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発表論文 2015-

2018年

  1. Preparation and Reactivity of Iron Complexes Bearing Anionic Carbazole-Based PNP-Type Pincer Ligands toward Catalytic Nitrogen Fixation
    J. Higuchi, S. Kuriyama, A. Eizawa, K. Arashiba, K. Nakajima, and Y. Nishibayashi
    Dalton Transactions00, in press (2018).
  2. Practical Synthesis of PCP-type Pincer Ligand and its Metal Complexes
    K. Matoba, A. Eizawa, S. Nishimura, K. Arashiba, K. Nakajima, and Y. Nishibayashi
    Synthesis (PSP)00, in press (2018).
  3. Mechanism and Reactivity of Catalytic Propargylic Substitution Reactions via Metal-Allenylidene Intermediates: A Theortical Perspective
    K. Sakata, and Y. Nishibayashi
    Catal. Sci. Technol., 00, in press (2018).
  4. 「東京大学工学教程 無機化学Ⅱ(錯体化学)」(分担)
    石井和之、北條博彦、西林仁昭
    丸善出版 (2018予定).

2017年

  1. Dicationic Thiolate-Bridged Diruthenium Complexes for Catalytic Oxidation of Molecular Dihydrogen
    M. Yuki, K. Sakata, K. Nakajima, S. Kikuchi, S. Sekine, H. Kawai, and Y. Nishibayashi
    Organometallics36, 4499–4506 (2017).
  2. Synthesis and Reactivity of Iron­–Dinitrogen Complexes Bearing Anionic Methyl- and Phenyl-Substituted Pyrrole-based PNP-Type Pincer Ligands toward Catalytic Nitrogen Fixation
    Y. Sekiguchi, S. Kuriyama, A. Eizawa, K. Arashiba, K. Nakajima, and Y. Nishibayashi
    Chem. Commun., 53, 12040–12043 (2017).
  3. Catalytic Conversion of Dinitrogen into Ammonia under Ambient Reaction Conditions by Using Proton Source from Water
    Y. Tanabe, K. Arashiba, K. Nakajima, and Y. Nishibayashi
    Chem. Asian J.12, 2544–2548 (2017). [Highlighted at Cover Picture]
  4. Hydroboration of Alkynes Catalyzed by Pyrrolide-Based PNP Pincer-Iron Complexes
    K. Nakajima, T. Kato, and Y. Nishibayashi
    Org. Lett., 19, 4323–4326 (2017).
  5. Catalytic Nitrogen Fixation via Direct Cleavage of Nitrogen–Nitrogen Triple Bond of Molecular Dinitrogen under Ambient Reaction Conditions
    K. Arashiba, A. Eizawa, H. Tanaka, K. Nakajima, K. Yoshizawa, and Y. Nishibayashi
    Bull. Chem. Soc. Jpn., 90, 1111–1118 (2017). [BCSJ Award Article] [Highlighted at Cover Picture]
  6. Synthesis and Reactivity of Iron- and Cobalt-Dinitrogen Complexes Bearing PSiP-Type Pincer Ligand toward Nitrogen Fixation
    R. Imayoshi, K. Nakajima, J. Takaya, N. Iwasawa, and Y. Nishibayashi
    Eur. J. Inorg. Chem., 3769–3778 (2017). [Selected as Very Important Paper] [Highlighted at Cover Picture] [Cover Profile]

