発表論文 (岩﨑准教授)

  1. Alternating Copolymerization of CO2 and Cyclohexene Oxide Catalyzed by Cobalt-Lanthanide Mixed Multinuclear Complexes
    H. Asaba, T. Iwasaki, M. Hatazawa, J. Deng, H. Nagae, K. Mashima, K. Nozaki
    Inorg. Chem. accepted. 10.1002/asia.202000138
  2. Effect of Alkyl Groups in Pyrene Chromophore on Mechanical Response of Pyrene-Octafluoronaphthalene Co-Crystals
    T. Iwasaki, S. Murakami, Y. Takeda, N. Tohnai, and N. Kambe
    Chem. Asian J. 2020, 15, 1349–1354. 10.1021/acs.inorgchem.0c01156
  3. Copper-catalyzed Amination of C(sp3)–H Bonds: From Anilides to Indolines
    J. Long, L. Le, T. Iwasaki, R. Qiu, and N. Kambe
    J. Org. Chem. 2020, 85, 482–492. 10.1021/acs.joc.9b02404
  4. Molecular Packing and Solid-state Photophysical Properties of 1,3,6,8-Tetraalkylpyrenes
    T. Iwasaki, S. Murakami, Y. Takeda, G. Fukuhara, N. Tohnai, Y. Yakiyama, H. Sakurai, N. Kambe
    Chem. Eur. J. 2019, 25, 14817–14825. 10.1002/chem.201903224 selected as Cover Picture.
  5. Structure of the Complex Ni(C8H12)(L) and Its Reactivity toward Organometallic Reagents
    T. Iwasaki, W. Yokoyama, N. Kambe
    Organometallics 2019, 38, 2701–2704. 10.1021/acs.organomet.9b00296 selected as Cover Picture.
  6. Pivalic Acid-Assisted Rh(III)-Catalyzed C-H Functionalization of 2-Arylpyridine Derivatives Using Arylsilanes
    A. Ghaderi, T. Iwasaki, N. Kambe
    Asian J. Org. Chem. 2019, 8, 1344–1347. 10.1002/ajoc.201900362
  7. Synthesis of Imidazolium Salts Bearing Two Cyclodextrins
    S. Tsuda, Y. Minami, R. Ueda, T. Iwasaki, S.-i. Fujiwara, H. Kuniyasu, N. Kambe
    Heterocycles 2018, 96, 2111–2118. 10.3987/COM-18-13993
  8. Synthesis of Cyclopropane Fatty Acids by C(sp3)–C(sp3) Cross-coupling Reaction and Formal Synthesis of α-Mycolic Acid
    T. Iwasaki, S. Terahigashi, Y. Wang, A. Tanaka, H. Zhao, Y. Fujimoto, K. Fukase, N. Kambe
    Adv. Synth. Catal. 2018, 360, 3810–3817. 10.1002/adsc.201800901
  9. Ni-catalyzed Dimerization and Hydroperfluoroarylation of 1,3-Dienes
    T. Iwasaki, X. Min, A. Fukuoka, L. Zhu, R. Qiu, T. Yang, M. Ehara, A. Sudalai, N. Kambe
    J. Org. Chem. 2018, 83, 9267–9277. 10.1021/acs.joc.8b01266 highlighted in Synfacts 2018, 14, 968.
  10. Cross-Coupling Reaction of Alkyl Halides with Alkyl Grignard Reagents Catalyzed by Cp-Iron Complexes in the Presence of 1,3-Butadiene
    T. Iwasaki, R. Shimizu, R. Imanishi, H. Kuniyasu, N. Kambe
    Chem. Lett. 2018, 47, 763–766. 10.1246/cl.180201
  11. Nickel-Catalyzed Coupling Reaction of Alkyl Halides with Aryl Grignard Reagents in the Presence of 1,3-Butadiene: Mechanistic Studies of Four-Component Coupling and Competing Cross-Coupling Reactions
    T. Iwasaki, A. Fukuoka, W. Yokoyama, X. Min, I. Hisaki, T. Yang, M. Ehara, H. Kuniyasu, N. Kambe
    Chem. Sci. 2018, 9, 2195–2211. 10.1039/C7SC04675H highlighted in Synfacts 2018, 14, 303.
