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研究業績


発表論文 2005-2009

2009年

  1. Synthesis and Protonolysis of Tungsten- and Molybdenum-Dinitrogen Complexes Bearing Bis(dialkylphosphinobenzene)chromiums as Auxiliary Ligands
    M. Yuki, Y. Miyake, and Y. Nishibayashi
    Organometallics,28, 5821-5827 (2009).
  2. Design and Synthesis of Diphosphine Ligands Bearing Osmium(II) Bis(terpyridyl) Moiety as a Light Harvesting Unit: Application to Photocatalytic Production of Dihydrogen
    Y. Miyake, K. Nakajima, K. Sasaki, R. Saito, H. Nakanishi, and Y. Nishibayashi
    Organometallics, 28, 5240-5243 (2009).
  3. Synthesis and Protonolysis of Tungsten- and Molybdenum-Dinitrogen Complexes Bearing Ruthenocenyldiphosphines
    M. Yuki, T. Midorikawa, Y. Miyake, and Y. Nishibayashi
    Organometallics, 28, 4741-4746 (2009).
  4. Enantioselective Ring-Opening Reactions of Racemic Ethynyl Epoxides via Copper-Allenylidene Intermediates: Efficient Approach to Chiral b-Amino Alcohols
    G. Hattori, A. Yoshida, Y. Miyake, and Y. Nishibayashi
    J. Org. Chem., 74, 7603-7607 (2009).[Selected as Featured Article] [Highlighted at Cover Picture] [Highlighted in Synfacts, 2010, 01]
  5. Ruthenium-Catalyze Enantioselective Intramolecular Propargylation of Thiophenes with Propargylic Alcohols
    K. Kanao, Y. Miyake, and Y. Nishibayashi
    Organometallics, 28, 2920-2926 (2009).
  6. Catalytic Cycloisomerization of 1,5-Enynes to 1,3-Cyclohexadienes via Ruthenium-Vinylidene Intermediates
    K. Fukamizu, Y. Miyake, and Y. Nishibayashi
    Angew. Chem. Int. Ed., 48, 2534-2537 (2009). [Highlighted in Organic Chemistry Portal, 2009, 12]
  7. Remarkable Effect of Halogens on Catalytic Activities of Thiolate-Bridged Diruthenium Complexes in Propargylic Substitution Reactions
    Y. Tanabe, K. Kanao, Y. Miyake, and Y. Nishibayashi
    Organometallics, 28, 1138-1142 (2009).
  8. A DFT Study on the Reaction Pathway for Carbon-Carbon Bond Forming Reactions between Propargylic Alcohols and Alkenes or Ketones Catalyzed by Thiolate-Bridged Diruthenium Complexes
    K. Sakata, Y. Miyake, and Y. Nishibayashi
    Chem. Asian J., 4, 81-88 (2009).
  9. Ruthenium-Catalyzed Oxypropargylation of Alkenes
    Y. Yamauchi, Y. Miyake, and Y. Nishibayashi
    Organometallics, 28, 48-50 (2009).
  10. 未来を拓く次世代型窒素固定法の開発―エネルギーおよび環境問題を解決するアンモニア社会の実現に向けて―
    西林仁昭
    現代化学, 10月号, 28-34 (2009).
  11. Catalytic Propargylic Substitution Reactions
    Y. Miyake, S. Uemura, and Y. Nishibayashi
    ChemCatChem, 1, 342-356 (2009).
  12. アンモニアによるエネルギー問題の解決―ハーバー・ボッシュ法に代わる新しい窒素固定法の開発を目指して
    田邊資明、三宅由寛、西林仁昭
    配管技術, 11月号, 7-13 (2009).
  13. 硫黄架橋二核ルテニウム錯体を用いた触媒的プロパルギル位置換反応の開発
    西林仁昭、三宅由寛
    触媒, 51, 594-600 (2009).
  14. ルテニウム-アレニリデン錯体を鍵中間体として経由する新規触媒反応の開発
    西林仁昭、三宅由寛、植村　榮
    有機合成化学協会誌, 67, 437-450 (2009).
  15. 銅錯体を用いた触媒的不斉プロパルギル位置換反応の開発
    西林仁昭
    旭硝子財団助成研究成果報告書, 55 (2009).
  16. 穏和な反応条件下での触媒的窒素固定反応の開発
    西林仁昭、三宅由寛、結城雅弘
    マツダ財団研究報告書, 151-157 (2009).

