発表論文 (野崎教授)

  1. Chemoselectivity Change in Catalytic Hydrogenolysis: Ureas to Formamides and Amines
    T. Iwasaki, K. Tsuge, N. Naito, K. Nozaki
    ChemRxiv 2023 (preprint) 10.26434/chemrxiv-2023-z49zw
  2. Multifunctional WO3−ZrO2-supported Platinum Catalyst for Remarkably Efficient Hydrogenolysis of Esters to Alkanes
    K. Yuan, Y. Yamazaki, X. Jin, K. Nozaki
    J. Am. Chem. Soc. in press. 10.1021/jacs.2c11145
  3. Chain Transfer Approach for Terminal Functionalization of Alternating Copolymerization of CO2 and Epoxide by Using Active Methylene Compounds as Chain Transfer Agents
    H. Nagae, S. Akebi, S. Matsushiro, K. Sakamoto, T. Iwasaki, K. Nozaki, K. Mashima
    Macromolecules 2022, 55, 9066–9073. 10.1021/acs.macromol.2c01761
  4. TEMPO as a Hydrogen Atom Transfer Catalyst for Aerobic Dehydrogenation of Activated Alkanes to Alkenes
    T. Ito, F. Seidel, X. Jin, K. Nozaki
    J. Org. Chem. 2022, 87, 12733–12740. 10.1021/acs.joc.2c01302 Selected as Most Read Articles in September 2022.
  5. Electron in a cube: Synthesis and characterization of perfluorocubane as an electron acceptor
    M. Sugiyama, M. Akiyama, Y. Yonezawa, K. Komaguchi, M. Higashi, K. Nozaki, T. Okazoe
    Science 2022, 377, 756–759. 10.1126/science.abq0516
    Press release from AGC Inc. and UTokyo, Highlighted in C&EN, MarketScreener, Tech+, Chem-Station
  6. Pincer-Supported Perfluororhodacyclopentanes: High Nucleophilicity of M–CF Bond
    S. Hayashi, T. Murayama, S. Kusumoto, K. Nozaki
    Angew. Chem. Int. Ed. 2022, 61, e202207760. 10.1002/anie.202207760
  7. Mechanistic Insight into Rh-Catalyzed C(sp2)–O Bond Cleavage Applied to Cross-Coupling Reaction of Benzofurans with Aryl Grignard Reagents
    T. Iwasaki, W. Ishiga, S. Pal, K. Nozaki, N. Kambe
    ACS Catal. 2022, 12, 7936–7949. 10.1021/acscatal.2c01974
  8. Cationic and Neutral Iridium(III) Hydride Complexes Supported by a Rigid, Bidentate Boryl/Phosphine Ligand
    F. Seidel, K. Nozaki
    Organometallics 2022, 41, 1063–1066. 10.1021/acs.organomet.2c00126
  9. Incorporation of CO2-derived Bicyclic Lactone into Conventional Vinyl Polymers
    M. Hill, S. Tang, K. Masada, Y. Hirooka, K. Nozaki
    Macromolecules 2022, 55, 3311–3316. 10.1021/acs.macromol.1c02503
  10. Statistical Analysis of Catalytic Performance in Ethylene/Methyl Acrylate Copolymerization Using Palladium/Phosphine–Sulfonate Catalysts
    S. Akita, J -Y. Guo, F. Seidel, M. Sigman, K. Nozaki
    Organometallics 2022, 41, 3185–3196. 10.1021/acs.organomet.2c00066
  11. Synthesis of Crystalline CF3-Rich Perfluoropolyethers from Hexafluoropropylene Oxide and (Trifluoromethyl)Trimethylsilane
    M. Koyama. M. Akiyama, K. Kashiwagi, K. Nozaki, T. Okazoe
    Macromol. Rapid Commun. 2022, 43, 2200038. 10.1002/marc.202200038
  12. Synthesis and Reactivity of PC(sp3)P-pincer Iridium Complexes Bearing Diborylmethyl Anion
    M. Kishino, S. Takaoka, Y. Shibutani, S. Kusumoto, K. Nozaki
    Dalton Trans. 2022, 51, 5009–5015. 10.1039/D2DT00513A
  13. Atom Swapping on Aromatic Rings: Conversion from Phosphinine Pincer Metal Complexes to Metallabenzenes Triggered by O2 Oxidation
    K. Masada, S. Kusumoto, K. Nozaki
    Angew. Chem. Int. Ed. 2022, 61, e202117096. 10.1002/anie.202117096 Featured on the cover.
  14. Cleavage of Si–H, Si–C Bonds by Metal–Ligand Cooperation: Formation of Silyl Anion and Silylene Equivalents from Tertiary Silanes
    T. Higashi, S. Kusumoto, K. Nozaki
    Organometallics 2022, 41, 659–665. 10.1021/acs.organomet.2c00037 Selected as ACS Editors' Choice. Selected as Most Read Articles in 2022.
  15. A Ni0 σ-Borane Complex Bearing a Rigid Bidentate Borane/Phosphine Ligand: Boryl Complex Formation by Oxidative Dehydrochloroborylation and Catalytic Activity for Ethylene Polymerization
    F. W. Seidel, K. Nozaki
    Angew. Chem. Int. Ed. 2022, 62, e202111691. 10.1002/anie.202111691
  16. Synthesis of Triptycenemonohydroquinonedibenzoquinone by Comproportionation
    Y. Takemasa, K. Nozaki
    J. Org. Chem. 2022, 87, 1502–1506. 10.1021/acs.joc.1c01683 Featured on the cover.
  17. Highly Active Cross Metathesis of Tetrafluoroethylene with a Seven-membered NHC-Ruthenium Catalyst
    K. Mori, M. Akiyama, K. Inada, Y. Imamura, Y. Ishibashi, Y. Takahira, K. Nozaki, T. Okazoe
    J. Am. Chem. Soc. 2021, 143, 20980–20987. 10.1021/jacs.1c10574 Highlighted in Synfact.
  18. One-Pot Synthesis of Polyethylene-Based Block Copolymers via a Dual Polymerization Pathway
    Y. Zhao, J. Jung, K. Nozaki
    J. Am. Chem. Soc. 2021, 143, 18832–18837. 10.1021/jacs.1c08512
  19. Accessing Divergent Main-Chain-Functionalized Polyethylenes via Copolymerization of Ethylene with a CO2/Butadiene-Derived Lactone
    S. Tang, Y. Zhao, K. Nozaki
    J. Am. Chem. Soc. 2021, 143, 17953–17957. 10.1021/jacs.1c08578
  20. High Density Polyethylenes Bearing Isolated In-Chain Carbonyls
    S. Tang, F. W. Seidel, K. Nozaki
    Angew. Chem. Int. Ed. 2021, 60, 26506–26510. 10.1002/anie.202110957
  21. Heterolytic Oxidative Addition of sp2 and sp3 C–H Bonds by Metal–Ligand Cooperation with an Electron-deficient Cyclopentadienone Iridium Complex
    T. Higashi, S. Kusumoto, K. Nozaki
    J. Am. Chem. Soc. 2021, 143, 12999–13004. 10.1021/jacs.1c06714 Featured on the cover.
  22. Lithium Hexaphenylrhodate(III) and –Iridate(III): Structure in the Solid State and in Solution
    T. Iwasaki, Y. Hirooka, H. Takaya, T. Honma, K. Nozaki
    Organometallics 2021, 40, 2489–2495. 10.1021/acs.organomet.1c00248
  23. Metal-Ligand Cooperative κ1-N-pyrazolate Cp*RhIII-Catalysts for Dehydrogenation of Dimethylamine-borane at Room Temperature
    S. Pal, T. Iwasaki, K. Nozaki
    Dalton Trans. 2021, 50, 7938–7943. 10.1039/D1DT01705E
  24. Copolymerization of Ethylene and Methyl Acrylate by Palladium Catalysts Bearing IzQO Ligand Containing Methoxyethyl Ether Moiety and Salt Effect for the Polymerization
    S. Akita, K. Nozaki
    Polym. J. 2021, 53, 1057–1060. 10.1038/s41428-021-00500-3
  25. Metal-Support Cooperation in Al(PO3)3-Supported Pt Nanoparticles for the Selective Hydrogenolysis of Phenols to Arenes
    X. Jin, R. Tsukimura, T. Aihara, H. Miura, T. Shishido, K. Nozaki
    Nat. Catal. 2021, 4, 312–321. 10.1038/s41929-021-00598-x See the article.
    Featured on the cover. Highlighted in press release, UTokyo FOCUS, Chem-Station, UTokyo FOCUS, EurekAlart!, AlphaGalileo, ScienceDaily, Phys.org, ScienMag, Science Bulletin, Mirage News, Laboratory Equipment.
