Publications (Dr. Takahashi)
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Degradation of Epoxy Resins in Water for Recovery of Small Organic Molecules: The Use of Platinum Catalyst under Hydrothermal Conditions
K. Nozaki, Y. Liao, S. Hosokawa, K. Takahashi, S. Nakagawa, N. Yoshie, Y. Yamasaki
Research Square 2024 (preprint) 10.21203/rs.3.rs-5298299/v1
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Crystallization of Strictly Linear Poly(ethylene-ran-acrylic acid) Copolymer: Impacts of Pendant Group Insertion and Hydrogen Bonding
J. Zhou, K. Takahashi, K. Nozaki, Y. Yamamoto, T. Katashima, N. Yoshie, S. Nakagawa
Macromolecules 2024, 57, 10176–10191. acs.macromol.4c01250
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Bimetallic Synergy in Ru−Pt Alloy Catalyst for Polyethylene Hydrogenolysis
Y. Yamazaki, X. Jin, W. Sun, K. Nomoto, K. Takahashi, H. Miura, T. Shishido, A. Nakayama, K. Nozaki
ChemRxiv 2024 (preprint) 10.26434/chemrxiv-2024-sm1lp
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Aliphatic Polyketones from Alternating Copolymerization of CO and Olefins: Phosphinoamidate Nickel Catalyst, Polymerization Study, Mechanical Properties and Degradations.
L. Zhu, J. Li, W. -Y. Chen, C. Ziegler, K. Takahashi, K. Nozaki, L. Jia
ACS Appl. Polym. Mater. 2024, 6, 9829–9836. 10.1021/acsapm.4c01691
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Synthesis of Long-Chain Polyamides via Main-Chain Modification of Polyethyleneketones
Y. Lu, K. Takahashi, J. Zhou, R. Nontarin, S. Nakagawa, N. Yoshie, K. Nozaki
Angew. Chem. Int. Ed. 2024, 63, e202410849. 10.1002/anie.202410849
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Mild Catalytic Degradation of Crystalline Polyethylene Units in Solid State Assisted by Carboxylic Acid Groups
B. Lu, K. Takahashi, J. Zhou, S. Nakagawa, Y. Yamamoto, T. Katashima, N. Yoshie, K. Nozaki
J. Am. Chem. Soc. 2024, 146, 19599–19608. 10.1021/jacs.4c07458 Highlighted in Press Release.
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Synthesis of novel polymers with biodegradability by main-chain editing of chiral polyketones
H. Yuan, K. Takahashi, S. Hayashi, M. Suzuki, N. Fujikake, K. Kasuya, J. Zhou, S. Nakagawa, N. Yoshie, C. Li, K. Yamaguchi, K. Nozaki
J. Am. Chem. Soc. 2024, 146, 13658–13665. 10.1021/jacs.4c04389 Highlighted in Press Release.
ChemRxiv 2023 (preprint) 10.26434/chemrxiv-2023-wj0p6
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Nickel-Catalyzed C(sp3)−O Hydrogenolysis via a Remote Concerted Oxidative Addition and its Application to Degradation of a Bisphenol A-Based Epoxy Resin
Y. Liao, K. Takahashi, K. Nozaki
J. Am. Chem. Soc. 2024, 146, 2419–2425. 10.1021/jacs.3c09061 Featured on the cover. Highlighted in OPR&D.
ChemRxiv 2023 (preprint) 10.26434/chemrxiv-2023-dz9v9-v2
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Nickel-Catalyzed Selective Incorporation of Isolated In-Chain Carbonyls into Ethylene/Carbon Monoxide Copolymer Using Metal Carbonyls as a Carbonyl Source
G. Yonezaki, F. Seidel, K. Takahashi, K. Nozaki
Bull. Chem. Soc. Jpn. 2023, 96, 545–549. 10.1246/bcsj.20230073 Selected as a Selected Paper. Featured on Back Cover Picture.
