略歴

荻原 直希 助教 (1990年11月30日 群馬県伊勢崎市生まれ)

〒153-8902 東京都目黒区駒場3－8－1
東京大学 駒場Iキャンパス16号館 424号室
E-mail:  cogiwara @ g.ecc.u-tokyo.ac.jp
TEL: 03-5454-6601
ORCID: 0000-0003-3207-586X 

2009年3月 群馬県立前橋高等学校 卒業
2014年3月 京都大学 工学部 工業化学科 卒業（北川 進 教授）
2016年3月 京都大学 大学院工学研究科 合成・生物化学専攻 修士課程 修了（北川 進 教授）
2017年4月 日本学術振興会 特別研究員（DC2）
2019年3月 京都大学 大学院理学研究科 化学専攻 博士後期課程 修了（北川 宏 教授） 博士（理学 京都大学）
2019年4月 東京工業大学 科学技術創成研究院 化学資源持続生産研究ユニット 研究員
2020年4月-東京大学 大学院総合文化研究科 広域科学専攻 相関基礎科学系 助教（現職）

講義担当科目

基礎実験Ⅰ(化学)、基礎実験Ⅱ(化学)、基礎実験Ⅲ(化学)、基礎実験Ⅳ(化学)、基礎化学実験

受賞歴

2018年 Journal of Materials Chemistry A poster prizes, 43rd International Conference on Coordination Chemistry
2018年 Best Poster Award, Americas International Meeting on Electrochemistry and Solid State Science 
2020年 第36回井上研究奨励賞
2023年 第2回相関基礎科学系研究教育奨励賞

発表論文

(47) “Reduction-Induced Uptake of Cs+ in Metal–Organic Frameworks Loaded with Polyoxometalates”, 
C. A. Nagasaka, N. Ogiwara*, S. Kobayashi, S. Uchida*, 
Small, 2023, 23007004.

(46) “Role of Thermo-alkaline-oxidized Kraft Lignin Aided by Concrete Waste as a Potential Reinforcement Material in Botanical Concrete”,
R. Wei*, Y. Sakai, N. Ogiwara, S. Uchida,
Constr. Build. Mater., 2023, 406, 133434.

(45) “Direct Synthesis of Eco-friendly Construction Material from Low-quality Sand via Sol-gel Method”, 
P. Qiu*, Y. Sakai, Y. Tamura, N. Ogiwara, S. Uchida, 
Constr. Build. Mater., 2023, 392, 131906.

(44) “Bismuth Substitution in HSbOI with Positively-Charged Oxide Clusters”, 
Y. Watanabe, T. Goto, J. Xia, N. Ogiwara, H. Tabe, S. Horike, Y. Noda, S. Uchida, H. Kageyama*,
Chem. Lett., 2023, 52, 430–433. 

(43) “A Redox-Active Inorganic Crown Ether Based on a Polyoxometalate Capsule”, 
N. Tamai, N. Ogiwara, E. Hayashi, K. Kamata, T. Misawa, T. Ito,T. Kojima, M. Segado, E. Petrus, C. Bo, S. Uchida*, 
Chem. Sci., 2023, 14 (20), 5453–5459.

(42) “Metal–Oxo-Cluster-Based Crystals as Solid Catalysts”, 
N. Ogiwara, S. Uchida*, 
Chem Catal., 2023, 3, 100607.

(41) “Surpassing Pt Hydrogen Production from {200} Facet-Riched Polyhedral Rh2P Nanoparticles by One-Step Synthesis”,
H. Xin, L.Sun, Y. Zhao, Z. Dai, Q. Luo, S. Guo, D. Li, Y. Chen, N. Ogiwara, H. Kitagawa, B. Huang*, F. Ma*,
Appl. Catal. B, 2023, 330, 122645.

(40) “Size-Controlled Synthesis of Luminescent Few-Atom Silver Clusters via Electron Transfer in Isostructural Redox-Active Porous Ionic Crystals”,
N. Haraguchi, N. Ogiwara, Y. Kumabe, S. Kikkawa, S. Yamazoe, T. Tachikawa*, S. Uchida*, 
Small, 2023, 2300743.