  12. Cu-Catalyzed Reductive Coupling of Perfluoroarenes with 1,3-Dienes
    T. Iwasaki, K. Okamoto, H. Kuniyasu, N. Kambe
    Chem. Lett. 2017, 46, 1504–1507. 10.1246/cl.170650
  13. Co-Catalyzed Cross-Coupling Reaction of Alkyl Fluorides with Alkyl Grignard Reagents
    T. Iwasaki, K. Yamashita, H. Kuniyasu, N. Kambe
    Org. Lett. 2017, 19, 3691–3694. 10.1021/acs.orglett.7b01370 highlighted in Synfacts 2017, 13, 1070.
  14. Nickel-Catalyzed Direct Alkylation of Thiophenes via Double C(sp3)-H/C(sp2)-H Bond Cleavage: The Importance of KH2PO4
    X. Wang, P. Xie, R. Qiu, L. Zhu, T. Liu, Y. Li, T. Iwasaki, C.-T. Au, X. Xu, Y. Xia, S.-F. Yin, N. Kambe
    Chem. Commun. 2017, 53, 8316–8319. 10.1039/C7CC04252C
  15. Intramolecular, Site-Selective, Iodine-Mediated, Amination of Unactivated (sp3)C-H Bonds for the Synthesis of Indoline Derivatives
    J. Long, X. Cao, L. Zhu, R. Qiu, C.-T. Au, S.-F. Yin, T. Iwasaki, N. Kambe
    Org. Lett. 2017, 19, 2793–2796. 10.1021/acs.orglett.7b00846
  16. Synthesis of Cyclic Nigerosylnigerose (CNN) Bis-Imidazolium Salts
    S. Tsuda, Y. Komatsu, Y. Minami, R. Ueda, S.-i. Fujiwara, T. Iwasaki, H. Kuniyasu, N. Kambe
    Heterocycles 2017, 95, 1197–1203. 10.3987/COM-16-S(S)69
  17. Multicomponent Coupling Reaction of Perfluoroarenes with 1,3-Butadiene and Aryl Grignard Reagents Promoted by an Anionic Ni(II) Complex
    T. Iwasaki, A. Fukuoka, X. Min, W. Yokoyama, H. Kuniyasu, N. Kambe
    Org. Lett. 2016, 18, 4868–4871. 10.1021/acs.orglett.6b02343
  18. Fe-Catalyzed Cross-Coupling Reaction of Vinylic Ethers with Aryl Grignard Reagents
    T. Iwasaki, R. Akimoto, H. Kuniyasu, N. Kambe
    Chem. Asian J. 2016, 11, 2834–2837. 10.1002/asia.201600972
  19. Regioselective Phosphorylation of myo-Inositol with BINOL-Derived Phosphoramidites, and Its Application for Protozoan Lysophosphatidylinositol
    T. Aiba, M. Sato, D. Umegaki, T. Iwasaki, N. Kambe, K. Fukase, Y. Fujimoto
    Org. Biomol. Chem. 2016, 14, 6672–6675. 10.1039/C6OB01062H
  20. Nickel-Catalyzed Dimerization and Alkylarylation of 1,3-Dienes with Alkyl Fluorides and Aryl Grignard Reagents
    T. Iwasaki, X. Min, A. Fukuoka, H. Kuniyasu, N. Kambe
    Angew. Chem. Int. Ed. 2016, 55, 5550–5554. 10.1002/anie.201601126 selected as Front Cover. highlighted in Synfacts 2016, 12, 523. 科学新聞4月15日付4面
  21. Cu-Catalyzed Regioselective Hydroalkylation of 1,3-Dienes with Alkyl Fluorides and Grignard Reagents
    T. Iwasaki, R. Shimizu, R. Imanishi, H. Kuniyasu, N. Kambe
    Angew. Chem. Int. Ed. 2015, 54, 9347–9350. 10.1002/anie.201503288 日経産業新聞7月1日付朝刊8面
  22. Nickel-catalyzed Synthesis of Diarylsulfides and Sulfones via C–H Bond Functionalization of Arylamides