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Catalytic Synthesis of a Methylmalonate Salt from Ethylene and Carbon Dioxide through Photoinduced Activation and Photoredox-Catalyzed Reduction of Nickelalactones
K. Takahashi, Y. Sakurazawa, A. Iwai, N. Iwasawa
ACS Catal. 2022, 12, 3776–3781. 10.1021/acscatal.2c01053
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2-Quinolyl Benzodiazaborine: A Tunable Platform for Aggregation‐Induced Emission Luminogens via Formation of Dimeric Borate Crystals with Acid Additives
S. Shimo, T. Nakamura, K. Takahashi, N. Toriumi, N. Iwasawa
ChemPhotoChem 2022, 6, e202100195. 10.1002/cptc.202100195
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Reversible C–C Double Bond Cleavage to Form a Metal Carbene and an Alkene Enabled on an Iridium Complex Bearing a Pincer-type Alkoxycarbene Ligand
K. Takahashi, N. Iwasawa
Organometallics 2021, 40, 3926–3934. 10.1021/acs.organomet.1c00498
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Supramolecular Photocatalysis by Utilizing the Host-Guest Charge-Transfer Interaction: Visible-Light-Induced Generation of Triplet Anthracenes for [4+2] Cycloaddition Reactions
T. Uchikura, M. Oshima, M. Kawasaki, K. Takahashi, N. Iwasawa
Angew. Chem. Int. Ed. 2020, 59, 7403–7408. 10.1002/anie.201916732
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Mechanistic Investigations of the Ruthenium-Catalyzed Synthesis of Acrylate Salt from Ethylene and CO2
K. Takahashi, Y. Hirataka, T. Ito, N. Iwasawa
Organometallics 2020, 39, 1561–1572. 10.1021/acs.organomet.9b00659
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Development of N-Phosphinomethyl-Substituted NHC-Nickel(0) Complexes as Robust Catalysts for Acrylate Salt Synthesis from Ethylene and CO2
K. Takahashi, K. Cho, A. Iwai, T. Ito, N. Iwasawa
Chem. Eur. J. 2019, 25, 13504–13508. 10.1002/chem.201903625
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Self-Assembly of Macrocyclic Boronic Esters Bearing Tellurophene Moieties and Their Guest-Responsive Phosphorescence
K. Takahashi, S. Shimo, E. Hupf, J. Ochiai, C. A. Brau, W. Delgado, L. Xu, G. He, E. Rivard, N. Iwasawa
Chem. Eur. J. 2019, 25, 8479–8483. 10.1002/chem.201901319
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1,2-Dihydro-1-hydroxy-2,3,1-benzodiazaborine Bearing an Acridine Moiety as a Circular Dichroism Probe for Determination of Absolute Configuration of Mono-Alcohols
S. Shimo, K. Takahashi, N. Iwasawa
Chem. Eur. J. 2019, 25, 3790–3794. 10.1002/chem.201900350
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Reactivity of a Ruthenium(0) Complex Bearing a Tetradentate Phosphine Ligand: Applications to Catalytic Acrylate Salt Synthesis from Ethylene and CO2
T. Ito, K. Takahashi, N. Iwasawa
Organometallics 2018, 38, 205–209. 10.1021/acs.organomet.8b00789
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Dynamic Interconversion between Boroxine Cages Based on Pyridine Ligation
K. Ono, S. Shimo, K. Takahashi, N. Yasuda, H. Uekusa, N. Iwasawa
Angew. Chem. Int. Ed. 2018, 57, 3113–3117. 10.1002/anie.201713221
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Utilization of Donor–Acceptor Interactions for the Catalytic Acceleration of Nucleophilic Additions to Aromatic Carbonyl Compounds
T. Uchikura. K. Ono, K. Takahashi, N. Iwasawa
Angew. Chem. Int. Ed. 2018, 57, 2130–2133. 10.1002/anie.201711726
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Ruthenium Catalyzed Hydrogenation of Aldehyde with Synthesis Gas
K. Takahashi, K. Nozaki
Org. Lett. 2014, 16, 5846–5849. 10.1021/ol502681y
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Tandem Isomerization/Hydroformylation/Hydrogenation of Internal Alkenes to normal-Alcohols Using Rh/Ru Dual or Ternary Catalyst Systems
Y. Yuki, K. Takahashi, Y. Tanaka, K. Nozaki
J. Am. Chem. Soc. 2013, 135, 17393–17400. 10.1021/ja407523j
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Tandem Hydroformylation/Hydrogenation of Alkenes to normal-Alcohols Using Rh/Ru Dual Catalyst or Ru Single Component Catalyst
K. Takahashi, M. Yamashita, K. Nozaki
J. Am. Chem. Soc. 2012, 134, 18746–18757. 10.1021/ja307998h
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CpRu/C5Me5/Bisphosphine- or Bisphosphite-Based Catalysts for normal-Selective Hydroformylation
K. Takahashi, M. Yamashita, Y. Tanaka, K. Nozaki
Angew. Chem. Int. Ed. 2012, 51, 4283–4387. 10.1002/anie.201108396
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High-Yielding Tandem Hydroformylation/Hydrogenation of a Terminal Olefin to Produce a Linear Alcohol Using a Rh/Ru Dual Catalyst System
K. Takahashi, M. Yamashita, T. Ichihara, K. Nakano, K. Nozaki
Angew. Chem. Int. Ed. 2010, 49, 4488–4490. 10.1002/anie.201001327 selected as an outside cover, highlighted in ChemCatChem, highlighted at the following blogs, NNNS chemistry blog, ユーキの有機化学Hot Topics
Review articles
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水素を用いた難分解性プラスチックのケミカルリサイクル
T. Iwasaki, K. Takahashi
高分子, 73 (5), 201–202 (2024).
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パラジウム触媒を用いた芳香族のC–H結合亜鉛化反応
K. Takahashi
月刊化学, 化学同人, 2021.
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一酸化炭素のC–O結合の開裂を伴うボロン酸エステルの合成法
K. Takahashi
Organometallic News, 近畿化学協会有機金属部会, 2021.
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オレフィンのヒドロホルミル化
K. Takahashi, K. Nozaki
有機合成のための新触媒反応101, 有機合成化学協会, 2021.
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パラジウムによるアミナールのC–N結合切断とアルケン類からの触媒的アミン合成への応用
K. Takahashi
有機合成化学協会誌, 有機合成化学協会, 75, 1055–1056 (2017).
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Hydroformylation of Epoxides
K. Takahashi, K. Nozaki
C-1 Building Blocks in Organic Synthesis 2, Science of Synthesis, Thieme, 207–217 (2014).
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ヒドロホルミル化
K. Takahashi, K. Nozaki
触媒調製ハンドブック, NTS出版, 370–374 (2011).