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Publications 2000-2004

2004年

  1. Ruthenium- and Platinum-Catalyzed Sequential Reactions: Selective Synthesis of Fused Polycyclic Compounds from Propargylic Alcohols and Alkenes
    Y. Nishibayashi, M. Yoshikawa, Y. Inada, M. Hidai, and S. Uemura
    J. Am. Chem. Soc., 126, 16066-16072 (2004).
  2. Ruthenium-Catalyzed Allylation of Aromatic Compounds and Allylic Ether Formation
    G. Onodera, H. Imajima, M. Yamanashi, Y. Nishibayashi, M. Hidai, and S. Uemura
    Organometallics, 23, 5841-5848 (2004).
  3. Double Phosphinylation of Propargylic Alcohols: a Novel Synthetic Route to 1,2-Bis(diphenylphosphino)ethane Derivatives
    M. D. Milton, G. Onodera, Y. Nishibayashi, and S. Uemura
    Org. Lett., 6, 3993-3995 (2004).
  4. Ruthenium- and Gold-Catalysed Sequential Reactions: a Straightforward Synthesis of Substituted Oxazoles from Propargylic Alcohols and Amides
    M. D. Milton, Y. Inada, Y. Nishibayashi, and S.Uemura
    Chem. Commun., 2712-2713 (2004).
  5. Preparation of Alkanechalcogenolate- and Benzenechalcogenolate-Bridged Diruthenium Complexes and Their Catalytic Activities toward Propargylation of Acetone with Propargylic Alcohols
    Y. Nishibayashi, H. Imajima, G. Onodera, Y. Inada, M. Hidai, and S. Uemura
    Organometallics, 23, 5100-5103 (2004).
  6. Stereospecific Carbon-Carbon Bond Formation by the Reaction of a Chiral Episelenonium Ion with Aromatic Compounds
    K. Okamoto, Y. Nishibayashi, S. Uemura, and A. Toshimitsu
    Tetrahedron Lett., 45, 6137-6139 (2004).
  7. A Non-metal System for Nitrogen Fixation
    Y. Nishibayashi, M. Saito, S. Uemura, S. Takekuma, H. Takekuma, and Z. Yoshida
    Nature, 428, 279-280 (2004).
  8. Synthesis of Dinuclear Complexes Bearing Metalloporphyrin-Phosphine Hybrid Ligand and Their Catalytic Activity toward Hydrosilylation of Ketones
    M. Saito, Y. Nishibayashi, and S. Uemura
    Organometallics, 23, 4012-4017 (2004).
  9. Ruthenium-Catalyzed Cycloaddition between Propargylic Alcohols and Cyclic 1,3-Dicarbonyl Compounds via Allenylidene Intermediates
    Y. Nishibayashi, M. Yoshikawa, Y. Inada, M. Hidai, and S. Uemura
    J. Org. Chem., 69, 3408-3412 (2004).
  10. Preparation of a Series of Chalcogenolate-Bridged Diruthenium Complexes and their Catalytic Activities toward the Propargylic Substitution Reactions
    Y. Nishibayashi, H. Imajima, G. Onodera, M. Hidai, and S. Uemura
    Organometallics, 23, 26-30 (2004).
  11. カルコゲン元素架橋二核ルテニウム錯体を触媒とする有機合成反応
    西林仁昭,植村 榮,干鯛眞信
    Organic Square, 13, 1-3 (2004).

