Publication List
Original Papers (Prof. Nozaki, 1986-Present)
- Synthesis of Functional Polyolefins Using Cationic Bisphosphine Monoxide-Palladium Complexes
B. P. Carrow, K. Nozaki
J. Am. Chem. Soc., in press. doi - Isolation of PBP-Pincer Rhodium Complex Stabilized by an Intermolecular C-H sigma-Coordination as the Fourth Ligand
M. Hasegawa, Y. Segawa, M. Yamashita, K. Nozaki
Angew. Chem. Int. Ed., in press. - CpRu/C5Me5/Bisphosphine- or Bisphosphite-Based Catalysts for normal-Selective Hydroformylation
K. Takahashi, M. Yamashita, Y. Tanaka, K. Nozaki
Angew. Chem. Int. Ed., 51, 4283-4387 (2012). doi - Syntheses and Thermolysis of Arylpalladium Hydroxide Complexes: Implications for C(sp2)–OH Bond-Forming Reductive Elimination to Generate Phenol Derivatives
Y. Hayashi, S. Wada, M. Yamashita, K. Nozaki
Organometallics, 31, 1073-1081 (2012). doi - Mechanistic Studies on the Reversible Hydrogenation of Carbon Dioxide Catalyzed by an Ir-PNP Complex
R. Tanaka, M. Yamashita, L. W. Chung, K. Morokuma, K. Nozaki
Organometallics, 30, 6742-6750 (2011). doi - Phosphora[7]helicenes: Synthesis, Properties, and Columnar Aggregation with One-Way Chirality
K. Nakano, H. Oyama, Y. Nishimura, S. Nakasako, K. Nozaki
Angew. Chem. Int. Ed., 51, 695-699 (2012). doi - Ethylene Polymerization by Palladium/Phosphine–Sulfonate Catalysts in the Presence and Absence of Protic Solvents: Structural and Mechanistic Differences
M. Kanazawa, S. Ito, K. Nozaki
Organometallics, 30, 6029-6032 (2011). doi
- Tetravalent Metal Complexes as a New Family of Catalysts for Copolymerization of Epoxides with Carbon Dioxide
K. Nakano, K. Kobayashi, K. Nozaki
J. Am. Chem. Soc., 133, 10720-10723 (2011). doi - One-Pot Carboboration of Alkynes Using Lithium Borylcyanocuprate and the Subsequent Suzuki-Miyaura Cross-Coupling Reaction of Resulting Tetrasubstituted Alkenylborane
Y. Okuno, M. Yamashita, K. Nozaki
Eur. J. Org. Chem., 3951-3958 (2011). doi The picture of Prof. Kyoko Nozaki appeared on the cover picture of this Special Issue: Women in Chemistry - Pd-Catalyzed Copolymerization of Methyl Acrylate with Carbon Monoxide: Structures, Properties and Mechanistic Aspects toward Ligand Design
A. Nakamura, K. Munakata, S. Ito, T. Kochi, L. W. Chung, K. Morokuma, K. Nozaki
J. Am. Chem. Soc., 133, 6761-6779 (2011). doi - Syntheses and Properties of Triborane(5) Possessing Bulky Diamino Substituents on Terminal Boron Atoms
Y. Hayashi, Y. Segawa, M. Yamashita, K. Nozaki
Chem. Commun., 47, 5888-5890 (2011). doi - Stereocomplex of Poly(propylene carbonate): Synthesis of Stereogradient Poly(propylene carbonate) via Stereo- and Enantioselective Copolymerization of Propylene Oxide with Carbon Dioxide
K. Nakano, S. Hashimoto, M. Nakamura, T. Kamada, K. Nozaki
Angew. Chem. Int. Ed., 50, 4868-4871 (2011). doi selected as VIP, highlighted in Nature Chemistry - Coordination-Insertion Copolymerization of Allyl Monomers with Ethylene
S. Ito, M. Kanazawa, K. Munakata, J.-i Kuroda, Y. Okumura, K. Nozaki
J. Am. Chem. Soc., 133, 1232-1235 (2011). doi - Vinylarene/CO Copolymerization and Vinylarene/Polar Vinyl Monomer/CO Terpolymerization Using Palladium/Phosphine-Sulfonate Catalysts
T. Kageyama, S. Ito, K. Nozaki
Chem. Asian J., 6, 690-697 (2011). doi - Borylcyanocuprate in a One-Pot Carboboration by a Sequential Reaction with an Electron-Deficient Alkyne and an Organic Carbon Electrophile
Y. Okuno, M. Yamashita, K. Nozaki
Angew. Chem. Int. Ed., 50, 920-923 (2011). doi
- Why Did Incorporation of Acrylonitrile to a Linear Polyethylene Become Possible? Comparison of Phosphine-Sulfonate Ligand with Diphosphine and Imine-Phenolate Ligands in the Pd-Catalyzed Ethylene/Acrylonitrile Copolymerization
K. Nozaki, S. Kusumoto, S. Noda, T. Kochi, L. W. Chung, K. Morokuma
J. Am. Chem. Soc., 132, 16030-16042 (2010). doi - A Catalytic Synthesis of Dialkylamines from Alkylamines Using Neopentyl-Substituted
PNP Pincer Iridium Complex
M. Yamashita, Y. Moroe, T. Yano, K. Nozaki
Inorg. Chim. Acta, 369, 15-18 (2011). doi - New Class of Catalysts for Alternating Copolymerization of Alkylene Oxide and Carbon Dioxide
A. Okada, S. Kikuchi, K. Nakano, K. Nishioka, K. Nozaki, T. Yamada
Chem. Lett., 39, 1066-1068 (2010). doi - Boryltrihydroborate: Synthesis, Structure, and Reactivity as a Reductant in Ionic, Organometallic and Radical Reactions
K. Nozaki, Y. Aramaki, M. Yamashita, S.-H. Ueng, M. Malacria, E. Lacote, D. Curran
J. Am. Chem. Soc., 132, 11449-11451 (2010). doi - Reduction of Base-Stabilized Difluoroboranes to Induce Rearrangement Reactions
M. Yamashita, Y. Aramaki, K. Nozaki