2008年

  1. Synthesis and Reactivity of Hybrid Phosphido- and Thiolate-Bridged Diruthenium Complexes
    Y. Miyake, S. Endo, M. Yuki, Y. Tanabe, and Y. Nishibayashi
    Organometallics, 27, 6039-6042 (2008).
  2. Ruthenium-Catalyzed Enantioselective Propargylation of Indoles with Propargylic Alcohols
    K. Kanao, H. Matsuzawa, Y. Miyake, and Y. Nishibayashi
    Synthesis (PSP, invitation), 3869-3873 (2008).
  3. Ruthenium-Catalyzed Enantioselective Carbon-Carbon Bond Forming Reaction via Allenylidene-Ene Process: Synthetic Approach to Chiral Heterocycles such as Chromane, Thiochromane, and 1,2,3,4-Tetrahydroquinoline Derivatives
    K. Fukamizu, Y. Miyake, and Y. Nishibayashi
    J. Am. Chem. Soc., 130, 10498-10499 (2008). [Highlighted in Synfacts, 2008, 10]
  4. Synthesis of Optically Active N,N,N’,N’-Tetraphenyl-1,1’-binaphthyl-2,2’-diamine Derivatives as Analogues of BINAP
    H. Matsuzawa, Y. Tanabe, Y. Miyake, and Y. Nishibayashi
    Organometallics, 27, 4021-4024 (2008).
  5. Novel Monophosphido-Bridged Diruthenium Complexes: Efficient Preparative Method and Catalytic Activity toward Reactions of Propargylic Alcohols with Aromatic Compounds
    Y. Miyake, S. Endo, Y. Nomaguchi, M. Yuki, and Y. Nishibayashi
    Organometallics, 27, 4017-4020 (2008).
  6. Synthesis and Reactivity of Tungsten- and Molybdenum-Dinitrogen Complexes Bearing Ferrocenyldiphosphines
    M. Yuki, Y. Miyake, Y. Nishibayashi, I. Wakiji, and M. Hidai
    Organometallics, 27, 3947-3953 (2008).
  7. Ruthenium-Catalyzed Intramolecular Cyclization of 3-Butyne-1,2-diols into Furans
    Y. Yada, Y. Miyake, and Y. Nishibayashi
    Organometallics, 27, 3614-3617 (2008).
  8. Copper-Catalyzed Asymmetric Propargylic Substitution Reactions of Propargylic Acetates with Amines: A Novel Synthetic Approach to Chiral Propargylic Amines
    G. Hattori, H. Matsuzawa, Y. Miyake, and Y. Nishibayashi
    Angew. Chem. Int. Ed., 47, 3781-3783 (2008). [Highlighted in Angew. Chem.] [Highlighted in Synfacts, 2008, 07]
  9. Ruthenium-Catalyzed Dienyne Formation from Propargylic Alcohols and 1,3-Conjugated Dienes
    M. Daini, M. Yoshikawa, Y. Inada, S. Uemura, K. Sakata, K. Kanao, Y. Miyake, and Y. Nishibayashi
    Organometallics, 27, 2046-2051 (2008).
  10. Ruthenium-Catalyzed Vinylic Substitution Reactions with Nucleophiles via Butatrienylidene Intermediates
    Y. Yamauchi, M. Yuki, Y. Tanabe, Y. Miyake, Y. Inada, S. Uemura, and Y. Nishibayashi
    J. Am. Chem. Soc., 130, 2908-2909 (2008).
  11. Optically Active Chiral Ligands Ferrocenyloxazolinylphosphines (FOXAP): Development and Application to Catalytic Asymmetric Reactions
    Y. Miyake, Y. Nishibayashi and S. Uemura
    Synlett, 1747-1758 (2008).
  12. Allenylidene Complexes in Catalysis
    Y. Nishibayashi, S. Uemura
    Metal Vinylidenes and Allenylidenes in Catalysis; Eds. P. H. Dixneuf and C. Bruneau, WILEY-VCH, 217-250 (2008).