(39) “Vanadium-Substituted Polycationic Al-Oxo Cluster in a Porous Ionic Crystal Exhibiting Lewis Acidity”,
W. Zhou, N. Ogiwara*, Z. Weng, C. Zhao, L. Yan, Y. Kikukawa, S. Uchida*,
Chem. Commun., 2022, 58, 12548–12551.

(38) “Bonding Mechanism of Botanical Concrete: Microstructural Changes between Waste Concrete Powder and Wood”,
R. Wei*, Y. Sakai, N. Ogiwara, S. Uchida,
J. Clean. Prod., 2022, 378, 134505.

(37) “Polyoxocationic Antimony Oxide Cluster with Highly Acidic Protons”,
Y. Watanabe, K. Hyeon-Deuk, T. Yamamoto, M. Yabuuchi, O. M. Karakulina, Y. Noda, T. Kurihara, I. Chang, M. Higashi, O. Tomita, C. Tassel, D. Kato, J. Xia, T. Goto, C. M. Brown, Y. Shimoyama, N. Ogiwara, J. Hadermann, A. M. Abakumov, S. Uchida*, R. Abe*, H. Kageyama*,
Sci. Adv., 2022, 8 (24), eabm5379.

(36) “Basicity of Isostructural Porous Ionic Crystals Composed of Nb/Ta-Substituted Keggin-Type Polyoxotungstates”, 
Z. Weng, N. Ogiwara, D. Yokogawa, T. Kitao, Y. Kikukawa, S. Uchida*, 
Dalton Trans., 2022, 51 (21), 8186–8191.

(35) “Proton Conduction in Ionic Crystals Based on Polyoxometalates”, 
N. Ogiwara, T. Iwano, T. Ito, S. Uchida*, 
Coord. Chem. Rev., 2022, 462, 214524. 

(34) “Syntheses, Polymorphic Transformations, and Functions of Ionic Crystals Based on Mononuclear Bismuth(III) Complexes and Polyoxometalates”, 
T. Iwano, D. Akutsu, Z. Weng, N. Ogiwara, S. Uchida*, 
ChemNanoMat, 2022, 8, e202100479.

(33) “Oxygen Evolution Reaction Driven by Charge Transfer from a Cr Complex to Co-Containing Polyoxometalate in a Porous Ionic Crystal”, 
Y. Shimoyama, N. Ogiwara, Z. Weng, S. Uchida*,
J. Am. Chem. Soc., 2022, 144 (7), 2980–2986.

(32) “Phase Control of Solid-solution Nanoparticles Beyond the Phase Diagram for Enhanced Catalytic Property”,
D. Wu*, K. Kusada*, S. Aspera, H. Nakanishi, Y. Chen, O. Seo, C. Song, J. Kim, S. Hiroi, O. Sakata, T. Yamamoto, S. Matsumura, Y. Nanba, M. Koyama, N. Ogiwara, S. Kawaguchi, Y. Kubota, H. Kitagawa*,
ACS Mater. Au, 2022, 2, (2), 110–116.

(31) “Incorporating Highly-basic Polyoxometalate Anions Comprising Nb or Ta into Nanoscale Reaction Fields of Porous Ionic Crystals”,
Z. Weng, N. Ogiwara, T. Kitao, Y. Kikukawa, Y. Gao, L. Yan, S. Uchida*,
Nanoscale, 2021,13 (44), 18451–18457.

(30) “Fabrication of Integrated Copper-Based Nanoparticles/Amorphous Metal–Organic Framework by Facile Spray-Drying Method: Highly Enhanced CO2 Hydrogenation Activity for Methanol Synthesis”, 
Y. Mitsuka*, N. Ogiwara, M. Mukoyoshi, H. Kitagawa*, T. Yamamoto, T. Toriyama, S. Matsumura, M. Haneda, S. Kawaguchi, Y. Kubota, H. Kobayashi*,
Angew. Chem. Int. Ed., 2021, 60 (41), 22283–22288.