New J. Chem., 34, 1774-1782 (2010). doi - New Low Temperature NMR Studies Establish the Presence of a Second Equatorial-Apical
Isomer of [(R,S)-Binaphos](CO)2RhH
D. A. Castillo Molina, C. P. Casey, I. Müller, K. Nozaki, C. Jäkel
Organometallics, 29, 3362-3367 (2010). doi - Bimetallic mechanism operating in the copolymerization of propylene oxide with carbon dioxide catalyzed by cobalt-salen complexes
K. Nakano, S. Hashimoto, K. Nozaki
Chem. Sci., 1, 369-373 (2010). doi - High-Yielding Tandem Hydroformylation/Hydrogenation of a Terminal Olefin to Produce a Linear Alcohol Using a Rh/Ru Dual Catalyst System
K. Takahashi, M. Yamashita, T. Ichihara, K. Nakano, K. Nozaki
Angew. Chem. Int. Ed., 49, 4488-4490 (2010). doi selected as an outside cover, highlighted in ChemCatChem, highlighted at the following blogs, NNNS chemistry blog, ユーキの有機化学Hot Topics - Regioselective Synthesis of Halohydrin Esters from Epoxides: Reaction with Acyl Halides and Rhodium-catalyzed Three-component Coupling Reaction with Alkyl Halides and Carbon Monoxide
K. Nakano, S. Kodama, Y. Permana, K. Nozaki
Chem. Commun., 6970-6972 (2009). doi - Diphenylphosphino- or Dicyclohexylphosphino-Tethered Boryl Pincer Ligands: Syntheses of PBP Iridium(III) Complexes and Their Conversion to Iridium–Ethylene Complexes
Y. Segawa, M. Yamashita, K. Nozaki
Organometallics, 28, 6234-6242 (2009). doi - Synthesis of N-Heterocyclic Carbene-Sulfonate Palladium Complexes
Y. Nagai, T. Kochi, K. Nozaki
Organometallics, 28, 6131-6134 (2009). doi - Copolymerization of Vinyl Acetate with Ethylene by Palladium/Alkylphosphine–Sulfonate Catalysts
S. Ito, K. Munakata, A. Nakamura, K. Nozaki
J. Am. Chem. Soc., 131, 14606-14607 (2009). doi - Group 4 Transition Metal Boryl Complexes: Syntheses, Structures, Boron–Metal
Bonding Properties, and Application as a Polymerization Catalyst
T. Terabayashi, T. Kajiwara, M. Yamashita, K. Nozaki
J. Am. Chem. Soc., 131, 14162-14163 (2009). doi - Catalytic Hydrogenation of Carbon Dioxide Using Ir(III)-Pincer Complexes
R. Tanaka, M. Yamashita, K. Nozaki
J. Am. Chem. Soc., 131, 14168-14169 (2009). doi highlighted in Angewandte Chemie - Mechanistic Studies on the Formation of Linear Polyethylene Chain Catalyzed by Palladium Phosphine–Sulfonate Complexes: Experiment and Theoretical Studies
S. Noda, A. Nakamura, T. Kochi, L. W. Chung, K. Morokuma, K. Nozaki
J. Am. Chem. Soc., 131, 14088-14100 (2009). doi - Alternating Copolymerization of Cyclohexene Oxide with Carbon Dioxide Catalyzed by (salalen)CrCl Complexes
K. Nakano, M. Nakamura, K. Nozaki
Macromolecules, 42, 6972-6980 (2009). doi - Syntheses of PBP Pincer Iridium Complexes: A Supporting Boryl Ligand
Y. Segawa, M. Yamashita, K. Nozaki
J. Am. Chem. Soc., 131, 9201-9203 (2009). doi highlighted in Angewandte Chemie - Rhodium Catalysts Bearing Mixed Thioether-Phosphine Ligands for Carbonylation of Methanol
K. Sakakibara, K. Nozaki
Bull. Chem. Soc. Jpn., 82, 1009-1011 (2009). doi - Sulfide-Bearing Phosphine Ligands: Their Pd Complexes and Application to
Copolymerizations of Olefins and CO
K. Sakakibara, K. Nozaki
Bull. Chem. Soc. Jpn., 82, 1006-1008 (2009). doi - Synthesis of p-Conjugated Copolymer with Dibenzo[d,d']benzo[1,2-b:4,5-b']difuran Unit in the Main Chain
K. Nakano, M. Takahashi, K. Kawaguchi, K. Nozaki
Synthetic Metals, 159, 939-942 (2009). doi - Synthesis of Allylnickel Complexes with Phosphine–Sulfonate Ligands and Their Application for Olefin Polymerization without Activators
S. Noda, T. Kochi, K. Nozaki
Organometallics, 27, 656-658 (2009). doi - Ring-opening reaction of Bus- and SES-protected aziridines using lithiated dithianes
K. Sakakibara, K. Nozaki
Org. Biomol. Chem., 7, 502-507 (2009). doi - Neopentyl-Substituted PNP-Pincer Ligand: Complexation with Iridium to Form an Iridacycle via Alkyl C-H Activation
T. Yano, Y. Moroe, M. Yamashita, K. Nozaki
Chem. Lett., 37, 1300-1301 (2008). doi - Chemistry of Boryllithium: Synthesis, Structure, and Reactivity
Y. Segawa, Y. Suzuki, M. Yamashita, K. Nozaki
J. Am. Chem. Soc., 130, 16069-16079 (2008). doi - Syntheses of Ester-Substituted Norbornyl Palladium Complexes Ligated with tBu3P: Studies on the Insertion of exo- and endo-Monomers in the Ester-Substituted Norbornene Polymerization
I. Takamiya, M. Yamashita, K. Nozaki
Organometallics, 27, 5347-5352 (2008). doi - Tandem Hydroformylation-Hydrogenation of 1-Decene Catalyzed by Rh-Bidentate Bis(trialkylphosphine)s
T. Ichihara, K. Nakano, M. Katayama, K. Nozaki
Chem. Asian J., 3, 1722-1728 (2008). doi - Regiocontrolled Copolymerization of Methyl Acrylate with Carbon Monoxide.
