発表論文 (Jin准教授)

  1. Synergy Effects in a Bimetallic Ru−Pt Alloy Catalyst for Low-H2-Pressure Hydrogenolysis of Low-Density Polyethylene
    Y. Yamazaki, X. Jin, W. Sun, S. Yamamoto, K. Nomoto, K. Takahashi, H. Miura, T. Shishido, A. Nakayama, K. Nozaki
    Chem. Eur. J. in press.
    ChemRxiv 2024 (preprint) 10.26434/chemrxiv-2024-sm1lp
  2. Photocatalytic Acceptorless Conversion of Carboxylic Acids, Aldehydes, and Alcohols to Alkenes by a TiO2 and Cobaloxime Dual Catalyst System
    E. Maruyama, X. Jin, K. Nozaki
    J. Org. Chem. 2025, 90, 10416-10424. 10.1021/acs.joc.5c01153 Highlighted in Chem-Stationスポットライトリサーチ
  3. Pt/Al(PO3)3-Catalyzed Transfer Hydrogenolysis of Phenols to Arenes Using Cyclic Alkanes as the Hydrogen Source
    K. Oshida, X. Jin, K. Nozaki
    Org. Lett. 2025, 27, 6117–6121. 10.1021/acs.orglett.5c01708 Highlighted in Synfacts.
  4. Electrochemical Conversion of Carboxylic Acids to Terminal Alkenes Enabled by Dialkyl Phosphate Electrolyte
    T. Ito, X. Jin, K. Nozaki
    Tetrahedron 2025, 176, 134560. 10.1016/j.tet.2025.134560 (Special issue: H-Atom Transfer Chemistry)
    ChemRxiv 2024 (preprint) 10.26434/chemrxiv-2024-hnsv9
  5. Bimetallic synergy in supported Ni–Pd catalyst for selective hydrogenolysis of C–O bonds in epoxy resins
    Y. Huang, Y. Yamazaki, K. Nomoto, H. Miura, T. Shishido, X. Jin, K. Nozaki
    Nat. Commun. 2025, 16, 1188. 10.1038/s41467-025-56488-4 Highlighted in Press release (東京大学工学部、JST), Bioengineer.org, ScienMag, EurekAlert!, Phys.org, ScienceDaily, 日本経済新聞, Editors' Highlights (Catalysis).
    ChemRxiv 2024 (preprint) 10.26434/chemrxiv-2024-lncxh
  6. Selective Hydrogenation of Aldehydes Under Syngas Using CeO2-Supported Au Nanoparticle Catalyst
    K. Shirayama, X. Jin, K. Nozaki
    J. Am. Chem. Soc. 2024, 146, 14086–14094. 10.1021/jacs.4c02531 Featured on the supplementary cover. Highlighted in Synfacts.
  7. Hydrogen-induced formation of surface acid sites on Pt/Al(PO3)3 enables remarkably efficient hydrogenolysis of C−O bonds in alcohols and ethers
    K. Oshida, K. Yuan, Y. Yamazaki, R. Tsukimura, H. Nishio, K. Nomoto, H. Miura, T. Shishido, X. Jin, K. Nozaki
    Angew. Chem. Int. Ed. 2024, 63, e202403092. 10.1002/anie.202403092 Highlighted in Synfacts.
    ChemRxiv 2023 (preprint) 10.26434/chemrxiv-2023-vjn0d
  8. Multifunctional WO3−ZrO2-supported Platinum Catalyst for Remarkably Efficient Hydrogenolysis of Esters to Alkanes
    K. Yuan, Y. Yamazaki, X. Jin, K. Nozaki
    J. Am. Chem. Soc. 2023, 145, 3454–3461. 10.1021/jacs.2c11145 Featured on the supplementary cover. Highlighted in Synfacts.
  9. TEMPO as a Hydrogen Atom Transfer Catalyst for Aerobic Dehydrogenation of Activated Alkanes to Alkenes
    T. Ito, F. Seidel, X. Jin, K. Nozaki
    J. Org. Chem. 2022, 87, 12733–12740. 10.1021/acs.joc.2c01302 Selected as Most Read Articles in September 2022.
  10. Metal-Support Cooperation in Al(PO3)3-Supported Pt Nanoparticles for the Selective Hydrogenolysis of Phenols to Arenes
    X. Jin, R. Tsukimura, T. Aihara, H. Miura, T. Shishido, K. Nozaki
    Nat. Catal. 2021, 4, 312–321. 10.1038/s41929-021-00598-x See the article.
    Featured on the cover. Highlighted in press release, UTokyo FOCUS, Chem-Station, UTokyo FOCUS, EurekAlart!, AlphaGalileo, ScienceDaily, Phys.org, ScienMag, Science Bulletin, Mirage News, Laboratory Equipment.
