研究業績｜東京大学　西林研究室

• 発表論文 2021-
• 発表論文 2015-2020
• 発表論文 2010-2014
• 発表論文 2005-2009
• 発表論文 2000-2004
• 発表論文 1999年以前
• 学会発表

発表論文 1999年以前

1999年

1. Novel Catalytic Hydrogenolysis of Trimethylsilyl Enol Ethers by the Use of an Acidic Ruthenium Dihydrogen Complex
   Y. Nishibayashi, I. Takei, and M. Hidai
   Angew. Chem. Int. Ed., 38, 3047-3050 (1999).
2. Extremely High-Enantioselective Redox Reaction of Ketones and Alcohols Catalyzed by RuCl₂(PPh₃)(oxazolinylferrocenylphosphine)
   Y. Nishibayashi, I. Takei, S. Uemura, and M. Hidai
   Organometallics, 18, 2291-2293 (1999).
3. Iridium-Catalyzed Asymmetric Hydrosilylation of Imines by Chiral Oxazolinyl-Phosphine Ligands
   I. Takei, Y. Nishibayashi, Y. Arikawa, S. Uemura, and M. Hidai
   Organometallics, 18, 2271-2274 (1999).
4. The Use of Chiral Diferrocenyl Diselenides for Highly Selective Asymmetric Intramolecular Selenocyclization
   H. Takada, Y. Nishibayashi, and S. Uemura
   J. Chem. Soc., Perkin Trans. 1, 1511-1516 (1999).
5. Ruthenium(II)-catalyzed Asymmetric Transfer Hydrogenation of Ketones using Chiral Oxazolinylferrocenylphosphines and its Ru(II) Complex
   Y. Arikawa, M. Ueoka, K. Matoba, Y. Nishibayashi, M. Hidai, and S. Uemura
   J. Organomet. Chem., 572, 163-168 (1999).
6. Sigmatropic Rearrangements of Organoselenium Compounds
   Y. Nishibayashi and S. Uemura
   Organoselenium Chemistry: A Practical Approach; Ed. T. G. Back, Oxford University Press, Oxford, 207-221 (1999).

1998年

1. Synthesis of Heterobimetallic Fe-M (M=Ni, Pd, Pt) Complexes Containing 1,1'-Ferrocenedithiolato Ligand and Their Conversion to Trinuclear Complexes
   S. Takemoto, S. Kuwata, Y. Nishibayashi, and M. Hidai
   Inorg. Chem., 37, 6428-6434 (1998).
2. Ruthenium-catalyzed Asymmetric Hydrosilylation of Ketones and Imine
   Y. Nishibayashi, I. Takei, S. Uemura, and M. Hidai
   Organometallics, 17, 3420-3422 (1998).
3. A Model for Protonation of Dinitrogen by Nitrogenase: Protonation of Coordinated Dinitrogen on Tungsten with Hydrosulfido-Bridged Dinuclear Complexes
   Y. Nishibayashi, S. Iwai, and M. Hidai
   J. Am. Chem. Soc., 120, 10559-10560 (1998).
4. Bimetallic System for Nitrogen Fixation: Ruthenium-assisted Protonation of Coordinated N₂ on Tungsten with H₂
   Y. Nishibayashi, S. Iwai, and M. Hidai
   Science, 279, 540-542 (1998).
5. ４級ホスホニウム塩のセレンディピティー的な効果　－不活性な塩化アリールの活性化と触媒活性の向上－
   西林仁昭
   化学，53, 63-64 (1998).
6. 分子状水素錯体を用いた新規な水素化反応の開発
   干鯛眞信，西林仁昭
   Organometallic News, 121-124 (1998).
7. 夢の常温での空中窒素固定法の開発に向けて，―窒素錯体と水素錯体との反応によるアンモニア合成―
   干鯛眞信，西林仁昭
   化学と工業，51, 1897-1899 (1998).
8. Highly Selective Asymmetric Intramolecular Selenocyclization
   H. Takada, Y. Nishibayashi, S. K. Srivastava, K. Ohe, and S. Uemura
   Phosphorus, Sulfur, and Silicon, 136-138, 629-632 (1998).