A. Nakamura, K. Munakata, T. Kochi, K. Nozaki
J. Am. Chem. Soc., 130, 8128-8129 (2008). doi - Syntheses, Structures, and Reactivities of Borylcopper and -zinc Compounds: 1,4-Silaboration of An a,b-Unsaturated Ketone to Form A g-Siloxyallylborane.
T. Kajiwara, T. Terabayashi, M. Yamashita, K. Nozaki
Angew. Chem. Int. Ed., 47, 6606-6610 (2008). doi - Crystal Structure of Boryllithium with Two THF Molecules and DFT Analysis of Its Property as a Boryl Anion.
M. Yamashita, Y. Suzuki, Y. Segawa, K. Nozaki
Chem. Lett., 37, 802-803 (2008). doi - Polymerization of Norbornene with a Pendent Sulfonyl Fluoride Group Catalyzed by Palladium Complex Bearing tBu3P Ligand.
I. Takamiya, M. Yamashita, E, Murotani, Y. Morizawa, K. Nozaki
J. Polym. Sci., Part A: Polym. Chem., 46, 5133-5141 (2008). doi - Synthesis, Structures, and Properties of Unsymmetrical Heteroacenes Containing both Pyrrole and Furan Rings
K. Kawaguchi, K. Nakano, K. Nozaki
Org. Lett., 10, 1199 -1202 (2008). doi - Carbonylative Polymerization of Oxetanes Initiated by Acetylcobalt Complexes
Y. Permana, K. Nakano, M. Yamashita, D. Watanabe, K. Nozaki
Chem. Asian J., 3, 710-718 (2008). doi - Synthesis of Sulfur-Rich Polymers: Copolymerization of Episulfide with Carbon Disulfide by Using [PPN]Cl/(salph)Cr(III)Cl System
K. Nakano, G. Tatsumi, K. Nozaki
J. Am. Chem. Soc., 129, 15116 -15117 (2007). doi - Synthesis, Structure of Borylmagnesium, and Its Reaction with Benzaldehyde to Form Benzoylborane
M. Yamashita, Y. Suzuki, Y. Segawa, K. Nozaki
J. Am. Chem. Soc., 129, 9570-9571 (2007). doi highlighted in Nachrichten aus der Chemie - Synthesis of alpha-Heteroarylpropanoic Acid via Asymmetric Hydroformylation Catalyzed by Rh(I)-(R,S)-BINAPHOS and the Subsequent Oxidation
R. Tanaka, K. Nakano, K. Nozaki
J. Org. Chem., 72, 8671-8676 (2007). doi - Boryl Anion Attacks Transition Metal Chlorides to Form Boryl Complexes: Syntheses, Spectroscopic and Structural Studies on Group 11 Borylmetal Complexes
Y. Segawa, M. Yamashita, K. Nozaki
Angew. Chem. Int. Ed., 46, 6710-6713 (2007). doi highlighted in Nachrichten aus der Chemie - Formation of linear copolymers of ethylene and acrylonitrile catalyzed by phosphine-sulfonate palladium complexes
T. Kochi, S. Noda, K. Yoshimura, K. Nozaki
J. Am. Chem. Soc., 129, 8948-8949 (2007). doi highlighted in Angewandte Chemie. - Alternating Copolymerization of Vinyl Acetate with Carbon Monoxide
T. Kochi, A. Nakamura, H. Ida, K. Nozaki
J. Am. Chem. Soc., 129, 7770-7771 (2007). doi highlighted in Angewandte Chemie. - Regio-Regular Polymerization of Fluorine-Containing Epoxides
K. Sakakibara, K. Nakano, K. Nozaki
Macromolecules, 40, 6136-6142 (2007). doi - Synthesis of Ladder-Type p-Conjugated Heteroacenes via Palladium-Catalyzed Double N-Arylation and Intramolecular O-Arylation.
K. Kawaguchi, K. Nakano, K. Nozaki
J. Org. Chem., 72, 5119-5128 (2007). doi - Boryllithium: Isolation, Characterization, and Reactivity as a Boryl Anion.
Y. Segawa, M. Yamashita, K. Nozaki
Science, 314, 113-115 (2006). doi [full text] [abstract] highlighted in Science, Chemistry World, C&EN, Angewandte Chemie, Kagaku to Kogyo, and Nachrichten aus der Chemie - Selective Formation of Polycarbonate over Cyclic Carbonate: Copolymerization of Epoxides with Carbon Dioxide Catalyzed by Cobalt(III) Complex with Piperidinium End-Capping Arm.
K. Nakano, T. Kamada, K. Nozaki
Angew. Chem. Int. Ed., 45, 7274-7277 (2006). doi
highlighted in Chemical & Engineering (2007, Nov. 16, pp 16). - Syntheses and Structures of Bulky Monophosphine-ligated Methylpalladium Complexes - Application to Homo- and Co-Polymerization of Norbornene and/or Methoxycarbonylnorbornene.