     
  7. Remarkable Catalytic Activity of Dinitrogen-Bridged Dimolybdenum Complexes Bearing NHC-Based PCP-Pincer Ligands toward Nitrogen Fixation
    A. Eizawa, K. Arashiba, H. Tanaka, S. Kuriyama, Y. Matsuo, K. Nakajima, K. Yoshizawa, and Y. Nishibayashi
    Nature Communications8, 14874 (2017). 
  8. Vanadium-Catalyzed Reduction of Molecular Dinitrogen into Silylamine under Ambient Reaction Conditions
    R. Imayoshi, K. Nakajima, and Y. Nishibayashi
    Chem. Lett., 46, 466–468 (2017). [Selected as Editor's Choice Paper]
  9. Catalytic Activity of Thiolate-Bridged Diruthenium Complexes Bearing Pendent Ether Moieties toward Oxidation of Molecular Dihydrogen
    M. Yuki, K. Sakata, S. Kikuchi, H. Kawai, T. Takahashi, M. Ando, K. Nakajima, and Y. Nishibayashi
    Chemistry-A European Journal, 23, 1007-1012 (2017). [Highlighted at Cover Picture] [Selected as Hot Paper]
  10. 分子触媒を利用した窒素固定反応の新展開
    —新しい反応経路を通ることで触媒活性が向上!
    化学, 12月号, 45-50 (2017). 
    西林仁昭、荒芝和也、永澤 彩、中島一成、吉澤一成、田中宏昌
  11. 遷移金属窒素錯体を用いた触媒的窒素固定反応の最近の進展
    西林仁昭
    Organometallic News, 63-67 (2017).
  12. Catalytic Nitrogen Fixation Using Molybdenum–Dinitrogen Complexes as Catalysts
    A. Eizawa and Y. Nishibayashi
    Topics in Organometallic Chemistry – Nitrogen Fixation; Ed. Y. Nishibayashi, Springer, 153-169 (2017).
  13. Catalytic Transformations of Molecular Dinitrogen by Iron and Cobalt–Dinitrogen Complexes as Catalysts
    S. Kuriyama and Y. Nishibayashi
    Topics in Organometallic Chemistry – Nitrogen Fixation; Ed. Y. Nishibayashi, Springer, 215-234 (2017).
  14. アンモニアによるエネルギー資源革命を目指して
    –分子触媒を利用したアンモニア合成反応–
    西林仁昭、荒芝和也、永澤 彩
    現代化学, 5月号, 30-36 (2017).
  15. 触媒的不斉プロパルギル位置換反応の開発
    西林仁昭
    有機合成化学協会誌, 75, 2-13 (2017).

2016年

  1. Nickel- and Photoredox-Catalyzed Cross-Coupling Reactions of Aryl Halides with 4-Alkyl-1,4-dihydropyridines as Visible Light-Mediated Formal Nucleophilic Alkylation Reagents
    K. Nakajima, S. Nojima, and Y. Nishibayashi
    Angew. Chem. Int. Ed. 55, 14106–14110 (2016).
  2. Iron-Catalyzed [2+2+2] Cycloaddition Reactions of Diynes with Oxyphosphaethynes to Construct 2-Phosphaphenol Derivatives
    K. Nakajima, W. Liang, and Y. Nishibayashi
    Org. Lett. 18, 5006–5009 (2016).
  3. Azaferrocene-Based PNP-Type Pincer Ligand: Synthesis of Molybdenum, Chromium, and Iron Complexes and Reactivity toward Nitrogen Fixation
    S. Kuriyama, K. Arashiba, K. Nakajima, H. Tanaka, K. Yoshizawa, and Y. Nishibayashi
    Eur. J. Inorg. Chem., 4856–4861 (2016).
  4. Direct Transformation of Molecular Dinitrogen into Ammonia Catalyzed by Cobalt Dinitrogen Complexes Bearing Anionic PNP Pincer Ligands
    S. Kuriyama, K. Arashiba, H. Tanaka, Y. Matsuo, K. Nakajima, K. Yoshizawa, and Y. Nishibayashi
    Angew. Chem. Int. Ed. 55, 14291–14295 (2016). [Highlighted at Cover Picture] [Selected as Hot Paper]
     