1997年

1. Catalytic Asymmetric Sulfimidation
   H. Takada, Y. Nishibayashi, K. Ohe, S. Uemura, C. P. Baird, T. J. Sparey, and P. C. Taylor
   J. Org. Chem., 62, 6512-6518 (1997).
2. Synthesis and Structure of Novel Chiral Oxazolinylferrocenes and Oxazolinylferrocenylphosphines, and Their Rhodium(I)-Complexes
   Y. Nishibayashi, K. Segawa, Y. Arikawa, K. Ohe, M. Hidai, and S. Uemura
   J. Organomet. Chem., 545 & 546, 381-398 (1997).
3. Synthesis, Structures and Reactivities of Rhodium and Ruthenium Complexes with Novel Chiral Cyclopentadienyl-ferrocenyldiphenylphosphine Bidentate Ligand
   Y. Nishibayashi, I. Takei, and M. Hidai
   Organometallics, 16, 3091-3093 (1997).
4. Allylation of Arenes Catalysed by Thiolate-Bridged Diruthenium Complexes
   Y. Nishibayashi, M. Yamanashi, Y. Takagi, and M. Hidai
   Chem. Commun., 859-860 (1997).
5. Rhodium(I)-, Iridium(I)-, and Ruthenium(II)-Catalyzed Asymmetric Transfer Hydrogenation of Ketones using Diferrocenyl Dichalcogenides as Chiral Ligands
   Y. Nishibayashi, J. D. Singh, Y. Arikawa, S. Uemura, and M. Hidai
   J. Organomet. Chem., 531, 13-18 (1997).
6. ジルコニウムに配位する窒素分子の新しい反応
   西林仁昭
   Organometallic News, 95-96 (1997).
7. Chiral Bis(oxazoline)-copper Catalyzed Enantioselective Imination of Sulfides
   H. Takada, Y. Nishibayashi, K. Ohe, and S. Uemura
   Phosphorus, Sulfur, and Silicon, 120-121, 363-364 (1997).

1996年

1. Palladium-catalyzed Homocoupling Reactions of Organic Tellurides
   Y. Nishibayashi, C. S. Cho, K. Ohe, and S. Uemura
   J. Organomet. Chem., 526, 335-339 (1996).
2. Oxidative Addition of Diferrocenyl Dichalcogenides to [(η⁵-C₅Me₅)Ru(μ₃-Cl)]₄. Syntheses, Crystal Structures and Some Reactivities of Ferrocenylchalcogenolate-Bridged Diruthenium Complexes [(η⁵-C₅Me₅)RuCl(μ₂-EFc)]₂ (E=S, Se, Te; Fc=ferrocenyl)
   H. Matsuzaka, J.-P. Qü, T. Ogino, M. Nishio, Y. Nishibayashi, Y. Ishii, S. Uemura, and M. Hidai
   J. Chem. Soc., Dalton Trans., 4307-4312 (1996).
3. Novel Asymmetric Catalytic Synthesis of Sulfimides
   H. Takada, Y. Nishibayashi, K. Ohe, and S. Uemura
   Chem. Commun., 931-932 (1996).
4. Iridium(I)-Catalysed Asymmetric Hydrosilylation of Ketones using Chiral Oxazolinylferrocene-Phosphine Hybrid Ligand
   Y. Nishibayashi, K. Segawa, H. Takada, K. Ohe, and S. Uemura
   Chem. Commun., 847-848 (1996).
5. Enantioselective ortho-Lithiation of Substituted Ferrocenes
   Y. Nishibayashi, Y. Arikawa, K. Ohe, and S. Uemura
   J. Org. Chem., 61, 1172-1174 (1996).
6. Novel Chiral Ligands, Diferrocenyl Dichalcogenides and Their Derivatives, for the Rh(I)- and Ir(I)-Catalyzed Asymmetric Hydrosilylation
   Y. Nishibayashi, J. D. Singh, K. Segawa, S. Fukuzawa, K. Ohe, and S. Uemura
   Organometallics, 15, 370-379 (1996).
7. Palladium-catalyzed Cross-coupling Reactions between Organic Tellurides and Alkenes
   Y. Nishibayashi, C. S. Cho, and S. Uemura
   J. Organomet. Chem., 507, 197-200 (1996).
8. Novel Synthesis of Chiral Diferrocenyl Dichalcogenides and Their Application to Asymmetric Reactions
   Y. Nishibayashi and S. Uemura
   Rev. Heteroatom Chem., MYU, Tokyo, 14, 83-118 (1996).

