int. Ed., 46, 5202-5205 (2007). (Hot paper)
    DOI: 10.1002/anie.200701273 Publication Date: 2007/05/30
  4. Olefin Epoxidation with Hydrogen Peroxide Catalyzed by Lacunary Polyoxometalate [γ-SiW10O34(H2O)2]4-
    K. Kamata, M. Kotani, K. Yamaguchi, S. Hikichi, N. Mizuno,
    Chem. Eur. J., 13, 639-648 (2007).
    [Corrigendum: 13, 4133 (2007)]
    DOI: 10.1002/chem.200600384 Publication Date: 2007/04/02
  5. Preparation of Monodispersed Nanoparticles by Electrostatic Assembly of Keggin-Type Polyoxometalates and 1,4,7-Triazacyclononane-Based Transition Metal Complexes
    S. Uchida, S. Hikichi, T. Akatsuka, T. Tanaka, R. Kawamoto, A. Lesbani, Y. Nakagawa, K. Uehara, N. Mizuno,
    Chem. Mater., 19, 4694-4701 (2007).
    DOI: 10.1021/cm071565y Publication Date: 2007/08/25
  6. States of Water in Ionic Crystals of [Cr3O(OOCH)6(H2O)3]+ Macrocation and α-Keggin-type Polyoxometalates
    Y. Ogasawara, S. Uchida, N. Mizuno,
    J. Phys. Chem. C, 111, 8218-8227 (2007).
    DOI: 10.1021/jp067640u Publication Date: 2007/05/23
  7. Mechanism of [γ-H2SiV2W10O40]4--Catalyzed Epoxidation of Alkenes with Hydrogen Peroxide
    Y. Nakagawa, N. Mizuno,
    Inorg. Chem., 46, 1727-1736 (2007).
    DOI: 10.1021/ic0623258 Publication Date: 2007/01/20
  8. Syntheses and Characterizations of Pd-Based Molecular Triangle / Square and the Hybrid Composites with Polyoxometalates
    K. Uehara, K. Kasai, N. Mizuno,
    Inorg. Chem., 46, 2563-2570 (2007).
    DOI: 10.1021/ic062156r Publication Date: 2007/03/01
  9. μ-η1:η1-Peroxo-Bridged Dinuclear Peroxotungstate Catalytically Active for Epoxidation of Olefins
    K. Kamata, S. Kuzuya, K. Uehara, S. Yamaguchi, N. Mizuno,
    Inorg. Chem., 46, 3768-3774 (2007).
    DOI: 10.1021/ic0701211 Publication Date: 2007/03/22
  10. Synthesis and Structual Characterization of a γ-Keggin-Type Dimeric Silicotungstate with a Bis(μ-hydroxo) Dizirconium Core [(γ-SiW10O36)2Zr2(μ-OH)2]10-
    S. Yamaguchi, Y. Kikukawa, K. Tsuchida, Y. Nakagawa, K. Uehara, K. Yamaguchi, N. Mizuno,
    Inorg. Chem., 46, 8502-8504 (2007).
    DOI: 10.1021/ic701488s Publication Date: 2007/09/19
  11. Acid-Base Catalyses by Dimeric Disilicoicosatungstates and Divacant γ-Keggin-type Silicodecatungstate Parent: Reactivity of the Polyoxometalate Compounds Controlled by Step-by-step Protonation of Lacunary W=O Sites
    A. Yoshida, S. Hikichi, N. Mizuno,
    J. Organomet. Chem., 692, 455-459 (2007). (Special Issue for Dynamic Complexes)
    DOI: 10.1016/j.jorganchem.2006.05.061 Publication Date: 2007/08/30
  12. Baeyer-Villiger Oxidation and C-C Bond Formation Reactions Catalyzed by Disilicoeicosatungstates
    A. Yoshida, K. Uehara, S. Hikichi, N. Mizuno,
    Stud. Surf. Sci. Catal., 172, 205-208 (2007). (special issue TOCAT 5)

Review

  1. Design and Syntheses of Nano-structured Ionic Crystals with Selective Sorption Properties,
    S. Uchida, N. Mizuno
    Coord. Chem. Rev., 251, 2537-2546 (2007).
    DOI: 10.1016/j.ccr.2007.02.019 Publication Date: 2007/03/01

Book

  1. 固定化水酸化ルテニウム触媒を用いた酸素酸化反応・水和反応
    水野 哲孝, 山口 和也,
    固定化触媒のルネッサンス, シーエムシー出版, 第7章, p.85-98 (2007).
  2. 5.1 ポリオキソメタレート触媒
    水野 哲孝, 鎌田 慶吾,
    環境調和型新材料シリーズ 触媒材料, 日刊工業新聞社, p.207-214 (2007).

2006

Journal

  1. Channel-Selective Independent Sorption and Collection of Hydrophilic and Hydrophobic Molecules by Cs2[Cr3O(OOCC2H5)6(H2O)3]2[α-SiW12O40] Ionic Crystal
    C. Jiang, A. Lesbani, R. Kawamoto, S. Uchida, N. Mizuno,
    J. Am. Chem. Soc., 128, 14240-14241 (2006).
    DOI: 10.1021/ja065732r Publication Date: 2006/10/18
  2. Formation of S-Shaped Disilicoeicosatungstate (W20) and the Efficient Baeyer-Villiger Oxidation with Hydrogen Peroxide
    A. Yoshida, M. Yoshimura, K. Uehara, S. Hikichi, N. Mizuno,
    Angew. Chem. Int. Ed., 45, 1956-1960 (2006).
    DOI: 10.1002/anie.200502543 Publication Date: 2006/02/17
  3. [γ-1,2-H2SiV2W10O40] Immobilized on Surface Modified SiO2 as a Heterogeneous Catalyst for Liquid-phase Oxidation with H2O2
    J. Kasai, Y. Nakagawa, S. Uchida, K. Yamaguchi, N. Mizuno,
    Chem. Eur. J., 12, 4176-4184 (2006).
    DOI: 10.1002/chem.200501414 Publication Date: 2006/03/07
  4. Synthesis, Structural Characterization, and Catalytic Performance of Dititanium-substituted γ-Keggin Silicotungstate
    Y. Goto, K. Kamata, K. Yamaguchi, K. Uehara, S. Hikichi, N. Mizuno,
    Inorg. Chem., 45, 2347-2356 (2006).
    DOI: 10.1021/ic052179q Publication Date: 2006/01/27
  5. Recognition of Small Polar Molecules with Ionic Crystal of Keggin-type Polyoxometalate with Macrocation
    S. Uchida, R. Kawamoto, N. Mizuno,
    Inorg. Chem., 45, 5136-5144 (2006).
    DOI: 10.1021/ic060684x Publication Date: 2006/05/27
  6. 2D-Grid Layered Pd-Based Cationic Infinite Coordination Polymer/Polyoxometalate Crystal with Hydrophilic Sorption
    K. Uehara, H. Nakao, R. Kawamoto, S.Hikichi, N. Mizuno,
    Inorg. Chem., 45, 9448-9453 (2006).
    DOI: 10.1021/ic061393r Publication Date: 2006/10/13
  7. An Immobilized Organocatalyst for Cyanosilylation and Epoxidation
    K. Yamaguchi, T. Imago, Y. Ogasawara, J. Kasai, M. Kotani, N. Mizuno,
    Adv. Synth. Catal., 348, 1516-1520 (2006). (invited)
    DOI: 10.1002/adsc.200606124 Publication Date: 2006/06/02
  8. Ruthenium hydroxide on magnetite as a magnetically separable heterogeneous catalyst for liquid-phase oxidations and reductions
    M. Kotani, T. Koike, K. Yamaguchi, N. Mizuno,
    Green Chem., 8, 735-741 (2006).
    DOI: 10.1039/b603204d Publication Date: 2006/06/19
  9. Bis(μ-hydroxo) Bridged Di-vanadium-catalyzed Selective Epoxidation of Alkenes with H2O2
    N. Mizuno, Y. Nakagawa, K. Yamaguchi,
    J. Mol. Catal., 251, 286-290 (2006). (special issue ADHOC 2005)
    DOI: 10.1016/j.molcata.2006.02.012 Publication Date: 2006/05/17