M. Yamashita, I. Takamiya, K. Jin, K. Nozaki
Organometallics, 25, 4588-4595 (2006). doi - Asymmetric Hydroformylation of Vinylfurans Catalyzed by {(11bS)-4-{[(1R)-2'-Phosphino[1,1'-binaphthalen]-2-yl]oxy}dinaphtho[2,1-d:1',2'-f]-[1,3,2]dioxaphosphepin}rhodium(I) [RhI{(R,S)-binaphos}] Derivatives
K. Nakano, R. Tanaka, and K. Nozaki
Helv. Chim. Acta, 89, 1681-1686 (2006). doi - Regio-Contorlled Ring-Opening Polymerization of Perfluoroalkyl-Substituted Epoxides
K. Sakakibara, K. Nakano, K. Nozaki
Chem. Commun., 3334-3336 (2006). doi - Syntheses and Characterizations of Methylpalladium Complexes Bearing a Biphenyl-Based Bulky Phosphine Ligand: Weak Interactions Suggested by NBO and QTAIM Analyses
M. Yamashita, I. Takamiya, K. Jin, K. Nozaki
J. Organomet. Chem., 691, 3189-3195 (2006). doi - Alternating Copolymerization of Fluoroalkenes with Carbon Monoxide
T. Fujita, K. Nakano, M. Yamashita, K. Nozaki
J. Am. Chem. Soc., 128, 1968-1975 (2006). doi - Synthesis of anionic methylpalladium complexes with phosphine–sulfonate ligands and their activities for olefin polymerization
T. Kochi, K. Yoshimura, K. Nozaki
Dalton Trans., 25-27 (2006). doi - Stereospecific Synthesis of Hetero[7]helicenes via the Palladium-Catalyzed Double N-Arylation and Intramolecular O-Arylation
K. Nakano, Y. Hidehira, K. Takahashi, T. Hiyama, K. Nozaki
Angew. Chem. Int. Ed., 44, 7136-7138 (2005). doi - Comparison of two preparative methods: a polymer-supported catalyst by metal-complexation with a polymeric ligand or by polymerization of a metal complex
S. Kinoshita, F. Shibahara, K. Nozaki
Green Chem., 7, 256-258 (2005). doi - Asymmetric amplification in asymmetric alternating copolymerization of cyclohexene oxide and carbon dioxide
K. Nakano, T. Hiyama, K. Nozaki
Chem. Commun., 1871-1873 (2005). doi - An Efficient Pd(II)-Based Catalyst System for Carboxylation of Aromatic C-H bond by Addition of a Phosphenium Salt.
K. Sakakibara, M. Yamashita, K. Nozaki
Tetrahedron Lett., 46, 959-962 (2005). doi - The Double N-Arylation of Primary Amines: Carbazole Synthesis from 2,2'-biphenyldiols.
A. Kuwahara, K. Nakano, K. Nozaki
J. Org. Chem., 70, 413-419 (2005). doi
Selected as the most accessed article in 2005. - A novel mild deprotection method for phosphine-boranes.
M. Schroeder, K. Nozaki, T. Hiyama
Bull. Chem. Soc. Jpn., 77, 1931-1932 (2004). doi - Synthesis of a polyester macromonomer via the cobalt-catalyzed alternating copolymerization of propylene oxide and carbon monoxide.
K. Nakano, F. Kondo, K. Nozaki
J. Polym. Sci., Part A: Polym. Chem., 42, 4666-4670 (2004). doi - Baeyer-Villiger Oxidation of an Optically Active 1,4-Polyketone.
N. Kosaka, T. Hiyama, K. Nozaki
Macromolecules, 37, 4484-4487 (2004). doi - An alternative route to protected aldols: Cobalt-catalyzed hydroformylation of epoxides and in situ protection of b-hydroxyaldehydes by HC(OMe)3.
K. Nakano, M. Katayama, S. Ishihara, T. Hiyama, K. Nozaki
Synlett, 1367-1370 (2004). doi - Palladium(II)-Catalyzed Sequential Hydroxylation-Carboxylation of Biphenyl Using Formic Acid as a Carbonyl Source.
F. Shibahara, S. Kinoshita, K. Nozaki
Org. Lett., 6, 2437-2439 (2004). doi - Synthesis and Photoisomerization of Optically Active 1,4-Polyketones Substituted by Azobenzene Side Chains.
N. Kosaka, T. Oda, T. Hiyama, K. Nozaki
Macromolecules, 37, 4484-4487 (2004). doi - Hydroesterification of vinylarenes catalyzed by palladium complexes of dialkylmonoaryl- and monoalkyldiarylphosphines.
Y. Kawashima, K. Okano, K. Nozaki, T. Hiyama
Bull. Chem. Soc. Jpn., 77, 347-355 (2004). doi - High-Pressure NMR Studies on the Alternating Copolymerization of Styrene with Carbon Monoxide Catalyzed by a Palladium(II)-(R,S)-BINAPHOS Complex.
J. A. Iggo, Y. Kawashima, J. Liu, T. Hiyama, K. Nozaki
Organometallics, 22, 5418 (2003). doi - Liquid-crystalline Stereoregular Polyketone Prepared from a Mesogenic Vinylarene and Carbon Monoxide.
Y. Kawashima, K. Nozaki, T. Hiyama, M Yoshio, K. Kanie, T. Kato
J. Polym. Sci., Part A: Polym. Chem., 41, 3556-3563 (2003). doi - Conformational Studies on an Optically Active 1,4-Polyketone in Solution.
N. Kosaka, K. Nozaki, T. Hiyama
Macromolecules, 36, 6884-6887 (2003). doi - Solvent-Free Asymmetric Olefin Hydroformylation Catalyzed by Highly Crosslinked Polystyrene-Supported (R,S)-BINAPHOS-Rh(I) Complex.
F. Shibahara, K. Nozaki, T. Hiyama
J. Am. Chem. Soc., 125, 8555-8560 (2003). doi - The Double N-arylation of Primary Amines: A New Synthetic Strategy toward Carbazoles with Unique Optical Properties.