  26. Synthesis and Properties of Spiro-double Sila[7]helicene: The LUMO Spiro-conjugation
    N. Terada, K. Uematsu, R. Higuchi, Y. Tokimaru, Y. Sato, K. Nakano, K. Nozaki
    Chem. Eur. J. 2021, 27, 9342–9349. 10.1002/chem.202100385
  27. Reversible PtII-CH3 Deuteration without Methane Loss: Metal-Ligand Cooperation vs Ligand-Assisted PtII-Protonation
    S. Pal, K. Nozaki, A. Vedernikov, J. Love
    Chem. Sci. 2021, 12, 2960–2969. 10.1039/D0SC06518H
  28. Umpolung of B–H Bonds by Metal–Ligand Cooperation with Cyclopentadienone Iridium Complexes
    T. Higashi, S. Kusumoto, K. Nozaki
    Angew. Chem. Int. Ed. 2021, 60, 2844–2848. 10.1002/anie.202011322
  29. Expedient Synthetic Identification of a Novel P-stereogenic Ligand Motif for the Palladium-Catalyzed Preparation of Isotactic Polar Polypropylenes
    F. W. Seidel, I. Tomizawa, K. Nozaki
    Angew. Chem. Int. Ed. 2020, 59, 22591–22601. 10.1002/anie.202009027 Highlighted in Press Release
  30. Synthesis of and Structural Insights into Contact Ion Pair and Solvent-Separated Ion Pair Diphenyliridate Complexes
    T. Iwasaki, T. Akaiwa, Y. Hirooka, S. Pal, K. Nozaki, N. Kambe
    Organometallics 2020, 39, 3077–3081. 10.1021/acs.organomet.0c00446
  31. Heavy Metal-Free Fischer-Tropsch Type Reaction: Sequential Homologation of Alkylborane Using a Combination of CO and Hydrides as Methylene Source
    A. Phanopoulos, S. Pal, T. Kawakami, K. Nozaki
    J. Am. Chem. Soc. 2020, 142, 14064–14068. 10.1021/jacs.0c06580 Highlighted in Hokkaido Shimbun Press, Science, UTokyo FOCUS, Synfact, and Asian Scientist
  32. Alternating Copolymerization of CO2 and Cyclohexene Oxide Catalyzed by Cobalt-Lanthanide Mixed Multinuclear Complexes
    H. Asaba, T. Iwasaki, M. Hatazawa, J. Deng, H. Nagae, K. Mashima, K. Nozaki
    Inorg. Chem. 2020, 59, 7928–7933. 10.1021/acs.inorgchem.0c01156
  33. Aluminum Porphyrins with Quaternary Ammonium Halides as Catalysts for Copolymerization of Cyclohexene Oxide and CO2: Metal–Ligand Cooperative Catalysis
    J. Deng, M. Ratanasak, Y. Sako, H. Tokuda, C. Maeda, J. Hasegawa, K. Nozaki, T. Ema
    Chem. Sci. 2020, 11, 5669–5675. 10.1039/D0SC01609H
  34. Metal–Metal Cooperative Bond Activation by Heterobimetallic Alkyl, Aryl, and Acetylide PtII/CuI Complexes
    S. Deolka, O. Rivada, S. L. Aristizábal, R. R. Fayzullin, S. Pal, K. Nozaki, E. Khaskin, J. R. Khusnutdinova
    Chem. Sci. 2020, 11, 5494–5502. 10.1039/D0SC00646G
  35. Reductive Coupling of Carbon Dioxide and an Aldehyde Mediated by a Copper(I) Complex toward the Synthesis of α-Hydroxycarboxylic Acids
    K. Masada, S. Kusumoto, K. Nozaki
    Org. Lett. 2020, 22, 4922–4926. 10.1021/acs.orglett.0c00995 Featured on the cover
  36. Copolymerization of Nonpolar Olefins and Allyl Acetate Using Nickel Catalysts Bearing a Methylene-bridged Bisphosphine Monoxide Ligand
    J. Jung, H. Yasuda, K. Nozaki
    Macromolecules 2020, 53, 2547–2556. 10.1021/acs.macromol.0c00183
  37. Synthesis of unsymmetrically substituted triarylamines via acceptorless dehydrogenative aromatization using a Pd/C and p-toluenesulfonic acid hybrid relay catalyst
    S. Takayama, T. Yatabe, Y. Koizumi, X. Jin, K. Nozaki, N. Mizuno, K. Yamaguchi
    Chem. Sci. 2020, 11, 4074–4084. 10.1039/C9SC06442G
  38. An Endergonic Synthesis of Single Sondheimer-Wong Diyne by Local Probe Chemistry
    S. Kawai, H. Sang, L. Kantorovich, K. Takahashi, K. Nozaki, S. Ito
    Angew. Chem. Int. Ed. 2020, 59, 10842–10847. 10.1002/anie.202001268
  39. Cleavage of C–C and C–O bonds in β-O-4 Linkage of Lignin Model Compound by Cyclopentadienone Group 8 and 9 Metals Complexes
    S. Kusumoto, M. Kishino, K. Nozaki
    Chem. Lett. 2020, 49, 477–480. 10.1246/cl.200037
  40. Synthesis of Fluorinated Dialkyl Carbonates from Carbon Dioxide as a Carbonyl Source
    M. Sugiyama, M. Akiyama, K. Nishiyama, T. Okazoe, K. Nozaki
    ChemSusChem 2020, 13, 1775–1784. 10.1002/cssc.202000090
  41. Single-molecule single-electron transistor (SM-SET) based on π-conjugated quinoidal-fused oligosilole and heteroepitaxial spherical Au/Pt nanogap electrodes
    S. Lee, J. Kim, T. Tsuda, R. Takano, R. Shintani, K. Nozaki, Y. Majima
    Appl. Phys. Express 2019, 12, 125007. 10.7567/1882-0786/ab56e5
  42. Synthesis of Polyethylene with in-chain α,β-Unsaturated Ketone and Isolated Ketone Units by Pd-catalyzed Ring-opening Copolymerization of Cyclopropenones with Ethylene
    X. Wang, F. W. Seidel, K. Nozaki
    Angew. Chem. Int. Ed. 2019, 58, 12955–12959. 10.1002/anie.201906990
  43. Reversible Polymer-Chain Modification: Ring-Opening and Closing of Polylactone
    S. Moon, K. Masada, K. Nozaki
    J. Am. Chem. Soc. 2019, 141, 10938–10942. 10.1021/jacs.9b03205
  44. Stepwise Reduction of Azapentabenzocorannulene
    Z. Zhou, Z. Wei, Y. Tokimaru, S. Ito, K. Nozaki, M. A. Petrukhina
    Angew. Chem. Int. Ed. 2019, 58, 12107–12111. 10.1002/anie.201906748
  45. Selective Synthesis of Primary Anilines from NH3 and Cyclohexanones by Utilizing Preferential Adsorption of Styrene on the Pd Nanoparticle Surface
    Y. Koizumi, X. Jin, T. Yatabe, R. Miyazaki, J. Hasegawa, K. Nozaki, N. Mizuno, K. Yamaguchi
    Angew. Chem. Int. Ed. 2019, 58, 10893–10897. 10.1002/anie.201903841
  46. Cyanide Free One-pot Synthesis of Methacrylic Esters from Acetone
    M. Koyama, T. Kawakami, T. Okazoe, K. Nozaki
    Chem. Eur. J. 2019, 25, 10913–10917. 10.1002/chem.201901933
  47. Metal–Ligand Cooperative C–H Bond Formation by Cyclopentadienone Platinum Complexes
    T. Higashi, H. Ando, S. Kusumoto, K. Nozaki
    J. Am. Chem. Soc. 2019, 141, 2247–2250. 10.1021/jacs.8b13829
  48. Synthesis of carbonyl-bridged dibenzofulvalenes and related compounds by rhodium-catalyzed stitching reaction
    R. Shintani, S. Kishikawa, K. Nakamura, T. Tsuda, K. Nozaki
    Chem. Commun. 2019, 55, 1072–1075. 10.1039/C8CC09943J
  49. Selective Chain-end Functionalization of Polar Polyethylenes: Orthogonal Reactivity of Carbene and Polar Vinyl Monomers in Their Copolymerization with Ethylene
    X. Wang, K. Nozaki
    J. Am. Chem. Soc. 2018, 140, 15635–15640. 10.1021/jacs.8b10335
  50. Palladium Complexes Bearing an N-Heterocyclic Carbene–Sulfonamide Ligand for Cooligomerization of Ethylene and Polar Monomers
    W. Tao, X. Wang, S. Ito, K. Nozaki
    J. Polym. Sci. Part A: Polym. Chem. 2019, 57, 474–477. 10.1002/pola.29270
  51. Functionalization of Azapentabenzocorannulenes via Five-fold C-H Borylation and Cross-Coupling Arylation: Application to Columnar Liquid Crystalline Materials
    T. Nagano, K. Nakamura, Y. Tokimaru, S. Ito, D. Miyajima, T. Aida, K. Nozaki
    Chem. Eur. J. 2018, 53, 14075–14078. 10.1002/chem.201803676
  52. Hydrogenation of Carbon Dioxide with Organic Base by PC(II)P-Ir Catalysts
    S. Takaoka, A. Eizawa, S. Kusumoto, K. Nakajima, Y. Nishibayashi, K. Nozaki
    Organometallics 2018, 37, 3001–3009. 10.1021/acs.organomet.8b00377 Featured on the cover
  53. Single-step construction of the anti-deoxypropionate motif from propylene: Formal total synthesis of the cuticular hydrocarbons isolated from Antitrogus parvulus
    T. Murayama, K. Nozaki
    Angew. Chem. Int. Ed. 2018, 57, 11394–11398. 10.1002/anie.201804711
  54. Synthesis and Reactivity of Methylpalladium Complexes Bearing a Partially Saturated IzQO Ligand
    S. Akita, R. Nakano, S. Ito, K. Nozaki
    Organometallics 2018, 37, 2286–2296. 10.1021/acs.organomet.8b00263
  55. Hybrid of Corannulene and Azacorannulene: Synthesis of a Highly Curved Nitrogen-Containing Buckybowl
    Y. Tokimaru, S. Ito, K. Nozaki
    Angew. Chem. Int. Ed. 2018, 57, 9818–9822. 10.1002/anie.201805678
  56. Palladium-Catalyzed Intramolecular C–H Arylation vs. 1,5-Palladium Migration: Theoretical Investigation
    N. Misawa, T. Tsuda, R. Shintani, K. Yamashita, K. Nozaki
    Chem. Asian. J. 2018, 13, 2566–2572. 10.1002/asia.201800603
  57. Phosphorescence Resulting from Interaction between Two Non-equivalent Metals on a Helical π-Conjugated Surface
    M. Akiyama, Y. Tsuchiya, A. Ishii, M. Hasegawa, Y. Kurashige, K. Nozaki
    Chem. Asian. J. 2018, 13, 1902-1905. 10.1002/asia.201800780
  58. Branched-Selective Hydroformylation of Non-Activated Olefins Using a N-Triphos/Rh Catalyst
    A. Phanopoulos, K. Nozaki
    ACS Catal. 2018, 8, 5799-5809. 10.1021/acscatal.8b00566
  59. Dehydrogenation of dimethylamine-borane catalyzed by half-sandwich Ir and Rh complexes: Mechanism and the role of Cp* non-innocence
    S. Pal, S. Kusumoto, K. Nozaki
    Organometallics 2018, 37, 906–914. 10.1021/acs.organomet.7b00889
  60. Methylene-Bridged Bisphosphine Monoxide Ligands for Palladium-Catalyzed Copolymerization of Ethylene and Polar Monomers
    Y. Mitsushige, H. Yasuda, B. Carrow, S. Ito, M. Kobayashi, T. Tayano, Y. Watanabe, Y. Okuno, S. Hayashi, J. Kuroda, Y. Okumura, K. Nozaki
    ACS Macro Lett. 2018, 7, 305–311. 10.1021/acsmacrolett.8b00034
  61. Nickel-Catalyzed Propylene/Polar Monomer Copolymerization
    Y. Konishi, W. Tao, H. Yasuda, S. Ito, Y. Oishi, H. Ohtaki, A. Tanna, T. Tayano, K. Nozaki
    ACS Macro Lett. 2018, 7, 213–217. 10.1021/acsmacrolett.7b00904
  62. Palladium/IzQO-Catalyzed Coordination–Insertion Copolymerization of Ethylene and 1,1-Disubstituted Ethylenes Bearing a Polar Functional Group
    H. Yasuda, R. Nakano, S. Ito, K. Nozaki
    J. Am. Chem. Soc. 2018, 140, 1876–1883. 10.1021/jacs.7b12593
  63. Synthesis of Pyrrole-Fused Corannulenes: 1,3-Dipolar Cycloaddition of Azomethine Ylides to Corannulene
    Y. Tokimaru, S. Ito, K. Nozaki