Review

  1. Molecular design of selective oxidation catalyst with polyoxometalate
    N. Mizuno, S. Hikichi, K. Yamaguchi, S. Uchida, Y. Nakagawa, K. Uehara, K. Kamata,
    Catal. Today,117, 32-36 (2006). (special issue 5WCOC)
    DOI: 10.1016/j.cattod.2006.05.002 Publication Date: 2006/09/30
  2. Structures and Sorption Properties of Ionic Crystals of Polyoxometalates with Macrocation
    N. Mizuno, S. Uchida,
    Chem. Lett., 35, 688-693 (2006). (Highlight Review)
    DOI: 10.1246/cl.2006.688 Publication Date: 2006/02/15
  3. Polyoxometalate Catalysts: Toward the Development of Green H2O2-based Epoxidation Systems
    N. Mizuno, K. Yamaguchi,
    Chem. Rec., 6, 12-22 (2006).
    DOI:10.1002/tcr.20067 Publication Date: 2006/02/07
  4. ポリオキソメタレート触媒を用いたエポキシド製造法の開発
    水野 哲孝, 山口 和也,
    月刊ファインケミカル, 35, 55 (2006).
  5. ポリオキソメタレート触媒を用いた過酸化水素を酸化剤とするオレフィンのエポキシ化反応の開発
    水野哲孝,
    化学工業, 57, 7-12 (pp.415-420) (2006).
  6. ポリオキソメタレートを用いた環境に優しい選択酸化触媒の分子設計
    水野 哲孝,
    環境管理, 42, 649 (2006).

Book

  1. Liquid Phase Oxidations Catalyzed by Polyoxometalates
    N. Mizuno, K. Kamata, K. Yamaguchi,
    Surface and Nanomolecular Catalysis, Taylor and Francis Group, LLC, New York, p.463 (2006).
  2. グリーンプロセス
    水野哲孝, 山口和也,
    実験化学講座(第5版)25巻, 日本化学会編, 丸善株式会社, p.148 (2006).