  5. Catalytic Transformation of Dinitrogen into Ammonia and Hydrazine by Iron-Dinitrogen Complexes Bearing Pincer Ligand 
    S. Kuriyama, K. Arashiba, K. Nakajima, Y. Matsuo, H. Tanaka, K. Ishii, K. Yoshizawa, and Y. Nishibayashi
    Nature Communications, 7, 12181 (2016).
  6. Construction of Chiral Tri- and Tetra-arylmethanes Bearing Quaternary Carbon by Using Copper-Catalyzed Enantioselective Propargylation of Indoles with Propargylic Esters
    K. Tsuchida, Y. Senda, K. Nakajima, and Y. Nishibayashi
    Angew. Chem. Int. Ed., 55, 9728–9732 (2016). [Highlighted in Synfacts, 2016, 11]
  7. Visible Light-Mediated Aromatic Substitution Reactions of Cyanoarenes with 4-Alkyl-1,4-dihydropyridines via Dual Carbon-Carbon Bonds Cleavage
    K. Nakajima, S. Nojima, K. Sakata, and Y. Nishibayashi
    ChemCatChem, 8, 1028–1032 (2016). [Highlighted at Cover Picture] [Cover Profile]
      
  8. Synthetic Utilization of α-Aminoalkyl Radicals and Related Species in Visible Light Photoredox Catalysis
    K. Nakajima, Y. Miyake, and Y. Nishibayashi
    Acc. Chem. Res., 49, 1946–1956 (2016).
  9. Interplay between Theory and Experiment for Ammonia Synthesis Catalyzed by Transition Metal Complexes
    H. Tanaka, Y. Nishibayashi, and K. Yoshizawa
    Acc. Chem. Res., 49, 987–995 (2016).
  10. Catalytic Dinitrogen Fixation to Form Ammonia at Ambient Reaction Conditions Using Transition Metal-Dinitrogen Complexes
    Y. Tanabe and Y. Nishibayashi
    Chemical Record, 16, 1549–1577 (2016).
  11. 分子触媒を用いた窒素固定法の最近の進展
    田邊資明、西林仁昭
    エネルギー・資源, 37, No. 6, 1–5 (2016).
  12. 常温常圧下での触媒的窒素固定法開発の最近の進展
    田邊資明、西林仁昭
    日本エネルギー学会誌, 5月号, 95, 371-381 (2016).
  13. 特集にあたって-ハーバー・ボッシュ法を超えるアンモニア合成法開発への挑戦-
    西林仁昭
    ファインケミカル, 3月号, 45, 5–6 (2016).
  14. 遷移金属錯体を触媒として利用した触媒的アンモニア合成法の開発
    田邊資明、西林仁昭
    ファインケミカル, 3月号, 45, 7-18 (2016). [Hydrogen Energy Sciety, 3, 12–23 (2016)]
  15. 非白金分子触媒による触媒的水素酸化反応の開発
    結城雅弘、西林仁昭
    ENEOS Technical Review, 58, No.1, 12–18 (2016).
  16. 有機分子触媒と遷移金属触媒とを協奏的に利用した分子変換反応
    三宅由寛、中島一成、西林仁昭
    有機分子触媒の最前線 (日本化学会 Current Review), 167–176 (2016).
  17. 「ウェイド 有機化学 原書7版」 問題の解き方 (分担)
    中村浩之、岩本武明、斎藤慎一、柴田高範、田中健、長澤和夫、西林仁昭
    丸善出版 (2016).
  18. 温和な反応条件下での触媒的窒素固定法に関する最近の進展
    荒芝和也、西林仁昭
    化学工業, 67, No.1, 1–5 (2016).