1995年

1. Synthesis of Chiral Diferrocenyl Dichalcogenides and Their Application to Asymmetric Nucleophilic Ring-Opening of meso-Epoxides
   Y. Nishibayashi, J. D. Singh, S. Fukuzawa, and S. Uemura
   J. Chem. Soc., Perkin Trans. 1, 2871-2876 (1995).
2. Chiral Oxazolinylferrocene-Phosphine Hybrid Ligand for the Asymmetric Hydrosilylation of Ketones
   Y. Nishibayashi, K. Segawa, K. Ohe, and S. Uemura
   Organometallics, 14, 5486-5487 (1995).
3. Allylic Amine Formation by Imination of Allylic Tellurides
   Y. Nishibayashi, S. K. Srivastava, K. Ohe, and S. Uemura
   Tetrahedron Lett., 36, 6725-6728 (1995).
4. Highly Selective Asymmetric Intramolecular Selenocyclisation
   Y. Nishibayashi, S. K. Srivastava, H. Takada, S. Fukuzawa, and S. Uemura
   J. Chem. Soc., Chem. Commun., 2321-2322 (1995).
5. The First Example of Enantioselective Carbenoid Addition to Organochalcogen Atoms : Application to [2,3]Sigmatropic Rearrangement of Allylic Chalcogen Ylides
   Y. Nishibayashi, K. Ohe, and S. Uemura
   J. Chem. Soc., Chem. Commun., 1245-1246 (1995).
6. High Chirality Transfer in Chiral Selenimides via [2,3]Sigmatropic Rearrangement
   Y. Nishibayashi, T. Chiba, K. Ohe, and S. Uemura
   J. Chem. Soc., Chem. Commun., 1243-1244 (1995).
7. Synthesis of [R,S;R,S]- and [S,R;S,R]-Bis[2-[1-(dimethylamino)ethyl]-ferrocenyl] Diselenides and Their Application to Asymmetric Selenoxide Elimination and [2,3]Sigmatropic Rearrangement
   Y. Nishibayashi, J. D. Singh, S. Fukuzawa, and S. Uemura
   J. Org. Chem., 60, 4114-4120 (1995).
8. The First Example of Chirality Transfer in Allylic Telluroxides - Possible [2,3]-Sigmatropic Rearrangement
   T. Chiba, Y. Nishibayashi, J. D. Singh, K. Ohe, and S. Uemura
   Tetrahedron Lett., 36, 1519-1522 (1995).
9. Stereo- and Chemo-Selectivity in Reduction of α-[Phenyl(or Methyl)seleno]- alkyl Aryl Ketones with Metal Hydrides
   I, Aoki, Y. Nishibayashi, and S. Uemura
   Bull. Chem. Soc. Jpn., 68, 337-340 (1995).
10. Asymmetric Synthesis and Highly Diastereoselective ortho-Lithiation of Oxazolinylferrocenes
    Y. Nishibayashi, and S. Uemura
    Synlett, 79-81 (1995).

1994年

1. Rhodium(I)-catalysed Asymmetric Hydrosilylation of Ketones using New Diferrocenyl Dichalcogenides (R,S)-{[EC₅H₃CHMe(NMe₂)]Fe(C₅H₅)}₂ (E=S, Se, Te) as Chiral Ligands
   Y. Nishibayashi, J. D. Singh, K. Segawa, S. Fukuzawa, and S. Uemura
   J. Chem. Soc., Chem. Commun., 1375-1376 (1994).
2. Syntheses and Reactivities of Ferrocenyl Organyl Tellurides
   Y. Nishibayashi, T. Chiba, J. D. Singh, S. Uemura, and S. Fukuzawa
   J. Organomet. Chem., 473, 205-213 (1994).
3. Synthesis of Chiral Diferrocenyl Diselenides and Their Application to Asymmetric Reactions
   Y. Nishibayashi, J. D. Singh, S. Uemura, and S. Fukuzawa
   Tetrahedron Lett., 35, 3115-3118 (1994).
4. Dinuclear (η⁵-C₅Me₅)Ru Complexes Triply Bridged by Tellurium or Selenium Ligands - Syntheses and Characterisation of (η⁵-C₅Me₅)Ru(μ₂-RTeTeR)(μ₂-TeR)₂Ru(η⁵-C₅Me₅) and [(η⁵-C₅Me₅)Ru(μ₂-SeR)₃Ru(η⁵-C₅Me₅)]Cl (R = Tol, Ph)
   H. Matsuzaka, T. Ogino, M. Nishio, M. Hidai, Y. Nishibayashi, and S. Uemura
   J. Chem. Soc., Chem. Commun., 223-224 (1994).

1993年

1. Asymmetric Selenoxide Elimination Leading to Chiral Allenic Sulfones
   N. Komatsu, T. Murakami, Y. Nishibayashi, T. Sugita, and S. Uemura
   J. Org. Chem., 58, 3697-3702 (1993).
2. Telluroxide Elimination by Oxidation of Alkyl Aryl Tellurides: Remarkable Effect of Added Triethylamine
   Y. Nishibayashi, N. Komatsu, K. Ohe, and S. Uemura
   J. Chem. Soc., Perkin Trans. 1, 1133-1138 (1993).
3. Asymmetric [2,3]Sigmatropic Rearrangement
   via Chiral Selenoxide with Sharpless Oxidants
   N. Komatsu, Y. Nishibayashi, and S. Uemura
   Tetrahedron Lett., 34, 2339-2342 (1993).

1992年

1. Catalytic Asymmetric Oxidation of Sulfides to Sulfoxides Using R-(+)-Binaphthol
   N. Komatsu, Y. Nishibayashi, T. Sugita, and S. Uemura
   Tetrahedron Lett., 33, 5391-5394 (1992).
2. The First Example of Asymmetric Selenoxide Elimination: Application to the Synthesis of Chiral Allenes
   N. Komatsu, Y. Nishibayashi, T. Sugita, and S. Uemura
   J. Chem. Soc., Chem. Commun., 46-47 (1992).