2005

Journal

  1. Peroxotungstate Immobilized on Ionic Liquid-modified Silica as a Heterogeneous Epoxidation Catalyst with Hydrogen Peroxide
    K. Yamaguchi, C. Yoshida, S. Uchida, N. Mizuno,
    J. Am. Chem. Soc., 127, 530-531 (2005).
    DOI: 10.1021/ja043688e Publication Date: 2004/12/23
  2. Heterogeneously Catalyzed Aerobic Oxidative Biaryl Coupling of 2-Naphthols and Substituted Phenols in Water
    M. Matsushita, K. Kamata, K. Yamaguchi, N. Mizuno,
    J. Am. Chem. Soc., 127, 6632-6640 (2005).
    DOI: 10.1021/ja050436k Publication Date: 2005/04/12
  3. Amphiphilic Guest Sorption of K2[Cr3O(OOCC2H5)6(H2O)3]2[α-SiW12O40] Ionic Crystal
    R. Kawamoto, S. Uchida, N. Mizuno,
    J. Am. Chem. Soc., 127, 10560-10567 (2005).
    DOI: 10.1021/ja042333s Publication Date: 2005/07/09
  4. Polyoxovanadometalate-Catalyzed Selective Epoxidation of Alkenes with Hydrogen Peroxide
    Y. Nakagawa, K. Kamata, M. Kotani, K. Yamaguchi, N. Mizuno,
    Angew. Chem. Int. Ed., 44, 5136-5141 (2005).
    DOI: 10.1002/anie.200500491 Publication Date: 2005/07/11
  5. Synthetic Scope and Mechanistic Studies of Ru(OH)x/Al2O3-Catalyzed Heterogeneous Hydrogen Transfer Reactions
    K. Yamaguchi, T. Koike, M. Kotani, M. Matsushita, S. Shinachi, N. Mizuno,
    Chem. Eur. J., 11, 6574-6582 (2005).
    DOI: 10.1002/chem.200500539 Publication Date: 2005/08/10
  6. Structures and Sorption Properties of Ionic Crystals of Macrocation-Dawson-type Polyoxometalates with Different Charges
    S. Uchida, R. Kawamoto, T. Akatsuka, S. Hikichi, N. Mizuno,
    Chem. Mater., 17, 1367-1375 (2005).
    DOI: 10.1021/cm047879s Publication Date: 2005/02/18
  7. Sterically Controlled Esterification on Bis(μ-hydroxo) Di-oxovanadium site in γ-H2SiV2W10O404-
    Y. Nakagawa, K. Uehara, N. Mizuno,
    Inorg. Chem., 44, 14-16 (2005).
    DOI: 10.1021/ic0483388 Publication Date: 2004/12/09
  8. Reactivity of Bis(μ-hydroxo) Divanadium Site in γ-H2SiV2W10O404- with Hydroxo Compounds
    Y. Nakagawa, K. Uehara, N. Mizuno,
    Inorg. Chem., 44, 9068-9075 (2005).
    DOI: 10.1021/ic051163x Publication Date: 2005/10/12
  9. Oxidation of adamantane with 1 atm molecular oxygen by vanadium-substituted polyoxometalates
    S. Shinachi, M. Matsushita, K. Yamaguchi, N. Mizuno,
    J. Catal., 233, 81-89 (2005).
    [Corrigendum: 246, 232-233 (2007)]
    DOI: 10.1016/j.jcat.2005.04.012 Publication Date: 2005/05/23

Review

  1. Epoxidation of Olefins with Hydrogen Peroxide Catalyzed by Polyoxometalates
    N. Mizuno, K. Yamaguchi, K. Kamata,
    Coord. Chem. Rev., 249, 1944-1956 (2005).
    DOI: 10.1016/j.ccr.2004.11.019 Publication Date: 2005/03/03
  2. 夢の環境調和型選択酸化触媒の開発
    水野 哲孝,
    未来材料, 5, 8 (2005).
  3. Ru担持アルミナ触媒による二トリル類の水和反応
    水野 哲孝,
    月刊ファインケミカル, 34, 34 (2005).

Book

  1. ポリオキソメタレートを用いた分子触媒設計とその酸化触媒作用
    水野 哲孝, 鎌田 慶吾, 山口 和也,
    触媒技術の動向と展望, 触媒学会編, p.21 (2005).