    Angew. Chem. Int. Ed. 2017, 56, 15560–15564. 10.1002/anie.201707087 Highlighted in Synfacts
  64. Cationic Co-Salphen Complexes Bisligated by DMAP as Catalysts for the Copolymerization of Cyclohexene Oxide with Phthalic Anhydride or Carbon Dioxide
    M. Hatazawa, R. Takahashi, J. Deng, H. Houjou, K. Nozaki
    Macromolecules 2017, 50, 7895–7900. 10.1021/acs.macromol.7b01130
  65. Selective Synthesis of Primary Anilines from Cyclohexanone Oximes by the Concerted Catalysis of a Mg−Al Layered Double Hydroxide Supported Pd Catalyst
    X. Jin, Y. Koizumi, K. Yamaguchi, K. Nozaki, N. Mizuno
    J. Am. Chem. Soc. 2017, 139, 13821-13829. 10.1021/jacs.7b07347
  66. Formal arylation of NH3 to produce diphenylamines over supported Pd catalysts
    Y. Koizumi, K. Taniguchi, X. Jin, K. Yamaguchi, K. Nozaki, N. Mizuno
    Chem. Commun. 2017, 53, 10827–10830. 10.1039/C7CC06737B
  67. Competing Annulene and Radialene Structures in a Single Anti-Aromatic Molecule Studied by High-Resolution Atomic Force Microscopy
    S. Kawai, K. Takahashi, S. Ito, R. Pawlak, T. Meier, P. Spijker, F. F. Canova, J. Tracey, K. Nozaki, A. S. Foster, E. Meyer
    ACS Nano 2017, 11, 8122–8130. 10.1021/acsnano.7b02973
  68. Palladium-Catalyzed Asymmetric Synthesis of Silicon-Stereogenic 5,10-Dihydrophenazasilines via Enantioselective 1,5-Palladium Migration
    Y. Sato, C. Takagi, R. Shintani, K. Nozaki
    Angew. Chem. Int. Ed. 2017, 31, 9211–9216. 10.1002/anie.201705500
  69. Cp*Ir-catalyzed Acceptorless Dehydrogenation of Carbon–Carbon Single Bonds
    H. Ando, S. Kusumoto, W. Wu, K. Nozaki
    Organometallics 2017, 36, 2317–2322. 10.1021/acs.organomet.7b00245
  70. Structures and Physical Properties of Chemically Reduced Diindenosiloles and Their π-Extended Derivatives
    R. Takano, R. Shintani, A. Fukazawa, S. Yamaguchi, K. Nakabayashi, S. Ohkoshi, K. Nozaki
    Organometallics 2017, 36, 2646–2653. 10.1021/acs.organomet.7b00260
  71. A Ni-Mg-Al layered triple hydroxide-supported Pd catalyst for heterogeneous acceptorless dehydrogenative aromitization
    X. Jin, K. Taniguchi, K. Yamaguchi, K. Nozaki, N. Mizuno
    Chem. Commun. 2017, 53, 5267–5270. 10.1039/C7CC01182B
  72. Synthesis of Quinoidal Fused Oligosiloles by Rhodium-Catalyzed Stitching Reaction and Theoretical Investigation of Their Properties
    R. Shintani, N. Misawa, T. Tsuda, R. Iino, M. Fujii, K. Yamashita, K. Nozaki
    J. Am. Chem. Soc. 2017, 139, 3861–3867. 10.1021/jacs.7b00344 Highlited in Synfacts
  73. Copolymerisation of Ethylene with Polar Monomers by Palladium Catalysts Bearing an N-Heterocyclic Carbene–Phosphine Oxide Bidentate Ligand
    W. Tao, S. Akita, R. Nakano, S. Ito, Y. Hoshimoto, S. Ogoshi, K. Nozaki
    Chem. Commun. 2017, 53, 2630–2633. 10.1039/C7CC00002B
  74. Facile styrene formation from ethylene and a phenylplatinum(II) complex leading to an observable platinum(II)-hydride
    S. Pal, S. Kusumoto, K.Nozaki
    Organometallics 2017, 36, 502–505. 10.1021/acs.organomet.6b00892
  75. Synthesis of Optically Pure Helicene Metallocenes
    M. Akiyama, K. Nozaki
    Angew. Chem. Int. Ed. 2017, 56, 2040–2044. 10.1002/anie.201611488
  76. Rhodium-Catalyzed Synthesis and Optical Properties of Silicon-Bridged Arylpyridines
    R. Shintani, N. Misawa, R. Takano, K. Nozaki
    Chem. Eur. J. 2017, 23, 2660–2665. 10.1002/chem.201605000
  77. Versatile routes for synthesis of diarylamines through acceptorless dehydrogenative aromatization catalysis over supported gold–palladium bimetallic nanoparticles
    K. Taniguchi, X. Jin, K. Yamaguchi, K. Nozaki, N. Mizuno
    Chem. Sci. 2017, 8, 2131–2142. 10.1039/C6SC04455G
  78. Selective Synthesis of Unsymmetric Dibenzo[a,e]pentalenes by Rhodium-Catalysed Stitching Reaction
    K. Takahashi, S. Ito, R. Shintani, K. Nozaki
    Chem. Sci. 2017, 8, 101–107. 10.1039/C6SC04560J Featured on the back cover. Highlighted in Synfacts
  79. A Potassium Diboryllithate: Synthesis, Bonding Properties, and the Deprotonation of Benzene
    T. Ohsato, Y. Okuno, S. Ishida, T. Iwamoto, K.-H. Lee, Z. Lin, M. Yamashita, K. Nozaki
    Angew. Chem. Int. Ed. 2016, 55, 11426–11430. 10.1002/anie.201605005
  80. Elucidating the Key Role of Phosphine–Sulfonate Ligands in Palladium-Catalyzed Ethylene Polymerization: Effect of Ligand Structure on the Molecular Weight and Linearity of Polyethylene
    R. Nakano, L. W. Chung, Y. Watanabe, Y. Okuno, Y. Okumura, S. Ito, K. Morokuma, K. Nozaki
    ACS Catal. 2016, 6, 6101–6113. 10.1021/acscatal.6b00911
  81. Synthesis and Properties of [7]Helicene-like Compounds Fused with a Fluorene Unit
    H. Oyama, M. Akiyama, K. Nakano, M. Naito, K. Nobusawa, K. Nozaki
    Org. Lett. 2016, 18, 3654–3657. 10.1021/acs.orglett.6b01708
  82. In Situ Generation of Salen/Co(III) Complexes for Copolymerization of Propylene Oxide and CO2
    M. Hatazawa, K. Nakabayashi, S. Ohkoshi, K. Nozaki
    Chem. Eur. J. 2016, 22, 13677–13681. 10.1002/chem.201602546
  83. Reactions of 2-Methyltetrahydropyran on Silica-Supported Nickel Phosphide in Comparison with 2-Methyltetrahydrofuran
    P. P. Bui, S. T. Oyama, A. Takagaki, B. P. Carrow, K. Nozaki
    ACS Catal. 2016, 6, 4549–4558. 10.1021/acscatal.6b01033
  84. Intermolecular Three-Component Arylsilylation of Alkynes under Palladium/Copper Cooperative Catalysis
    R. Shintani, H. Kurata, K. Nozaki
    J. Org. Chem. 2016, 81, 3065–3069. 10.1021/acs.joc.6b00587
  85. Crystalline Isotactic Polar Polypropylene from the Palladium-Catalyzed Copolymerization of Propylene and Polar Monomers
    Y. Ota, S. Ito, M. Kobayashi, S. Kitade, K. Sakata, T. Tayano, K. Nozaki
    Angew. Chem. Int. Ed. 2016, 55, 7505–7509. 10.1002/anie.201600819
  86. Rhodium-Catalyzed Stitching Reaction: Convergent Synthesis of Quinoidal Fused Oligosiloles
    R. Shintani, R. Iino, K. Nozaki
    J. Am. Chem. Soc. 2016, 138, 3635–3638. 10.1021/jacs.6b00082 highlighted in Synfacts
  87. A Qualitative Analysis of a “Bora-Brook Rearrangement”: the Ambident Reactivity of Boryl-Substituted Alkoxide Including the Carbon-to-Oxygen Migration of a Boryl Group
    H. Kisu, H. Sakaino, F. Ito, M. Yamashita, K. Nozaki
    J. Am. Chem. Soc. 2016, 138, 3548–3552. 10.1021/jacs.6b00283
  88. One-step catalytic asymmetric synthesis of all-syn deoxypropionate motif from propylene: Total synthesis of (2R,4R,6R,8R)-2,4,6,8-tetramethyldecanoic acid
    Y. Ota, T. Murayama, K. Nozaki
    Proc. Natl. Acad. Sci. USA 2016, 113, 2857–2861. 10.1073/pnas.1518898113 highlighted in UTokyo Research (Japanese), UTokyo Research (English), and Synform
  89. Pyrazole Supported Zinc(II) Benzoates as Catalysts for the Ring Opening Copolymerization of Cyclohexene Oxide and Carbon Dioxide
    M. L. Lephoto, K. Nakano, D. Appavoo, B. O. Owaga, K. Nozaki, J. Darkwa
    Catalysts 2016, 6, 17. 10.3390/catal6010017
  90. Copolymerization of Ethylene and Polar Monomers Using Ni/IzQO Catalysts
    W. Tao, R. Nakano, S. Ito, K. Nozaki
    Angew. Chem. Int. Ed. 2016, 55, 2835–2839. 10.1002/anie.201510077
  91. Rhodium-Catalyzed Asymmetric Synthesis of Silicon-Stereogenic Silicon-Bridged Arylpyridinones
    R. Shintani, R. Takano, K. Nozaki
    Chem. Sci. 2016, 7, 1205–1211. 10.1039/C5SC03767K highlighted in Synfacts
  92. Ligand-Controlled Insertion Regioselectivity Accelerates Copolymerisation of Ethylene with Methyl Acrylate by Cationic Bisphosphine Monoxide-Palladium Catalysts
    Y. Mitsushige, B. P. Carrow, S. Ito, K. Nozaki
    Chem. Sci. 2016, 7, 737–744. 10.1039/C5SC03361F
  93. Iron-Catalyzed Homo- and Copolymerization of Propylene: Steric Influence of Bis(imino)pyridine Ligands
    T. Kawakami, S. Ito, K. Nozaki
    Dalton Trans. 2015, 44, 20745–20752. 10.1039/C5DT03551A
  94. Development of Highly Active Ir–PNP Catalysts for Hydrogenation of Carbon Dioxide with Organic Bases
    W. Aoki, N. Wattanabinin, S. Kusumoto, K. Nozaki
    Bull. Chem. Soc. Jpn. 2016, 89, 113–124. 10.1246/bcsj.20150311 highlighted as BCSJ Selected Papers
  95. Copolymerization of Propylene and Polar Monomers Using Pd/IzQO Catalysts
    R. Nakano, K. Nozaki
    J. Am. Chem. Soc. 2015, 137, 10934–10937. 10.1021/jacs.5b06948 highlighted in ACS Selects Virtual Issue
  96. Rhodium-Catalyzed Intramolecular Alkynylsilylation of Alkynes
    R. Shintani, H. Kurata, K. Nozaki
    Chem. Commun. 2015, 51, 11378–11381. 10.1039/C5CC04172D highlighted in Chemistry World
  97. The Retro-Hydroformylation Reaction
    S. Kusumoto, T. Tatsuki, K. Nozaki
    Angew. Chem. Int. Ed. 2015, 54, 8458–8461. 10.1002/anie.201503620 highlighted in Front cover, Wiley-Japan Science Cafe, and 現代化学
  98. Benzene-Fused Azacorannulene Bearing an Internal Nitrogen Atom
    S. Ito, Y. Tokimaru, K. Nozaki
    Angew. Chem. Int. Ed. 2015, 54, 7256–7260. 10.1002/anie.201502599 highlighted in Frontispiece and Synfacts
  99. Formal Aryne/Carbon Monoxide Copolymerization to Form Aromatic Polyketones/Polyketals
    S. Ito, W. Wang, K. Nishimura, K. Nozaki
    Macromolecules 2015, 48, 1959–1962. 10.1021/acs.macromol.5b00315
  100. Synthesis and Properties of Benzophospholo[3,2-b]benzofuran Derivatives
    M. Takahashi, K. Nakano, K. Nozaki
    J. Org. Chem. 2015, 80, 3790–3797. 10.1021/jo502889r highlighted in Synfacts
  101. Formal Aryne/Ethylene Copolymerization to Form Polyethylene Containing o-Arylene Units in the Main Chain
    S. Ito, W. Wang, K. Nozaki
    Polym. J. 2015, 47, 474–480. 10.1038/pj.2015.27
  102. Direct and Selective Hydrogenolysis of Arenols and Aryl Methyl Ethers
    S. Kusumoto, K. Nozaki
    Nat. Commun. 2015, 6, 6296. 10.1038/ncomms7296 highlighted in C&E News and UTokyo Research.