2007年

  1. Remarkable Effect of N-Substituent on Enantioselective Ruthenium-Catalyzed Propargylation of Indoles with Propargylic Alcohols
    H. Matsuzawa, K. Kanao, Y. Miyake, and Y. Nishibayashi
    Org. Lett., 9, 5561-5564 (2007). [Highlighted in Angew. Chem.] [Highlighted in Synfacts, 2008, 03]
  2. Design and Preparation of Chiral Ligand Based on a Pseudorotaxane Skeleton: Application to Rhodium-Catalyzed Enantioselective Hydrogenation of Enamides
    G. Hattori, T. Hori, Y. Miyake, and Y. Nishibayashi
    J. Am. Chem. Soc., 129, 12930-12931 (2007). [Highlighted in Synfacts, 2008, 01]
  3. Ruthenium-Catalyzed Enantioselective Propargylation of Aromatic Compounds with Propargylic Alcohols via Allenylidene Intermediates
    H. Matsuzawa, Y. Miyake, and Y. Nishibayashi
    Angew. Chem. Int. Ed., 46, 6488-6491 (2007). [Selected as VIP (Very Important Paper)] [Highlighted at Cover Picture] [Highlighted in Angew. Chem.] [Highlighted in Synfacts, 2007, 11]
  4. Synthesis and Reactivity of Diphosphine-Bridged Diruthenium Complexes
    Y. Miyake, Y. Nomaguchi, M. Yuki, and Y. Nishibayashi
    Organometallics, 26, 3611-3613 (2007).
  5. Ruthenium-Catalyzed Reactions of 1-Cyclopropyl-2-propyn-1-ols with Anilines and Water via Allenylidene Intermediates: Selective Preparation of Tri- and Tetrasubstituted Conjugated Enynes
    Y. Yamauchi, G. Onodera, K. Sakata, M. Yuki, Y. Miyake, S. Uemura, and Y. Nishibayashi
    J. Am. Chem. Soc., 129, 5175-5179 (2007).
  6. Ruthenium-Catalyzed Sequential Reactions: Deracemization of Secondary Benzylic Alcohols
    Y. Shimada, Y. Miyake, H. Matsuzawa, and Y. Nishibayashi
    Chem. Asian J., 2, 393-396 (2007).
  7. 二核ルテニウム錯体の特性を用いた新規触媒反応の開発―セレンディピティー的発見から阿吽の呼吸による協奏作用まで
    西林仁昭
    化学と工業，60, 1088-1091 (2007).
  8. 光学活性フェロセニルオキサゾリニルホスフィン(FOXAP)配位子の開発と触媒的不斉合成反応への応用
    西林仁昭、三宅由寛、植村　榮
    有機合成化学協会誌, 65, 761-771 (2007).
  9. C-C Bond Formation by Substitution Reaction: Substitution at Propargylic and Benzylic Positions
    Y. Nishibayashi and S. Uemura
    Comprehensive Organometallic Chemistry III; Eds. R. H. Crabtree and D. M. P. Mingos, Elsevier, Vol. 11; 75-122 (2007).
  10. C-C Bond Formation by Substitution Reaction: Allylic Alkylation
    Y. Nishibayashi and S. Uemura
    Comprehensive Organometallic Chemistry III; Eds. R. H. Crabtree and D. M. P. Mingos, Elsevier, Vol. 11; 123-150 (2007).
  11. 多核錯体が構築する特異な反応場の設計とその利用
    西林仁昭
    倉田奨励金研究報告, 70-71 (2007).