K. Nozaki, K. Takahashi, K. Nakano, T. Hiyama, H.-Z. Tang, M. Fujiki, S. Yamaguchi, K. Tamao
Angew. Chem. Int. Ed.,42, 2051-2053 (2003). doi - Asymmetric Alternating Copolymerization of Cyclohezene Oxide and CO2 with Dimeric Zinc Complexes.
K. Nakano, K. Nozaki, T. Hiyama
J. Am. Chem. Soc., 125, 5501-5510 (2003). doi - Asymmetric Terpolymerization of Styrene or Its Derivative and Aliphatic 1-Alkenes with CO Catalyzed by Pd-(R,S)-BINAPHOS.
Y. Kawashima, K. Nozaki, T. Hiyama
Inorg. Chim. Acta, 350, 577-582 (2003). doi - High Pressure IR Studies on the Asymmetric Hydroformylation of Styrene Catalyzed by Rh(I)-(R,S)-BINAPHOS'es.
K. Nozaki, T. Matsuo, F. Shibahara, T. Hiyama
Organometallics, 22, 594-600 (2003). doi - Carbon-Monoxide Free Aminocarbonylation of Organic Halides Using DMF as an Amide Source.
K. Hosoi, K. Nozaki, T. Hiyama
Org. Lett., 4, 2849-2851 (2002). doi - Palladium-catalyzed cross-coupling reaction using alkenyldimethyl(2-thienyl)silanes.
K. Hosoi, K. Nozaki, T. Hiyama
Proc. Japan Acad., 78, Ser. B, 154-160 (2002). - Asymmetric Hydroformylation with Highly Crosslinked Polystyrene-Supported (R,S)-BINAPHOS-Rh(I) Complexes: The Effect of Immobilization Positions.
F. Shibahara, K. Nozaki, T. Matsuo, T. Hiyama
Bioorg. Med. Chem. Lett., 12, 1825-1827 (2002). doi - Methylenation of Optically Active g-Polyketones.
K. Nozaki, N. Kosaka, V. M. Graubner, T. Hiyama
Polymer J., 34, 376-382 (2002). doi - Alkenyldimethyl(2-thienyl)silanes, Excellent Coupling Partner for the Palladium-Catalyzed Cross-Coupling Reaction.
K. Hosoi, K. Nozaki, T. Hiyama
Chem. Lett, 138-139 (2002). doi - Synthesis and Liquid Crystalline Behavior of Stereoregular Polyketones with Mesogenic Side Chains.
K. Nozaki, Y. Kawashima, T. Oda, T. Hiyama, K. Kanie, T. Kato
Macromolecules, 35, 1140-1142 (2002). doi - Asymmetric Synthesis of Optically Active Polymers with Main-Chain Chirality.
Kyoko Nozaki
Kobunshironbunshu, 58, 375-381 (2001). - Spectral Assignment of Poly[Cyclohexene Oxide-alt-Carbon Dioxide].
K. Nakano, K. Nozaki, T. Hyama
Macromolecules, 34, 6325-6332 (2001). doi - Methylenation of an Optically Active g-Polyketone: Synthesis of a New Class of Hydrocarbon Polymers with Main-Chain Chirality.
K. Nozaki, N. Kosaka, V. M. Graubner, T. Hiyama
Macromolecules, 34, 6167-6168 (2001). doi - Alternating Copolymerization of w-Perfluoroalkyl-1-alkenes with Carbon Monoxide Catalyzed by Homogeneous and Polymer-Supported Pd-Complexes.
K. Nozaki, F. Shibahara, S. Elzner, T. Hiyama
Can. J. Chem., 593-597 (2001). doi - Solid Phase Cross-coupling Reaction of Aryl(halo)silanes with 4-Iodobenzoic Acid.
F. Homsi, K. Hosoi, K. Nozaki, T. Hiyama
J. Organomet. Chem., 624, 208-216 (2001). doi - Substituent Effect in Asymmetric Hydroformylation of Olefins Catalyzed by Rhodium(I) Complexes of (R,S)-BINAPHOS Derivatives: A Protocol for Improvement of Regio- and Enantioselectivities.
K. Nozaki, T. Matsuo, F. Shibahara, T. Hiyama
Adv. Syn. Catal., 343, 61-63 (2001). doi - Predominant 1,2-Insertion of Styrene in the Pd-Catalyzed Alternating Copolymerization with Carbon Monoxide.
K. Nozaki, H. Komaki, Y. Kawashima, T. Hiyama, T. Matsubara
J. Am. Chem. Soc., 123, 534-544 (2001). doi - Asymmetric Reduction of an Enantiomerically pure g-polyketone.
K .Nozaki, N. Kosaka, S. Muguruma, T. Hiyama
Macromolecules, 33, 5340-5346 (2000). doi - Solid Phase Cross-Coupling Reactions of Aryl(fluoro)silanes with 4-iodobenzoic acid.
F. Homsi, K. Nozaki, T. Hiyama
Tetrahedron Lett., 41, 5869-5872 (2000). doi - Vapor-Phase Asymmetric Hydroformylation.
K. Nozaki, F. Shibahara, T. Hiyama
Chem. Lett., 694-695 (2000). doi - High Pressure NMR Studies on the Alternating Copolymerization of Propene with Carbon Monoxide Catalyzed by a Palladium(II) Complex of an Unsymmetrical Phosphine-Phosphite.
K. Nozaki, T. Hiyama, S. Kacker, I. T. Horvah
Organometallics, 19, 2031-2035 (2000). doi - Practical Stereoselective Synthesis of (2,3,4,5-Tetrahydro-1H-Benzo[b]azepin-5-yl)acetic Acid.
T. Shinohara, K. Kondo, H. Ogawa, T. Mori, K. Nozaki, T. Hiyama
Chirality, 12, 425-430 (2000). doi - Optically Active Polycarbonates: Asymmetric Alternating Copolymerization of Cyclohexene Oxide with Carbon Dioxide.