2003年

  1. Novel Catalytic Hydrogenolysis of Silyl Enol Ethers by the Use of Acidic Ruthenium Dihydrogen Complexes
    I. Takei, Y. Nishibayashi, Y. Ishii, Y. Mizobe, S. Uemura, and M. Hidai
    J. Organomet. Chem., 679, 32-42 (2003).
  2. Oxidative Kinetic Resolution of Racemic Alcohols Catalyzed by Chiral Ferrocenyloxazolinylphosphine-Ruthenium Complexes
    Y. Nishibayashi, A. Yamauchi, G. Onodera, and S. Uemura
    J. Org. Chem., 68, 5875 (2003).
  3. Novel Ruthenium- and Platinum-Catalyzed Sequential Reactions: Synthesis of Tri- and Tetra-Substituted Furans and Pyrroles from Propargylic Alcohols and Ketones
    Y. Nishibayashi, M. Yoshikawa, Y. Inada, M. D. Milton, M. Hidai, and S. Uemura
    Angew. Chem. Int. Ed., 42, 2681-2684 (2003).[Selected as VIP (Very Important Paper)] [Highlighted at Cover Picture]
  4. Ruthenium-Catalyzed Carbon-Carbon Bond Formation between Propargylic Alcohols and Alkenes via the Allenylidene -Ene Reaction
    Y. Nishibayashi, Y. Inada, M. Hidai, and S. Uemura
    J. Am. Chem. Soc., 125, 6060-6061 (2003).
  5. Propargylation of Aromatic Compounds with Propargylic Alcohols Catalyzed by Cationic Diruthenium Complex
    Y. Nishibayashi, Y. Inada, M. Yoshikawa, M. Hidai, and S. Uemura
    Angew. Chem. Int. Ed., 42, 1495-1498 (2003).
  6. Synthesis of Diruthenium Complexes Containing Chiral Thiolate-bridged Ligands and Their Application to Catalytic Propargylic Alkylation of Propargylic Alcohols with Acetone
    Y. Nishibayashi, G. Onodera, Y. Inada, M. Hidai, and S. Uemura
    Organometallics, 22, 873-876 (2003).
  7. Kinetic Resolution of Racemic Ferrocenylphosphine Compounds by Enantioselective Oxidation Using Cyclic Selenoxides Having a Chiral Ligand
    Y. Miyake, A. Yamauchi, Y. Nishibayashi, and S. Uemura
    Bull. Chem. Soc. Jpn., 76, 381-387 (2003).
  8. 新規N,P-不斉配位子(FOXAP)の開発と不斉合成反応への応用
    西林仁昭,植村 榮
    Organic Square, 11, 1-3 (2003).
  9. オレフィンメタセシスによる大環状高分子化合物の合成
    西林仁昭
    Organometallic News, 110 (2003).

2002年

  1. Ruthenium-Catalyzed Propargylic Substitution Reaction of Propargylic Alcohols with Thiols: A General Synthetic Route to Propargylic Sulfides
    Y. Inada, Y. Nishibayashi, M. Hidai, and S. Uemura
    J. Am. Chem. Soc., 124, 15172-15173 (2002).
  2. Ruthenium-Catalyzed Propargylation of Aromatic Compounds with Propargylic Alcohols
    Y. Nishibayashi, M. Yoshikawa, Y. Inada, M. Hidai, and S. Uemura
    J. Am. Chem. Soc., 124, 11846-11847 (2002).
  3. Ruthenium-Catalyzed Cycloaddition of Propargylic Alcohols with Phenol Derivatives via Allenylidene Intermediates: Catalytic Use of the Allenylidene Ligand as C3 Unit
    Y. Nishibayashi, Y. Inada, M. Hidai, and S. Uemura
    J. Am. Chem. Soc., 124, 7900-7901 (2002).
  4. Asymmetric Baeyer-Villiger Oxidation of Cyclic Ketones Using Chiral Organoselenium Catalysts
    Y. Miyake, Y. Nishibayashi, and S. Uemura
    Bull. Chem. Soc. Jpn., 75, 2233-2237 (2002).
  5. Palladium(II) Complex-Catalysed Enantioselective Benzoylation of Alcohols Using Carbon Monoxide and Organobismuth(V) Compounds
    T. Iwata, Y. Miyake, Y. Nishibayashi, and S. Uemura
    J. Chem. Soc., Perkin Trans. 1, 2002, 1548-1554.
  6. Asymmetric Synthesis of Epoxides from Aromatic Aldehydes and Benzyl Halides Catalyzed by C2 Symmetric Optically Active Sulfides Having a Binaphthyl Skeleton
    Y. Miyake, A. Oyamada, Y. Nishibayashi, and S. Uemura
    Heteroatom Chem., 13, 270-275 (2002).
  7. Kinetic Resolution of Racemic Ferrocenylphosphine Compounds Using Optically Active Cyclic Selenoxides as Oxidants
    Y. Miyake, A. Yamauchi, Y. Nishibayashi, and S. Uemura
    Phosphorus, Sulfur, and Silicon, 177, 2107-2108 (2002).

