伊藤喜光
2022年度スタートの「分子界面工学研究室」についてはこちら
1977年生まれ。神奈川県出身。2006年東京工業大学において「有機フッ素化合物の合成反応に関する実験的および計算化学的検討」により博士（工学）を取得（三上幸一教授）。その後最初のポスドクとして東京大学中村栄一教授のもと有機金属触媒の研究に携わる。二つ目のポスドク先であるコロンビア大学では、 Colin Nuckolls教授のもと自己組織化単分子膜と有機薄膜トランジスタの研究を行う。2008年、東京大学化学生命工学専攻相田研究室の助教としてアカデミックキャリアをスタートさせた。2016年に講師、2019年に准教授に昇任。現在は電場による化学システムの変調（反応、集合、物性）を利用した材料開発に注目して研究を行っている。
学歴
2001年 東京工業大学工学部 学士
2003年 東京工業大学理工学研究科 修士
2006年 東京工業大学理工学研究科 博士（工学）
研究歴
2001.4–2006.3: 博士課程学生、東京工業大学（三上幸一教授）
2005.7–2005.9: 訪問学生、カリフォルニア大学ロサンゼルス校（K. N. Houk 研究室）
2006.4–2007.8: 日本学術振興会特別研究員、東京大学（中村栄一研究室）
2007.9–2008.8: 日本学術振興会特別研究員、コロンビア大学（Colin Nuckolls 研究室）
2008.9–2016.9: 助教、東京大学（相田卓三研究室）
2016.10–2019.5: 講師、東京大学（相田卓三研究室）
2019.6–現在: 准教授、東京大学（相田卓三研究室）
受賞
2013年 ゴードン会議（Self-Assembly & Supramolecular Chemistry）Emerging Leaders賞
2016年 日本化学会、若い世代の特別講演証
2017年 文部科学大臣表彰若手科学者賞
2018年 第67回高分子学会年次大会、パブリシティ賞
2019年 第68回高分子学会年次大会、パブリシティ賞
2019年 高分子学会日立化成賞
論文
Alternating Heterochiral Supramolecular Copolymerization
Michihisa Ueda, Tsubasa Aoki, Takayoshi Akiyama, Takayuki Nakamuro, Keitaro Yamashita, Haruaki Yanagisawa, Osamu Nureki, Masahide Kikkawa, Eiichi Nakamura, Takuzo Aida,* Yoshimitsu Itoh*
J. Am. Chem. Soc. 2021, 143, 5121–5126.
Bio-Adhesive Nanoporous Module : Toward Autonomous Gating
Hyuna Jo, Takashi Kitao, Ayumi Kimura, Yoshimitsu Itoh, Takuzo Aida,* Kou Okuro*
Angew. Chem. Int. Ed. 2020, 60, 8932–8937 (selected as “Cover Picture”).
Anomalously Slow Conformational Change Dynamics of Polar Groups Anchored to Hydrophobic Surfaces in Aqueous Media.
Chem. Asian. J. 2020, 15, 3321–3325.
Tengfei Fu, Hao Xing, Eric S. Silver, Yoshimitsu Itoh,* Shuo Chen, Takuya Masuda, Kohei Uosaki, Feihe Huang,* Takuzo Aida*
[DOI: 10.1002/asia.202000742]
Supramolecular Polymerization in Liquid Crystalline Media: Toward Modular Synthesis of Multifunctional Core-Shell Columnar Liquid Crystals.
J. Am. Chem. Soc. 2019, 141, 10033–10038 (selected as “Cover Picture”).
Keiichi Yano, Takahiro Hanebuchi, Xu-Jie Zhang, Yoshimitsu Itoh,* Yoshiaki Uchida, Takuro Sato, Keisuke Matsuura, Fumitaka Kagawa, Fumito Araoka, and Takuzo Aida*
Nematic-to-Columnar Mesophase Transition by In situ Supramolecular Polymerization.
Science 2019, 363, 161–165.
Keiichi Yano, Yoshimitsu Itoh,* Fumito Araoka, Go Watanabe, Takaaki Hikima, and Takuzo Aida *
[DOI: 10.1126/science.aan1019 ]
An Electrochemical Cholesteric Liquid Crystalline Device for Quick and Low-Voltage Color Modulation.
