発表論文 (楠本助教)

  1. Pincer-Supported Perfluororhodacyclopentanes: High Nucleophilicity of M–CF Bond
    S. Hayashi, T. Murayama, S. Kusumoto, K. Nozaki
    Angew. Chem. Int. Ed. 2022, 61, e202207760. 10.1002/anie.202207760
  2. Synthesis and Reactivity of PC(sp3)P-pincer Iridium Complexes Bearing Diborylmethyl Anion
    M. Kishino, S. Takaoka, Y. Shibutani, S. Kusumoto, K. Nozaki
    Dalton Trans. 2022, 51, 5009–5015. 10.1039/D2DT00513A
  3. Atom Swapping on Aromatic Rings: Conversion from Phosphinine Pincer Metal Complexes to Metallabenzenes Triggered by O2 Oxidation
    K. Masada, S. Kusumoto, K. Nozaki
    Angew. Chem. Int. Ed. 2022, 61, e202117096. 10.1002/anie.202117096 Featured on the cover.
  4. Cleavage of Si–H, Si–C Bonds by Metal–Ligand Cooperation: Formation of Silyl Anion and Silylene Equivalents from Tertiary Silanes
    T. Higashi, S. Kusumoto, K. Nozaki
    Organometallics 2022, 41, 659–665. 10.1021/acs.organomet.2c00037 Selected as ACS Editors' Choice. Selected as Most Read Articles in 2022.
  5. Heterolytic Oxidative Addition of sp2 and sp3 C–H Bonds by Metal–Ligand Cooperation with an Electron-deficient Cyclopentadienone Iridium Complex
    T. Higashi, S. Kusumoto, K. Nozaki
    J. Am. Chem. Soc. 2021, 143, 12999–13004. 10.1021/jacs.1c06714 Featured on the cover
  6. Umpolung of B–H Bonds by Metal–Ligand Cooperation with Cyclopentadienone Iridium Complexes
    T. Higashi, S. Kusumoto, K. Nozaki
    Angew. Chem. Int. Ed. 2021, 60, 2844–2848. 10.1002/anie.202011322
  7. Reductive Coupling of Carbon Dioxide and an Aldehyde Mediated by a Copper(I) Complex toward the Synthesis of α-Hydroxycarboxylic Acids
    K. Masada, S. Kusumoto, K. Nozaki
    Org. Lett. 2020, 22, 4922–4926. 10.1021/acs.orglett.0c00995 Featured on the cover
  8. Cleavage of C–C and C–O bonds in β-O-4 Linkage of Lignin Model Compound by Cyclopentadienone Group 8 and 9 Metals Complexes
    S. Kusumoto, M. Kishino, K. Nozaki
    Chem. Lett. 2020, 49, 477–480. 10.1246/cl.200037
  9. Metal–Ligand Cooperative C–H Bond Formation by Cyclopentadienone Platinum Complexes
    T. Higashi, H. Ando, S. Kusumoto, K. Nozaki
    J. Am. Chem. Soc. 2019, 141, 2247–2250. 10.1021/jacs.8b13829
  10. Hydrogenation of Carbon Dioxide with Organic Base by PC(II)P-Ir Catalysts
    S. Takaoka, A. Eizawa, S. Kusumoto, K. Nakajima, Y. Nishibayashi, K. