発表論文(List of Publications) 学会発表はこちら
2016年
- Catalytic Transformation of Dinitrogen into Ammonia and Hydrazine by Iron-Dinitrogen Complexes Bearing Pincer Ligand
S. Kuriyama, K. Arashiba, K. Nakajima, Y. Matsuo, H. Tanaka, K. Ishii, K. Yoshizawa, and Y. Nishibayashi
Nature Communications, 7, 12181 (2016).
- Construction of Chiral Tri- and Tetra-arylmethanes Bearing Quaternary Carbon by Using Copper-Catalyzed Enantioselective Propargylation of Indoles with Propargylic Esters
K. Tsuchida, Y. Senda, K. Nakajima, and Y. Nishibayashi
Angew. Chem. Int. Ed., 55, in press (2016).
- Visible Light-Mediated Aromatic Substitution Reactions of Cyanoarenes with 4-Alkyl-1,4-dihydropyridines via Dual Carbon-Carbon Bonds Cleavage
K. Nakajima, S. Nojima, K. Sakata, and Y. Nishibayashi
ChemCatChem, 8, 1028-1032 (2016). [Highlighted at Cover Picture] [Cover Profile]
- Interplay between Theory and Experiment for Ammonia Synthesis Catalyzed by Transition Metal Complexes
H. Tanaka, Y. Nishibayashi, and K. Yoshizawa
Acc. Chem. Res., 49, 987-995 (2016).
- Catalytic Dinitrogen Fixation to Form Ammonia at Ambient Reaction Conditions Using Transition Metal-Dinitrogen Complexes
Y. Tanabe and Y. Nishibayashi
Chemical Record, 16, 1549-1577 (2016).
- 「東京大学工学教程 無機化学U(錯体化学)」 (分担)
石井和之、北條博彦、西林仁昭
丸善出版 (2016予定).
- 常温常圧下での触媒的窒素固定法開発の最近の進展
田邊資明、西林仁昭
日本エネルギー学会誌, 5月号, 95, 371-381 (2016).
- 特集にあたって-ハーバー・ボッシュ法を超えるアンモニア合成法開発への挑戦-
西林仁昭
ファインケミカル, 3月号, 45, 5-6 (2016).
- 遷移金属錯体を触媒として利用した触媒的アンモニア合成法の開発
田邊資明、西林仁昭
ファインケミカル, 3月号, 45, 7-18 (2016). [Hydrogen Energy Sciety, 3, 12-23 (2016)]
- 非白金分子触媒による触媒的水素酸化反応の開発
結城雅弘、西林仁昭
ENEOS Technical Review, 58, No.1, 12-18 (2016).
- 有機分子触媒と遷移金属触媒とを協奏的に利用した分子変換反応
三宅由寛、中島一成、西林仁昭
有機分子触媒の最前線 (日本化学会 Current Review), 000-000 (2016).
- 「ウェイド 有機化学 原書7版」 問題の解き方 (分担)
中村浩之、岩本武明、斎藤慎一、柴田高範、田中健、長澤和夫、西林仁昭
丸善出版 (2016).
- 温和な反応条件下での触媒的窒素固定法に関する最近の進展
荒芝和也、西林仁昭
化学工業, 67, No.1, 1-5 (2016).
2015年
- Recent Progress in Transition Metal-Catalyzed Reduction of Molecular Dinitrogen under Ambient Reaction Conditions
Y. Nishibayashi
Inorg. Chem. (forum article for special issue), 54, 9234-9247 (2015).
- Nitrogen Fixation Catalyzed by Ferrocene-Substituted Dinitrogen-Bridged Dimolybdenum-Dinitrogen Complexes: Unique Behavior of Ferrocene Moiety as Redox Active Site
S. Kuriyama, K. Arashiba, K. Nakajima, H. Tanaka, K. Yoshizawa, and Y. Nishibayashi
Chem. Sci., 6, 3940-3951 (2015).
- Synthesis of Phosphabenzenes by Iron-Catalyzed [2+2+2] Cycloaddition Reaction of Diynes with Phosphaalkynes
K. Nakajima, S. Takata, K. Sakata, and Y. Nishibayashi
Angew. Chem. Int. Ed., 54, 7597-7601 (2015).
- Catalytic Reduction of Dinitrogen into Ammonia by Use of Molybdenum-Nitride Complexes Bearing Tridentate Triphosphine as Catalysts
K. Arashiba, E. Kinoshita, S. Kuriyama, A. Eizawa, K. Nakajima, H. Tanaka, K. Yoshizawa, and Y. Nishibayashi
J. Am. Chem. Soc., 137, 5666-5669 (2015). [Highlighted at ChemistryViews]
- Cobalt-Catalyzed Transformation of Molecular Dinitrogen into Silylamine under Ambient Reaction Conditions
R. Imayoshi, H. Tanaka, Y. Matsuo, M. Yuki, K. Nakajima, K. Yoshizawa, and Y. Nishibayashi
Chemistry-A European Journal, 21, 8905-8909 (2015).
- Thiolate-Bridged Dinuclear Ruthenium- and Iron-Complexex as Robust and Efficient Catalysts toward Oxidation of Molecular Dihydrogen in Protic Solvents
M. Yuki, K. Sakata, Y. Hirao, N. Nonoyama, K. Nakajima, and Y. Nishibayashi
J. Am. Chem. Soc., 137, 4173-4182 (2015).
- Copper-Catalyzed Enantioselective Etherification of Propargylic Esters with Alcohols
K. Nakajima, M. Shibata, and Y. Nishibayashi
J. Am. Chem. Soc., 137, 2472-2475 (2015). [Highlighted in Synfacts, 2015, 5]
- Synthesis and Catalytic Activity of Molybdenum-Nitride Complexes Bearing Pincer Ligands
E. Kinoshita, K. Arashiba, S. Kuriyama, A. Eizawa, K. Nakajima, and Y. Nishibayashi
Eur. J. Inorg. Chem., 1789-1794 (2015).
- Radical Addition to Corannulene Mediated by Visible Light-Photoredox Catalysts
K. Nakajima, Y. Ashida, S. Nojima, and Y. Nishibayashi
Chem. Lett., 44, 545-547 (2015).
- Cooperative Catalytic Reactions: Enantioselective Propargylic Alkylation of Propargylic Alcohols with Enecarbamates Using Ruthenium and Phosphoramide Hybrid Catalysts
Y. Senda, K. Nakajima, and Y. Nishibayashi
Angew. Chem. Int. Ed., 54, 4060-4064 (2015). [Highlighted in Synfacts, 2015, 5]
- Synthesis and Reactivity of Molybdenum-Dinitrogen Complexes Bearing PNN-Type Pincer Ligand
K. Arashiba, K. Nakajima, and Y. Nishibayashi
Z. Anorg. Allg. Chem. (invitation for special issue), 641, 100-104 (2015).
- 白金触媒に匹敵するアノード分子触媒の開発
結城雅弘、西林仁昭
エネルギーデバイス, 2, No.7, 92-96 (2015).
- 常温常圧でのアンモニアの合成
田邊資明、西林仁昭
アンモニアを用いた水素利用システム, 87-101 (2015).
- Molybdenum-Catalyzed Reduction of Molecular Dinitrogen under Ambient Reaction Conditions
Y. Nishibayashi
Comptes rendus Chimie (invitation for special issue),18, 776-784 (2015).
- 温和な反応条件下での遷移金属窒素錯体を分子触媒として用いた窒素分子からのアンモニア合成反応の開発
西林仁昭
触媒, 57, 33-38 (2015).
2014年
- Synthesis and Reactivity of Ruthenium Complexes Bearing Arsenic-Containing ANA-Type Pincer Ligand
Y. Tanabe, S. Kuriyama, K. Arashiba, K. Nakajima, and Y. Nishibayashi
Organometallics 33, 5295-5300 (2014).
- Cleavage and Formation of Molecular Dinitrogen in a Single System Assisted by Molybdenum Complexes Bearing Ferrocenyldiphosphine
T. Miyazaki, H. Tanaka, Y. Tanabe, M. Yuki, K. Nakajima, K. Yoshizawa, and Y. Nishibayashi
Angew. Chem. Int. Ed., 53, 11488-11492 (2014). [Highlighted in Angew. Chem.]
- Synthesis of Nitrogen Heterocycles via a-Aminoalkyl Radicals Generated from a-Silyl Secondary-Amines under Visible Light Irradiation
K. Nakajima, M. Kitagawa, Y. Ashida, Y. Miyake, and Y. Nishibayashi
Chem. Commun., 50, 8900-8903 (2014).
- Copper-Catalyzed Nucleophilic Trifluoromethylation of Benzylic Chlorides
Y. Miyake, S. Ota, M. Shibata, K. Nakajima, and Y. Nishibayashi
Org. Biomol. Chem., 12, 5594-5596 (2014).
- Catalytic Formation of Ammonia from Molecular Dinitrogen by Use of Dinitrogen-Bridged Dimolybdenum-Dinitrogen Complexes Bearing PNP-Pincer Ligands: Remarkable Effect of Substituent at PNP-Pincer Ligand
S. Kuriyama, K. Arashiba, K. Nakajima, H. Tanaka, N. Kamaru, K. Yoshizawa, and Y. Nishibayashi
J. Am. Chem. Soc., 136, 9719-9731 (2014).
- Synthesis and Redox Properties of PNP Pincer Complexes Based on N-Methyl-4,4'-Bipyridinium
Y. Miyake, K. Nakajima, Y. Higuchi, and Y. Nishibayashi
Eur. J. Inorg. Chem., 4273-4280 (2014). [Highlighted at Cover Picture] [Cover Profile]
- Enantioselective Intramolecular Propargylic Amination Using Chiral Copper-Pybox Catalyst
M. Shibata, K. Nakajima, and Y. Nishibayashi
Chem. Commun., 50, 7874-7877 (2014). [Highlighted in Synfacts, 2014, 10]
- Unique Behavior of Dinitrogen-Bridged Dimolybdenum Complexes Bearing Pincer Ligand towards Catalytic Formation of Ammonia
H. Tanaka, K. Arashiba, S. Kuriyama, A. Sasada, K. Nakajima, K. Yoshizawa, and Y. Nishibayashi
Nature Communications, 5, 3737 (2014).
- Visible Light-Mediated Addition of a-Aminoalkyl Radicals to [60]Fullerene Using Photoredox Catalysts
Y. Miyake, Y. Ashida, K. Nakajima, and Y. Nishibayashi
Chemistry-A European Journal, 20, 6120-6126 (2014).
- ウェイド 有機化学 原書7版 上巻・下巻 (分担)
中村浩之、岩本武明、斎藤慎一、柴田高範、田中健、長澤和夫、西林仁昭
丸善出版 (2014).
- 遷移金属窒素錯体を用いた触媒的窒素固定反応に関する最近の進展
西林仁昭、荒芝和也、結城雅弘
有機合成化学協会誌, 72, 529-537 (2014).
- 常温常圧下での触媒的アンモニア合成反応開発の現状と将来展望
田邊資明、西林仁昭
日本エネルギー学会誌, 5月号, 386-392 (2014).
2013年
- Preparation and Reactivity of Dinitrogen-Bridged Dimolybdenum Tetrachloride Complex
K. Arashiba, S. Kuriyama, K. Nakajima, and Y. Nishibayashi
Chem. Commun., 49, 11215-11217 (2013).
- Preparation and Reactivity of Molybdenum-Dinitrogen Complexes Bearing Arsenic-Containing ANA-Type Pincer Ligand
Y. Tanabe, S. Kuriyama, K. Arashiba, Y. Miyake, K. Nakajima, and Y. Nishibayashi
Chem. Commun., 49, 9290-9292 (2013).
- Design and Preparation of Molybdenum-Dinitrogen Complexes Bearing Ferrocenyldiphosphine and Pentamethylcyclopentadienyl Moieties as Auxiliary Ligands
T. Miyazaki, Y. Tanabe, M. Yuki, Y. Miyake, K. Nakajima, and Y. Nishibayashi
Chemistry-A European Journal, 19, 11874-11877 (2013).
- Copper-Catalyzed Nucleophilic Trifluoromethylation of Propargylic Halides
Y. Miyake, S. Ota, M. Shibata, K. Nakajima, and Y. Nishibayashi
Chem. Commun., 49, 7809-7811 (2013).
- Visible Light-Mediated Oxidative Decarboxylation of Arylacetic Acids into Benzyl Radicals: Addition to Electron-Deficient Alkenes by Using Photoredox Catalysts
Y. Miyake, K. Nakajima, and Y. Nishibayashi
Chem. Commun., 49, 7854-7856 (2013).
- Synthesis, Structure, and Reactivity of Group VI Metal Complexes Bearing Group IV Metallocenyldiphosphine Moieties and Pentamethylcyclopentadienyl Ligand
T. Miyazaki, Y. Tanabe, M. Yuki, Y. Miyake, and Y. Nishibayashi
Organometallics 32, 2007-2013 (2013).
- Ruthenium-Triggered Ring-Opening of Ethynylcyclopropanes Leading to [3+2] Cycloaddition with Aldehydes and Aldimines via Metal-Allenylidene Intermediates
Y. Miyake, S. Endo, T. Moriyama, K. Sakata, and Y. Nishibayashi
Angew. Chem. Int. Ed., 52, 1758-1762 (2013). [Highlighted in Synfacts, 2013, 05]
- 遷移金属窒素錯体を用いた触媒的アンモニア合成法の最近の進展と今後の展望
西林仁昭
錯体化学会誌(Bull. Jpn. Soc. Coord. Chem.), 62, 21-25 (2013).
- Developing More Sustainable Processes for Ammonia Synthesis
Y. Tanabe and Y. Nishibayashi
Coord. Chem. Rev. (invitation), 257, 2551-2564 (2013).
- 穏和な条件下での触媒的アンモニア合成の開発を目指して
田邊資明、西林仁昭
ファインケミカル, 7月号, 42-48 (2013).
- 鉄錯体は「窒素固定能」を秘めていた!-常温常圧の窒素ガスからのアンモニア変換に光明
西林仁昭
化学, 6月号, 37-42 (2013).
- Cycloaromatization via Transition Metal-Comulenylidenes
Y. Nishibayashi
Transition-Metal-Mediated Aromatic Ring Construction;; Ed. K. Tanaka, WILEY-VCH, 547-567 (2013).
2012年
- Iron-Catalysed Transformation of Molecular Dinitrogen into Silylamine under Ambient Conditions
M. Yuki, H. Tanaka, K. Sasaki, Y. Miyake, K. Yoshizawa, and Y. Nishibayashi
Nature Communications, 3, 1254 (2012).
- Synthesis and Catalytic Activity of Molybdenum-Dinitrogen Complexes Bearing Unsymmetric PNP-Type Pincer Ligands
E. Kinoshita, K. Arashiba, S. Kuriyama, Y. Miyake, R. Shimazaki, H. Nakanishi, and Y. Nishibayashi
Organometallics 31, 8437-8443 (2012).
- Direct sp3 C-H Amination of Nitrogen-Containing Benzoheterocycles Mediated by Visible-Light-Photoredox Catalysis
Y. Miyake, K. Nakajima, and Y. Nishibayashi
Chemistry-A European Journal, 18, 16473-16477 (2012).
- Copper-Catalyzed Nucleophilic Trifluoromethylation of Allylic Halides
Y. Miyake, S. Ota, and Y. Nishibayashi
Chemistry-A European Journal, 18, 13255-13258 (2012).
- Enantioselective Alkylation of b-Keto Phosphonates by Direct Use of Diaryl Methanols as Electrophiles
M. Shibata, M. Ikeda, K. Motoyama, Y. Miyake, and Y. Nishibayashi
Chem. Commun., 48, 9528-9530 (2012).
- Visible Light Mediated Addition of a-Aminoalkyl Radicals Generated from a-Silylamine to a,b-Unsaturated Carbonyl Compounds
Y. Miyake, Y. Ashida, K. Nakajima, and Y. Nishibayashi
Chem. Commun., 48, 6966-6968 (2012).
- Cooperative Catalytic Reactions Using Organocatalysts and Transition Metal Catalysts: Enantioselective Propargylic Allylation of Propargylic Alcohols with a,b-Unsaturated Aldehydes
M. Ikeda, Y. Miyake, and Y. Nishibayashi
Organometallics, 31, 3810-3813 (2012).
- Synthesis of Sulfur- and Nitrogen-Bridged Diiron Complexes and Catalytic Behavior toward Hydrazines
M. Yuki, Y. Miyake, and Y. Nishibayashi
Organometallics, 31, 2953-2956 (2012).
- Ruthenium- and Copper-Catalyzed Enantioseletive Propargylic Alkylation of Propargylic Alcohols with b-Keto Phosphonates
K. Motoyama, M. Ikeda, Y. Miyake, and Y. Nishibayashi
Organometallics, 31, 3426-3430 (2012).
- Synthesis and Reactivity of Hybrid Phophido- and Hydrosulfido-Bridged Diruthenium Complex: Transformations into Diruthenium and Tetraruthenium Complexes Bridged by Phosphido and Sulfido Ligands
Y. Miyake, T. Moriyama, Y. Tanabe, S. Endo, and Y. Nishibayashi
Organometallics, 31, 3292-3299 (2012).
- Synthesis and Protonation of Molybdenum- and Tungsten-Dinitrogen Complexes Bearing PNP-type Pincer Ligands
K. Arashiba, K. Sasaki, S. Kuriyama, Y. Miyake, H. Nakanishi, and Y. Nishibayashi
Organometallics, 31, 2035-2041 (2012).
- Visible Light Mediated Utilization of a-Aminoalkyl Radicals: Addition to Electron Deficient Alkenes Using Photoredox Catalysts
Y. Miyake, K. Nakajima, and Y. Nishibayashi
J. Am. Chem. Soc., 134, 3338-3341 (2012).
- Cooperative Catalytic Reactions Using Distinct Metal Catalysts: Ruthenium- and Copper-Catalyzed Enantioselective Propargylic Alkylation
M. Ikeda, Y. Miyake, and Y. Nishibayashi
Chemistry-A European Journal, 18, 3321-3328 (2012).
- Molybdenum-Catalyzed Reduction of Molecular Dinitrogen under Mild Reaction Conditions
Y. Nishibayashi
Dalton Transactions (Perspective, invitation), 41, 7447-7453 (2012). [Highlighted at Cover Picture]
- Transition Metal-Catalyzed Enantioselective Propargylic Substitution Reactions of Propargylic Alcohol Derivatives with Nucleophiles
Y. Nishibayashi
Synthesis (Review, invitation), 44, 489-503 (2012).
- Selenoxide Elimination and [2,3]-Sigmatropic Rearrangement
Y. Nishibayashi and S. Uemura
Organoselenium Chemistry-Synthesis and Reactions; Ed. T. Wirth, WILEY-VCH, 287-320 (2012).
- (S,S)-FOXAP; Ferrocene, 1-[(4S)-4,5-dihydro-4-(1-methylethyl)-2-oxazolyl]-2-(diphenylphosphino)-, (2R)-
Y. Nishibayashi
Electronic Encyclopedia of Reagents for Organic Synthesis, RN01404 (2012).
2011年
- Remarkable Effect of Valence Electrons in Thiolato-Bridged Diruthenium Complexes toward Catalytic Dimerization of a-Methylstyrenes
Y. Miyake, T. Moriyama, Y. Tanabe, G. Onodera, and Y. Nishibayashi
Organometallics, 30, 5972-5977 (2011).
- Propargylic Substitution Reaction Catalyzed by Group IV (Ti, Zr, Hf)-Ru Heterobimetallic Complexes
T. Miyazaki, Y. Tanabe, M. Yuki, Y. Miyake, and Y. Nishibayashi
Organometallics, 30, 3194-3199 (2011).
- Copper-Catalyzed Enantioselective Propargylic Amination of Non-Aromatic Propargylic Esters with Amines
A. Yoshida, G. Hattori, Y. Miyake, and Y. Nishibayashi
Org. Lett., 13, 2460-2463 (2011). [Highlighted in Synfacts, 2011, 08]
- Synthesis of Group IV (Zr, Hf)-Group VIII (Fe, Ru) Heterobimetallic Complexes Bearing Metallocenyl Diphosphine Moieties and their Application to Catalytic Dehydrogenation of Amine-Boranes
T. Miyazaki, Y. Tanabe, M. Yuki, Y. Miyake, and Y. Nishibayashi
Organometallics, 30, 2394-2404 (2011).
- Cooperative Catalytic Reactions Using Lewis Acid Catalysts and Organocatalysts: Enantioselective Propargylic Alkylation of Propargylic Alcohols Bearing Internal Alkyne with Aldehydes
K. Motoyama, M. Ikeda, Y. Miyake, and Y. Nishibayashi
Eur. J. Org. Chem., 2239-2246 (2011). [Highlighted at Cover Picture] [Spotlighted in Angew. Chem.]
- Molybdenum-Catalyzed Transformation of Molecular Dinitrogen into Silylamine: Experimental and DFT Study on Remarkable Role of Ferrocenyldiphosphine Ligands
H. Tanaka, A. Sasada, T. Kouno, M. Yuki, Y. Miyake, H. Nakanishi, Y. Nishibayashi, and K. Yoshizawa
J. Am. Chem. Soc., 133, 3498-3506 (2011).
- Cooperative Catalytic Reactions Using Organocatalysts and Transition Metal Catalysts: Enantioselective Propargylic Alkylation of Propargylic Esters with Aldehydes
A. Yoshida, M. Ikeda, G. Hattori, Y. Miyake, and Y. Nishibayashi
Org. Lett., 13, 592-595 (2011).
- A Molybdenum Complex Bearing PNP-Type Pincer Ligands Leads to the Catalytic Reduction of Dinitrogen into Ammonia
K. Arashiba, Y. Miyake, and Y. Nishibayashi
Nature Chemistry, 3, 120-125 (2011). [Highlight at news & views in Nature Chem. 3, 95-96 (2011) by R. R. Schrock]
- 銅-アセチリド錯体を鍵中間体として経由する触媒反応の最近の進展
服部 岳、三宅由寛、西林仁昭
有機合成化学協会誌, 69, 1086-1098 (2011).
- Nitrogen Fixation: Nitrido Complexes Step up
Y. Nishibayashi
Nature Chemistry, 3, 502-504 (2011).
- Haber-Bosch法を超えるアンモニア合成
西林仁昭
化学, 7月号, 18-22 (2011).
- 窒素分子の活性化に基づく窒素固定法の開発
西林仁昭
不活性結合・不活性分子の活性化 (日本化学会 Current Review), 125-137 (2011).
- 窒素固定酵素ニトロゲナーゼに学ぶ次世代型窒素固定法の開発
西林仁昭
岩谷直治記念財団研究報告書, 34, 39-41 (2011).
2010年
- Preparation of Thiolate-Bridged Dinuclear Ruthenium Complexes Bearing a Phosphine Ligand and Application to Propargylic Reduction of Propargylic Alcohols with 2-Propanol
M. Yuki, Y. Miyake, and Y. Nishibayashi
Organometallics, 29, 5994-6001 (2010).
- Preparation and Reactivity of a Ruthenium Complex Bearing a 2,6-Bis(trimethylsilyl)benzenethiolate Ligand
M. Yuki, Y. Miyake, and Y. Nishibayashi
Organometallics, 29, 4148-4153 (2010).
- Copper-Catalyzed Enantioselective Propargylic Amination of Propargylic Esters with Amines: Copper-Allenylidene Complexes as Key Intermediates
G. Hattori, K. Sakata, H. Matsuzawa, Y. Tanabe, Y. Miyake, and Y. Nishibayashi
J. Am. Chem. Soc., 132, 10592-10608 (2010).
- Cooperative Catalytic Reactions Using Organocatalysts and Transition Metal Catalysts: Enantioselective Propargylic Alkylation of Propargylic Alcohols with Aldehydes
M. Ikeda, Y. Miyake, and Y. Nishibayashi
Angew. Chem. Int. Ed., 49, 7289-7293 (2010). [Selected as Hot Paper] [Highlighted at Cover Picture] [Highlighted in Synfacts, 2010, 12]
- Intramolecular Edge-to-Face Aromatic p-p Interaction in Optically Active Ruthenium-Allenylidene Complexes for Enantioselective Propargylic Substitution Reactions
K. Kanao, Y. Tanabe, Y. Miyake, and Y. Nishibayashi
Organometallics, 29, 2381-2384 (2010).
- Ruthenium-Catalyzed Enantioselective [3+3] Cycloaddition of Propargylic Alcohols with 2-Naphthols
K. Kanao, Y. Miyake, and Y. Nishibayashi
Organometallics, 29, 2126-2131 (2010).
- Copper-Catalyzed Diastereo- and Enantio-selective Sequential Reactions of Propargylic Acetates with (E)-2,4-Pentadienylamine
G. Hattori, Y. Miyake, and Y. Nishibayashi
ChemCatChem, 2, 155-158 (2010).