    V. P. Reddy, R. Qiu, T. Iwasaki, N. Kambe
    Org. Biomol. Chem. 2015, 13, 6803–6813. 10.1039/C5OB00149H
  23. Copper-mediated Thiolation of Carbazole Derivatives and Related N-heterocycle Compounds
    L. Zhu, X. Cao, R. Qiu, T. Iwasaki, V. P. Reddy, X. Xu, S.-F. Yin, N. Kambe
    RSC Adv. 2015, 5, 39358–39365. 10.1039/C5RA04965B
  24. Regioselective Cis Insertion of DMAD into Au−P Bonds: Effect of Auxiliary Ligands on the Reaction Mechanism
    H. Kuniyasu, T. Nakajima, T. Tamaki, T. Iwasaki, N. Kambe
    Organometallics 2015, 34, 1373–1376. 10.1021/acs.organomet.5b00078
  25. AlCl3-catalyzed Insertion of Isocyanides into Nitrogen-sulfur Bonds of Sulfenamides
    D. Shiro, S.-i. Fujiwara, S. Tsuda, T. Iwasaki, H. Kuniyasu, N. Kambe
    Tetrahedron Lett. 2015, 56, 1531–1534. 10.1016/j.tetlet.2015.01.096
  26. Palladium-Catalyzed Insertion Reactions of Isocyanides into Thiocarbamates and Selenocarbamates
    D. Shiro, S.-i. Fujiwara, S. Tsuda, T. Iwasaki, H. Kuniyasu, N. Kambe
    Chem. Lett. 2015, 44, 465–467. 10.1246/cl.141141
  27. Palladium Catalyzed Intramolecular Vinylselenation and Vinylthiolation of Allenes
    S. Tsuda, M. Okuyama, S.-i. Fujiwara, T. Iwasaki, H. Kuniyasu, N. Kambe
    Heterocycles 2015, 90, 1323–1331. 10.3987/COM-14-S(K)80
  28. The Palladium-Catalyzed Intermolecular C–H Chalcogenation of Arenes
    R. Qiu, V. P. Reddy, T. Iwasaki, N. Kambe
    J. Org. Chem. 2015, 80, 367–374. 10.1021/jo502402d.
  29. Palladium-Catalyzed Decarbonylative Rearrangement of NI-Allenyl Seleno- and Tellurocarbamates
    D. Shiro, H. Nagai, S.-i. Fujiwara, S. Tsuda, T. Iwasaki, H. Kuniyasu, N. Kambe
    Heteroatom Chem. 2014, 25, 518–524. 10.1002/hc.21217
  30. Halogen Exchange by Reaction of CpRu(Cl)(PPh3)2 with MeC(O)X (X = Br, I) and its Mechanistic Study
    H. Kuniyasu, A. Sanagawa, T. Nakajima, T. Iwasaki, N. Kambe, K. Bobuatong, M. Ehara
    J. Organomet. Chem. 2014, 769, 34–37. 10.1016/j.jorganchem.2014.06.018
  31. Copper-Catalyzed Alkyl-Alkyl Cross-Coupling Reactions Using Hydrocarbon Additives: Efficiency of Catalyst and Roles of Additives
    T. Iwasaki, R. Imanishi, R. Shimizu, H. Kuniyasu, J. Terao, N. Kambe
    J. Org. Chem. (Featured Article) 2014, 79, 8522–8532. 10.1021/jo501006u selected as Cover picture and most read articles in month top 20.
  32. Diarylrhodates as Promising Active Catalysts for the Arylation of Vinyl Ethers with Grignard Reagents
    T. Iwasaki, Y. Miyata, R. Akimoto, Y. Fujii, H. Kuniyasu, N. Kambe
    J. Am. Chem. Soc. 2014, 136, 9260–9263. 10.1021/ja5043534
  33. The Cobalt-Catalyzed Cross-Coupling Reaction of Alkyl Halides with Alkyl Grignard Reagents: A New Route to Constructing Quaternary Carbon Centers