K. Nozaki, K. Nakano, T. Hiyama
J. Am. Chem. Soc. 121, 11008-11009 (1999). doi - Alternating Copolymerization of Various Alkenes with Carbon Monoxide Using a Cationic Pd(II) Complexes of (R,S)-BINAPHOS as an Initiator.
K. Nozaki, Y. Kawashima, K. Nakamoto, T. Hiyama
Polymer J., 31, 1057-1060 (1999). doi - Asymmetric Hydroformylation of Olefins in Highly Crosslinked Polymer Matrixes.
K. Nozaki, F. Shibahara, Y. Itoi, T. Ohta, H. Takaya, T. Hiyama
Bull Chem. Soc. Jpn. 72, 1911-1918 (1999). doi - Asymmetric Terpolymerization of Propene, Vinylarene, and Carbon Monoxide.
K. Nozaki, Y. Kawashima, K. Nakamoto, T. Hiyama
Macromolecules, 32, 5168-5170 (1999). doi - A Chiral Bometallic Lewis Acid as a Reaction Template. Asymmetric Reduction of Unsymmetric Ketones with LiBH4.
K. Nozaki, K. Kobori, T. Uemura, T. Tsutsumi, H. Takaya, T. Hiyama
Bull. Chem. Soc. Jpn., 72, 1109-1113 (1999). doi - Asymmetric Hydroformylation of Olefins in a Highly Crosslinked Polymer Matrix.
K. Nozaki, Y. Itoi, F. Shibahara, E. Shirakawa, T. Ohta, H. Takaya, T. Hiyama
J. Am. Chem. Soc., 120, 4051-4052 (1998). doi - Double Helical Oligo Esters: Chiral Twist of Two Aromatic Ester Chains.
K. Nozaki, T. Terakawa, H. Takaya, T. Hiyama
Angew. Chem., Int. Ed. Engl., 37, 131-133 (1998). (Angew. Chem., 110, 138-140 (1998).)
doi - Chiral and achiral phosphine phosphite ligands in Pd(II)-catalyzed alternating copolymerization of propene with CO.
K. Nozaki, M. Yasutomi, K. Nakamoto, T. Hiyama
Polyhedron, 17, 1159-1164 (1998). doi - Mechanistic Aspects of the Alternating Copolymerization of Propylene with Carbon Monoxide Catalyzed by Pd(II) Complexes of Unsymmetrical Phosphine-phosphite Ligands.
K. Nozaki, N. Sato, Y. Tonomura, M. Yasutomi, H. Takaya, T. Hiyama
J. Am. Chem. Soc., 119, 12779-12793 (1997). doi - Cyclic Polyamides Consisting of 1,1'-Binaphthyls. "Chiral Twist" of Glycine Residues.
K. Nozaki, T. Terakawa, H. Takaya, T. Hiyama
Tetrahedron: Asymmetry, 8, 3430-3436 (1997). doi
- Asymmetric Hydroformylation of Allylic Alcohols Catalyzed by Rh(I) (R,S)-BINAPHOS.
K. Nozaki, W. G. Li, T. Horiuchi, H. Takaya
Tetrahedron Lett., 38, 4611-4614 (1997). doi - Asymmetric Hydroformylation of Hetrocyclic Olefins Catalyzed by Chiral Phosphine Phosphite Rh(I) Complex.
T. Horiuchi, T. Ohta, E. Shirakawa, K. Nozaki, H. Takaya
J. Org. Chem., 62, 4285-4292 (1997). doi - Mechanistic Aspects of Asymmetric Hydroformylation of Olefins Catalyzed by Chiral Phosphine-Phosphite Rh(I) Complexes.
T. Horiuchi, E. Shirakawa, K. Nozaki, H. Takaya
Organometallics, 16, 2981-2986 (1997). doi - Asymmetric Hydroformylation of Conjugated Dienes Catalyzed by Chiral Phosphine Phosphite Rh(I) Complex.
T. Horiuchi, T. Ohta, E. Shirakawa, K. Nozaki, H. Takaya
Tetrahedron, 53, 7795-7804 (1997). doi - Highly Enantioselective Hydroformylation of Olefins Catalyzed by Rhodium(I) Complexes of New Chiral Phosphine-Phosphite Ligands.
K. Nozaki, N. Sakai, T. Higashijima, S. Mano, T. Horiuchi, H. Takaya
J. Am. Chem. Soc. 119, 4413-4423 (1997). doi - Hydroestrification of Styrene Catalyzed by Montmorillonite diphenylphosphinepalladium(II) Chloride in the Presence of Chiral Phosphines.
K. Nozaki, M. L. Kantam, T. Horiuchi, H. Takaya
J. Mol. Cat., A., 118, 247-253 (1997). - Cyclocopolymerization of a,w-Dienes with Carbon Monoxide Catalyzed by (R,S)-BINAPHOS Pd(II).
K. Nozaki, N. Sato, K. Nakamoto, H. Takaya
Bull. Chem. Soc. Jpn., 70, 659-664 (1997). - Synthesis of (R)-2-diphenylphosphino-2'-diphenylphosphinomethyl-1,1'-binaphthyl and its use for asymmetric hydrogenation of a-alkylstyrenes.
K. Inagaki, T. Ohta, K. Nozaki, H. Takaya
J. Organomet. Chem. 531, 159-163 (1997). - Asymmetric Michael Reaction of a-Cyano Esters by Chiral Rh(I) Complex with a New Optically Active Bisphosphine Ligand.
K. Inagaki, K. Nozaki, H. Takaya
Synlett. 119-120 (1997). - Asymmetric Hydroformylation Catalyzed by a Rh(I) (R,S)-BINAPHOS Complex: Substituent Effects in Olefins on the Regioselectivity.
K. Nozaki, T. Nanno, and H. Takaya
J. Organomet. Chem., 527, 103-108 (1997). - (R,S)-BINAPHOS Ni(0) and Pd(0) Complexes: Characterization and Their Use for Asymmetric Hydrocyanation of Norbornene.