- 銅触媒による不斉プロパルギル位置換反応の開発
服部 岳、三宅由寛、西林仁昭
化学工業, 702-710 (2010).
- 窒素固定酵素ニトロゲナーゼに学ぶ次世代型窒素固定法の開発
西林仁昭
岩谷直治記念財団研究報告書, 33, 109-111 (2010).
2009年
- Synthesis and Protonolysis of Tungsten- and Molybdenum-Dinitrogen Complexes Bearing Bis(dialkylphosphinobenzene)chromiums as Auxiliary Ligands
M. Yuki, Y. Miyake, and Y. Nishibayashi
Organometallics, 28, 5821-5827 (2009).
- Design and Synthesis of Diphosphine Ligands Bearing Osmium(II) Bis(terpyridyl) Moiety as a Light Harvesting Unit: Application to Photocatalytic Production of Dihydrogen
Y. Miyake, K. Nakajima, K. Sasaki, R. Saito, H. Nakanishi, and Y. Nishibayashi
Organometallics, 28, 5240-5243 (2009).
- Synthesis and Protonolysis of Tungsten- and Molybdenum-Dinitrogen Complexes Bearing Ruthenocenyldiphosphines
M. Yuki, T. Midorikawa, Y. Miyake, and Y. Nishibayashi
Organometallics, 28, 4741-4746 (2009).
- Enantioselective Ring-Opening Reactions of Racemic Ethynyl Epoxides via Copper-Allenylidene Intermediates: Efficient Approach to Chiral b-Amino Alcohols
G. Hattori, A. Yoshida, Y. Miyake, and Y. Nishibayashi
J. Org. Chem., 74, 7603-7607 (2009). [Selected as Featured Article] [Highlighted at Cover Picture] [Highlighted in Synfacts, 2010, 01]
- Ruthenium-Catalyze Enantioselective Intramolecular Propargylation of Thiophenes with Propargylic Alcohols
K. Kanao, Y. Miyake, and Y. Nishibayashi
Organometallics, 28, 2920-2926 (2009).
- Catalytic Cycloisomerization of 1,5-Enynes to 1,3-Cyclohexadienes via Ruthenium-Vinylidene Intermediates
K. Fukamizu, Y. Miyake, and Y. Nishibayashi
Angew. Chem. Int. Ed., 48, 2534-2537 (2009). [Highlighted in Organic Chemistry Portal, 2009, 12]
- Remarkable Effect of Halogens on Catalytic Activities of Thiolate-Bridged Diruthenium Complexes in Propargylic Substitution Reactions
Y. Tanabe, K. Kanao, Y. Miyake, and Y. Nishibayashi
Organometallics, 28, 1138-1142 (2009).
- A DFT Study on the Reaction Pathway for Carbon-Carbon Bond Forming Reactions between Propargylic Alcohols and Alkenes or Ketones Catalyzed by Thiolate-Bridged Diruthenium Complexes
K. Sakata, Y. Miyake, and Y. Nishibayashi
Chem. Asian J., 4, 81-88 (2009).
- Ruthenium-Catalyzed Oxypropargylation of Alkenes
Y. Yamauchi, Y. Miyake, and Y. Nishibayashi
Organometallics, 28, 48-50 (2009).
- 未来を拓く次世代型窒素固定法の開発―エネルギーおよび環境問題を解決するアンモニア社会の実現に向けて―
西林仁昭
現代化学, 10月号, 28-34 (2009).
- Catalytic Propargylic Substitution Reactions
Y. Miyake, S. Uemura, and Y. Nishibayashi
ChemCatChem, 1, 342-356 (2009).
- アンモニアによるエネルギー問題の解決―ハーバー・ボッシュ法に代わる新しい窒素固定法の開発を目指して
田邊資明、三宅由寛、西林仁昭
配管技術, 11月号, 7-13 (2009).
- 硫黄架橋二核ルテニウム錯体を用いた触媒的プロパルギル位置換反応の開発
西林仁昭、三宅由寛
触媒, 51, 594-600 (2009).
- ルテニウム-アレニリデン錯体を鍵中間体として経由する新規触媒反応の開発
西林仁昭、三宅由寛、植村 榮
有機合成化学協会誌, 67, 437-450 (2009).
- 銅錯体を用いた触媒的不斉プロパルギル位置換反応の開発
西林仁昭
旭硝子財団助成研究成果報告書, 55 (2009).
- 穏和な反応条件下での触媒的窒素固定反応の開発
西林仁昭、三宅由寛、結城雅弘
マツダ財団研究報告書, 151-157 (2009).
2008年
- Synthesis and Reactivity of Hybrid Phosphido- and Thiolate-Bridged Diruthenium Complexes
Y. Miyake, S. Endo, M. Yuki, Y. Tanabe, and Y. Nishibayashi
Organometallics, 27, 6039-6042 (2008).
- Ruthenium-Catalyzed Enantioselective Propargylation of Indoles with Propargylic Alcohols
K. Kanao, H. Matsuzawa, Y. Miyake, and Y. Nishibayashi
Synthesis (PSP, invitation), 3869-3873 (2008).
- Ruthenium-Catalyzed Enantioselective Carbon-Carbon Bond Forming Reaction via Allenylidene-Ene Process: Synthetic Approach to Chiral Heterocycles such as Chromane, Thiochromane, and 1,2,3,4-Tetrahydroquinoline Derivatives
K. Fukamizu, Y. Miyake, and Y. Nishibayashi
J. Am. Chem. Soc., 130, 10498-10499 (2008). [Highlighted in Synfacts, 2008, 10]
- Synthesis of Optically Active N,N,N’,N’-Tetraphenyl-1,1’-binaphthyl-2,2’-diamine Derivatives as Analogues of BINAP
H. Matsuzawa, Y. Tanabe, Y. Miyake, and Y. Nishibayashi
Organometallics, 27, 4021-4024 (2008).
- Novel Monophosphido-Bridged Diruthenium Complexes: Efficient Preparative Method and Catalytic Activity toward Reactions of Propargylic Alcohols with Aromatic Compounds
Y. Miyake, S. Endo, Y. Nomaguchi, M. Yuki, and Y. Nishibayashi
Organometallics, 27, 4017-4020 (2008).
- Synthesis and Reactivity of Tungsten- and Molybdenum-Dinitrogen Complexes Bearing Ferrocenyldiphosphines
M. Yuki, Y. Miyake, Y. Nishibayashi, I. Wakiji, and M. Hidai
Organometallics, 27, 3947-3953 (2008).
- Ruthenium-Catalyzed Intramolecular Cyclization of 3-Butyne-1,2-diols into Furans
Y. Yada, Y. Miyake, and Y. Nishibayashi
Organometallics, 27, 3614-3617 (2008).
- Copper-Catalyzed Asymmetric Propargylic Substitution Reactions of Propargylic Acetates with Amines: A Novel Synthetic Approach to Chiral Propargylic Amines
G. Hattori, H. Matsuzawa, Y. Miyake, and Y. Nishibayashi
Angew. Chem. Int. Ed., 47, 3781-3783 (2008). [Highlighted in Angew. Chem.] [Highlighted in Synfacts, 2008, 07]
- Ruthenium-Catalyzed Dienyne Formation from Propargylic Alcohols and 1,3-Conjugated Dienes
M. Daini, M. Yoshikawa, Y. Inada, S. Uemura, K. Sakata, K. Kanao, Y. Miyake, and Y. Nishibayashi
Organometallics, 27, 2046-2051 (2008).
- Ruthenium-Catalyzed Vinylic Substitution Reactions with Nucleophiles via Butatrienylidene Intermediates
Y. Yamauchi, M. Yuki, Y. Tanabe, Y. Miyake, Y. Inada, S. Uemura, and Y. Nishibayashi
J. Am. Chem. Soc., 130, 2908-2909 (2008).
- Optically Active Chiral Ligands Ferrocenyloxazolinylphosphines (FOXAP): Development and Application to Catalytic Asymmetric Reactions
Y. Miyake, Y. Nishibayashi and S. Uemura
Synlett, 1747-1758 (2008).
- Allenylidene Complexes in Catalysis
Y. Nishibayashi, S. Uemura
Metal Vinylidenes and Allenylidenes in Catalysis; Eds. P. H. Dixneuf and C. Bruneau, WILEY-VCH, 217-250 (2008).