2006年

  1. Ruthenium-Catalyzed Propargylic Reduction of Propargylic Alcohols with Silanes
    Y. Nishibayashi, A. Shinoda, Y. Miyake, H. Matsuzawa, and M. Sato
    Angew. Chem. Int. Ed., 45, 4835-4839 (2006).
  2. Iridium- and Ruthenium-Catalyzed Sequential Reactions: Asymmetric a-Alkylative Reduction of Ketones with Alcohols
    G. Onodera, Y. Nishibayashi, and S. Uemura
    Angew. Chem. Int. Ed., 45, 3819-3822 (2006). [Highlighted in Synfacts, 2006, 09]
  3. Ruthenium-Catalyzed Propargylation of Aromatic Compounds with Propargylic Alcohols
    Y. Inada, M. Yoshikawa, M. D. Milton, Y. Nishibayashi, and S. Uemura
    Eur. J. Org. Chem., 881-890 (2006). [Highlighted at Cover Picture] [Highlighted in Synfacts, 2006, 09]
  4. Ruthenium-Catalyzed Reductive Coupling Reaction of Propargylic Alcohols via Hydroboration of Allenylidene Intermediates
    G. Onodera, Y. Nishibayashi, and S. Uemura
    Organometallics, 25, 35-37 (2006).
  5. Ruthenium-Catalyzed Novel Carbon-Carbon Bond Forming Reactions via Ruthenium-Allenylidene Complexes
    Y. Nishibayashi and S. Uemura
    Current Organic Chemistry, 10, 135-150 (2006).
  6. 触媒的不斉プロパルギル位置換反応の開発
    西林仁昭
    池谷科学技術振興財団年報, 31-32 (2006).
  7. 複数の金属を用いた新規分子変換反応の開発
    西林仁昭
    徳山科学技術振興財団年報, 60-63 (2006).
  8. 触媒的不斉プロパルギル位置換反応の開発
    西林仁昭
    長瀬科学技術振興財団研究報告集, 55-65 (2006).

2005年

  1. Ruthenium-Catalyzed Asymmetric Propargylic Substitution Reaction of Propargylic Alcohols with Acetone
    Y. Inada, Y. Nishibayashi, and S. Uemura
    Angew. Chem. Int. Ed., 44, 7715-7717 (2005). [Highlighted at Cover Picture] [Highlighted in Angew. Chem.] [Highlighted in Synfacts, 2006, 03]
  2. Preparation of Dicationic Chalcogenolate-Bridged Diruthenium Complexes and Their Catalytic Activity toward Reactions Between Propargylic Alcohols and Acetone
    G. Onodera, H. Matsumoto, Y. Nishibayashi, and S. Uemura
    Organometallics, 24, 5799-5801 (2005).
  3. Ruthenium-Catalyzed Formation of Aryl(diphenyl)phosphine Oxides by Reactions of Propargylic Alcohols with Diphenylphosphine Oxide
    G. Onodera, H. Matsumoto, M. D. Milton, Y. Nishibayashi, and S. Uemura
    Org. Lett., 7, 4029-4032 (2005).
  4. A Novel Method for the Preparation of Enantiomerically Pure Propargylic Substituted Compounds
    Y. Nishibayashi, H. Imajima, G. Onodera, and S. Uemura
    Organometallics, 24, 4106-4109 (2005).
  5. Asymmetric Carboselenenylation Reaction of Alkenes with Aromatic Compounds
    K. Okamoto, Y. Nishibayashi, S. Uemura, and A. Toshimitsu
    Angew. Chem. Int. Ed., 44, 3588-3591 (2005).
  6. Synergistic Dimetallic Effects in Propargylic Substitution Reaction Catalyzed by Thiolate-bridged Diruthenium Complex
    S. C. Ammal, N. Yoshikai, Y. Inada, Y. Nishibayashi, and E. Nakamura
    J. Am. Chem. Soc., 127, 9428-9438 (2005).
  7. Ruthenium-Catalyzed Propargylic Substitution Reactions of Propargylic Alcohols with Oxygen-, Nitrogen-, and Phosphorus-Centered Nucleophiles
    Y. Nishibayashi, M. D. Milton, Y. Inada, M. Yoshikawa, I. Wakiji, M. Hidai, and S. Uemura
    Chemistry-A European Journal, 11, 1433-1451 (2005). [Highlighted at Cover Picture]
  8. 次世代の窒素固定法の開発に向けて：フラーレンを用いた窒素固定法の開発
    西林仁昭
    触媒, 47, 233-238 (2005).
  9. A Non-Metal System for Nitrogen Fixation Utilizing Buckminsterfullerene
    Y. Nishibayashi, S. Uemura, S. Takekuma, and Z. Yoshida
    Biological Nitrogen Fixation, Sustainable Agriculture and the Environment, Ed. Y.-P. Wang, M. Lin, Z.-X. Tian, C. Elmerich, W. E. Newton., Springer, 39-40 (2005).
  10. フラーレンを用いた新規窒素固定法の開発
    西林仁昭
    近畿地方発明センター研究助成成果報告書, 44-47 (2005).


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西林研究室

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応用化学専攻
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