2001年

  1. Ruthenium-Catalysed Asymmetric Hydrosilylation of Ketoximes Using Chiral Oxazolinylferrocenylphosphines,
    I. Takei, Y. Nishibayashi, Y. Ishii, Y. Mizobe, S. Uemura, and M. Hidai
    Chem. Commun., 2360-2361 (2001).
  2. Ruthenium-Catalyzed Propargylic Alkylation of Propargylic Alcohols with Ketones: Straightforward Synthesis of γ-Keto Acetylenes
    Y. Nishibayashi, I. Wakiji, Y. Ishiii, S. Uemura, and M. Hidai
    J. Am. Chem. Soc., 123, 3393-3394 (2001).
  3. Protonation of Coordinated N2 on Tungsten with H2 Mediated by Sulfido-bridged Dinuclear Molybdenum Complexes
    Y. Nishibayashi, I. Wakiji, K. Hirata, M. Rakowski DuBois, and M. Hidai
    Inorg. Chem., 40, 578-590 (2001).
  4. Kinetic Resolution of Secondary Alcohols via Chiral Pd(II)-Complex-Catalysed Enantioselective Benzoylation using CO and Organobismuth(V) Compound
    Y. Miyake, T. Iwata, K.-G. Chung, Y. Nishibayashi, and S. Uemura
    Chem. Commun. 2001, 2584-2585.
  5. Heterolytic Cleavage of Dihydrogen by Ruthenium and Molybdenum Complexes to Protonate Coordinated Dinitrogen and Cleave Si-O Bond
    M. Hidai and Y. Nishibayashi
    Recent Advances in Hydrides Chemistry; Ed. R. Poli, Elsevier Science, 117-138 (2001).

2000年

  1. Novel Propargylic Substitution Reactions Catalyzed by Thiolate-Bridged Diruthenium Complexes via Allenylidene Intermediates
    Y. Nishibayashi, I Wakiji, and M. Hidai
    J. Am. Chem. Soc., 122, 11019-11020 (2000).
  2. Formation of Ammonia in the Reactions of a Tungsten Dinitrogen with Ruthenium Dihydrogen Complexes under Mild Reaction Conditions
    Y. Nishibayashi, S. Takemoto, S. Iwai, and M. Hidai
    Inorg. Chem., 39, 5946-5957 (2000).
  3. Synthesis and Structures of 1,1'-Ferrocenedithiolato-Bridged Di- and Trinuclear Ruthenium Complexes
    S. Takemoto, S. Kuwata, Y. Nishibayashi, and M. Hidai
    Organometallics, 19, 3249-3252 (2000).
  4. Cyclization of Terminal Diynes Catalyzed by Thiolate-bridged Diruthenium Complexes: A Simple Synthetic Route to
    Endo-Macrocyclic (Z)-1-En-3-ynes
    Y. Nishibayashi, M. Yamanashi, I. Wakiji, and M. Hidai
    Angew. Chem. Int. Ed., 39, 2909-2911 (2000).
  5. 「化学のフロンティア2000」21世紀を担う次世代の空中窒素固定法の開発 ―温和な条件下での窒素と水素からのアンモニア合成―
    西林仁昭
    化学と工業,53, 131-135 (2000).
  6. Selenium Compounds as Ligands and Catalysts
    Y. Nishibayashi and S. Uemura
    Topics of Current Chemistry, 208: Organoselenium Chemistry, Modern Developments in Organic Synthesis; Ed. T. Wirth, Springer-Verlag, Berlin, 235-255 (2000).
  7. Selenoxide Elimination and [2,3]Sigmatropic Rearrangement
    Y. Nishibayashi and S. Uemura
    Topics of Current Chemistry, 208: Organoselenium Chemistry, Modern Developments in Organic Synthesis; Ed. T. Wirth, Springer-Verlag, Berlin, 201-233 (2000).


Molybdenum-catalyzed ammonia production with samarium diiodide and alcohols or water
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Nishibayashi Lab.

Department of Applied Chemistry
School of Engineering
The University of Tokyo
7-3-1 Hongo, Bunkyo-ku, Tokyo 113-8656, Japan
TEL : +81-3-5841-7708
FAX : +81-3-5841-1175
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Department of Systems Innovation Department of System Innovation, Faculity of Engineering, The University of Tokyo The University of Tokyo

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