2007年
- Remarkable Effect of N-Substituent on Enantioselective Ruthenium-Catalyzed Propargylation of Indoles with Propargylic Alcohols
H. Matsuzawa, K. Kanao, Y. Miyake, and Y. Nishibayashi
Org. Lett., 9, 5561-5564 (2007). [Highlighted in Angew. Chem.] [Highlighted in Synfacts, 2008, 03]
- Design and Preparation of Chiral Ligand Based on a Pseudorotaxane Skeleton: Application to Rhodium-Catalyzed Enantioselective Hydrogenation of Enamides
G. Hattori, T. Hori, Y. Miyake, and Y. Nishibayashi
J. Am. Chem. Soc., 129, 12930-12931 (2007). [Highlighted in Synfacts, 2008, 01]
- Ruthenium-Catalyzed Enantioselective Propargylation of Aromatic Compounds with Propargylic Alcohols via Allenylidene Intermediates
H. Matsuzawa, Y. Miyake, and Y. Nishibayashi
Angew. Chem. Int. Ed., 46, 6488-6491 (2007). [Selected as VIP (Very Important Paper)] [Highlighted at Cover Picture] [Highlighted in Angew. Chem.] [Highlighted in Synfacts, 2007, 11]
- Synthesis and Reactivity of Diphosphine-Bridged Diruthenium Complexes
Y. Miyake, Y. Nomaguchi, M. Yuki, and Y. Nishibayashi
Organometallics, 26, 3611-3613 (2007).
- Ruthenium-Catalyzed Reactions of 1-Cyclopropyl-2-propyn-1-ols with Anilines and Water via Allenylidene Intermediates: Selective Preparation of Tri- and Tetrasubstituted Conjugated Enynes
Y. Yamauchi, G. Onodera, K. Sakata, M. Yuki, Y. Miyake, S. Uemura, and Y. Nishibayashi
J. Am. Chem. Soc., 129, 5175-5179 (2007).
- Ruthenium-Catalyzed Sequential Reactions: Deracemization of Secondary Benzylic Alcohols
Y. Shimada, Y. Miyake, H. Matsuzawa, and Y. Nishibayashi
Chem. Asian J., 2, 393-396 (2007).
- 二核ルテニウム錯体の特性を用いた新規触媒反応の開発―セレンディピティー的発見から阿吽の呼吸による協奏作用まで
西林仁昭
化学と工業,60, 1088-1091 (2007).
- 光学活性フェロセニルオキサゾリニルホスフィン(FOXAP)配位子の開発と触媒的不斉合成反応への応用
西林仁昭、三宅由寛、植村 榮
有機合成化学協会誌, 65, 761-771 (2007).
- C-C Bond Formation by Substitution Reaction: Substitution at Propargylic and Benzylic Positions
Y. Nishibayashi and S. Uemura
Comprehensive Organometallic Chemistry III; Eds. R. H. Crabtree and D. M. P. Mingos, Elsevier, Vol. 11; 75-122 (2007).
- C-C Bond Formation by Substitution Reaction: Allylic Alkylation
Y. Nishibayashi and S. Uemura
Comprehensive Organometallic Chemistry III; Eds. R. H. Crabtree and D. M. P. Mingos, Elsevier, Vol. 11; 123-150 (2007).
- 多核錯体が構築する特異な反応場の設計とその利用
西林仁昭
倉田奨励金研究報告, 70-71 (2007).
2006年
- Ruthenium-Catalyzed Propargylic Reduction of Propargylic Alcohols with Silanes
Y. Nishibayashi, A. Shinoda, Y. Miyake, H. Matsuzawa, and M. Sato
Angew. Chem. Int. Ed., 45, 4835-4839 (2006).
- Iridium- and Ruthenium-Catalyzed Sequential Reactions: Asymmetric a-Alkylative Reduction of Ketones with Alcohols
G. Onodera, Y. Nishibayashi, and S. Uemura
Angew. Chem. Int. Ed., 45, 3819-3822 (2006). [Highlighted in Synfacts, 2006, 09]
- Ruthenium-Catalyzed Propargylation of Aromatic Compounds with Propargylic Alcohols
Y. Inada, M. Yoshikawa, M. D. Milton, Y. Nishibayashi, and S. Uemura
Eur. J. Org. Chem., 881-890 (2006). [Highlighted at Cover Picture] [Highlighted in Synfacts, 2006, 09]
- Ruthenium-Catalyzed Reductive Coupling Reaction of Propargylic Alcohols via Hydroboration of Allenylidene Intermediates
G. Onodera, Y. Nishibayashi, and S. Uemura
Organometallics, 25, 35-37 (2006).
- Ruthenium-Catalyzed Novel Carbon-Carbon Bond Forming Reactions via Ruthenium-Allenylidene Complexes
Y. Nishibayashi and S. Uemura
Current Organic Chemistry, 10, 135-150 (2006).
- 触媒的不斉プロパルギル位置換反応の開発
西林仁昭
池谷科学技術振興財団年報, 31-32 (2006).
- 複数の金属を用いた新規分子変換反応の開発
西林仁昭
徳山科学技術振興財団年報, 60-63 (2006).
- 触媒的不斉プロパルギル位置換反応の開発
西林仁昭
長瀬科学技術振興財団研究報告集, 55-65 (2006).
2005年
- Ruthenium-Catalyzed Asymmetric Propargylic Substitution Reaction of Propargylic Alcohols with Acetone
Y. Inada, Y. Nishibayashi, and S. Uemura
Angew. Chem. Int. Ed., 44, 7715-7717 (2005). [Highlighted at Cover Picture] [Highlighted in Angew. Chem.] [Highlighted in Synfacts, 2006, 03]
- Preparation of Dicationic Chalcogenolate-Bridged Diruthenium Complexes and Their Catalytic Activity toward Reactions Between Propargylic Alcohols and Acetone
G. Onodera, H. Matsumoto, Y. Nishibayashi, and S. Uemura
Organometallics, 24, 5799-5801 (2005).
- Ruthenium-Catalyzed Formation of Aryl(diphenyl)phosphine Oxides by Reactions of Propargylic Alcohols with Diphenylphosphine Oxide
G. Onodera, H. Matsumoto, M. D. Milton, Y. Nishibayashi, and S. Uemura
Org. Lett., 7, 4029-4032 (2005).
- A Novel Method for the Preparation of Enantiomerically Pure Propargylic Substituted Compounds
Y. Nishibayashi, H. Imajima, G. Onodera, and S. Uemura
Organometallics, 24, 4106-4109 (2005).
- Asymmetric Carboselenenylation Reaction of Alkenes with Aromatic
Compounds
K. Okamoto, Y. Nishibayashi, S. Uemura, and A. Toshimitsu
Angew. Chem. Int. Ed., 44, 3588-3591 (2005).
- Synergistic Dimetallic Effects in Propargylic Substitution Reaction
Catalyzed by Thiolate-bridged Diruthenium Complex
S. C. Ammal, N. Yoshikai, Y. Inada, Y. Nishibayashi, and E. Nakamura
J. Am. Chem. Soc., 127, 9428-9438 (2005).
- Ruthenium-Catalyzed Propargylic Substitution Reactions of Propargylic
Alcohols with Oxygen-, Nitrogen-, and Phosphorus-Centered Nucleophiles
Y. Nishibayashi, M. D. Milton, Y. Inada, M. Yoshikawa, I. Wakiji,
M. Hidai, and S. Uemura
Chemistry-A European Journal, 11, 1433-1451 (2005). [Highlighted at Cover Picture]
- 次世代の窒素固定法の開発に向けて:フラーレンを用いた窒素固定法の開発
西林仁昭
触媒, 47, 233-238 (2005).
- A Non-Metal System for Nitrogen Fixation Utilizing Buckminsterfullerene
Y. Nishibayashi, S. Uemura, S. Takekuma, and Z. Yoshida
Biological Nitrogen Fixation, Sustainable Agriculture and the Environment, Ed. Y.-P. Wang, M. Lin, Z.-X. Tian, C. Elmerich, W. E. Newton., Springer, 39-40 (2005).
- フラーレンを用いた新規窒素固定法の開発
西林仁昭
近畿地方発明センター研究助成成果報告書, 44-47 (2005).
2004年
- Ruthenium- and Platinum-Catalyzed Sequential Reactions: Selective
Synthesis of Fused Polycyclic Compounds from Propargylic Alcohols
and Alkenes
Y. Nishibayashi, M. Yoshikawa, Y. Inada, M. Hidai, and S. Uemura
J. Am. Chem. Soc., 126, 16066-16072 (2004).
- Ruthenium-Catalyzed Allylation of Aromatic Compounds and Allylic
Ether Formation
G. Onodera, H. Imajima, M. Yamanashi, Y. Nishibayashi, M. Hidai, and
S. Uemura
Organometallics, 23, 5841-5848 (2004).