2004

Journal

  1. Zeotype Ionic Crystal of Cs5[Cr3O(OOCH)6(H2O)3][α-CoW12O40]・7.5H2O with Shape-Selective Adsorption of Water
    S. Uchida, N. Mizuno,
    J. Am. Chem. Soc., 126, 1602-1603 (2004).
    DOI: 10.1021/ja038063f Publication Date: 2004/02/18
  2. Efficient Hydration of Nitriles to Amides in Water Catalyzed by Ruthenium Hydroxide on Alumina
    K. Yamaguchi, M. Matsushita, N. Mizuno,
    Angew. Chem. Int. Ed., 43, 1576-1580 (2004).
    DOI: 10.1002/anie.200353461 Publication Date: 2004
  3. Highly Selective, Recyclable Epoxidation of Allylic Alcohols with Hydrogen Peroxide in Water Catalyzed by Dinuclear Peroxotungstate
    K. Kamata, K. Yamaguchi, N. Mizuno,
    Chem. Eur. J., 10, 4728-4734 (2004).
    DOI: 10.1002/chem.200400352 Publication Date: 2004/10/04
  4. Nitration of Alkanes with Nitric Acid by Vanadium-Substituted Polyoxometalates
    S. Shinachi, H. Yahiro, K. Yamaguchi, N. Mizuno,
    Chem. Eur. J., 10, 6489-6496 (2004).
    DOI: 10.1002/chem.200400049 Publication Date: 2004/12/17
  5. Preparation and Characterization of Cs2.8H1.2PMo11Fe(H2O)O396H2O and Investigation of Effects of Iron-substitution on Heterogeneous Oxidative Dehydrogenation of 2-Propanol
    N. Mizuno, J.-S. Min, A. Taguchi,
    Chem. Mater., 16, 2819-2825 (2004).
    DOI: 10.1021/cm0348996 Publication Date: 2004/07/13
  6. Efficient Heterogenious Oxidation of Alkylarenes with Molecular Oxygen
    K. Kamata, J. Kasai, K. Yamaguchi, N. Mizuno,
    Org. Lett., 6, 3577-3580 (2004).
    DOI: 10.1021/ol0485363 Publication Date: 2004/09/30
  7. In-situ IR Spectrum of 12-Tungstophosphoric Acid Hexahydrate with Planar H5O2+
    M. Hashimoto, G. Koyano, N. Mizuno,
    J. Phys. Chem. B, 108, 12368-12374 (2004).
    DOI: 10.1021/jp0485744 Publication Date: 2004/08/19
  8. [VO(H2O)5]HPMo12O40-catalyzed nitration of alkanes with nitric acid
    K. Yamaguchi, S. Shinachi, N. Mizuno,
    Chem. Commun., 424-425 (2004).
    DOI: 10.1039/b314978a Publication Date: 2004/02/21
  9. Efficient, regioselective epoxidation of dienes with hydrogen peroxide catalyzed by [γ-SiW10O34(H2O)2]4-
    K. Kamata, Y. Nakagawa, K. Yamaguchi, N. Mizuno,
    J. Catal., 224, 224-228 (2004).
    DOI: 10.1016/j.jcat.2004.02.027 Publication Date: 2004/05/15
  10. The Hydrothermal Synthesis and Crystal Structure of (H2O)[Ge5O10] and [(CH3)4N][Ge10O20OH], Two Novel Porous Germanates
    Y. Xu, W. Fan, N. Chino, K. Uehara, S. Hikichi, N. Mizuno, M. Ogura, T. Okubo,
    Chem. Lett., 33, 74-75 (2004).
    DOI: 10.1246/cl.2004.74 Publication Date: 2004/01/05

Review

  1. ポリオキソメタレート-マクロカチオン複合体の構造制御とその分子収着特性
    水野 哲孝, 内田 さやか,
    ゼオライト, 21, 138 (2004).
  2. 酸化物クラスターの特長を生かした環境調和型反応系の開発
    水野 哲孝,
    化学と教育, 52, 392 (2004).

Book

  1. 置換, 担持型ポリオキソメタレートを用いた分子状酸素を酸化剤とした選択酸化触媒作用
    水野 哲孝,
    触媒活用大事典(展望編), ㈱工業調査会書籍部, p.979 (2004).
  2. 触媒物質・材料調製・合成法
    水野 哲孝,
    触媒活用大事典(基礎編), ㈱工業調査会書籍部, p.17 (2004).
  3. 多孔性ポリオキソメタレートの合成と吸着・触媒特性
    水野 哲孝, 内田 さやか, 河本 亮介,
    新時代の多孔性材料とその応用(北川 進監修), シーエムシー出版, p.177 (2004).