(29) “Isomeric Effects on the Acidity of Al13 Keggin Clusters in Porous Ionic Crystals”,
W. Zhou, N. Ogiwara, Z. Weng, N. Tamai, C. Zhao, L. Yan, S. Uchida*,
Chem. Commun., 2021, 57 (71), 8893–8896.

(28) “Recording the Pt-beyond Hydrogen Production Electrocatalysis by Dirhodium Phosphide with an Overpotential of Only 4.3 mV in Alkaline Electrolyte”,
H. Xin, Z. Dai, Y. Zhao, S. Guo, J. Sun, Q. Luo, P. Zhang, L. Sun, N. Ogiwara, H. Kitagawa, B. Huang*, F. Ma*,
Appl. Catal. B, 2021, 297, 120457.

(27) “Integrating Molecular Design and Crystal Engineering Approaches in Non-humidified Intermediate-temperature Proton Conductors Based on a Dawson-type Polyoxometalate and Poly(ethylene glycol) Derivatives”, 
N. Ogiwara,‡ M. Tomoda,‡ S. Miyazaki, Z. Weng, H. Takatsu, H. Kageyama, T. Misawa, T. Ito, S. Uchida*, (‡equal contribution)
Nanoscale, 2021, 13 (17), 8049–8057.

(26) “Ultrahigh Proton Conduction via Extended Hydrogen-Bonding Network in a Preyssler-Type Polyoxometalate-Based Framework Functionalized with Lanthanide Ion”,  
T. Iwano, K. Shitamatsu, N. Ogiwara, M. Okuno, Y. Kikukawa, S. Ikemoto, S. Shirai, S. Murasugu, P. Waddell, R. J. Errington, M. Sadakane*, S. Uchida*,
ACS Appl. Mater. Interfaces, 2021, 13 (16), 19138–19147.

(25) “Formation of Mixed-Valence Luminescent Silver Clusters via Cation-Coupled Electron-Transfer in a Redox-Active Ionic Crystal Based on a Dawson-type Polyoxometalate with Closed Pores”,
N. Haraguchi, T. Okunaga, Y. Shimoyama, N. Ogiwara, S. Kikkawa, S. Yamazoe, M. Inada, T. Tachikawa, S. Uchida*,
Eur. J. Inorg. Chem., 2021, 1531–1535.

(24) “Crystalline to Amorphous Transformation in Solid-Solution Alloy Nanoparticles Induced by Boron Doping”, 
K. Kobayashi, K. Kusada, D. Wu, N. Ogiwara, H. Kobayashi*, M. Haruta, H. Kurata, S. Hiroi, O. Seo, C. Song, Y. Chen, J. M. Kim, A. Tayal, O. Sakata, K. Ohara, T. Honma, H. Kitagawa*,
Chem. Commun., 2020, 56 (85), 12941–12944.

(23) “Isostructural Mesoporous Ionic Crystals as a Tunable Platform for Acid Catalysis”,
Y. Shimoyama, Z. Weng, N. Ogiwara, T. Kitao, Y. Kikukawa, S. Uchida*, 
Dalton Trans., 2020, 49 (30), 10328–10333.

(22) “Probing Dynamics of Carbon Dioxide in a Metal–Organic Framework under High Pressure by High-Resolution Solid-State NMR”,
M. Inukai*, T. Kurihara, Y. Noda, W. Jiang, K. Takegoshi, N. Ogiwara, H. Kitagawa, K. Nakamura,
Phys. Chem. Chem. Phys., 2020, 22 (26), 14465–14470.

(21) “Ligand Functionalization-Controlled Activity of Metal–Organic Framework-Encapsulated Pt Nanocatalyst toward Activation of Water”,
N. Ogiwara, H. Kobayashi*, M. Inukai, Y. Nishiyama, P. Concepción, F. Rey, H. Kitagawa*,
Nano Lett., 2020, 20 (1), 426–432.