  103. Rhodium-Catalyzed Asymmetric Synthesis of Silicon-Stereogenic Dibenzosiloles via Enantioselective [2+2+2] Cycloaddition
    R. Shintani, C. Takagi, T. Ito, M. Naito, K. Nozaki
    Angew. Chem. Int. Ed. 2015, 54, 1616–1620. 10.1002/anie.201409733
  104. Isoquinolino[4,3,2-de]phenanthridine: Synthesis and Its Use in 1,3-Dipolar Cycloadditions to Form Nitrogen-Containing Polyaromatic Hydrocarbons
    S. Ito, Y. Tokimaru, K. Nozaki
    Chem. Commun. 2015, 51, 221–224. 10.1039/C4CC06643J
  105. Ruthenium Catalyzed Hydrogenation of Aldehyde with Synthesis Gas
    K. Takahashi, K. Nozaki
    Org. Lett. 2014, 16, 5846–5849. 10.1021/ol502681y
  106. Quantification of the Steric Influence of Alkylphosphine–Sulfonate Ligands on Polymerization, Leading to High-Molecular-Weight Copolymers of Ethylene and Polar Monomers
    Y. Ota, S. Ito, J. Kuroda, Y. Okumura, K. Nozaki
    J. Am. Chem. Soc. 2014, 136, 11898–11901. 10.1021/ja505558e
  107. Facile Estimation of Catalytic Activity and Selectivities in Copolymerization of Propylene Oxide with Carbon Dioxide Mediated by Metal Complexes with Planer Tetradentate Ligand
    T. Ohkawara, K. Suzuki, K. Nakano, S. Mori, K. Nozaki
    J. Am. Chem. Soc. 2014, 136, 10728–10735. 10.1021/ja5046814 highlighted in JACS Spotlight.
  108. Rhodium-Catalyzed Polymerization of 3,3-Diarylcyclopropenes Involving a 1,4-Rhodium Migration
    R. Shintani, R. Iino, K. Nozaki
    J. Am. Chem. Soc. 2014, 136, 7849–7852. 10.1021/ja5032002 highlighted in Synfacts.
  109. Formal Aryne Polymerization: Use of [2.2.1]Oxabicyclic Alkenes as Aryne Equivalents
    S. Ito, K. Takahashi, K. Nozaki
    J. Am. Chem. Soc. 2014, 136, 7547–7550. 10.1021/ja502073k highlighted in Synfacts.
  110. Silylative Cyclopropanation of Allyl Phosphates with Silylboronates
    R. Shintani, R. Fujie, M. Takeda, K. Nozaki
    Angew. Chem. Int. Ed. 2014, 53, 6546–6549. 10.1002/anie.201403726 highlighted in Synfacts.
  111. Assessing the Brønsted Basicity of Diaminoboryl Anions: Reactivity toward Methylated Benzenes and Dihydrogen
    N. Dettenrieder, Y. Aramaki, B. Wolf, C. Maichle-Mössmer, X. Zhao, M. Yamashita, K. Nozaki, R. Anwander
    Angew. Chem. Int. Ed. 2014, 53, 6259–6262. 10.1002/anie.201402175
  112. Copolymerization of Carbon Dioxide and Butadiene via a Lactone Intermediate
    R. Nakano, S. Ito, K. Nozaki
    Nature Chem. 2014, 6, 325–331. 10.1038/nchem.1882 highlighted in Nature Chemistry, Chemistry World, C&E News, Chemical Enginnering, Chem-Station, Angew. Chem. Int. Ed..
  113. Manganese-Corrole Complex as a Versatile Catalyst for Ring-Opening Homo- and Co-polymerization of Epoxide
    C. Robert, T. Ohkawara, K. Nozaki
    Chem. Eur. J. 2014, 20, 4789–4795. 10.1002/chem.201303703
  114. Solvent and Co-catalyst Dependent Pyrazolylpyridinamine and Pyrazolylpyrroleamine Nickel(II) Catalyzed Oligomerization and Polymerization of Ethylene
    C. Obuah, B. Omondi, K. Nozaki, J. Darkwa
    J. Mol. Catal. A: Chem. 2014, 382, 31–40. 10.1016/j.molcata.2013.10.024
  115. Acceptorless Dehydrogenation of C–C Single Bonds Adjacent to Functional Groups by Metal-Ligand Cooperation
    S. Kusumoto, M. Akiyama, K. Nozaki
    J. Am. Chem. Soc. 2013, 135, 18726–18729. 10.1021/ja409672w
  116. Tandem Isomerization/Hydroformylation/Hydrogenation of Internal Alkenes to normal-Alcohols Using Rh/Ru Dual or Ternary Catalyst Systems
    Y. Yuki, K. Takahashi, Y. Tanaka, K. Nozaki
    J. Am. Chem. Soc. 2013, 135, 17393–17400. 10.1021/ja407523j
  117. Direct Aldol Polymerization of Acetaldehyde with Organocatalyst/Brønsted Acid Systems
    S. Kusumoto, S. Ito, K. Nozaki
    Asian J. Org. Chem. 2013, 2, 977–982. 10.1002/ajoc.201300134 This paper will be listed in a special issue on the Mukaiyama aldol reaction.
  118. Efficient Catalyst Removal and Recycling in Copolymerization of Epoxides with Carbon Dioxide via Simple Liquid–Liquid Phase Separation
    K. Nakano, R. Fujie, R. Shintani, K. Nozaki
    Chem. Commun. 2013, 49, 9332–9334. 10.1039/C3CC45622F
  119. Copolymerization of Epoxides with Carbon Dioxide Catalyzed by Iron–Corrole Complexes: Synthesis of a Crystalline Copolymer
    K. Nakano, K. Kobayashi, T. Ohkawara, H. Imoto, K. Nozaki
    J. Am. Chem. Soc. 2013, 135, 8456–8459. 10.1021/ja4028633
  120. Oxidative Addition of a Strained C–C Bond onto Electron-Rich Rhodium(I) at Room Temperature
    Y. Masuda, M. Hasegawa, M. Yamashita, K. Nozaki, N. Ishida, M. Murakami
    J. Am. Chem. Soc. 2013, 135, 7142–7145. 10.1021/ja403461f
  121. Facile Synthetic Route to Highly Luminescent Sila[7]helicene
    H. Oyama, K. Nakano, T. Harada, R. Kuroda, M. Naito, K. Nobusawa, K. Nozaki
    Org. Lett. 2013, 15, 2104–2107. 10.1021/ol4005036 highlighted in Noteworthy Chemistry
  122. Copper-Catalyzed Hydroboration of Carbon Dioxide
    R. Shintani, K. Nozaki
    Organometallics 2013, 32, 2459–2462. 10.1021/om400175h
  123. Ethylene and Styrene Carbon Monoxide Copolymerization Catalyzed by Pyrazolyl Palladium(II) Complexes
    C. Obuah, M. K. Ainooson, S. Boltina, I. A. Guzei, K. Nozaki, J. Darkwa
    Organometallics 2013, 32, 980–988. 10.1021/om300798y
  124. Synthesis and Characterization of B-Heterocyclic π-Radical and Its Reactivity as a Boryl Radical
    Y. Aramaki, H. Omiya, M. Yamashita, K. Nakabayashi, S.-i. Ohkoshi, K. Nozaki
    J. Am. Chem. Soc. 2012, 134, 19989–19992. 10.1021/ja3094372
  125. Tandem Hydroformylation/Hydrogenation of Alkenes to normal-Alcohols Using Rh/Ru Dual Catalyst or Ru Single Component Catalyst
    K. Takahashi, M. Yamashita, K. Nozaki
    J. Am. Chem. Soc. 2012, 134, 18746–18757. 10.1021/ja307998h
  126. Ethylene/Allyl Monomer Cooligomerization by Nickel/Phosphine–Sulfonate Catalysts
    S. Ito, Y. Ota, K. Nozaki
    Dalton Trans. 2012, 41, 13807–13809. 10.1039/C2DT31771K
  127. Ping-Pong Polymerization by Allylation and Hydroformylation for Alternating Vinyl Alcohol-Vinyl Monomer Copolymers
    S. Ito, M. Noguchi, K. Nozaki
    Chem. Commun. 2012, 48, 10481–10483. 10.1039/C2CC34980A Featured in the front cover
  128. P-Chiral Phosphine–Sulfonate/Palladium-Catalyzed Asymmetric Copolymerization of Vinyl Acetate with Carbon Monoxide
    A. Nakamura, T. Kageyama, H. Goto, B. P. Carrow, S. Ito, K. Nozaki
    J. Am. Chem. Soc. 2012, 134, 12366–12369. 10.1021/ja3044344
  129. Synthesis of Functional Polyolefins Using Cationic Bisphosphine Monoxide-Palladium Complexes
    B. P. Carrow, K. Nozaki
    J. Am. Chem. Soc. 2012, 134, 8802–8805. 10.1021/ja303507t
  130. Isolation of PBP-Pincer Rhodium Complex Stabilized by an Intermolecular C-H sigma-Coordination as the Fourth Ligand
    M. Hasegawa, Y. Segawa, M. Yamashita, K. Nozaki
    Angew. Chem. Int. Ed. 2012, 51, 6956–6960. 10.1002/anie.201201916
  131. CpRu/C5Me5/Bisphosphine- or Bisphosphite-Based Catalysts for normal-Selective Hydroformylation
    K. Takahashi, M. Yamashita, Y. Tanaka, K. Nozaki
    Angew. Chem. Int. Ed. 2012, 51, 4283–4387. 10.1002/anie.201108396
  132. Syntheses and Thermolysis of Arylpalladium Hydroxide Complexes: Implications for C(sp2)–OH Bond-Forming Reductive Elimination to Generate Phenol Derivatives
    Y. Hayashi, S. Wada, M. Yamashita, K. Nozaki
    Organometallics 2012, 31, 1073–1081. 10.1021/om201142s
  133. Mechanistic Studies on the Reversible Hydrogenation of Carbon Dioxide Catalyzed by an Ir-PNP Complex
    R. Tanaka, M. Yamashita, L. W. Chung, K. Morokuma, K. Nozaki
    Organometallics 2011, 30, 6742–6750. 10.1021/om2010172
  134. Phosphora[7]helicenes: Synthesis, Properties, and Columnar Aggregation with One-Way Chirality
    K. Nakano, H. Oyama, Y. Nishimura, S. Nakasako, K. Nozaki
    Angew. Chem. Int. Ed. 2012, 51, 695–699. 10.1002/anie.201106157
  135. Ethylene Polymerization by Palladium/Phosphine–Sulfonate Catalysts in the Presence and Absence of Protic Solvents: Structural and Mechanistic Differences
    M. Kanazawa, S. Ito, K. Nozaki
    Organometallics 2011, 30, 6049–6052. 10.1021/om2004207
  136. Tetravalent Metal Complexes as a New Family of Catalysts for Copolymerization of Epoxides with Carbon Dioxide
    K. Nakano, K. Kobayashi, K. Nozaki
    J. Am. Chem. Soc. 2011, 133, 10720–10723. 10.1021/ja203382q
  137. One-Pot Carboboration of Alkynes Using Lithium Borylcyanocuprate and the Subsequent Suzuki-Miyaura Cross-Coupling Reaction of Resulting Tetrasubstituted Alkenylborane
    Y. Okuno, M. Yamashita, K. Nozaki
    Eur. J. Org. Chem. 2011, 3951–3958. 10.1002/ejoc.201100373 The picture of Prof. Kyoko Nozaki appeared on the cover picture of this Special Issue: Women in Chemistry
  138. Pd-Catalyzed Copolymerization of Methyl Acrylate with Carbon Monoxide: Structures, Properties and Mechanistic Aspects toward Ligand Design
    A. Nakamura, K. Munakata, S. Ito, T. Kochi, L. W. Chung, K. Morokuma, K. Nozaki
    J. Am. Chem. Soc. 2011, 133, 6761–6779. 10.1021/ja2003268
  139. Syntheses and Properties of Triborane(5) Possessing Bulky Diamino Substituents on Terminal Boron Atoms
    Y. Hayashi, Y. Segawa, M. Yamashita, K. Nozaki
    Chem. Commun. 2011, 47, 5888–5890. 10.1039/C1CC11334H
  140. Stereocomplex of Poly(propylene carbonate): Synthesis of Stereogradient Poly(propylene carbonate) via Stereo- and Enantioselective Copolymerization of Propylene Oxide with Carbon Dioxide
    K. Nakano, S. Hashimoto, M. Nakamura, T. Kamada, K. Nozaki
    Angew. Chem. Int. Ed. 2011, 50, 4868–4871. 10.1002/anie.201007958 selected as VIP, highlighted in Nature Chemistry
  141. Coordination-Insertion Copolymerization of Allyl Monomers with Ethylene
    S. Ito, M. Kanazawa, K. Munakata, J. Kuroda, Y. Okumura, K. Nozaki
    J. Am. Chem. Soc. 2011, 133, 1232–1235. 10.1021/ja1092216
  142. Vinylarene/CO Copolymerization and Vinylarene/Polar Vinyl Monomer/CO Terpolymerization Using Palladium/Phosphine-Sulfonate Catalysts
    T. Kageyama, S. Ito, K. Nozaki