2003

Journal

  1. Efficient Epoxidation of Olefins with ≥ 99% Selectivity and Use of Hydrogen Peroxide
    K. Kamata, K. Yonehara, Y. Sumida, K. Yamaguchi, S. Hikichi, N. Mizuno,
    Science, 300, 964-966 (2003).
    DOI: 10.1126/science.1083176 Publication Date: 2003/05/09
  2. Efficient Heterogeneous Aerobic Oxidation of Amines by a Supported Ruthenium Catalyst
    K. Yamaguchi, N. Mizuno,
    Angew. Chem. Int. Ed., 42, 1480-1483 (2003).
    DOI: 10.1002/anie.200250779 Publication Date: 2003/04/07
  3. Scope, Kinetics, and Mechanistic Aspects of Aerobic Oxidations Catalyzed by Ruthenium Supported on Alumina
    K. Yamaguchi, N. Mizuno,
    Chem. Eur. J., 9, 4353-4361 (2003).
    DOI: 10.1002/chem.200304916 Publication Date: 2003/12/11
  4. Unique Guest Inclusion Properties of Breathing Ionic Crystal of K3{Cr3(OOCH)6(H2O)3}[α-SiW12O40]16H2O
    S. Uchida, N. Mizuno,
    Chem. Eur. J., 9, 5850-5857 (2003).
    DOI: 10.1002/chem.200304874 Publication Date: 2003/12/05
  5. {W(=O)(O2)2(H2O)(μ-O)}22--Catalyzed Epoxidation of Allylic Alcohols in Water with High Selectivity and Utilization of Hydrogen Peroxide
    K. Kamata, K. Yamaguchi, S. Hikichi, N. Mizuno,
    Adv. Synth. Catal., 345, 1193-1196 (2003).
    DOI: 10.1002/chem.200304874 Publication Date: 2003/11/19
  6. Catalytic Activity and Structural Stability of La0.9Ce0.1Co1-xFexO3Perovskite Catalysts for Automotive Emissions Control
    H. Tanaka, N. Mizuno, M. Misono,
    Appl. Catal. A:General, 244, 371-382 (2003).
  7. A Green Route to Epoxide-Catalutic Selective Epoxidation of Alkenes with 1atm Molecular Oxygen with 10000 Turnover Number
    Y. Nishiyama, T. Hayashi, Y. Nakagawa, N. Mizuno,
    Stud. Surf. Sci. Catal., 145, 255 (2003).

Book

  1. ヘテロポリ酸,
    奥原 敏夫, 水野 哲孝
    化学便覧第6版(応用化学編分担執筆), 日本化学会編, 丸善株式会社, (2003).
  2. 夢のグリーン酸化反応
    水野 哲孝,
    動け!日本, 動け日本タスクフォース編, p.246 (2003).
  3. I.有機金属化学 (3)不均一系との接点
    水野 哲孝,
    先端科学シリーズ 有機金属/キラル/触媒/高分子, 日本化学会編, 丸善株式会社, p.15 (2003).

2002

Journal

  1. A Breathing Ionic Crystal Displaying Selective Binding of Small Alcohols and Nitriles
    S. Uchida, M. Hashimoto, N. Mizuno,
    Angew. Chem. Int. Ed., 41, 2814-2817 (2002).
    DOI: 10.1002/1521-3773(20020802)41:15<2814::AID-ANIE2814>3.0.CO;2-I Publication Date: 2002/08/02
  2. Supported Ruthenium Catalyst for Heterogeneous Oxidations of Alcohols with Molecular Oxygen
    K. Yamaguchi, N. Mizuno,
    Angew. Chem. Int. Ed., 41, 4538-4542 (2002).
    DOI: 10.1002/1521-3773(20021202)41:23<4538::AID-ANIE4538>3.0.CO;2-6 Publication Date: 2002/11/27
  3. Heterogeneously Catalyzed Liquid-phase Oxidation of Alkanes and Alcohols with Molecular Oxygen
    K. Yamaguchi, N. Mizuno,
    New J. Chem., 26, 972-974 (2002).
    DOI: 10.1039/B203262G Publication Date: 2002/06/27
  4. A Novel Channeled Complex of Cr(III) Trinuclear Cation with Polyoxometalate Aimed for Heterogeneous Catalysis: Synthesis and Structure
    S. Uchida, S. Sakamoto, N. Mizuno,
    Res. Chem. Interm., 28, 389-396 (2002).
    DOI: 10.1163/156856702760346806 Publication Date: 2002/07/01
  5. Control of Structure of Oxide Cluster and the Application to Catalytic Technology
    N. Mizuno,
    Int. J. Soc. Mater. Eng. Resour., 10, 135 (2002).