(20) “Missing-Linker Metal-organic Frameworks for Oxygen Evolution Reaction”,
Z. Xue, K. Liu, Q. Liu, Y. Li, M. Li, C. Su, N. Ogiwara, H. Kobayashi, H. Kitagawa, M. Liu*, G. Li*,
Nat. Commun., 2019, 10, 5048.

(19) “The First Study on the Reactivity of Water Vapor in Metal–Organic Frameworks with Platinum Nanocrystals”,
N. Ogiwara, H. Kobayashi*, P. Concepción, F. Rey, H. Kitagawa*,
Angew. Chem. Int. Ed., 2019, 58 (34), 11731–11736.

(18) “The Effect of Amorphization on the Molecular Motion of the 2-Methylimidazolate Linkers in ZIF-8”,
N. Ogiwara, D. I. Kolokolov*, M. Donoshita, H. Kobayashi, S. Horike, A. G. Stepanov, H. Kitagawa*,
Chem. Commun., 2019, 55 (42), 5906–5909.

(17) “Solid-Solution Alloy Nanoparticles of A Combination of Immiscible Au and Ru with A Large Gap of Reduction Potential and Their Enhanced Oxygen Evolution Reaction Performance”,
Q. Zhang, K. Kusada*, D. Wu, N. Ogiwara, T. Yamamoto, T. Toriyama, S. Matsumura, S. Kawaguchi, Y. Kubota, T. Honma, H. Kitagawa*,
Chem. Sci., 2019, 10 (19), 5133–5137.

(16) “Conductive Metal–Organic Framework Nanowires Array for Electrocatalytic Oxygen Evolution”, 
W. Li, Q. Li, J. Xie, N. Ogiwara, H. Jiang, H. Kitagawa, G. Xu*, Y. Wang*,
J. Mater. Chem. A, 2019, 7 (17), 10431–10438.

(15) “Charge Transfer Dependence on CO2 Hydrogenation Activity to Methanol in Cu Nanoparticles Covered with Metal–Organic Framework systems”,
H. Kobayashi*, J. M Taylor, Y. Mitsuka, N. Ogiwara, T. Yamamoto, T. Toriyama, S. Matsumura, H. Kitagawa*,
Chem. Sci., 2019, 10 (11), 3289–3294.

(14) “Coating of 2D Flexible Metal–Organic Frameworks on Metal Nanocrystals”, 
N. Ogiwara, H. Kobayashi*, K. Kobayashi, T. Yamamoto, T. Toriyama, S. Matsumura, H. Kitagawa*, 
Chem. Lett., 2019, 48 (2), 173–176.

(13) “Lanthanide-Based Porous Coordination Polymers: Syntheses, Slow Relaxation of Magnetization, and Magnetocaloric Effect”,
C. Das, A. Upadhyay, K. Ansari, N. Ogiwara, T. Kitao, S. Horike*, M. Shanmugam*,
Inorg. Chem., 2018, 57 (11), 6584–6598.

(12) “Sequence-regulated Copolymerization based on Periodic Covalent Positioning of Monomers along One-Dimensional Nanochannels”, 
S. Mochizuki, N. Ogiwara, M. Takayanagi, M. Nagaoka, S. Kitagawa, T. Uemura*,
Nat. Commun., 2018, 9, 329.

(11) “Imidazolium Cation Transportation in a 1-D Coordination Polymer”,
W. Chen, N. Ogiwara, K. Kadota, K. Panyarat, S. Kitagawa*, S. Horike*,
Dalton Trans., 2017, 46 (33), 10798–10801.

(10) “Mechanical Alloying of Metal–Organic Frameworks”, 
T. Panda, S. Horike*, K. Hagi, N. Ogiwara, K. Kadota, T. Itakura, M. Tsujimoto, S. Kitagawa*,
Angew. Chem. Int. Ed., 2017, 56 (9), 2413–2417.