- Double Phosphinylation of Propargylic Alcohols: a Novel Synthetic
Route to 1,2-Bis(diphenylphosphino)ethane Derivatives
M. D. Milton, G. Onodera, Y. Nishibayashi, and S. Uemura
Org. Lett., 6, 3993-3995 (2004).
- Ruthenium- and Gold-Catalysed Sequential Reactions: a Straightforward
Synthesis of Substituted Oxazoles from Propargylic Alcohols and Amides
M. D. Milton, Y. Inada, Y. Nishibayashi, and S.Uemura
Chem. Commun., 2712-2713 (2004).
- Preparation of Alkanechalcogenolate- and Benzenechalcogenolate-Bridged
Diruthenium Complexes and Their Catalytic Activities toward Propargylation
of Acetone with Propargylic Alcohols
Y. Nishibayashi, H. Imajima, G. Onodera, Y. Inada, M. Hidai, and S.
Uemura
Organometallics, 23, 5100-5103 (2004).
- Stereospecific Carbon-Carbon Bond Formation by the Reaction of
a Chiral Episelenonium Ion with Aromatic Compounds
K. Okamoto, Y. Nishibayashi, S. Uemura, and A. Toshimitsu
Tetrahedron Lett., 45, 6137-6139 (2004).
- A Non-metal System for Nitrogen Fixation
Y. Nishibayashi, M. Saito, S. Uemura, S. Takekuma, H. Takekuma, and Z.
Yoshida
Nature, 428, 279-280 (2004).
- Synthesis of Dinuclear Complexes Bearing Metalloporphyrin-Phosphine
Hybrid Ligand and Their Catalytic Activity toward Hydrosilylation
of Ketones
M. Saito, Y. Nishibayashi, and S. Uemura
Organometallics, 23, 4012-4017 (2004).
- Ruthenium-Catalyzed Cycloaddition between Propargylic Alcohols
and Cyclic 1,3-Dicarbonyl Compounds via Allenylidene Intermediates
Y. Nishibayashi, M. Yoshikawa, Y. Inada, M. Hidai, and S. Uemura
J. Org. Chem., 69, 3408-3412 (2004).
- Preparation of a Series of Chalcogenolate-Bridged Diruthenium Complexes
and their Catalytic Activities toward the Propargylic Substitution
Reactions
Y. Nishibayashi, H. Imajima, G. Onodera, M. Hidai, and S. Uemura
Organometallics, 23, 26-30 (2004).
- カルコゲン元素架橋二核ルテニウム錯体を触媒とする有機合成反応
西林仁昭,植村 榮,干鯛眞信
Organic Square, 13, 1-3 (2004).
2003年
- Novel Catalytic Hydrogenolysis of Silyl Enol Ethers by the Use
of Acidic Ruthenium Dihydrogen Complexes
I. Takei, Y. Nishibayashi, Y. Ishii, Y. Mizobe, S. Uemura, and M. Hidai
J. Organomet. Chem., 679, 32-42 (2003).
- Oxidative Kinetic Resolution of Racemic Alcohols Catalyzed by Chiral
Ferrocenyloxazolinylphosphine-Ruthenium Complexes
Y. Nishibayashi, A. Yamauchi, G. Onodera, and S. Uemura
J. Org. Chem., 68, 5875 (2003).
- Novel Ruthenium- and Platinum-Catalyzed Sequential Reactions: Synthesis
of Tri- and Tetra-Substituted Furans and Pyrroles from Propargylic
Alcohols and Ketones
Y. Nishibayashi, M. Yoshikawa, Y. Inada, M. D. Milton, M. Hidai, and
S. Uemura
Angew. Chem. Int. Ed., 42, 2681-2684 (2003). [Selected as VIP (Very Important Paper)] [Highlighted at Cover Picture]
- Ruthenium-Catalyzed Carbon-Carbon Bond Formation between Propargylic
Alcohols and Alkenes via the Allenylidene -Ene Reaction
Y. Nishibayashi, Y. Inada, M. Hidai, and S. Uemura
J. Am. Chem. Soc., 125, 6060-6061 (2003).
- Propargylation of Aromatic Compounds with Propargylic Alcohols
Catalyzed by Cationic Diruthenium Complex
Y. Nishibayashi, Y. Inada, M. Yoshikawa, M. Hidai, and S. Uemura
Angew. Chem. Int. Ed., 42, 1495-1498 (2003).
- Synthesis of Diruthenium Complexes Containing Chiral Thiolate-bridged
Ligands and Their Application to Catalytic Propargylic Alkylation
of Propargylic Alcohols with Acetone
Y. Nishibayashi, G. Onodera, Y. Inada, M. Hidai, and S. Uemura
Organometallics, 22, 873-876 (2003).
- Kinetic Resolution of Racemic Ferrocenylphosphine Compounds by
Enantioselective Oxidation Using Cyclic Selenoxides Having a Chiral
Ligand
Y. Miyake, A. Yamauchi, Y. Nishibayashi, and S.
Uemura
Bull. Chem. Soc. Jpn., 76, 381-387 (2003).
- 新規N,P-不斉配位子(FOXAP)の開発と不斉合成反応への応用
西林仁昭,植村 榮
Organic Square, 11, 1-3 (2003).
- オレフィンメタセシスによる大環状高分子化合物の合成
西林仁昭
Organometallic News, 110 (2003).
2002年
- Ruthenium-Catalyzed Propargylic Substitution Reaction of Propargylic
Alcohols with Thiols: A General Synthetic Route to Propargylic Sulfides
Y. Inada, Y. Nishibayashi, M. Hidai, and S. Uemura
J. Am. Chem. Soc., 124, 15172-15173 (2002).
- Ruthenium-Catalyzed Propargylation of Aromatic Compounds with Propargylic
Alcohols
Y. Nishibayashi, M. Yoshikawa, Y. Inada, M. Hidai, and S. Uemura
J. Am. Chem. Soc., 124, 11846-11847 (2002).
- Ruthenium-Catalyzed Cycloaddition of Propargylic Alcohols with
Phenol Derivatives via Allenylidene Intermediates: Catalytic Use of
the Allenylidene Ligand as C3 Unit
Y. Nishibayashi, Y. Inada, M. Hidai, and S. Uemura
J. Am. Chem. Soc., 124, 7900-7901 (2002).
- Asymmetric Baeyer-Villiger Oxidation of Cyclic Ketones Using Chiral
Organoselenium Catalysts
Y. Miyake, Y. Nishibayashi, and S. Uemura
Bull. Chem. Soc. Jpn., 75, 2233-2237 (2002).
- Palladium(II) Complex-Catalysed Enantioselective Benzoylation of
Alcohols Using Carbon Monoxide and Organobismuth(V) Compounds
T. Iwata, Y. Miyake, Y. Nishibayashi, and S.
Uemura
J. Chem. Soc., Perkin Trans. 1, 2002, 1548-1554.
- Asymmetric Synthesis of Epoxides from Aromatic Aldehydes and Benzyl
Halides Catalyzed by C2 Symmetric Optically
Active Sulfides Having a Binaphthyl Skeleton
Y. Miyake, A. Oyamada, Y. Nishibayashi, and S.
Uemura
Heteroatom Chem., 13, 270-275 (2002).
- Kinetic Resolution of Racemic Ferrocenylphosphine Compounds Using Optically Active Cyclic Selenoxides as Oxidants
Y. Miyake, A. Yamauchi, Y. Nishibayashi, and S. Uemura
Phosphorus, Sulfur, and Silicon, 177, 2107-2108 (2002).
2001年
- Ruthenium-Catalysed Asymmetric Hydrosilylation of Ketoximes Using
Chiral Oxazolinylferrocenylphosphines,
I. Takei, Y. Nishibayashi, Y. Ishii, Y. Mizobe, S. Uemura, and M. Hidai
Chem. Commun., 2360-2361 (2001).