T. Horiuchi, E. Shirakawa, K. Nozaki, H. Takaya
Tetrahedron: Asymmetry, 8, 57-63 (1997). - New Stereocontrolled Approach to 1b-Methylcarbapenem: Asymmetric Hydroformylation of 4-Vinyl-b-lactams Catalyzed by Rh(I) Complexes of Chiral Phosphine-phosphites and Phosphine-phosphinites.
K. Nozaki, W.-g. Li, T. Horiuchi, H. Takaya, T. Saito, A, Yoshida, K. Matsumura, Y. Kato, T. Imai, T. Miura and H. Kumobayashi
J. Org. Chem., 61, 7658-7659 (1996). - Highly Efficient Enantioselective Synthesis of Optically Active Carboxylic Acids by Ru(OCOCH3)2[(S)-H8-BINAP].
T. Uemura, X. Zhang, K. Matsumura, N. Sayo, H. Kumobayashi, T. Ohta, K. Nozaki and H. Takaya
J. Org. Chem., 61, 5510-5516 (1996). - Synthesis of Highly Functionalized g-Butyrolactones from Activated Carbonyl Compounds and Dimethyl Acetylenedicarboxylate.
K. Nozaki, N. Sato, K. Ikeda and H. Takaya
J. Org. Chem., 61, 4516-4519 (1996). - Chiral Bimetallic Boronic Esters: A Donor Acceptor Coexisting Receptor for Amines.
K. Nozaki, M. Yoshida and H. Takaya
Bull. Chem. Soc. Jpn., 69, 2043-2052 (1996). - Palladium-Catalyzed Acylcyanation of Terminal Arylacetylenes. Synthesis of 1,3-Diaryl-3-cyano-2-propen-1-ones and Tetrasubstituted Furans.
K. Nozaki, N. Sato and H. Takaya
Bull. Chem. Soc. Jpn., 69, 1629-1637 (1996). - Anionic Dinuclear BINAP-Ru(II) Complex: Crystal Structure of [NH2Et2][{RuCl(R)-p-MeO-binap)}2(m-Cl)3] and Its Use for Asymmetric Hydrogenation.
T. Ohta, Y. Tonomura, K. Nozaki and H. Takaya
Organometallics, 15, 1521-1523 (1996). - Asymmetric Hydroformylation of Conjugated Dienes Catalyzed by [(R)-2-diphenylphosphino-1,1'-dinaphthalen-2'-yl] [(S)-1,1'-dinaphthalene-2,2'-diyl]phosphite-rhodium(I).
T. Horiuchi, T. Ohta, K. Nozaki, and H. Takaya
Chem. Commun., 155-156, (1996). - Asymmetric Hydroformylation of Sulfur-Containing Olefins Catalyzed by BINAPHOS-Rh(I) Complexes.
T. Nanno, N. Sakai, K. Nozaki and H. Takaya
Tetrahedron: Asymmetry, 6, 2583-2591 (1995). - Selective Binding of Diamines to a Chiral Lewis Acid with Two Boron Centers.
K. Nozaki, T. Tsutsumi and H. Takaya
J. Org. Chem., 60, 6668-6669 (1995). - Highly Enantioselective Alternating Copolymerization of Propene with Carbon Monoxide Catalyzed by a Chiral Phosphine-Phosphite Complex of Palladium(II).
K. Nozaki, N. Sato and H. Takaya
J. Am. Chem. Soc., 117, 9911-9912 (1995). - A Chiral Lewis Acid with Two "Metal" Centers: Cooperative Binding of Two Amine Molecules to a Chiral Diboronic Ester.
K. Nozaki, M. Yoshida and H. Takaya
Angew. Chem., Int. Ed. Engl., 33, 2452-2454 (1994). - Cationic BINAP-Ru(II) Halide Complexes: Highly Efficient Catalysts for Stereoselective Asymmetric Hydrogenation of a- and b-Functionalized Ketones.
K. Mashima, K. Kusano, Y. Matsumura, N. Sato, K. Nozaki, H. Kumobayashi, N. Sayo, Y. Hori, T. Ishizaki, S. Akutagawa and H. Takaya
J. Org. Chem., 59, 3064-3076 (1994). - Acylcyanation of Terminal Acetylenes: Palladium Catalyzed Addition of Aryloyl Cyanides to Arylacetylenes
K. Nozaki, N. Sato and H. Takaya
J. Org. Chem., 59, 2679-2681 (1994). - Reaction Rate Enhancement by Addition of Anionic Surfactant SDS in the Ruthenium Catalyzed Hydrogen Transfer from a 1,4-Diols to 4-Phenyl-3-buten-2-one.
K. Nozaki, M. Yoshida and H. Takaya
J. Organomet. Chem., 473, 253-256 (1994). - Synthesis of New Chiral Phosphinephosphites Having 2-Diphenyl-phosphinobiphenyl-2'-yl Backbone and Their Use in Rh(I) Catalyzed Asymmetric Hydroformylations.
T. Higashijima, N. Sakai, K. Nozaki and H. Takaya
Tetrahedron Lett., 35, 2023-2026 (1994). - Asymmetric Hydroformylation of 1,2-Di-substituted Olefins Catalyzed by Chiral Phosphinephosphite-Rh(I) Complexes.
N. Sakai, K. Nozaki and H. Takaya
J. Chem. Soc., Chem. Commun., 3395-3396 (1994). - Enantioselective Synthesis of L- and D-Isoserine via Asymmetric Hydrogenation of Methyl N-Phthaloyl-3-amino-2-oxopropanoate.
K. Nozaki, N. Sato and H. Takaya
Tetrahedron: Asymmetry, 4, 2179-2182 (1993). - Highly Enantioselective Hydroformylation of Olefins Catalyzed by New Phosphinephosphite-Rh(I) Complexes.