Review

  1. ポリオキソメタレートを用いた活性点制御と分子状酸素を酸化剤とした均一系選択酸化触媒作用
    水野 哲孝,
    触媒, 44, 23 (2002).

Book

  1. Selective Oxidation of Hydrocarbons with Molecular Oxygen Catalyzed by Transition-metal-substituted Polyoxometalates
    N. Mizuno, M. Hashimoto, Y. Sumida, Y. Nakagawa, K. Kamata
    Polyoxometalate Chemistry for Nano-Composite Design, Kluwer Academic Publ./Wiley, p.197 (2002).
  2. 濃アンモニア水の保管
    水野 哲孝,
    教育現場からの化学Q&A, 日本化学会編, p.153 (2002).

2001

Journal

  1. High Turnover Numbers for Catalytic Selective Epoxidation of Alkenes with 1 atm Molecular Oxygen
    Y. Nishiyama, T. Hayashi, Y. Nakagawa, N. Mizuno,
    Angew. Chem. Int. Ed., 40, 3639-3641 (2001).
    [Corrigendum: 46, 4006 (2007)]
    DOI: 10.1002/1521-3773(20011001)40:19<3639::AID-ANIE3639>3.0.CO;2-0 Publication Date: 2001/10/02
  2. Tunable Syntheses of Cubic, Lamellar, and Hexagonal Mesostructured Vanadium-Phosphorus Oxides
    N. Mizuno, A. Taguchi, H. Hatayama,
    Chem. Mater., 13, 179-184 (2001).
    DOI: 10.1021/cm000524y Publication Date: 2000/12/12
  3. Low-temperature Selective Oxidation of Methane into Formic Acid with Hydrogen-Oxygen Gas Mixture Catalyzed by Bifunctional Catalyst of Palladium-Heteropoly Compound
    J.-S. Min, H. Ishige, M.Misono, N. Mizuno,
    J. Catal., 198, 116-121 (2001).
    DOI: 10.1006/jcat.2000.3117 Publication Date: 2001/02/15
  4. Iron as An Effective Additive for Enhancement of Catalytic Performance of Cesium Hydrogen Salt of Molybdovanadophosphoric Acid for Selective Oxidation of Isobutane, Propane, and Ethane and The Catalyst Design
    J.-S. Min, N. Mizuno,
    Catal. Today, 66, 47-52 (2001).
    DOI: 10.1016/S0920-5861(00)00603-9 Publication Date: 2001/03/15
  5. Stability of iron in the Keggin anion of heteropoly acid catalysts for selective oxidation of isobutane
    C. Knapp, T. Ui, K. Nagai, N. Mizuno,
    Catal. Today, 71, 111-119 (2001).
    DOI: 10.1016/S0920-5861(01)00433-3 Publication Date: 2001/11/15
  6. Remarkable Effect of Iron-substitution for Molybdenum in 12-Molybdophosphate on Oxidative Dehydrogenation of 2-Propanol
    J.-S. Min, M. Misono, A. Taguchi, N. Mizuno,
    Chem. Lett., 30, 28-29 (2001).
    DOI: 10.1246/cl.2001.28 Publication Date: 2000/10/10
  7. Origin of Microporosity of Ammonium Dodecatungstophosphate Unveiled by Single Crystal Structure Analysis
    T. Itoh, M. Hashimoto, S. Uchida, N. Mizuno,
    Chem. Lett., 30, 1272-1273 (2001).
    DOI: 10.1246/cl.2001.1272 Publication Date: 2001/08/06
  8. Synthesis of Novel Layered Vanadyl Alkylphosphates as Catalyst Precursors for Selective Oxidation of n-Butane
    Y. Kamiya, E. Nishikawa, A. Satsuma, N. Mizuno, T. Okuhara,
    SekiyuGakkaishi, 44, 265 (2001).