- Ruthenium-Catalyzed Propargylic Alkylation of Propargylic Alcohols with Ketones: Straightforward Synthesis of γ-Keto Acetylenes
Y. Nishibayashi, I. Wakiji, Y. Ishiii, S. Uemura, and M. Hidai
J. Am. Chem. Soc., 123, 3393-3394 (2001).
- Protonation of Coordinated N2 on Tungsten
with H2 Mediated by Sulfido-bridged Dinuclear
Molybdenum Complexes
Y. Nishibayashi, I. Wakiji, K. Hirata, M. Rakowski DuBois, and M. Hidai
Inorg. Chem., 40, 578-590 (2001).
- Kinetic Resolution of Secondary Alcohols via Chiral Pd(II)-Complex-Catalysed
Enantioselective Benzoylation using CO and Organobismuth(V) Compound
Y. Miyake, T. Iwata, K.-G. Chung, Y. Nishibayashi,
and S. Uemura
Chem. Commun. 2001, 2584-2585.
- Heterolytic Cleavage of Dihydrogen by Ruthenium and Molybdenum Complexes to Protonate Coordinated Dinitrogen and Cleave Si-O Bond
M. Hidai and Y. Nishibayashi
Recent Advances in Hydrides Chemistry; Ed. R. Poli, Elsevier Science, 117-138 (2001).
2000年
- Novel Propargylic Substitution Reactions Catalyzed by Thiolate-Bridged
Diruthenium Complexes via Allenylidene Intermediates
Y. Nishibayashi, I Wakiji, and M. Hidai
J. Am. Chem. Soc., 122, 11019-11020 (2000).
- Formation of Ammonia in the Reactions of a Tungsten Dinitrogen
with Ruthenium Dihydrogen Complexes under Mild Reaction Conditions
Y. Nishibayashi, S. Takemoto, S. Iwai, and M. Hidai
Inorg. Chem., 39, 5946-5957 (2000).
- Synthesis and Structures of 1,1'-Ferrocenedithiolato-Bridged Di-
and Trinuclear Ruthenium Complexes
S. Takemoto, S. Kuwata, Y. Nishibayashi, and M. Hidai
Organometallics, 19, 3249-3252 (2000).
- Cyclization of Terminal Diynes Catalyzed by Thiolate-bridged Diruthenium
Complexes: A Simple Synthetic Route to
Endo-Macrocyclic (Z)-1-En-3-ynes
Y. Nishibayashi, M. Yamanashi, I. Wakiji, and M. Hidai
Angew. Chem. Int. Ed., 39, 2909-2911 (2000).
- 「化学のフロンティア2000」21世紀を担う次世代の空中窒素固定法の開発 ―温和な条件下での窒素と水素からのアンモニア合成―
西林仁昭
化学と工業,53, 131-135 (2000).
- Selenium Compounds as Ligands and Catalysts
Y. Nishibayashi and S. Uemura
Topics of Current Chemistry, 208: Organoselenium Chemistry, Modern Developments in Organic Synthesis; Ed. T. Wirth, Springer-Verlag, Berlin, 235-255 (2000).
- Selenoxide Elimination and [2,3]Sigmatropic Rearrangement
Y. Nishibayashi and S. Uemura
Topics of Current Chemistry, 208: Organoselenium Chemistry, Modern Developments in Organic Synthesis; Ed. T. Wirth, Springer-Verlag, Berlin, 201-233 (2000).
1999年
- Novel Catalytic Hydrogenolysis of Trimethylsilyl Enol Ethers by
the Use of an Acidic Ruthenium Dihydrogen Complex
Y. Nishibayashi, I. Takei, and M. Hidai
Angew. Chem. Int. Ed., 38, 3047-3050 (1999).
- Extremely High-Enantioselective Redox Reaction of Ketones and Alcohols
Catalyzed by RuCl2(PPh3)(oxazolinylferrocenylphosphine)
Y. Nishibayashi, I. Takei, S. Uemura, and M. Hidai
Organometallics, 18, 2291-2293 (1999).
- Iridium-Catalyzed Asymmetric Hydrosilylation of Imines by Chiral
Oxazolinyl-Phosphine Ligands
I. Takei, Y. Nishibayashi, Y. Arikawa, S. Uemura, and M. Hidai
Organometallics, 18, 2271-2274 (1999).
- The Use of Chiral Diferrocenyl Diselenides for Highly Selective
Asymmetric Intramolecular Selenocyclization
H. Takada, Y. Nishibayashi, and S. Uemura
J. Chem. Soc., Perkin Trans. 1, 1511-1516 (1999).
- Ruthenium(II)-catalyzed Asymmetric Transfer Hydrogenation of Ketones
using Chiral Oxazolinylferrocenylphosphines and its Ru(II) Complex
Y. Arikawa, M. Ueoka, K. Matoba, Y. Nishibayashi, M. Hidai, and S. Uemura
J. Organomet. Chem., 572, 163-168 (1999).
- Sigmatropic Rearrangements of Organoselenium Compounds
Y. Nishibayashi and S. Uemura
Organoselenium Chemistry: A Practical Approach; Ed. T. G. Back, Oxford University Press, Oxford, 207-221 (1999).
1998年
- Synthesis of Heterobimetallic Fe-M (M=Ni, Pd, Pt) Complexes Containing
1,1'-Ferrocenedithiolato Ligand and Their Conversion to Trinuclear
Complexes
S. Takemoto, S. Kuwata, Y. Nishibayashi, and M. Hidai
Inorg. Chem., 37, 6428-6434 (1998).
- Ruthenium-catalyzed Asymmetric Hydrosilylation of Ketones and Imine
Y. Nishibayashi, I. Takei, S. Uemura, and M. Hidai
Organometallics, 17, 3420-3422 (1998).
- A Model for Protonation of Dinitrogen by Nitrogenase: Protonation
of Coordinated Dinitrogen on Tungsten with Hydrosulfido-Bridged Dinuclear
Complexes
Y. Nishibayashi, S. Iwai, and M. Hidai
J. Am. Chem. Soc., 120, 10559-10560 (1998).
- Bimetallic System for Nitrogen Fixation: Ruthenium-assisted Protonation
of Coordinated N2 on Tungsten with H2
Y. Nishibayashi, S. Iwai, and M. Hidai
Science, 279, 540-542 (1998).
- 4級ホスホニウム塩のセレンディピティー的な効果 −不活性な塩化アリールの活性化と触媒活性の向上−
西林仁昭
化学,53, 63-64 (1998).
- 分子状水素錯体を用いた新規な水素化反応の開発
干鯛眞信,西林仁昭
Organometallic News, 121-124 (1998).
- 夢の常温での空中窒素固定法の開発に向けて,―窒素錯体と水素錯体との反応によるアンモニア合成―
干鯛眞信,西林仁昭
化学と工業,51, 1897-1899 (1998).
- Highly Selective Asymmetric Intramolecular Selenocyclization
H. Takada, Y. Nishibayashi, S. K. Srivastava, K. Ohe, and S. Uemura
Phosphorus, Sulfur, and Silicon, 136-138, 629-632 (1998).
1997年
- Catalytic Asymmetric Sulfimidation
H. Takada, Y. Nishibayashi, K. Ohe, S. Uemura, C. P. Baird, T. J.
Sparey, and P. C. Taylor
J. Org. Chem., 62, 6512-6518 (1997).
- Synthesis and Structure of Novel Chiral Oxazolinylferrocenes and
Oxazolinylferrocenylphosphines, and Their Rhodium(I)-Complexes
Y. Nishibayashi, K. Segawa, Y. Arikawa, K. Ohe, M. Hidai, and S. Uemura
J. Organomet. Chem., 545 & 546, 381-398 (1997).
- Synthesis, Structures and Reactivities of Rhodium and Ruthenium
Complexes with Novel Chiral Cyclopentadienyl-ferrocenyldiphenylphosphine
Bidentate Ligand
Y. Nishibayashi, I. Takei, and M. Hidai
Organometallics, 16, 3091-3093 (1997).
- Allylation of Arenes Catalysed by Thiolate-Bridged Diruthenium
Complexes
Y. Nishibayashi, M. Yamanashi, Y. Takagi, and M. Hidai
Chem. Commun., 859-860 (1997).
- Rhodium(I)-, Iridium(I)-, and Ruthenium(II)-Catalyzed Asymmetric
Transfer Hydrogenation of Ketones using Diferrocenyl Dichalcogenides
as Chiral Ligands
Y. Nishibayashi, J. D. Singh, Y. Arikawa, S. Uemura, and M. Hidai
J. Organomet. Chem., 531, 13-18 (1997).
- ジルコニウムに配位する窒素分子の新しい反応
西林仁昭
Organometallic News, 95-96 (1997).