(9) “Encapsulating Mobile Proton Carriers into Structural Defects in Coordination Polymer Crystals: High Anhydrous Proton Conduction and Fuel Cell Application”, 
M. Inukai, S. Horike*, T. Itakura, R. Shinozaki, N. Ogiwara, D. Umeyama, S. Nagarkar, Y. Nishiyama, M. Malon, A. Hayashi, T. Ohhara, R. Kiyanagi, S. Kitagawa*,
J. Am. Chem. Soc., 2016, 138, (27), 8505–8511.

(8) “Fast Conduction of Organic Cations in Metal Sulfate Frameworks”,
N. Ogiwara, M. Inukai, T. Itakura, S. Horike*, S. Kitagawa*,
Chem. Mater., 2016, 28 (11), 3968–3975.

(7) “Crystal engineering of a Family of Hybrid Ultramicroporous Materials based upon Interpenetration and Dichromate Linkers”,
H. Scott,‡ N. Ogiwara,‡ K. Chen, D. Madden, T. Pham, K. Forrest, B. Space, S. Horike, J. Perry IV, S. Kitagawa*, M. J. Zaworotko*, (‡equal contribution)
Chem. Sci., 2016, 7 (8), 5470–5476.

(6) “Glass Formation of a Coordination Polymer Crystal for Enhanced Proton Conductivity and Material Flexibility”,
W. Chen, S. Horike*, D. Umeyama, N. Ogiwara, T. Itakura, C. Tassel, Y. Goto, H. Kageyama, S. Kitagawa*, 
Angew. Chem. Int. Ed., 2016, 55 (17), 5195–5200.

(5) “Direct Synthesis of Hierarchically Porous Metal–Organic Frameworks with High Stability and Strong Brønsted Acidity: The Decisive Role of Hafnium in Efficient and Selective Fructose Dehydration”,
Z. Hu, Y. Peng, Y. Gao, Y. Qian, S. Ying, D. Yuan, S. Horike, N. Ogiwara, R. Babarao, Y. Wang, N. Yan, D. Zhao*,
Chem. Mater., 2016, 28 (8), 2659–2667.

(4) “A pH-Responsive Phase Transformation of a Sulfonated Metal–Organic Framework from Amorphous to Crystalline for Efficient CO2 Capture”,
Z. Hu, J. Lin, N. Ogiwara, A. Rodriguez, Y. Peng, Y. Wang, S. Horike*, D. Zhao*,
CrystEngComm, 2016, 18 (16), 2803–2807.

(3) “Control of Molecular Rotor Rotational Frequencies in Porous Coordination Polymers Using a Solid-Solution Approach”,
M. Inukai, T. Fukushima, Y. Hijikata, N. Ogiwara, S. Horike*, S. Kitagawa*,
J. Am. Chem. Soc., 2015, 137 (38), 12183–12186.

(2) “Formation of Foam‐like Microstructural Carbon Material by Carbonization of Porous Coordination Polymers through a Ligand‐Assisted Foaming Process”,
K. Kongpatpanich, S. Horike*, Y. Fujiwara, N. Ogiwara, H. Nishihara, S. Kitagawa*,
Chem. Eur. J., 2015, 21 (38), 13278–13283.

(1)  “Pressure-Induced Amorphization of a Dense Coordination Polymer and its Impact on Proton Conductivity”, 
D. Umeyama, S.Horike*, C. Tassel, H. Kageyama, Y. Higo, K. Hagi, N. Ogiwara, S. Kitagawa*,
APL Mater., 2014, 2 (12), 124401.

その他出版物等

(3) 「ナノ金属と多孔性金属錯体との複合化による相乗的な触媒機能」
   荻原 直希
   触媒, 2023, Vol.65, No.2, 137.

(2) 「金属酸化物クラスターが創るイオン結晶の細孔に閉じ込められたポリマーによる高速プロトン伝導」 
　岩野 司, 荻原 直希, 内田 さやか,  
　セラミック, 2021, 第56巻 9月号,  615–618.

(1) 「多孔性金属錯体と金属ナノ結晶の複合化による水の反応性の制御」
   荻原 直希, 小林 浩和, 北川 宏,
   触媒, 2021, Vol.63, No.4,  209–213.

所属学会

　日本化学会、錯体化学会