    Chem. Asian J. 2011, 6, 690–697. 10.1002/asia.201000668
  143. Borylcyanocuprate in a One-Pot Carboboration by a Sequential Reaction with an Electron-Deficient Alkyne and an Organic Carbon Electrophile
    Y. Okuno, M. Yamashita, K. Nozaki
    Angew. Chem. Int. Ed. 2011, 50, 920–923. 10.1002/anie.201005667
  144. Why Did Incorporation of Acrylonitrile to a Linear Polyethylene Become Possible? Comparison of Phosphine-Sulfonate Ligand with Diphosphine and Imine-Phenolate Ligands in the Pd-Catalyzed Ethylene/Acrylonitrile Copolymerization
    K. Nozaki, S. Kusumoto, S. Noda, T. Kochi, L. W. Chung, K. Morokuma
    J. Am. Chem. Soc. 2010, 132, 16030–16042. 10.1021/ja104837h
  145. A Catalytic Synthesis of Dialkylamines from Alkylamines Using Neopentyl-Substituted PNP Pincer Iridium Complex
    M. Yamashita, Y. Moroe, T. Yano, K. Nozaki
    Inorg. Chim. Acta 2011, 369, 15–18. 10.1016/j.ica.2010.08.034
  146. New Class of Catalysts for Alternating Copolymerization of Alkylene Oxide and Carbon Dioxide
    A. Okada, S. Kikuchi, K. Nakano, K. Nishioka, K. Nozaki, T. Yamada
    Chem. Lett. 2010, 39, 1066–1068. 10.1246/cl.2010.1066
  147. Boryltrihydroborate:Synthesis, Structure, and Reactivity as a Reductant in Ionic, Organometallic and Radical Reactions
    K. Nozaki, Y. Aramaki, M. Yamashita, S.-H. Ueng, M. Malacria, E. Lacote, D. Curran
    J. Am. Chem. Soc. 2010, 132, 11449–11451. 10.1021/ja105277u
  148. Reduction of Base-Stabilized Difluoroboranes to Induce Rearrangement Reactions
    M. Yamashita, Y. Aramaki, K. Nozaki
    New J. Chem. 2010, 34, 1774–1782. 10.1039/C0NJ00363H
  149. New Low Temperature NMR Studies Establish the Presence of a Second Equatorial-Apical Isomer of [(R,S)-Binaphos](CO)2RhH
    D. A. Castillo Molina, C. P. Casey, I. Müller, K. Nozaki, C. Jäkel
    Organometallics 2010, 29, 3362–3367. 10.1021/om100323q
  150. Bimetallic mechanism operating in the copolymerization of propylene oxide with carbon dioxide catalyzed by cobalt-salen complexes
    K. Nakano, S. Hashimoto, K. Nozaki
    Chem. Sci. 2010, 1, 369–373. 10.1039/c0sc00220h
  151. High-Yielding Tandem Hydroformylation/Hydrogenation of a Terminal Olefin to Produce a Linear Alcohol Using a Rh/Ru Dual Catalyst System
    K. Takahashi, M. Yamashita, T. Ichihara, K. Nakano, K. Nozaki
    Angew. Chem. Int. Ed. 2010, 49, 4488–4490. 10.1002/anie.201001327 selected as an outside cover, highlighted in ChemCatChem, highlighted at the following blogs, NNNS chemistry blog, ユーキの有機化学Hot Topics
  152. Regioselective Synthesis of Halohydrin Esters from Epoxides: Reaction with Acyl Halides and Rhodium-catalyzed Three-component Coupling Reaction with Alkyl Halides and Carbon Monoxide
    K. Nakano, S. Kodama, Y. Permana, K. Nozaki
    Chem. Commun. 2009, 6970–6972. 10.1039/b912907c
  153. Diphenylphosphino- or Dicyclohexylphosphino-Tethered Boryl Pincer Ligands: Syntheses of PBP Iridium(III) Complexes and Their Conversion to Iridium–Ethylene Complexes
    Y. Segawa, M. Yamashita, K. Nozaki
    Organometallics 2009, 28, 6234–6242. 10.1021/om9006455
  154. Synthesis of N-Heterocyclic Carbene-Sulfonate Palladium Complexes
    Y. Nagai, T. Kochi, K. Nozaki
    Organometallics 2009, 28, 6131–6134. 10.1021/om9004252
  155. Copolymerization of Vinyl Acetate with Ethylene by Palladium/Alkylphosphine–Sulfonate Catalysts
    S. Ito, K. Munakata, A. Nakamura, K. Nozaki
    J. Am. Chem. Soc. 2009, 131, 14606–14607. 10.1021/ja9050839
  156. Group 4 Transition Metal Boryl Complexes: Syntheses, Structures, Boron–Metal Bonding Properties, and Application as a Polymerization Catalyst
    T. Terabayashi, T. Kajiwara, M. Yamashita, K. Nozaki
    J. Am. Chem. Soc. 2009, 131, 14162–14163. 10.1021/ja905950g
  157. Catalytic Hydrogenation of Carbon Dioxide Using Ir(III)-Pincer Complexes
    R. Tanaka, M. Yamashita, K. Nozaki
    J. Am. Chem. Soc. 2009, 131, 14168–14169. 10.1021/ja903574e highlighted in Angewandte Chemie
  158. Mechanistic Studies on the Formation of Linear Polyethylene Chain Catalyzed by Palladium Phosphine–Sulfonate Complexes: Experiment and Theoretical Studies
    S. Noda, A. Nakamura, T. Kochi, L. W. Chung, K. Morokuma, K. Nozaki
    J. Am. Chem. Soc. 2009, 131, 14088–14100. 10.1021/ja9047398
  159. Alternating Copolymerization of Cyclohexene Oxide with Carbon Dioxide Catalyzed by (salalen)CrCl Complexes
    K. Nakano, M. Nakamura, K. Nozaki
    Macromolecules, 2009, 42, 6972–6980. 10.1021/ma9012626
  160. Syntheses of PBP Pincer Iridium Complexes: A Supporting Boryl Ligand
    Y. Segawa, M. Yamashita, K. Nozaki
    J. Am. Chem. Soc. 2009, 131, 9201–9203. 10.1021/ja9037092 highlighted in Angewandte Chemie
  161. Rhodium Catalysts Bearing Mixed Thioether-Phosphine Ligands for Carbonylation of Methanol
    K. Sakakibara, K. Nozaki
    Bull. Chem. Soc. Jpn. 2009, 82, 1009–1011. 10.1246/bcsj.82.1009
  162. Sulfide-Bearing Phosphine Ligands: Their Pd Complexes and Application to Copolymerizations of Olefins and CO
    K. Sakakibara, K. Nozaki
    Bull. Chem. Soc. Jpn. 2009, 82, 1006–1008. 10.1246/bcsj.82.1006
  163. Synthesis of p-Conjugated Copolymer with Dibenzo[d,d']benzo[1,2-b:4,5-b']difuran Unit in the Main Chain
    K. Nakano, M. Takahashi, K. Kawaguchi, K. Nozaki
    Synthetic Metals 2009, 159, 939–942. 10.1016/j.synthmet.2009.02.001
  164. Synthesis of Allylnickel Complexes with Phosphine–Sulfonate Ligands and Their Application for Olefin Polymerization without Activators
    S. Noda, T. Kochi, K. Nozaki
    Organometallics 2009, 28, 656–658. 10.1021/om800781b
  165. Ring-opening reaction of Bus- and SES-protected aziridines using lithiated dithianes
    K. Sakakibara, K. Nozaki
    Org. Biomol. Chem. 2009, 7, 502–507. 10.1039/b814413c
  166. Neopentyl-Substituted PNP-Pincer Ligand: Complexation with Iridium to Form an Iridacycle via Alkyl C-H Activation
    T. Yano, Y. Moroe, M. Yamashita, K. Nozaki
    Chem. Lett. 2008, 37, 1300–1301. 10.1246/cl.2008.1300
  167. Chemistry of Boryllithium: Synthesis, Structure, and Reactivity
    Y. Segawa, Y. Suzuki, M. Yamashita, K. Nozaki
    J. Am. Chem. Soc. 2008, 130, 16069–16079. 10.1021/ja8057919
  168. Syntheses of Ester-Substituted Norbornyl Palladium Complexes Ligated with tBu3P: Studies on the Insertion of exo- and endo-Monomers in the Ester-Substituted Norbornene Polymerization
    I. Takamiya, M. Yamashita, K. Nozaki
    Organometallics 2008, 27, 5347–5352. 10.1021/om800566j
  169. Tandem Hydroformylation-Hydrogenation of 1-Decene Catalyzed by Rh-Bidentate Bis(trialkylphosphine)s
    T. Ichihara, K. Nakano, M. Katayama, K. Nozaki
    Chem. Asian J. 2008, 3, 1722–1728. 10.1002/asia.200800163
  170. Regiocontrolled Copolymerization of Methyl Acrylate with Carbon Monoxide.
    A. Nakamura, K. Munakata, T. Kochi, K. Nozaki
    J. Am. Chem. Soc. 2008, 130, 8128–8129. 10.1021/ja802161n
  171. Syntheses, Structures, and Reactivities of Borylcopper and -zinc Compounds: 1,4-Silaboration of An α,β-Unsaturated Ketone to Form A γ-Siloxyallylborane.
    T. Kajiwara, T. Terabayashi, M. Yamashita, K. Nozaki
    Angew. Chem. Int. Ed. 2008, 47, 6606–6610. 10.1002/anie.200801728
  172. Crystal Structure of Boryllithium with Two THF Molecules and DFT Analysis of Its Property as a Boryl Anion.
    M. Yamashita, Y. Suzuki, Y. Segawa, K. Nozaki
    Chem. Lett. 2008, 37, 802–803. 10.1246/cl.2008.802
  173. Polymerization of Norbornene with a Pendent Sulfonyl Fluoride Group Catalyzed by Palladium Complex Bearing tBu3P Ligand.
    I. Takamiya, M. Yamashita, E, Murotani, Y. Morizawa, K. Nozaki
    J. Polym. Sci., Part A: Polym. Chem. 2008, 46, 5133–5141. 10.1002/pola.22841
  174. Synthesis, Structures, and Properties of Unsymmetrical Heteroacenes Containing both Pyrrole and Furan Rings
    K. Kawaguchi, K. Nakano, K. Nozaki
    Org. Lett. 2008, 10, 1199–1202. 10.1021/ol703110g
  175. Carbonylative Polymerization of Oxetanes Initiated by Acetylcobalt Complexes
    Y. Permana, K. Nakano, M. Yamashita, D. Watanabe, K. Nozaki
    Chem. Asian J. 2008, 3, 710–718. 10.1002/asia.200700339
  176. Synthesis of Sulfur-Rich Polymers: Copolymerization of Episulfide with Carbon Disulfide by Using [PPN]Cl/(salph)Cr(III)Cl System
    K. Nakano, G. Tatsumi, K. Nozaki
    J. Am. Chem. Soc. 2007, 129, 15116–15117. 10.1021/ja076056b
  177. Synthesis, Structure of Borylmagnesium, and Its Reaction with Benzaldehyde to Form Benzoylborane
    M. Yamashita, Y. Suzuki, Y. Segawa, K. Nozaki
    J. Am. Chem. Soc. 2007, 129, 9570–9571. 10.1021/ja073037t highlighted in Nachrichten aus der Chemie
  178. Synthesis of alpha-Heteroarylpropanoic Acid via Asymmetric Hydroformylation Catalyzed by Rh(I)-(R,S)-BINAPHOS and the Subsequent Oxidation
    R. Tanaka, K. Nakano, K. Nozaki
    J. Org. Chem. 2007, 72, 8671–8676. 10.1021/jo0712190
  179. Boryl Anion Attacks Transition Metal Chlorides to Form Boryl Complexes: Syntheses, Spectroscopic and Structural Studies on Group 11 Borylmetal Complexes
    Y. Segawa, M. Yamashita, K. Nozaki
    Angew. Chem. Int. Ed. 2007, 46, 6710–6713. 10.1002/anie.200702369 highlighted in Nachrichten aus der Chemie
  180. Formation of linear copolymers of ethylene and acrylonitrile catalyzed by phosphine-sulfonate palladium complexes
    T. Kochi, S. Noda, K. Yoshimura, K. Nozaki
    J. Am. Chem. Soc. 2007, 129, 8948–8949. 10.1021/ja0725504 highlighted in Angewandte Chemie.
  181. Alternating Copolymerization of Vinyl Acetate with Carbon Monoxide
    T. Kochi, A. Nakamura, H. Ida, K. Nozaki
    J. Am. Chem. Soc. 2007, 129, 7770–7771. 10.1021/ja072859n highlighted in Angewandte Chemie.
  182. Regio-Regular Polymerization of Fluorine-Containing Epoxides
    K. Sakakibara, K. Nakano, K. Nozaki
    Macromolecules 2007, 40, 6136–6142. 10.1021/ma070428j
  183. Synthesis of Ladder-Type π-Conjugated Heteroacenes via Palladium-Catalyzed Double N-Arylation and Intramolecular O-Arylation.