J. Vis. Exp. 2019, 144, e59244.
Shoichi Tokunaga, Mengyan Zeng, Yoshimitsu Itoh,* Fumito Araoka, and Takuzo Aida*
Columnar Liquid Crystalline Assembly of a U-Shaped Molecular Scaffold Stabilized by Covalent or Noncovalent Incorporation of Aromatic Molecules
J. Polym. Sci. A, Polym. Chem. 2019, 57, 342–351.
Yoshiki Shibuya, Yoshimitsu Itoh,* and Takuzo Aida*
A Redox-Responsive Chiral Dopant for Quick Electrochemical Color Modulation of Cholesteric Liquid Crystal
J. Am. Chem. Soc. 2018, 140, 10946–10949 (selected as “Cover Picture”).
Shoichi Tokunaga, Yoshimitsu Itoh,* Hiroyuki Tanaka, Fumito Araoka, and Takuzo Aida*
Enhancement of Superconducting Transition Temperature in FeSe Electric-Double-Layer Transistor with Multivalent
Ionic Liquids
Phys. Rev. Mater. 2018, 2, 031801.
Tomoki Miyakawa, Junichi Shiogai,* Sunao Shimizu, Michio Matsumoto, Yukihiro Ito, Takayuki Harada, Kohei Fujiwara, Tsutomu Nojima, Yoshimitsu Itoh, Takuzo Aida, Yoshihiro Iwasa, and Atsushi Tsukazaki
[DOI: 10.1103/PhysRevMaterials.2.031801 ]
Exceptionally High Electric Double Layer Capacitances of Oligomeric Ionic Liquids
Michio Matsumoto, Sunao Shimizu, Rina Sotoike, Masayoshi Watanabe, Yoshihiro Iwasa,* Yoshimitsu Itoh, and Takuzo Aida*
J. Am. Chem. Soc. 2017, 139, 8784-8787.
Water dynamics: Gliding and trudging
Yoshimitsu Itoh* and Takuzo Aida*
Nature Chem. 2017, 9, 934-936.
Energetics of Baird aromaticity supported by inversion of photoexcited chiral [4n]annulene derivatives
Michihisa Ueda, Kjell Jorner, Young Mo Sung, Tadashi Mori, Qi Xiao, Dongho Kim,* Henrik Ottosson,* Takuzo Aida,* and Yoshimitsu Itoh*
Nature Commun. 2017, 8, 346.
[DOI: 10.1038/s41467-017-00382-1 ]
Jumping Crystals of Pyrene Tweezers: Crystal-to-Crystal Transition Involving π/π-to-CH/π Assembly Mode Switching
Yoshiki Shibuya, Yoshimitsu Itoh,* and Takuzo Aida*
Chem. Asian J. 2017, 12, 811-815.
[DOI: 10.1002/asia.201700083 ]
Electrophoretic Deposition for Cholesteric Liquid-Crystalline Devices with Memory and Modulation of Reflection Colors.
Shoichi Tokunaga, Yoshimitsu Itoh,* Yuya Yaguchi, Hiroyuki Tanaka, Fumito Araoka, Hideo Takezoe, Takuzo Aida*
Adv. Mater. 2016, 28, 4077–4083.
[DOI: 10.1002/adma.201600258 ]
Subnanoscale Hydrophobic Modulation of Salt Bridges in Aqueous Media
S. Chen, Y. Itoh,* T. Masuda, S. Shimizu, J. Zhao, J. Ma, S. Nakamura, K. Okuro, H. Noguchi, K. Uosaki, T. Aida*
Science 2015, 348, 555–559.
[DOI: 10.1126/science.aaa7532 ]
A Rational Strategy for the Realization of Chain-Growth Supramolecular Polymerization
J. Kang, D. Miyajima,* T. Mori, Y. Inoue, Y. Itoh, T. Aida*
Science 2015, 347, 646–651.
[DOI: 10.1126/science.aaa4249 ]
C5-Symmetric Chiral Corannulenes: Desymmetrization of Bowl Inversion Equilibrium via “Intramolecular” Hydrogen-Bonding Network
Jiheong Kang, Daigo Miyajima,* Yoshimitsu Itoh, Tadashi Mori, Hiroki Tanaka, Masahito Yamauchi, Yoshihisa Inoue, Soichiro Harada, and Takuzo Aida*
J. Am. Chem. Soc. 2014, 136, 10640–10644.
Homochiral supramolecular polymerization of bowl-shaped chiral macrocycles in solution
K. Sato, Y. Itoh,* T. Aida*
Chem. Sci. 2014, 5, 136–140.
Theoretical Study on the Regioselectivity of Baeyer–Villiger Reaction of α-Me-, -F-, -CF3-Cyclohexanones
Y.Itoh, M. M. Yamanaka, K. Mikami*
J.Org. Chem. 2013, 78, 146–153.