    T. Iwasaki, H. Takagawa, K. Okamoto, S. P. Singh, H. Kuniyasu, N. Kambe
    Synthesis 2014, 46, 1583–1592. 10.1055/s-0033-1341152
  34. Co-Catalyzed Cross-Coupling of Alkyl Halides with Tertiary Alkyl Grignard Reagents Using a 1,3-Butadiene Additive
    T. Iwasaki, H. Takagawa, S. P. Singh, H. Kuniyasu, N. Kambe
    J. Am. Chem. Soc. 2013, 135, 9604–9607. 10.1021/ja404285b highlighted in Synfacts 2013, 1002.
  35. Facile Halogen Exchange Method between Au(Cl)(L) and MeC(O)X (L = PPh3 and IPr; X = Br and I) via σ-Bond Metathesis Supported by DFT Calculation
    A. Sanagawa, H. Kuniyasu, T. Iwasaki, N. Kambe, K. Bobuatong, M. Ehara
    Chem. Lett. 2013, 42, 831–832. 10.1246/cl.130335
  36. σ-Bond Metathesis between M–X and RC(O)X’ (M = Pt, Pd; X, X’ = Cl, Br, I): Facile Determination of the Relative ΔG Values of the Oxidative Additions of RC(O)X to an M(0) Complex, Evidence by Density Functional Theory Calculations, and Synthetic Applications
    H. Kuniyasu, A. Sanagawa, D. Nakane, T. Iwasaki, N. Kambe, K. Bobuatong, Y. Lu, M. Ehara
    Organometallics 2013, 32, 2026–2032. 10.1021/om400157a
  37. Rhodium-Catalyzed Intermolecular Oxidative Cross-Coupling of (Hetero)Arenes with Chalcogenophenes
    V. P. Reddy, R. Qiu, T. Iwasaki, N. Kambe
    Org. Lett. 2013, 15, 1290–1293. 10.1021/ol400230y
  38. Synthesis of Imidazo and Benzimidazo[2,1-a]-isoquinolines by Rhodium-Catalyzed Intramolecular Double C-H Bond Activation
    V. P. Reddy, T. Iwasaki, N. Kambe
    Org. Biomol. Chem. 2013, 11, 2249–2253. 10.1039/c3ob27396b
  39. Ni-Butadiene Catalytic System for the Cross-Coupling of Bromoalkanoic Acids with Alkyl Grignard Reagents: A Practical and Versatile Method for Preparing Fatty Acids
    T. Iwasaki, K. Higashikawa, V. P. Reddy, W. W. S. Ho, Y. Fujimoto, K. Fukase, J. Terao, H. Kuniyasu, N. Kambe
    Chem. Eur. J. 2013, 19, 2956–2960. 10.1002/chem.201204222
  40. The Nickel-Catalyzed Coupling of Thiomethyl-Substituted 1,3-Benzothiazoles with Secondary Alkyl Grignard Reagents
    A. Ghaderi, T. Iwasaki, A. Fukuoka, J. Terao, N. Kambe
    Chem. Eur. J. 2013, 19, 2951–2955. 10.1002/chem.201203413
  41. Palladium-Catalyzed Vinylselenation of Allenes
    S.-i. Fujiwara, M. Okuyama, S. Tsuda, T. Iwasaki, H. Kuniyasu, N. Kambe
    Tetrahedron 2012, 68, 10523–20529. 10.1016/j.tet.2012.10.003
  42. A Computational Study of Lithium Cuprate Mixed Aggregates
    C. N. D. Khiem, L. N. Thach, T. Iwasaki, N. Kambe, A. A. Boguslavskiy, L. M. Pratt
    J. Phys. Chem. A 2012, 116, 9027–9032. 10.1021/jp3034424
  43. Copper-Catalyzed Coupling Reaction of Unactivated Secondary Alkyl Iodides with Alkyl Grignard Reagents in the Presence of 1,3-Butadiene as an Effective Additive
    R. Shen, T. Iwasaki, J. Terao, N. Kambe
    Chem. Commun. 2012, 48, 9313–9315. 10.1039/C2CC34847K
  44. Cross-coupling of Grignard reagents with Alkyl Halides or Tosylates by the Use of Nickel or Palladium Containing Perovskite
    S. P. Singh, T. Iwasaki, J. Terao, N. Kambe
    Tetrahedron Lett. 2011, 52, 774–776. 10.1016/j.tetlet.2010.12.011