2015年

  1. Recent Progress in Transition Metal-Catalyzed Reduction of Molecular Dinitrogen under Ambient Reaction Conditions
    Y. Nishibayashi
    Inorg. Chem. (forum article for special issue), 54, 9234–9247 (2015).
  2. Nitrogen Fixation Catalyzed by Ferrocene-Substituted Dinitrogen-Bridged Dimolybdenum-Dinitrogen Complexes: Unique Behavior of Ferrocene Moiety as Redox Active Site
    S. Kuriyama, K. Arashiba, K. Nakajima, H. Tanaka, K. Yoshizawa, and Y. Nishibayashi
    Chem. Sci., 6, 3940–3951 (2015).
  3. Synthesis of Phosphabenzenes by Iron-Catalyzed [2+2+2] Cycloaddition Reaction of Diynes with Phosphaalkynes
    K. Nakajima, S. Takata, K. Sakata, and Y. Nishibayashi
    Angew. Chem. Int. Ed., 54, 7597–7601 (2015).
  4. Catalytic Reduction of Dinitrogen into Ammonia by Use of Molybdenum-Nitride Complexes Bearing Tridentate Triphosphine as Catalysts
    K. Arashiba, E. Kinoshita, S. Kuriyama, A. Eizawa, K. Nakajima, H. Tanaka, K. Yoshizawa, and Y. Nishibayashi
    J. Am. Chem. Soc., 137, 5666–5669 (2015). [Highlighted at ChemistryViews]
  5. Cobalt-Catalyzed Transformation of Molecular Dinitrogen into Silylamine under Ambient Reaction Conditions
    R. Imayoshi, H. Tanaka, Y. Matsuo, M. Yuki, K. Nakajima, K. Yoshizawa, and Y. Nishibayashi
    Chemistry-A European Journal, 21, 8905–8909 (2015).
  6. Thiolate-Bridged Dinuclear Ruthenium- and Iron-Complexex as Robust and Efficient Catalysts toward Oxidation of Molecular Dihydrogen in Protic Solvents
    M. Yuki, K. Sakata, Y. Hirao, N. Nonoyama, K. Nakajima, and Y. Nishibayashi
    J. Am. Chem. Soc., 137, 4173–4182 (2015).
  7. Copper-Catalyzed Enantioselective Etherification of Propargylic Esters with Alcohols
    K. Nakajima, M. Shibata, and Y. Nishibayashi
    J. Am. Chem. Soc., 137, 2472–2475 (2015). [Highlighted in Synfacts, 2015, 5]
  8. Synthesis and Catalytic Activity of Molybdenum-Nitride Complexes Bearing Pincer Ligands
    E. Kinoshita, K. Arashiba, S. Kuriyama, A. Eizawa, K. Nakajima, and Y. Nishibayashi
    Eur. J. Inorg. Chem., 1789–1794 (2015).
  9. Radical Addition to Corannulene Mediated by Visible Light-Photoredox Catalysts
    K. Nakajima, Y. Ashida, S. Nojima, and Y. Nishibayashi
    Chem. Lett., 44, 545–547 (2015).
  10. Cooperative Catalytic Reactions: Enantioselective Propargylic Alkylation of Propargylic Alcohols with Enecarbamates Using Ruthenium and Phosphoramide Hybrid Catalysts
    Y. Senda, K. Nakajima, and Y. Nishibayashi
    Angew. Chem. Int. Ed., 54, 4060–4064 (2015). [Highlighted in Synfacts, 2015, 5]
  11. Synthesis and Reactivity of Molybdenum-Dinitrogen Complexes Bearing PNN-Type Pincer Ligand
    K. Arashiba, K. Nakajima, and Y. Nishibayashi
    Z. Anorg. Allg. Chem. (invitation for special issue), 641, 100–104 (2015).
  12. 白金触媒に匹敵するアノード分子触媒の開発
    結城雅弘、西林仁昭
    エネルギーデバイス, 2, No.7, 92–96 (2015).
  13. 常温常圧でのアンモニアの合成
    田邊資明、西林仁昭
    アンモニアを用いた水素利用システム, 87-101 (2015).
  14. Molybdenum-Catalyzed Reduction of Molecular Dinitrogen under Ambient Reaction Conditions
    Y. Nishibayashi
    Comptes rendus Chimie (invitation for special issue),18, 776–784 (2015).
  15. 温和な反応条件下での遷移金属窒素錯体を分子触媒として用いた窒素分子からのアンモニア合成反応の開発
    西林仁昭
    触媒, 57, 33–38 (2015).
 


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