Columnarly Assembled Liquid Crystalline Peptidic Macrocycles Unidirectionally Orientable over a Large Area by Electric Field.
K. Sato, Y. Itoh,* T. Aida* J. Am. Chem. Soc. 2011, 133, 13767–13769.
Simple Formation of C60 and C60-Ferrocene Conjugated Monolayers Anchored onto Silicon Oxide with Five Carboxylic Acids and Their Transistor Applications.
Y. Itoh,* B. Kim, R. I. Gearba, N. J. Tremblay, R. Pindak, Y. Matsuo, E. Nakamura, C. Nuckolls
Chem. Mater. 2011, 23, 970–975.
Highly enantioselective synthesis of α-(perfluoroalkyl)amines via hydrogenation of enamide precursors in the presence of chiraphos-rhodium catalyst.
K. Mikami,* T. Murase, L. Zhai, Y. Itoh, S. Ito
Tetrahedron Asymmetry 2010, 21, 1158–1161.
Activation of C-F Bonds in Preference to C-I Bonds: Difluoromethylation of Lithium Enolates with Trifluoromethyl Iodide
K. Mikami,* Y. Tomita, Y. Itoh
Angew. Chem. Int. Ed. 2010, 49, 3819–3822.
Photovoltaic Universal Joints: Ball-and-Socket Interfaces in Molecular Photovoltaic Cells
N. J. Tremblay, A. A. Gorodetsky, M. P. Cox, T. Schiros, B. Kim, R. Steiner, Z. Bullard, A. Sattler, W.–Y. So, Y. Itoh, M. F. Toney, H. Ogasawara, A. P. Ramirez, I. Kymissis,* M. L. Steigerwald, C. Nuckolls*
ChemPhysChem 2010, 11, 799–803.
Sequential Perfluoroalkylation and Asymmetric Reduction of Nitriles Triggered with Perfluoroalkyl Titanates:
Catalytic Asymmetric Synthesis of Perfluoroalkyl Amines.
K. Mikami,* T. Murase, L. Zhai, S. Kawauchi, Y. Itoh, S. Ito.
Tetrahedron Lett. 2010, 51, 1371–1373.
Efficient Formation of Ring Structures Utilizing Multisite Activation by Indium Catalysis
. Y.Itoh, H. Tsuji, K. Yamagata, K. Endo, I. Tanaka, M. Nakamura, E. Nakamura*
J. Am. Chem. Soc. 2008, 130, 17161–17167.
Dialkylzinc-accelerated α-Trifluoromethylation of Carbonyl Compounds Catalyzed by Late-transition-metal Complexes
Y. Tomita, Y. Itoh, K. Mikami*
Chem. Lett. 2008, 37, 1080–1081.
Modular Synthesis of Benzo[b]phosphole Derivatives via BuLi-Mediated Cyclization of (o-Alkynylphenyl)phosphin
H. Tsuji,* K. Sato, L. Ilies, Y. Itoh, Y. Sato, E. Nakamura*
Org. Lett. 2008, 10, 2263–2265.
Zncate-Type Enolate for Radical α-Trifluoromethylation
Y. Tomita, Y. Ichikawa, Y. Itoh, K. Kawada, K. Mikami*
Tetrahedron Lett. 2007, 48, 8922–8925.
Indium-Catalyzed Cycloisomerization of ω-Alkynyl-β-ketoesters into Six- to Fifteen-Membered Rings
H. Tsuji, K. Yamagata, Y. Itoh, K. Endo, M. Nakamura, E. Nakamura*
Angew. Chem. Int. Ed. 2007, 46, 8060–8062.
Tandem Reductive Perfluoroalkylation of Esters with Perfluoroalkyl Titanate-Type Reagents
K. Mikami,* T. Murase, Y. Itoh
J. Am. Chem. Soc. 2007, 129, 11686–11687.
Catalytic Asymmetric Synthesis and Anticancer Effects of the Novel Non-Calcemic Analog of Vitamin D, 2α-Fluoro-19-nor-22-oxa-1α,25-dihydroxyvitamin D3 in Metastatic Lung Carcinoma
K. Nakagawa, T. Okano, K. Ozono, S. Kato, N. Kubodera, S. Ohba, Y. Itoh, K. Mikami*
J. Fluorine Chem. 2007, 128, 654–667.
Trifluoromethylation of Metal Enolates and Theoretical Guideline
K. Mikami,* Y. Itoh
In Current Fluoroorganic Chemistry. New Synthetic Directions, Technologies, Materials and Biological Applications; V. A. Soloshonok, K. Mikami, T. Yamazaki, J. T. Welch, J. Honec, Eds.; American Chemical Society: Washington, DC, 2007; p 2–24.