    K. Kawaguchi, K. Nakano, K. Nozaki
    J. Org. Chem. 2007, 72, 5119–5128. 10.1021/jo070427p
  184. Boryllithium: Isolation, Characterization, and Reactivity as a Boryl Anion.
    Y. Segawa, M. Yamashita, K. Nozaki
    Science 2006, 314, 113–115. 10.1126/science.1131914 [full text] [abstract] highlighted in Science, Chemistry World, C&EN, Angewandte Chemie, Kagaku to Kogyo, and Nachrichten aus der Chemie
  185. Selective Formation of Polycarbonate over Cyclic Carbonate: Copolymerization of Epoxides with Carbon Dioxide Catalyzed by Cobalt(III) Complex with Piperidinium End-Capping Arm.
    K. Nakano, T. Kamada, K. Nozaki
    Angew. Chem. Int. Ed. 2006, 45, 7274–7277. 10.1002/anie.200603132
    highlighted in Chemical & Engineering (2007, Nov. 16, pp 16).
  186. Syntheses and Structures of Bulky Monophosphine-ligated Methylpalladium Complexes - Application to Homo- and Co-Polymerization of Norbornene and/or Methoxycarbonylnorbornene.
    M. Yamashita, I. Takamiya, K. Jin, K. Nozaki
    Organometallics 2006, 25, 4588–4595. 10.1021/om060347w
  187. Asymmetric Hydroformylation of Vinylfurans Catalyzed by {(11bS)-4-{[(1R)-2'-Phosphino[1,1'-binaphthalen]-2-yl]oxy}dinaphtho[2,1-d:1',2'-f]-[1,3,2]dioxaphosphepin}rhodium(I) [RhI{(R,S)-binaphos}] Derivatives
    K. Nakano, R. Tanaka, and K. Nozaki
    Helv. Chim. Acta 2006, 89, 1681–1686. 10.1002/hlca.200690166
  188. Regio-Contorlled Ring-Opening Polymerization of Perfluoroalkyl-Substituted Epoxides
    K. Sakakibara, K. Nakano, K. Nozaki
    Chem. Commun. 2006, 3334–3336. 10.1039/b606693c
  189. Syntheses and Characterizations of Methylpalladium Complexes Bearing a Biphenyl-Based Bulky Phosphine Ligand: Weak Interactions Suggested by NBO and QTAIM Analyses
    M. Yamashita, I. Takamiya, K. Jin, K. Nozaki
    J. Organomet. Chem. 2006, 691, 3189–3195. 10.1016/j.jorganchem.2006.02.001
  190. Alternating Copolymerization of Fluoroalkenes with Carbon Monoxide
    T. Fujita, K. Nakano, M. Yamashita, K. Nozaki
    J. Am. Chem. Soc. 2006, 128, 1968–1975. 10.1021/ja055862k
  191. Synthesis of anionic methylpalladium complexes with phosphine–sulfonate ligands and their activities for olefin polymerization
    T. Kochi, K. Yoshimura, K. Nozaki
    Dalton Trans. 2006, 25–27. 10.1039/b512452m
  192. Stereospecific Synthesis of Hetero[7]helicenes via the Palladium-Catalyzed Double N-Arylation and Intramolecular O-Arylation
    K. Nakano, Y. Hidehira, K. Takahashi, T. Hiyama, K. Nozaki
    Angew. Chem. Int. Ed. 2005, 44, 7136–7138. 10.1002/anie.200502855
  193. Comparison of two preparative methods: a polymer-supported catalyst by metal-complexation with a polymeric ligand or by polymerization of a metal complex
    S. Kinoshita, F. Shibahara, K. Nozaki
    Green Chem. 2005, 7, 256–258. 10.1039/b418264b
  194. Asymmetric amplification in asymmetric alternating copolymerization of cyclohexene oxide and carbon dioxide
    K. Nakano, T. Hiyama, K. Nozaki
    Chem. Commun. 2005, 1871–1873. 10.1039/b417973k
  195. An Efficient Pd(II)-Based Catalyst System for Carboxylation of Aromatic C-H bond by Addition of a Phosphenium Salt.
    K. Sakakibara, M. Yamashita, K. Nozaki
    Tetrahedron Lett. 2005, 46, 959–962. 10.1016/j.tetlet.2004.12.027
  196. The Double N-Arylation of Primary Amines: Carbazole Synthesis from 2,2'-biphenyldiols.
    A. Kuwahara, K. Nakano, K. Nozaki
    J. Org. Chem. 2005, 70, 413–419. 10.1021/jo048472+
    Selected as the most accessed article in 2005.
  197. A novel mild deprotection method for phosphine-boranes.
    M. Schroeder, K. Nozaki, T. Hiyama
    Bull. Chem. Soc. Jpn. 2004, 77, 1931–1932. 10.1246/bcsj.77.1931
  198. Synthesis of a polyester macromonomer via the cobalt-catalyzed alternating copolymerization of propylene oxide and carbon monoxide.
    K. Nakano, F. Kondo, K. Nozaki
    J. Polym. Sci., Part A: Polym. Chem. 2004, 42, 4666–4670. 10.1002/pola.20383
  199. Baeyer-Villiger Oxidation of an Optically Active 1,4-Polyketone.
    N. Kosaka, T. Hiyama, K. Nozaki
    Macromolecules 2004, 37, 4484–4487. 10.1021/ma0359638
  200. An alternative route to protected aldols: Cobalt-catalyzed hydroformylationof epoxides and in situ protection of β-hydroxyaldehydes by HC(OMe)3.
    K. Nakano, M. Katayama, S. Ishihara, T. Hiyama, K. Nozaki
    Synlett 2004, 1367–1370. 10.1055/s-2004-825620
  201. Palladium(II)-Catalyzed Sequential Hydroxylation-Carboxylation of Biphenyl Using Formic Acid as a Carbonyl Source.
    F. Shibahara, S. Kinoshita, K. Nozaki
    Org. Lett. 2004, 6, 2437–2439. 10.1021/ol049166l
  202. Synthesis and Photoisomerization of Optically Active 1,4-Polyketones Substituted by Azobenzene Side Chains.
    N. Kosaka, T. Oda, T. Hiyama, K. Nozaki
    Macromolecules 2004, 37, 3159–3164. 10.1021/ma0358430
  203. Hydroesterification of vinylarenes catalyzed by palladium complexes of dialkylmonoaryl- and monoalkyldiarylphosphines.
    Y. Kawashima, K. Okano, K. Nozaki, T. Hiyama
    Bull. Chem. Soc. Jpn. 2004, 77, 347–355. 10.1246/bcsj.77.347
  204. High-Pressure NMR Studies on the Alternating Copolymerization of Styrene with Carbon Monoxide Catalyzed by a Palladium(II)-(R,S)-BINAPHOS Complex.
    J. A. Iggo, Y. Kawashima, J. Liu, T. Hiyama, K. Nozaki
    Organometallics 2003, 22, 5418–5422. 10.1021/om0304917
  205. Liquid-crystalline Stereoregular Polyketone Prepared from a Mesogenic Vinylarene and Carbon Monoxide.
    Y. Kawashima, K. Nozaki, T. Hiyama, M Yoshio, K. Kanie, T. Kato
    J. Polym. Sci., Part A: Polym. Chem. 2003, 41, 3556–3563. 10.1002/pola.10843
  206. Conformational Studies on an Optically Active 1,4-Polyketone in Solution.
    N. Kosaka, K. Nozaki, T. Hiyama
    Macromolecules 2003, 36, 6884–6887. 10.1021/ma025979i
  207. Solvent-Free Asymmetric Olefin Hydroformylation Catalyzed by Highly Crosslinked Polystyrene-Supported (R,S)-BINAPHOS-Rh(I) Complex.
    F. Shibahara, K. Nozaki, T. Hiyama
    J. Am. Chem. Soc. 2003, 125, 8555–8560. 10.1021/ja034447u
  208. The Double N-arylation of Primary Amines: A New Synthetic Strategy toward Carbazoles with Unique Optical Properties.
    K. Nozaki, K. Takahashi, K. Nakano, T. Hiyama, H.-Z. Tang, M. Fujiki, S. Yamaguchi, K. Tamao
    Angew. Chem. Int. Ed. 2003, 42, 2051–2053. 10.1002/anie.200250648
  209. Asymmetric Alternating Copolymerization of Cyclohezene Oxide and CO2 with Dimeric Zinc Complexes.
    K. Nakano, K. Nozaki, T. Hiyama
    J. Am. Chem. Soc. 2003, 125, 5501–5510. 10.1021/ja028666b
  210. Asymmetric Terpolymerization of Styrene or Its Derivative and Aliphatic 1-Alkenes with CO Catalyzed by Pd-(R,S)-BINAPHOS.
    Y. Kawashima, K. Nozaki, T. Hiyama
    Inorg. Chim. Acta 2003, 350, 577–582. 10.1016/S0020-1693(02)01542-6
  211. High Pressure IR Studies on the Asymmetric Hydroformylation of Styrene Catalyzed by Rh(I)-(R,S)-BINAPHOS'es.
    K. Nozaki, T. Matsuo, F. Shibahara, T. Hiyama
    Organometallics 2003, 22, 594–600. 10.1021/om020245f
  212. Carbon-Monoxide Free Aminocarbonylation of Organic Halides Using DMF as an Amide Source.
    K. Hosoi, K. Nozaki, T. Hiyama
    Org. Lett. 2002, 4, 2849–2851. 10.1021/ol026236k
  213. Palladium-catalyzed cross-coupling reaction using alkenyldimethyl(2-thienyl)silanes.
    K. Hosoi, K. Nozaki, T. Hiyama
    Proc. Jpn. Acad., Ser. B 2002, 78, 154–160.
  214. Asymmetric Hydroformylation with Highly Crosslinked Polystyrene-Supported (R,S)-BINAPHOS-Rh(I) Complexes: The Effect of Immobilization Positions.
    F. Shibahara, K. Nozaki, T. Matsuo, T. Hiyama
    Bioorg. Med. Chem. Lett. 2002, 12, 1825–1827. 10.1016/S0020-1693(02)01542-6
  215. Methylenation of Optically Active γ-Polyketones.
    K. Nozaki, N. Kosaka, V. M. Graubner, T. Hiyama
    Polymer J. 2002, 34, 376–382. 10.1295/polymj.34.376
  216. Alkenyldimethyl(2-thienyl)silanes, Excellent Coupling Partner for the Palladium-Catalyzed Cross-Coupling Reaction.
    K. Hosoi, K. Nozaki, T. Hiyama
    Chem. Lett 2002, 138–139. 10.1246/cl.2002.138
  217. Synthesis and Liquid Crystalline Behavior of Stereoregular Polyketones with Mesogenic Side Chains.
    K. Nozaki, Y. Kawashima, T. Oda, T. Hiyama, K. Kanie, T. Kato
    Macromolecules 2002, 35, 1140–1142. 10.1021/ma0113125
  218. Asymmetric Synthesis of Optically Active Polymers with Main-Chain Chirality.
    Kyoko Nozaki
    Kobunshironbunshu 2001, 58, 375–381.