N. Sakai, S. Mano, K. Nozaki and H. Takaya
J. Am. Chem. Soc., 115, 7033-7034 (1993). - Asymmetric Hydroformylation of Vinyl Acetate By Use of Chiral Bis(triarylphosphite)-Rhodium(I) Complexes.
N. Sakai, K. Nozaki, K. Mashima and H. Takaya
Tetrahedron: Asymmetry, 3, 583-586 (1992). - Isomerization of Olefins by Means of R3SnH-Et3B and Stereochemical Study on Reduction of Alkenyl Iodides.
M. Taniguchi, K. Nozaki, K. Miura, K. Oshima and K. Utimoto
Bull. Chem. Soc. Jpn., 65, 349-353 (1992). - Triethylborane Induced 1,4-Reduction of a,b-Unsaturated Carbonyl Compounds with Triphenyltin Hydride or Tributyltin Hydride.
K. Nozaki, K. Oshima and K. Utimoto
Bull. Chem. Soc. Jpn., 64, 2585-2587 (1991). - Palladium Catalyzed Reaction of Silacyclobutanes with Acetylenes.
Y. Takeyama, K. Nozaki, K. Matsumoto, K. Oshima and K. Utimoto
Bull. Chem. Soc. Jpn., 64, 1461-1466 (1991). - Trialkylborane as an Initiator and Terminator of Free Radical Reactions: Facile Routs to Boron Enolates via a-Carbonyl Radicals and Aldol Reaction of Boron Enolates.
K. Nozaki, K. Oshima and K. Utimoto
Bull. Chem. Soc. Jpn., 64, 403-409 (1991). - On the Mechanism of Lewis Acid Mediated Nucleophilic Substitution Reactions of Acetals.
I. Mori, K. Ishihara, L. A. Flippin, K. Nozaki, H. Yamamoto, P. A. Bartlett, and C. H. Heathcock
J. Org. Chem., 55, 6107-6115 (1990). - Triethylborane Induced Perfluoroalkylation of Silyl Enol Ethers or Germyl Enol Ethers with Perfluoroalkyl Iodides.
K. Miura, M. Taniguchi, K. Nozaki, K. Oshima and K. Utimoto
Tetrahedron Lett., 31, 6391-6394 (1990). - Facile Reduction of Dithiocarbonates Derived from Secondary Alcohols with n-Bu3SnH-Et3B and Synthesis of 2-Furanthiones and 2-Furanones by Intramolecular Addition of Alkoxythiocarbonyl Free Radicals to Acetylenic Lincages.
K. Nozaki, K. Oshima and K. Utimoto
Bull. Chem. Soc. Jpn., 63, 2578-2583 (1990). - Et3B-Induced Stereoselective Radical Addition of Ph3GeH to Carbon-Carbon Multiple Bonds and Its Application to Isomerization of Olefins.
K. Nozaki, Y. Ichinose, K. Wakamatsu, K. Oshima and K. Utimoto
Bull. Chem. Soc. Jpn., 63, 2268-2272 (1990). - Et3B-Induced Radical Addition of Ph3SnH to Acetylenes and Its Application to Cyclization Reaction.
K. Nozaki, K. Oshima and K. Utimoto
Tetrahedron, 45, 923-933, (1989). - Et3B-Induced Hydrodehalogenation of Organic Halides by Tin Hydrides.
K. Miura, Y. Ichinose, K. Nozaki, K. Fugami, K. Oshima and K. Utimoto
Bull. Chem. Soc. Jpn., 62, 143-147 (1989). - Synthesis of Lactones by Intramolecular Addition of Alkoxythiocarbonyl Free Radicals to Acetylenes.
K. Nozaki, K. Oshima and K. Utimoto
Tetrahedron Lett., 29, 6127-6128 (1988). - Facile Reduction of Dithiocarbonates with n-Bu3SnH-Et3B: Easy Access to Hydrocarbons from Secondary Alcohols.
K. Nozaki, K. Oshima, and K. Utimoto
Tetrahedron Lett., 29, 6125-6126 (1988). - Facile Routes to Boron Enolates: Et3B-Mediated Reformatsky Type Reaction and Three-Component Coupling Reaction of Alkyl Iodides, Methyl Vinyl Ketone, and Carbonyl Compounds.
K. Nozaki, K. Oshima and K. Utimoto
Tetrahedron Lett., 29, 1041-1044 (1988). - Synthesis of a-Methylene-g-butyrolactones via Addition of Tin Hydride to Enynes Induced by Triethylborane.
K. Nozaki, K. Oshima and K. Utimoto
Bull. Chem. Soc. Jpn., 60, 3465-3467 (1987). - Et3B-Induced Radical Addition of Thiols to Acetylenes.
Y. Ichinose, K. Wakamatsu, K. Nozaki, J.-L. Birbaum, K. Oshima and K. Utimoto
Chem. Lett., 1647-1650 (1987). - Et3B-Induced Stereoselective Radical Addition of Ph3GeH to Carbon-Carbon Multiple Bonds and Its Application to Isomerization of Olefins.
Y. Ichinose, K. Nozaki, K. Wakamatsu, K. Oshima and K. Utimoto
Tetrahedron Lett., 28, 3709-3712 (1987). - Et3B-Induced Radical Addition of R3SnH to Acetylenes and Its Application to Cyclization Reaction.
K. Nozaki, K. Oshima and K. Utimoto
J. Am. Chem. Soc., 109, 2547-2549 (1987). - Transition-Metal Catalyzed Regioselective Addition of PhMe2SiBEt3Li and Bu3SnBEt3Li to Acetylenic Compounds in the Presence of Methanol.
K. Nozaki, K. Wakamatsu, T. Nonaka, W. Tukmantel, K. Oshima and K. Utimoto
Tetrahedron Lett., 27, 2007-2010 (1986).