  45. The First Example of Palladium-Catalyzed Intermolecular Allylaryloxylation of an Internal Alkyne by Allyl Aryl Ethers
    H. Kuniyasu, K. Takekawa, A. Sanagawa, T. Wakasa, T. Iwasaki, and N. Kambe
    Tetrahedron Lett. 2011, 52, 5501–5503. 10.1016/j.tetlet.2011.08.065
  46. Silver-Catalyzed Regioselective Carbomagnesiation of Alkynes with Alkyl Halides and Grignard Reagents
    N. Kambe, Y. Moriwaki, Y. Fujii, T. Iwasaki, J. Terao
    Org. Lett. 2011, 13, 4656–4659. 10.1021/ol2018664
  47. Additive Effect of N-Heteroaromatics on Transesterification Catalyzed by Tetranuclear Zinc Cluster
    Y. Maegawa, T. Ohshima, Y. Hayashi, K. Agura, T. Iwasaki, K. Mashima
    ACS Catal. 2011, 1, 1178–1182. 10.1021/cs200224b
  48. Kinetic Studies of the Ni-Catalyzed Cross-Coupling of Alkyl Halides and a Tosylate with Butyl Grignard Reagent in the Presence of 1,3-Butadiene
    T. Iwasaki, A. Tsumura, T. Omori, H. Kuniyasu, J. Terao, N. Kambe
    Chem. Lett. 2011, 40, 1024–1026. 10.1246/cl.2011.1024
  49. C1-Symmetric Rh-Phebox-Catalyzed Asymmetric Alkynylation of Keto Ester
    T. Ohshima, T. Kawabata, Y. Takeuchi, T. Kakinuma, T. Iwasaki, T. Yonezawa, H. Murakami, H. Nishiyama, K. Mashima
    Angew. Chem. Int. Ed. 2011, 50, 6296–6300. 10.1002/anie.201100252 selected as Synfact of the Month; Synfacts 2011, 967.
  50. A Tetranuclear-Zinc-Cluster-Catalyzed Practical and Versatile Deprotection of Acetates and Benzoates
    T. Iwasaki, K. Agura, Y. Maegawa, Y. Hayashi, T. Ohshima, K. Mashima
    Chem. Eur. J. 2010, 16, 11567–11571. 10.1002/chem.201000960
  51. Theoretical Study of Al(III)-Catalyzed Conversion of Glyoxal to Glycolic Acid: Dual Activated 1,2-Hydride Shift Mechanism by Protonated Al(OH)3 Species
    T. Ohshima, Y. Yamamoto, U. Takaki, Y. Inoue, T. Saeki, K. Itou, Y. Maegawa, T. Iwasaki, K. Mashima
    Chem. Commun. 2009, 2688-2690. 10.1039/B902729G
  52. A Simple, General, and Highly Chemoselective Acetylation of Alcohols Using Ethyl Acetate as the Acetyl Donor Catalyzed by a Tetranuclear Zinc Cluster
    T. Iwasaki, Y. Maegawa, Y. Hayashi, T. Ohshima, K. Mashima
    Synlett 2009, 1659-1663. 10.1055/s-0029-1217335
  53. Zinc-Catalyzed Cycloisomerizations. Synthesis of Substituted Furans and Furopyrimidine Nucleosides
    A. Sniady, A. Durham, M. S. Morreale, A. Marcinek, S. Szafert, T. Lis, K. R. Brzezinska, T. Iwasaki, T. Ohshima, K. Mashima, R. Dembinski
    J. Org. Chem. 2008, 73, 5881–5889. 10.1021/jo8007995 highlighted in Synfacts 2008, 1084.
  54. Transesterification of Various Methyl Esters Under Mild Conditions Catalyzed by Tetranuclear Zinc Cluster
    T. Iwasaki, Y. Maegawa, Y. Hayashi, T. Ohshima, K. Mashima
    J. Org. Chem. 2008, 73, 5147–5150. 10.1021/jo800625v highlighted in Synfacts 2008, 975.
  55. Enzyme-Like Chemoselective Acylation of Alcohol in the Presence of Amines Catalyzed by a Tetranuclear Zinc Cluster
    T. Ohshima, T. Iwasaki, Y. Maegawa, A. Yoshiyama, K. Mashima
    J. Am. Chem. Soc. 2008, 130, 2944-2945. 10.1021/ja711349r highlighted in Science 2008, 319, 1163, Nature 2008, 452, 415-416, Synfacts 2008, 627, 化学 2008, 63, 57–58.