Review

  1. Catalysis by Heteropoly Compounds -Recent Developments
    T. Okuhara, N. Mizuno, M. Misono,
    Appl. Catal. A: General, 222, 63-77 (2001).
    DOI: 10.1016/S0926-860X(01)00830-4 Publication Date: 2001/12/20
  2. Synthesis of Di-iron-containing Inorganic Synzyme, γ-SiW10{Fe(OH2)}2O386-, and The Liquid-phase Oxidation Catalysis
    N. Mizuno,
    Catal. Surv. from Japan, 4, 149-154 (2001).
    DOI: 10.1023/A:1011411622118 Publication Date: 2001/07
  3. 置換型ポリオキソメタレートによる選択的酸化反応の開発
    水野 哲孝,
    ペトロテック, 24, 55 (2001).
  4. コンビナトリアルケミストリにおける固体触媒パラレル合成ならびにAI利用
    山田 祐介, 小林 哲彦, 水野 哲孝,
    触媒, 43, 310 (2001).

Book

  1. Oxidation of Hydrocarbons with Hydrogen Peroxide Catalyzed by Di-Iron-substituted Silicotungstate
    N. Mizuno,
    Polyoxometalate Chemistry (Ed. by M. T. Pope and A. Muller), Kluwer Academic Publ., p.335 (2001).

2000

Journal

  1. Reaction Mechanism of Oxidation of Methane with Hydrogen Peroxide Catalyzed by 11-Molybdo-1-vanadophosphoric Acid Catalyst Precursor
    Y. Seki, J. S. Min, M. Misono, N. Mizuno,
    J. Phys. Chem. B, 104, 5940-5944 (2000).
    DOI: 10.1021/jp000406y Publication Date: 2000/05/31
  2. High Turnover Number of γ-SiW10{Mn3+(OH2)}2O386- for Oxygenation of Cyclohexane with 1 atm Molecular Oxygen
    T. Hayashi, A. Kishida, N. Mizuno,
    Chem. Commun., 381-382 (2000).
    DOI: 10.1039/a910334l Publication Date: 2000/02/03
  3. Comparison of Catalytic Performance of 11-Molybdo-1-vanadophosphoric Acid Catalyst Precursor with Those of V-containing Compounds and The Optimization of Conditions for Oxidation of Methane with Hydrogen Peroxide
    Y. Seki, N. Mizuno, M. Misono,
    Appl. Catal. A: General, 194-195, 13-20 (2000).
  4. Synthesis of Cubic Mesostructured Vanadium-Phosphorus Oxide
    H. Hatayama, M.Misono, A. Taguchi, N. Mizuno,
    Chem. Lett., 29, 884-885 (2000).
  5. Remarkable Effect of Manganese Center on Catalytic Activity for Decomposition of Hydrogen Peroxide
    A. Kishida, A. Taguchi, N. Mizuno,
    Chem. Lett., 29, 1374-1375 (2000).
  6. Oxidation of Alkanes with Hydrogen Peroxide Catalyzed by Di-Iron-substituted Inorganic Synzyme
    N. Mizuno, Y. Nishiyama, I. Kiyoto, M. Misono,
    Stud. Surf. Sci. Catal., 130, 797 (2000).
  7. Comparison of Catalytic Activity and Efficiency of Hydrogen Peroxide Utilization of Di-Iron-Containing Silicotungstate with Iron Containing Complexes and The Oxidation of Methane and Ethane
    N. Mizuno, M. Misono, Y. Nishiyama, Y. Seki, I. Kiyoto, C. Nozaki,
    Res. Chem. Interm., 26, 193 (2000).

Review

  1. コンビナトリアル手法の触媒開発への応用
    魚住 泰広, 水野 哲孝,
    化学工学, 64, 279 (2000).

Book

  1. 触媒の事典
    水野 哲孝,
    朝倉書店(分担執筆), (2000).