  11. Mechanistic Study of C–H Bond Activation by O2 on Negatively Charged Au Clusters: α,β-Dehydrogenation of 1-Methyl-4-piperidone by Supported Au Catalysts
    R. Miyazaki, X. Jin, D. Yoshii, T. Yatabe, T. Yabe, N. Mizuno, K. Yamaguchi, J. Hasegawa
    Catal. Sci. Technol. 2021, 11, 3333–3346. 10.1039/D1CY00178G
  12. CeO2-Supported Pd(II)-on-Au Nanoparticle Catalyst for Aerobic Selective α,β-Desaturation of Carbonyl Compounds Applicable to Cyclohexanones
    D. Takei, T. Yatabe, X. Jin, T. Yabe, N. Mizuno, K. Yamaguchi
    ACS Catal. 2020, 10, 5057–5063. 10.1021/acscatal.0c00277
  13. Synthesis of unsymmetrically substituted triarylamines via acceptorless dehydrogenative aromatization using a Pd/C and p-toluenesulfonic acid hybrid relay catalyst
    S. Takayama, T. Yatabe, Y. Koizumi, X. Jin, K. Nozaki, N. Mizuno, K. Yamaguchi
    Chem. Sci. 2020, 11, 4074–4084. 10.1039/C9SC06442G
  14. Selective Synthesis of Primary Anilines from NH3 and Cyclohexanones by Utilizing Preferential Adsorption of Styrene on the Pd Nanoparticle Surface
    Y. Koizumi, X. Jin, T. Yatabe, R. Miyazaki, J. Hasegawa, K. Nozaki, N. Mizuno, K. Yamaguchi
    Angew. Chem. Int. Ed., 2019, 58, 10893–10897. 10.1002/anie.201903841
  15. Selective Dehydrogenative Mono- or Diborylation of Styrenes by Supported Copper Catalysts
    D. Yoshii, X. Jin, N. Mizuno, K. Yamaguchi
    ACS Catal. 2019, 9, 3011–3016. 10.1021/acscatal.9b00761
  16. Heterogeneously Palladium-catalyzed Acceptorless Dehydrogenative Aromatization of Cyclic Amines
    T. Oyama, T. Yatabe, X. Jin, N. Mizuno, K. Yamaguchi
    Chem. Lett. 2019, 48, 517–520. 10.1246/cl.190080
  17. CuCl/TMEDA/nor-AZADO-catalyzed aerobic oxidative acylation of amides with alcohols to produce imides
    K. Kataoka, K. Wachi, X. Jin, K. Suzuki, Y. Sasano, Y. Iwauchi, J. Hasegawa, N. Mizuno, K. Yamaguchi
    Chem. Sci. 2018, 9, 4756–4768. 10.1039/c8sc01410h
  18. Unusual Olefinic C–H Functionalization of Simple Chalcones Toward Aurones Enabled by the Rational Design of a Function-Integrated Heterogeneous Catalyst
    T. Yatabe, X. Jin, N. Mizuno, K. Yamaguchi
    ACS Catal. 2018, 8, 4969–4978. 10.1021/acscatal.8b00727
  19. Selective Synthesis of Primary Anilines from Cyclohexanone Oximes by the Concerted Catalysis of a Mg−Al Layered Double Hydroxide Supported Pd Catalyst
    X. Jin, Y. Koizumi, K. Yamaguchi, K. Nozaki, N. Mizuno
    J. Am. Chem. Soc. 2017, 139, 13821-13829. 10.1021/jacs.7b07347
  20. Formal arylation of NH3 to produce diphenylamines over supported Pd catalysts
    Y. Koizumi, K. Taniguchi, X. Jin, K. Yamaguchi, K. Nozaki, N. Mizuno
    Chem. Commun. 2017, 53, 10827–10830. 10.1039/C7CC06737B
  21. A Ni-Mg-Al layered triple hydroxide-supported Pd catalyst for heterogeneous acceptorless dehydrogenative aromitization
    X. Jin, K. Taniguchi, K. Yamaguchi, K. Nozaki, N. Mizuno
    Chem. Commun. 2017, 53, 5267–5270. 10.1039/C7CC01182B
  22. Versatile routes for synthesis of diarylamines through acceptorless dehydrogenative aromatization catalysis over supported gold–palladium bimetallic nanoparticles
    K. Taniguchi, X. Jin, K. Yamaguchi, K. Nozaki, N. Mizuno
    Chem. Sci. 2017, 8, 2131–2142. 10.1039/C6SC04455G
  23. Gold Nanoparticles on OMS-2 for Heterogeneously Catalyzed Aerobic Oxidative α,β-Dehydrogenation of β-Heteroatom-Substituted Ketones
    D. Yoshii, X. Jin, T. Yatabe, J. Hasegawa, K. Yamaguchi, N. Mizuno
    Chem. Commun. 2016, 52, 14314–14317. 10.1039/C6CC07846J
  24. Au‒Pd Alloy Nanoparticles Supported on Layered Double Hydroxide for Heterogeneously Catalyzed Aerobic Oxidative Dehydrogenation of Cyclohexanols and Cyclohexanones to Phenols