  56. Direct Conversion of Esters, Lactones, and Carboxylic Acids to Oxazolines Catalyzed by Tetranuclear Zinc Cluster
    T. Ohshima, T. Iwasaki, K. Mashima
    Chem. Commun. 2006,2711-2713. 10.1039/B605066B

Review articles

  1. Catalytic functionalization of 1,3-butadiene by carbon electrophiles
    T. Iwasaki
    J. Jpn. Petrol. Inst., in press.
  2. フッ化アルキルを求電子剤として利用する触媒的炭素骨格構築法
    T. Iwasaki
    有機合成化学協会誌, 78, 109–120 (2020). 10.5059/yukigoseikyokaishi.78.109
  3. アニオン性有機金属錯体触媒による1,3-ブタジエンへの選択的炭素官能基導入法の開発
    T. Iwasaki
    ペトロテック, 42, 708–712 (2019).
  4. カルボン酸とアミンとの触媒的縮合反応
    T. Iwasaki
    化学と工業, 71, 497 (2018).
  5. 極性転換が導く遷移金属の新機能−アニオン性有機金属化学種を活用する合成反応
    T. Iwasaki
    化学と工業, 69, 979–980 (2016).
  6. Ni-Catalyzed C–C Couplings Using Alkyl Electrophiles
    T. Iwasaki, N. Kambe
    Top. Curr. Chem. (Z), 374, article number 66 (2016). Part of the topical collection: Ni-Based and Fe-Based Cross-Coupling Reactions10.1007/s41061-016-0067-6
  7. 光を用いてNiの酸化状態を制御する-Ni触媒を用いたクロスカップリング反応の新展開
    T. Iwasaki, N. Kambe
    化学, 71, 70–71 (2016).
  8. 不斉アルキルーアルキルカップリング反応の新展開
    T. Iwasaki
    Organometallic News, 38, 38 (2015).
  9. Transition Metal Catalyzed Alkylation at sp3-, sp2-, and sp-Carbons
    N. Kambe, J. Terao, T. Iwasaki
    J. Synth. Org. Chem. Jpn., special issue in English, 69, 1271–1281 (2011). 10.5059/yukigoseikyokaishi.69.1271
  10. Pd-Catalyzed Cross-Coupling Reaction of Alkyl Halides
    N. Kambe, T. Iwasaki, J. Terao
    Chem. Soc. Rev., 40, 4937–4947 (2011). 10.1039/C1CS15129K
  11. 亜鉛四核クラスター触媒による環境調和型反応の開発
    T. Iwasaki, T. Ohshima, K. Mashima
    科学と工業, 84, 268–281 (2010).
  12. 亜鉛四核クラスター錯体による環境調和型触媒の開発
    T. Ohshima, T. Iwasaki, K. Mashima
    有機合成化学協会誌, 67, 494–506 (2009). 10.5059/yukigoseikyokaishi.67.494

Book chapters

  1. クロスカップリング反応の新展開—sp3炭素上での結合形成反応—
    T. Iwasaki, N. Kambe
    触媒年鑑触媒技術の動向と展望, 26–36 (2017).
  2. 触媒化学 —基礎から応用まで (エキスパート応用化学テキストシリーズ)
    Y. Tanaka, H. Yamashita, A. Satsuma, M. Machida, T. Shishido, N. Kambe, T. Iwasaki, M. Ehara, H. Mori, D. Miura
    講談社サイエンティフィク
    ISBN-10: 4061568116
  3. Coupling Reactions Between sp3 Carbon Centers
    T. Iwasaki, N. Kambe
    In Comprehensive Organic Synthesis, 2nd edition; G. A. Molander, P. Knochel Eds., Elsevier, Oxford, Vol. 3, Chapter 07, 337–391 (2014). 10.1016/B978-0-08-097742-3.00311-6
  4. Esterification
    T. Iwasaki, Y. Maegawa, T. Ohshima, K. Mashima
    In Kirk-Othmer Encyclopedia of Chemical Technology, John Wiley & Sons, 1–33 (2012). 10.1002/0471238961.0519200501191201.a01.pub2