Radical Trifluoromethylation of Ketone Silyl Enol Ethers by Activation with Dialkylzinc
K. Mikami,* Y. Tomita, Y. Ichikawa, K. Amikura, Y. Itoh
Org. Lett. 2006, 8, 4671–4673.
Experimental and Theoretical Studies on Radical Trifluoromethylation of Titanium Ate and Lithium Enolates
Y. Itoh, K. N. Houk, K. Mikami*
J. Org. Chem. 2006, 71, 8918–8925.
Radical Trifluoromethylation of Ketone Li Enolates
Y. Itoh, K. Mikami*
Tetrahedron 2006, 62, 7199–7203.
Nanoflow Microreactor for Dramatic Increase not only in Reactivity but also in Selectivity: Baeyer-Villiger Oxidation by Aqueous Hydrogen Peroxide using Lowest Concentration of a Fluorous Lanthanide Catalyst
K. Mikami,* M. Yamanaka, Md. N. Islam, T. Tonoi, Y. Itoh, M. Shinoda, K. Kudo
J. Fluorine Chem. 2006, 127, 592–596.
Radical Trifluoromethylation of Ti Ate Enolate: Possible Intervention of Transformation of Ti(IV) to Ti(III) for Radical Termination
Y. Itoh, K. Mikami*
J. Fluorine Chem. 2006, 127, 539–544.
Metal Enolates of α-CF3 Ketones: Theoretical Guideline, Direct Generation, and Synthetic Use
K. Mikami,* Y. Itoh
Chem. Rec. 2006, 6, 1–11.
Facile Radical Trifluoromethylation of Lithium Enolates
Y. Itoh, K. Mikami*
Org. Lett. 2005, 7, 4883–4885.
Radical Trifluoromethylation of Titanium Ate Enolate
Y. Itoh, K. Mikami*
Org. Lett. 2005, 7, 649–651.
Fluorinated Synthon: Asymmetric Catalytic Reactions
K. Mikami,* Y. Itoh, M. Yamanaka
In Fluorine-Containing Synthons; V. A. Soloshonok Ed.; American Chemical Society: Washington, DC, 2005; p 356–367.
Direct Generation of Ti-Enolate of α-CF3 Ketone: Theoretical Study and High-Yielding and Diastereoselective Aldol Reaction
Y. Itoh, M. Yamanaka, K. Mikami*
J. Am. Chem. Soc. 2004, 126, 13174–13175.
Hybrid Reagent of Ammonium Hydrogen Fluoride and Scandium Triflate: Highly Efficient Catalyst for Ring-Opening Fluorination of 2,3-Epoxyalcohols
Y. Itoh, S. Jang, S. Ohba, K. Mikami*
Chem. Lett. 2004, 33, 776–777.
Nanoflow System for Perfect Regiocontrol in the Baeyer-Villiger Oxidation by Aqueous Hydrogen Peroxide using Lowest Concentration of a Fluorous Lanthanide Catalyst
K. Mikami,* Md. N. Islam, M. Yamanaka, Y. Itoh, M. Shinoda, K. Kudo
Tetrahedron Lett. 2004, 45, 3681–3683.
Fluorinated Carbonyl and Olefinic Compounds: Basic Character and Asymmetric Catalytic Reactions
K. Mikami,* Y. Itoh, M. Yamanaka
Chem. Rev. 2004, 104, 1–16.
Dipole Interaction-Controlled Stereoselectivity in Aldol Reaction of α-CF3 Enolate with Fluoral.
Y. Itoh, M. Yamanaka, K. Mikami*
Org. Lett. 2003, 5, 4807–4809.
Complete Reversal in Regioselectivity in the Baeyer-Villiger Reaction of an α-CF3-Ketone and Theoretical Rationale for Axial Orientation of Sterically Demanding CF3 group at the Transition State
Y. Itoh, M. Yamanaka, K. Mikami*
Org. Lett. 2003, 5, 4803–4806.
Organic Fluorine Compounds with Full of Character: Their (Catalytic) Asymmetric Synthesis (2).
K. Mikami,* Y. Itoh, M. Yamanaka
Fine Chemical 2003, 32 (2), 11–20.
Organic Fluorine Compounds with Full of Character: Their (Catalytic) Asymmetric Synthesis (1).
K. Mikami,* Y. Itoh, M. Yamanaka
Fine Chemical 2003, 32 (1), 35–50.
伊藤 喜光
准教授
東京大学大学院工学系研究科
化学生命工学専攻
itoh＠macro.t.u-tokyo.ac.jp