- Chiral Bis(oxazoline)-copper Catalyzed Enantioselective Imination of Sulfides
H. Takada, Y. Nishibayashi, K. Ohe, and S. Uemura
Phosphorus, Sulfur, and Silicon, 120-121, 363-364 (1997).
1996年
- Palladium-catalyzed Homocoupling Reactions of Organic Tellurides
Y. Nishibayashi, C. S. Cho, K. Ohe, and S. Uemura
J. Organomet. Chem., 526, 335-339 (1996).
- Oxidative Addition of Diferrocenyl Dichalcogenides to [(η5-C5Me5)Ru(μ3-Cl)]4.
Syntheses, Crystal Structures and Some Reactivities of Ferrocenylchalcogenolate-Bridged
Diruthenium Complexes [(η5-C5Me5)RuCl(μ2-EFc)]2
(E=S, Se, Te; Fc=ferrocenyl)
H. Matsuzaka, J.-P. Qü, T. Ogino, M. Nishio, Y. Nishibayashi,
Y. Ishii, S. Uemura, and M. Hidai
J. Chem. Soc., Dalton Trans., 4307-4312 (1996).
- Novel Asymmetric Catalytic Synthesis of Sulfimides
H. Takada, Y. Nishibayashi, K. Ohe, and S. Uemura
Chem. Commun., 931-932 (1996).
- Iridium(I)-Catalysed Asymmetric Hydrosilylation of Ketones using
Chiral Oxazolinylferrocene-Phosphine Hybrid Ligand
Y. Nishibayashi, K. Segawa, H. Takada, K. Ohe, and S. Uemura
Chem. Commun., 847-848 (1996).
- Enantioselective ortho-Lithiation of Substituted Ferrocenes
Y. Nishibayashi, Y. Arikawa, K. Ohe, and S. Uemura
J. Org. Chem., 61, 1172-1174 (1996).
- Novel Chiral Ligands, Diferrocenyl Dichalcogenides and Their Derivatives,
for the Rh(I)- and Ir(I)-Catalyzed Asymmetric Hydrosilylation
Y. Nishibayashi, J. D. Singh, K. Segawa, S. Fukuzawa, K. Ohe, and S. Uemura
Organometallics, 15, 370-379 (1996).
- Palladium-catalyzed Cross-coupling Reactions between Organic Tellurides
and Alkenes
Y. Nishibayashi, C. S. Cho, and S. Uemura
J. Organomet. Chem., 507, 197-200 (1996).
- Novel Synthesis of Chiral Diferrocenyl Dichalcogenides and Their Application to Asymmetric Reactions
Y. Nishibayashi and S. Uemura
Rev. Heteroatom Chem., MYU, Tokyo, 14, 83-118 (1996).
1995年
- Synthesis of Chiral Diferrocenyl Dichalcogenides and Their Application
to Asymmetric Nucleophilic Ring-Opening of meso-Epoxides
Y. Nishibayashi, J. D. Singh, S. Fukuzawa, and S. Uemura
J. Chem. Soc., Perkin Trans. 1, 2871-2876 (1995).
- Chiral Oxazolinylferrocene-Phosphine Hybrid Ligand for the Asymmetric
Hydrosilylation of Ketones
Y. Nishibayashi, K. Segawa, K. Ohe, and S. Uemura
Organometallics, 14, 5486-5487 (1995).
- Allylic Amine Formation by Imination of Allylic Tellurides
Y. Nishibayashi, S. K. Srivastava, K. Ohe, and S. Uemura
Tetrahedron Lett., 36, 6725-6728 (1995).
- Highly Selective Asymmetric Intramolecular Selenocyclisation
Y. Nishibayashi, S. K. Srivastava, H. Takada, S. Fukuzawa, and S. Uemura
J. Chem. Soc., Chem. Commun., 2321-2322 (1995).
- The First Example of Enantioselective Carbenoid Addition to Organochalcogen
Atoms : Application to [2,3]Sigmatropic Rearrangement of Allylic Chalcogen
Ylides
Y. Nishibayashi, K. Ohe, and S. Uemura
J. Chem. Soc., Chem. Commun., 1245-1246 (1995).
- High Chirality Transfer in Chiral Selenimides via [2,3]Sigmatropic
Rearrangement
Y. Nishibayashi, T. Chiba, K. Ohe, and S. Uemura
J. Chem. Soc., Chem. Commun., 1243-1244 (1995).
- Synthesis of [R,S;R,S]- and [S,R;S,R]-Bis[2-[1-(dimethylamino)ethyl]-ferrocenyl]
Diselenides and Their Application to Asymmetric Selenoxide Elimination
and [2,3]Sigmatropic Rearrangement
Y. Nishibayashi, J. D. Singh, S. Fukuzawa, and S. Uemura
J. Org. Chem., 60, 4114-4120 (1995).
- The First Example of Chirality Transfer in Allylic Telluroxides
- Possible [2,3]-Sigmatropic Rearrangement
T. Chiba, Y. Nishibayashi, J. D. Singh, K. Ohe, and S. Uemura
Tetrahedron Lett., 36, 1519-1522 (1995).
- Stereo- and Chemo-Selectivity in Reduction of α-[Phenyl(or
Methyl)seleno]- alkyl Aryl Ketones with Metal Hydrides
I, Aoki, Y. Nishibayashi, and S. Uemura
Bull. Chem. Soc. Jpn., 68, 337-340 (1995).
- Asymmetric Synthesis and Highly Diastereoselective ortho-Lithiation
of Oxazolinylferrocenes
Y. Nishibayashi, and S. Uemura
Synlett, 79-81 (1995).
1994年
- Rhodium(I)-catalysed Asymmetric Hydrosilylation of Ketones using
New Diferrocenyl Dichalcogenides (R,S)-{[EC5H3CHMe(NMe2)]Fe(C5H5)}2
(E=S, Se, Te) as Chiral Ligands
Y. Nishibayashi, J. D. Singh, K. Segawa, S. Fukuzawa, and S. Uemura
J. Chem. Soc., Chem. Commun., 1375-1376 (1994).
- Syntheses and Reactivities of Ferrocenyl Organyl Tellurides
Y. Nishibayashi, T. Chiba, J. D. Singh, S. Uemura, and S. Fukuzawa
J. Organomet. Chem., 473, 205-213 (1994).
- Synthesis of Chiral Diferrocenyl Diselenides and Their Application
to Asymmetric Reactions
Y. Nishibayashi, J. D. Singh, S. Uemura, and S. Fukuzawa
Tetrahedron Lett., 35, 3115-3118 (1994).
- Dinuclear (η5-C5Me5)Ru
Complexes Triply Bridged by Tellurium or Selenium Ligands - Syntheses
and Characterisation of (η5-C5Me5)Ru(μ2-RTeTeR)(μ2-TeR)2Ru(η5-C5Me5)
and [(η5-C5Me5)Ru(μ2-SeR)3Ru(η5-C5Me5)]Cl
(R = Tol, Ph)
H. Matsuzaka, T. Ogino, M. Nishio, M. Hidai, Y. Nishibayashi, and S. Uemura
J. Chem. Soc., Chem. Commun., 223-224 (1994).
1993年
- Asymmetric Selenoxide Elimination Leading to Chiral Allenic Sulfones
N. Komatsu, T. Murakami, Y. Nishibayashi, T. Sugita, and S. Uemura
J. Org. Chem., 58, 3697-3702 (1993).
- Telluroxide Elimination by Oxidation of Alkyl Aryl Tellurides:
Remarkable Effect of Added Triethylamine
Y. Nishibayashi, N. Komatsu, K. Ohe, and S. Uemura
J. Chem. Soc., Perkin Trans. 1, 1133-1138 (1993).
- Asymmetric [2,3]Sigmatropic Rearrangement
via Chiral Selenoxide with Sharpless Oxidants
N. Komatsu, Y. Nishibayashi, and S. Uemura
Tetrahedron Lett., 34, 2339-2342 (1993).
1992年
- Catalytic Asymmetric Oxidation of Sulfides to Sulfoxides Using
R-(+)-Binaphthol
N. Komatsu, Y. Nishibayashi, T. Sugita, and S. Uemura
Tetrahedron Lett., 33, 5391-5394 (1992).
- The First Example of Asymmetric Selenoxide Elimination: Application
to the Synthesis of Chiral Allenes
N. Komatsu, Y. Nishibayashi, T. Sugita, and S. Uemura
J. Chem. Soc., Chem. Commun., 46-47 (1992).
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