    X. Jin, K. Taniguchi, K. Yamaguchi, N. Mizuno
    Chem. Sci. 2016, 7, 5371–5383. 10.1039/C6SC00874G
  25. Supported Gold Nanoparticles for Efficient α-Oxygenation of Secondary and Tertiary Amines into Amides
    X. Jin, K. Kataoka, T. Yatabe, K. Yamaguchi, N. Mizuno
    Angew. Chem. Int. Ed. 2016, 55, 7212–7217. 10.1002/anie.201602695
  26. Facile Access to N-Substituted Anilines via Dehydrogenative Aromatization Catalysis over Supported Gold-Palladium Bimetallic Nanoparticles
    K. Taniguchi, X. Jin, K. Yamaguchi, N. Mizuno
    Catal. Sci. Technol. 2016, 6, 3929–3937. 10.1039/C5CY01908G
  27. Phosphovanadomolybdic Acids Catalyzed Desulfurization-Oxygenation of Secondary and Tertiary Thioamides into Amides Using Molecular Oxygen as the Terminal Oxidant
    N. Xu, X. Jin, K. Suzuki, K. Yamaguchi, N. Mizuno
    New. J. Chem. 2016, 40, 4865–4869. 10.1039/C5NJ03579A
  28. Synthesis of N-Acylsulfenamides through Aerobic Cross Dehydrogenative Coupling of Thiols and Amides by Supported Copper Hydroxide Catalyst
    K. Sakagami, X. Jin, K. Suzuki, K. Yamaguchi, N. Mizuno
    Chem. Lett. 2016, 45, 173–175. 10.1246/cl.151090
  29. Gold Nanoparticles Supported on a Layered Double Hydroxide as Efficient Catalysts for the One-Pot Synthesis of Flavones
    T. Yatabe, X. Jin, K. Yamaguchi, N. Mizuno
    Angew. Chem. Int. Ed. 2015, 54, 13302–13306. 10.1002/anie.201507134
  30. Supported Gold-Palladium Alloy Nanoparticle Catalyzed Tandem Oxidation Routes to N-Substituted Anilines from Non-aromatic Compounds
    K. Taniguchi, X. Jin, K. Yamaguchi, N. Mizuno
    Chem. Commun. 2015, 51, 14969–14972. 10.1039/C5CC06514C
  31. Regioselective Direct Oxidative C‒H Cyanation of Quinoline and Its Derivatives Catalyzed by Vanadium-Containing Heteropoly acids
    K. Yamaguchi, N. Xu, X. Jin, K. Suzuki, N. Mizuno
    Chem. Commun. 2015, 51, 10034–10037. 10.1039/C5CC02797G
  32. Gold-Catalyzed Heterogeneous Aerobic Dehydrogenative Amination of α,β-Unsaturated Aldehydes to Enaminals
    X. Jin, K. Yamaguchi, N. Mizuno
    Angew. Chem. Int. Ed. 2014, 53, 455–458. 10.1002/anie.201308260
  33. Aerobic Cross-Dehydrogenative Coupling of Terminal Alkynes and Tertiary Amines by a Combined Catalyst of Zn2+ and OMS-2
    X. Jin, K. Yamaguchi, N. Mizuno
    RSC Adv. 2014, 4, 34712–34715. 10.1039/C4RA05105J
  34. Oxidative Nucleophilic Strategy for Synthesis of Thiocyanates and Trifluoromethyl Sulfides from Thiols
    K. Yamaguchi, K. Sakagami, Y. Miyamoto, X. Jin, N. Mizuno
    Org. Biomol. Chem. 2014, 12, 9200–9206. 10.1039/C4OB01655F
  35. Copper-Catalyzed Oxidative Cross-Coupling of H-Phosphonates and Amides to N-Acylphosphoramidates
    X. Jin, K. Yamaguchi, N. Mizuno
    Org. Lett. 2013, 15, 418–421. 10.1021/ol303420g
  36. Heterogeneously Catalyzed Self-Condensation of Primary Amines to Secondary Amines by Supported Copper Catalysts
    I. Kim, S. Itagaki, X. Jin, K. Yamaguchi, N. Mizuno
    Catal. Sci. Technol. 2013, 3, 2397–2403. 10.1039/C3CY00405H
  37. Heterogeneously Catalyzed Selective Aerobic Oxidative Cross-Coupling of Terminal Alkynes and Amides with Simple Copper(II) Hydroxide
    X. Jin, K. Yamaguchi, N. Mizuno
    Chem. Commun. 2012, 48, 4974–4976. 10.1039/C2CC31159C
  38. A Green Synthetic Route to Imides from Terminal Alkynes and Amides by Simple Solid Catalysts
    X. Jin, K. Yamaguchi, N. Mizuno
    Chem. Lett. 2012, 41, 866–867. 10.1246/cl.2012.866
  39. Heterogeneously Catalyzed Efficient Hydration of Alkynes by Tin-Tungsten Mixed Oxides
    X. Jin, T. Oishi, K. Yamaguchi, N. Mizuno
    Chem. Eur. J. 2011, 17, 1261–1267. 10.1002/chem.201002761