  219. Spectral Assignment of Poly[Cyclohexene Oxide-alt-Carbon Dioxide].
    K. Nakano, K. Nozaki, T. Hiyama
    Macromolecules 2001, 34, 6325–6332. 10.1021/ma010732r
  220. Methylenation of an Optically Active γ-Polyketone: Synthesis of a New Class of Hydrocarbon Polymers with Main-Chain Chirality.
    K. Nozaki, N. Kosaka, V. M. Graubner, T. Hiyama
    Macromolecules 2001, 34, 6167–6168. 10.1021/ma0107713
  221. Alternating Copolymerization of ω-Perfluoroalkyl-1-alkenes with Carbon Monoxide Catalyzed by Homogeneous and Polymer-Supported Pd-Complexes.
    K. Nozaki, F. Shibahara, S. Elzner, T. Hiyama
    Can. J. Chem. 2001, 593–597. 10.1139/v01-073
  222. Solid Phase Cross-coupling Reaction of Aryl(halo)silanes with 4-Iodobenzoic Acid.
    F. Homsi, K. Hosoi, K. Nozaki, T. Hiyama
    J. Organomet. Chem. 2001, 624, 208–216. 10.1016/S0022-328X(01)00664-7
  223. Substituent Effect in Asymmetric Hydroformylation of Olefins Catalyzed by Rhodium(I) Complexes of (R,S)-BINAPHOS Derivatives: A Protocol for Improvement of Regio- and Enantioselectivities.
    K. Nozaki, T. Matsuo, F. Shibahara, T. Hiyama
    Adv. Syn. Catal. 2001, 343, 61–63. 10.1002/1615-4169(20010129)343:1%3C61::AID-ADSC61%3E3.0.CO;2-L
  224. Predominant 1,2-Insertion of Styrene in the Pd-Catalyzed Alternating Copolymerization with Carbon Monoxide.
    K. Nozaki, H. Komaki, Y. Kawashima, T. Hiyama, T. Matsubara
    J. Am. Chem. Soc. 2001, 123, 534–544. 10.1021/ja001395p
  225. Asymmetric Reduction of an Enantiomerically pure γ-polyketone.
    K .Nozaki, N. Kosaka, S. Muguruma, T. Hiyama
    Macromolecules 2000, 33, 5340–5346. 10.1021/ma000424d
  226. Solid Phase Cross-Coupling Reactions of Aryl(fluoro)silanes with 4-iodobenzoic acid.
    F. Homsi, K. Nozaki, T. Hiyama
    Tetrahedron Lett. 2000, 41, 5869–5872. 10.1016/S0040-4039(00)00789-9
  227. Vapor-Phase Asymmetric Hydroformylation.
    K. Nozaki, F. Shibahara, T. Hiyama
    Chem. Lett. 2000, 694–695. 10.1246/cl.2000.694
  228. High Pressure NMR Studies on the Alternating Copolymerization of Propene with Carbon Monoxide Catalyzed by a Palladium(II) Complex of an Unsymmetrical Phosphine-Phosphite.
    K. Nozaki, T. Hiyama, S. Kacker, I. T. Horvah
    Organometallics 2000, 19, 2031–2035. 10.1021/om990985x
  229. Practical Stereoselective Synthesis of (2,3,4,5-Tetrahydro-1H-Benzo[b]azepin-5-yl)acetic Acid.
    T. Shinohara, K. Kondo, H. Ogawa, T. Mori, K. Nozaki, T. Hiyama
    Chirality 2000, 12, 425–430. 10.1002/(SICI)1520-636X(2000)12:5/6%3C425::AID-CHIR23%3E3.0.CO;2-E
  230. Optically Active Polycarbonates: Asymmetric Alternating Copolymerization of Cyclohexene Oxide with Carbon Dioxide.
    K. Nozaki, K. Nakano, T. Hiyama
    J. Am. Chem. Soc. 1999, 121, 11008–11009. 10.1021/ja992433b
  231. Alternating Copolymerization of Various Alkenes with Carbon Monoxide Using a Cationic Pd(II) Complexes of (R,S)-BINAPHOS as an Initiator.
    K. Nozaki, Y. Kawashima, K. Nakamoto, T. Hiyama
    Polymer J. 1999, 31, 1057–1060. 10.1295/polymj.31.1057
  232. Asymmetric Hydroformylation of Olefins in Highly Crosslinked Polymer Matrixes.
    K. Nozaki, F. Shibahara, Y. Itoi, T. Ohta, H. Takaya, T. Hiyama
    Bull Chem. Soc. Jpn. 1999, 72, 1911–1918. 10.1246/bcsj.72.1911
  233. Asymmetric Terpolymerization of Propene, Vinylarene, and Carbon Monoxide.
    K. Nozaki, Y. Kawashima, K. Nakamoto, T. Hiyama
    Macromolecules 1999, 32, 5168–5170. 10.1021/ma9902807
  234. A Chiral Bometallic Lewis Acid as a Reaction Template. Asymmetric Reduction of Unsymmetric Ketones with LiBH4.
    K. Nozaki, K. Kobori, T. Uemura, T. Tsutsumi, H. Takaya, T. Hiyama
    Bull. Chem. Soc. Jpn. 1999, 72, 1109–1113. 10.1246/bcsj.72.1109
  235. Asymmetric Hydroformylation of Olefins in a Highly Crosslinked Polymer Matrix.
    K. Nozaki, Y. Itoi, F. Shibahara, E. Shirakawa, T. Ohta, H. Takaya, T. Hiyama
    J. Am. Chem. Soc. 1998, 120, 4051–4052. 10.1021/ja973408d
  236. Double Helical Oligo Esters: Chiral Twist of Two Aromatic Ester Chains.
    K. Nozaki, T. Terakawa, H. Takaya, T. Hiyama
    Angew. Chem., Int. Ed. Engl. 1998, 37, 131–133. 10.1002/(SICI)1521-3773(19980202)37:1/2<131::AID-ANIE131>3.0.CO;2-K
  237. Chiral and achiral phosphine phosphite ligands in Pd(II)-catalyzed alternating copolymerization of propene with CO.
    K. Nozaki, M. Yasutomi, K. Nakamoto, T. Hiyama
    Polyhedron 1998, 17, 1159–1164. 10.1016/S0277-5387(97)00503-2
  238. Mechanistic Aspects of the Alternating Copolymerization of Propylene with Carbon Monoxide Catalyzed by Pd(II) Complexes of Unsymmetrical Phosphine-phosphite Ligands.
    K. Nozaki, N. Sato, Y. Tonomura, M. Yasutomi, H. Takaya, T. Hiyama
    J. Am. Chem. Soc. 1997, 119, 12779–12793. 10.1021/ja973199x
  239. Cyclic Polyamides Consisting of 1,1'-Binaphthyls. "Chiral Twist" of Glycine Residues.
    K. Nozaki, T. Terakawa, H. Takaya, T. Hiyama
    Tetrahedron: Asymmetry 1997, 8, 3430–3436. 10.1016/S0957-4166(97)00460-6
  240. Asymmetric Hydroformylation of Allylic Alcohols Catalyzed by Rh(I) (R,S)-BINAPHOS.
    K. Nozaki, W. G. Li, T. Horiuchi, H. Takaya
    Tetrahedron Lett. 1997, 38, 4611–4614. 10.1016/S0040-4039(97)00988-X
  241. Asymmetric Hydroformylation of Hetrocyclic Olefins Catalyzed by Chiral Phosphine Phosphite Rh(I) Complex.
    T. Horiuchi, T. Ohta, E. Shirakawa, K. Nozaki, H. Takaya
    J. Org. Chem. 1997, 62, 4285–4292. 10.1021/jo9624051
  242. Mechanistic Aspects of Asymmetric Hydroformylation of Olefins Catalyzed by Chiral Phosphine-Phosphite Rh(I) Complexes.
    T. Horiuchi, E. Shirakawa, K. Nozaki, H. Takaya
    Organometallics 1997, 16, 2981–2986. 10.1021/om970134u
  243. Asymmetric Hydroformylation of Conjugated Dienes Catalyzed by Chiral Phosphine Phosphite Rh(I) Complex.
    T. Horiuchi, T. Ohta, E. Shirakawa, K. Nozaki, H. Takaya
    Tetrahedron 1997, 53, 7795–7804. 10.1016/S0040-4020(97)00471-7
  244. Highly Enantioselective Hydroformylation of Olefins Catalyzed by Rhodium(I) Complexes of New Chiral Phosphine-Phosphite Ligands.
    K. Nozaki, N. Sakai, T. Higashijima, S. Mano, T. Horiuchi, H. Takaya
    J. Am. Chem. Soc. 1997, 119, 4413–4423. 10.1021/ja970049d
  245. Hydroestrification of Styrene Catalyzed by Montmorillonite diphenylphosphinepalladium(II) Chloride in the Presence of Chiral Phosphines.
    K. Nozaki, M. L. Kantam, T. Horiuchi, H. Takaya
    J. Mol. Catal. A. 1997, 118, 247–253. 10.1016/S1381-1169(96)00385-8
  246. Cyclocopolymerization of α,ω-Dienes with Carbon Monoxide Catalyzed by (R,S)-BINAPHOS Pd(II).
    K. Nozaki, N. Sato, K. Nakamoto, H. Takaya
    Bull. Chem. Soc. Jpn. 1997, 70, 659–664. 10.1246/bcsj.70.659
  247. Synthesis of (R)-2-diphenylphosphino-2'-diphenylphosphinomethyl-1,1'-binaphthyl and its use for asymmetric hydrogenation of α-alkylstyrenes.
    K. Inagaki, T. Ohta, K. Nozaki, H. Takaya
    J. Organomet. Chem. 1997, 531, 159–163. 10.1016/S0022-328X(96)06712-5
  248. Asymmetric Michael Reaction of α-Cyano Esters by Chiral Rh(I) Complex with a New Optically Active Bisphosphine Ligand.
    K. Inagaki, K. Nozaki, H. Takaya
    Synlett 1997, 119–120. 10.1055/s-1997-712
  249. Asymmetric Hydroformylation Catalyzed by a Rh(I) (R,S)-BINAPHOS Complex: Substituent Effects in Olefins on the Regioselectivity.
    K. Nozaki, T. Nanno, H. Takaya
    J. Organomet. Chem. 1997, 527, 103–108. 10.1016/S0022-328X(96)06620-X
  250. (R,S)-BINAPHOS Ni(0) and Pd(0) Complexes: Characterization and Their Use for Asymmetric Hydrocyanation of Norbornene.
    T. Horiuchi, E. Shirakawa, K. Nozaki, H. Takaya
    Tetrahedron: Asymmetry 1997, 8, 57–63. 10.1016/S0957-4166(96)00483-1
  251. New Stereocontrolled Approach to 1β-Methylcarbapenem: Asymmetric Hydroformylation of 4-Vinyl-β-lactams Catalyzed by Rh(I) Complexes of Chiral Phosphine-phosphites and Phosphine-phosphinites.
    K. Nozaki, W.-g. Li, T. Horiuchi, H. Takaya, T. Saito, A, Yoshida, K. Matsumura, Y. Kato, T. Imai, T. Miura, H. Kumobayashi
    J. Org. Chem. 1996, 61, 7658–7659. 10.1021/jo961689m
  252. Highly Efficient Enantioselective Synthesis of Optically Active Carboxylic Acids by Ru(OCOCH3)2[(S)-H8-BINAP].
    T. Uemura, X. Zhang, K. Matsumura, N. Sayo, H. Kumobayashi, T. Ohta, K. Nozaki, H. Takaya
    J. Org. Chem. 1996, 61, 5510–5516. 10.1021/jo960426p
  253. Synthesis of Highly Functionalized γ-Butyrolactones from Activated Carbonyl Compounds and Dimethyl Acetylenedicarboxylate.
    K. Nozaki, N. Sato, K. Ikeda, H. Takaya
    J. Org. Chem. 1996, 61, 4516–4519. 10.1021/jo951828k
  254. Chiral Bimetallic Boronic Esters: A Donor Acceptor Coexisting Receptor for Amines.
    K. Nozaki, M. Yoshida, H. Takaya
    Bull. Chem. Soc. Jpn. 1996, 69, 2043–2052. 10.1246/bcsj.69.2043
  255. Palladium-Catalyzed Acylcyanation of Terminal Arylacetylenes. Synthesis of 1,3-Diaryl-3-cyano-2-propen-1-ones and Tetrasubstituted Furans.
    K. Nozaki, N. Sato, H. Takaya
    Bull. Chem. Soc. Jpn. 1996, 69, 1629–1637. 10.1246/bcsj.69.1629
  256. Anionic Dinuclear BINAP-Ru(II) Complex: Crystal Structure of [NH2Et2][{RuCl(R)-p-MeO-binap)}2(μ-Cl)3]and Its Use for Asymmetric Hydrogenation.
    T. Ohta, Y. Tonomura, K. Nozaki, H. Takaya
    Organometallics 1996, 15, 1521–1523. 10.1021/om9508905
  257. Asymmetric Hydroformylation of Conjugated Dienes Catalyzed by [(R)-2-diphenylphosphino-1,1'-dinaphthalen-2'-yl][(S)-1,1'-dinaphthalene-2,2'-diyl]phosphite-rhodium(I).
    T. Horiuchi, T. Ohta, K. Nozaki, H. Takaya
    Chem. Commun. 1996, 155–156. 10.1039/CC9960000155
  258. Asymmetric Hydroformylation of Sulfur-Containing Olefins Catalyzed by BINAPHOS-Rh(I) Complexes.
    T. Nanno, N. Sakai, K. Nozaki, H. Takaya
    Tetrahedron: Asymmetry 1995, 6, 2583–2591. 10.1016/0957-4166(95)00339-Q
  259. Selective Binding of Diamines to a Chiral Lewis Acid with Two Boron Centers.
    K. Nozaki, T. Tsutsumi, H. Takaya
    J. Org. Chem. 1995, 60, 6668–6669. 10.1021/jo00126a009
  260. Highly Enantioselective Alternating Copolymerization of Propene with Carbon Monoxide Catalyzed by a Chiral Phosphine-Phosphite Complex of Palladium(II).
    K. Nozaki, N. Sato, H. Takaya
    J. Am. Chem. Soc. 1995, 117, 9911–9912. 10.1021/ja00144a018
  261. A Chiral Lewis Acid with Two "Metal" Centers: Cooperative Binding of Two Amine Molecules to a Chiral Diboronic Ester.
    K. Nozaki, M. Yoshida, H. Takaya
    Angew. Chem., Int. Ed. Engl. 1994, 33, 2452–2454. 10.1002/anie.199424521
  262. Cationic BINAP-Ru(II) Halide Complexes: Highly Efficient Catalysts for Stereoselective Asymmetric Hydrogenation of a- and b-Functionalized Ketones.
    K. Mashima, K. Kusano, Y. Matsumura, N. Sato, K. Nozaki, H. Kumobayashi, N. Sayo, Y. Hori, T. Ishizaki, S. Akutagawa, H. Takaya
    J. Org. Chem. 1994, 59, 3064–3076. 10.1021/jo00090a026
  263. Acylcyanation of Terminal Acetylenes: Palladium Catalyzed Addition of Aryloyl Cyanides to Arylacetylenes
    K. Nozaki, N. Sato, H. Takaya
    J. Org. Chem. 1994, 59, 2679–2681. 10.1021/jo00089a006
  264. Reaction Rate Enhancement by Addition of Anionic Surfactant SDS in the Ruthenium Catalyzed Hydrogen Transfer from a 1,4-Diols to 4-Phenyl-3-buten-2-one.
    K. Nozaki, M. Yoshida, H. Takaya
    J. Organomet. Chem. 1994, 473, 253–256. 10.1016/0022-328X(94)80125-8
  265. Synthesis of New Chiral Phosphinephosphites Having 2-Diphenyl-phosphinobiphenyl-2'-yl Backbone and Their Use in Rh(I) Catalyzed Asymmetric Hydroformylations.
    T. Higashijima, N. Sakai, K. Nozaki, H. Takaya
    Tetrahedron Lett. 1994, 35, 2023–2026. 10.1016/S0040-4039(00)73039-5
  266. Asymmetric Hydroformylation of 1,2-Di-substituted Olefins Catalyzed by Chiral Phosphinephosphite-Rh(I) Complexes.
    N. Sakai, K. Nozaki and H. Takaya
    J. Chem. Soc., Chem. Commun. 1994, 395–396. 10.1039/C39940000395
  267. Enantioselective Synthesis of L- and D-Isoserine via Asymmetric Hydrogenation of Methyl N-Phthaloyl-3-amino-2-oxopropanoate.
    K. Nozaki, N. Sato, H. Takaya
    Tetrahedron: Asymmetry 1993, 4, 2179–2182. 10.1016/S0957-4166(00)80068-3
  268. Highly Enantioselective Hydroformylation of Olefins Catalyzed by New Phosphinephosphite-Rh(I) Complexes.
    N. Sakai, S. Mano, K. Nozaki, H. Takaya
    J. Am. Chem. Soc. 1993, 115, 7033–7034. 10.1021/ja00068a095
  269. Asymmetric Hydroformylation of Vinyl Acetate By Use of Chiral Bis(triarylphosphite)-Rhodium(I) Complexes.
    N. Sakai, K. Nozaki, K. Mashima, H. Takaya
    Tetrahedron: Asymmetry 1992, 3, 583–586. 10.1016/S0957-4166(00)82286-7
  270. Isomerization of Olefins by Means of R3SnH-Et3B and Stereochemical Study on Reduction of Alkenyl Iodides.
    M. Taniguchi, K. Nozaki, K. Miura, K. Oshima and K. Utimoto
    Bull. Chem. Soc. Jpn. 1992, 65, 349–353. 10.1246/bcsj.65.349
  271. Triethylborane Induced 1,4-Reduction of α,β-Unsaturated Carbonyl Compounds with Triphenyltin Hydride or Tributyltin Hydride.
    K. Nozaki, K. Oshima, K. Utimoto
    Bull. Chem. Soc. Jpn. 1991, 64, 2585–2587. 10.1246/bcsj.64.2585
  272. Palladium Catalyzed Reaction of Silacyclobutanes with Acetylenes.
    Y. Takeyama, K. Nozaki, K. Matsumoto, K. Oshima, K. Utimoto
    Bull. Chem. Soc. Jpn. 1991, 64, 1461–1466. 10.1246/bcsj.64.1461
  273. Trialkylborane as an Initiator and Terminator of Free Radical Reactions: Facile Routs to Boron Enolates via a-Carbonyl Radicals and Aldol Reaction of Boron Enolates.
    K. Nozaki, K. Oshima, K. Utimoto
    Bull. Chem. Soc. Jpn. 1991, 64, 403–409. 10.1246/bcsj.64.403
  274. On the Mechanism of Lewis Acid Mediated Nucleophilic Substitution Reactions of Acetals.
    I. Mori, K. Ishihara, L. A. Flippin, K. Nozaki, H. Yamamoto, P. A. Bartlett, C. H. Heathcock
    J. Org. Chem. 1990, 55, 6107–6115. 10.1021/jo00312a015
  275. Triethylborane Induced Perfluoroalkylation of Silyl Enol Ethers or Germyl Enol Ethers with Perfluoroalkyl Iodides.
    K. Miura, M. Taniguchi, K. Nozaki, K. Oshima, K. Utimoto
    Tetrahedron Lett. 1990, 31, 6391–6394. 10.1016/S0040-4039(00)97073-4
  276. Facile Reduction of Dithiocarbonates Derived from Secondary Alcohols with n-Bu3SnH-Et3B and Synthesis of 2-Furanthiones and 2-Furanones by Intramolecular Addition of Alkoxythiocarbonyl Free Radicals to Acetylenic Lincages.
    K. Nozaki, K. Oshima, K. Utimoto
    Bull. Chem. Soc. Jpn. 1990, 63, 2578–2583. 10.1246/bcsj.63.2578
  277. Et3B-Induced Stereoselective Radical Addition of Ph3GeH to Carbon-Carbon Multiple Bonds and Its Application to Isomerization of Olefins.
    K. Nozaki, Y. Ichinose, K. Wakamatsu, K. Oshima, K. Utimoto
    Bull. Chem. Soc. Jpn. 1990, 63, 2268–2272. 10.1246/bcsj.63.2268
  278. Et3B-Induced Radical Addition of Ph3SnH to Acetylenes and Its Application to Cyclization Reaction.
    K. Nozaki, K. Oshima, K. Utimoto
    Tetrahedron 1989, 45, 923–933. 10.1016/0040-4020(89)80004-3
  279. Et3B-Induced Hydrodehalogenation of Organic Halides by Tin Hydrides.
    K. Miura, Y. Ichinose, K. Nozaki, K. Fugami, K. Oshima, K. Utimoto
    Bull. Chem. Soc. Jpn. 1989, 62, 143–147. 10.1246/bcsj.62.143
  280. Synthesis of Lactones by Intramolecular Addition of Alkoxythiocarbonyl Free Radicals to Acetylenes.
    K. Nozaki, K. Oshima, K. Utimoto
    Tetrahedron Lett. 1988, 29, 6127–6128. 10.1016/S0040-4039(00)82284-4
  281. Facile Reduction of Dithiocarbonates with n-Bu3SnH-Et3B: Easy Access to Hydrocarbons from Secondary Alcohols.
    K. Nozaki, K. Oshima, K. Utimoto
    Tetrahedron Lett. 1988, 29, 6125–6126. 10.1016/S0040-4039(00)82283-2
  282. Facile Routes to Boron Enolates: Et3B-Mediated Reformatsky Type Reaction and Three-Component Coupling Reaction of Alkyl Iodides, Methyl Vinyl Ketone, and Carbonyl Compounds.
    K. Nozaki, K. Oshima, K. Utimoto
    Tetrahedron Lett. 1988, 29, 1041–1044. 10.1016/0040-4039(88)85330-9
  283. Synthesis of α-Methylene-γ-butyrolactones via Addition of Tin Hydride to Enynes Induced by Triethylborane.
    K. Nozaki, K. Oshima, K. Utimoto
    Bull. Chem. Soc. Jpn. 1987, 60, 3465–3467. 10.1246/bcsj.60.3465
  284. Et3B-Induced Radical Addition of Thiols to Acetylenes.
    Y. Ichinose, K. Wakamatsu, K. Nozaki, J.-L. Birbaum, K. Oshima, K. Utimoto
    Chem. Lett. 1987, 1647–1650. 10.1246/cl.1987.1647
  285. Et3B-Induced Stereoselective Radical Addition of Ph3GeH to Carbon-Carbon Multiple Bonds and Its Application to Isomerization of Olefins.
    Y. Ichinose, K. Nozaki, K. Wakamatsu, K. Oshima, K. Utimoto
    Tetrahedron Lett. 1987, 28, 3709–3712. 10.1016/S0040-4039(00)96363-9
  286. Et3B-Induced Radical Addition of R3SnH to Acetylenes and Its Application to Cyclization Reaction.
    K. Nozaki, K. Oshima, K. Utimoto
    J. Am. Chem. Soc. 1987, 109, 2547–2549. 10.1021/ja00242a068
  287. Transition-Metal Catalyzed Regioselective Addition of PhMe2SiBEt3Li and Bu3SnBEt3Li to Acetylenic Compounds in the Presence of Methanol.
    K. Nozaki, K. Wakamatsu, T. Nonaka, W. Tukmantel, K. Oshima, K. Utimoto
    Tetrahedron Lett. 1986, 27, 2007–2010. 10.1016/S0040-4039(00)84434-2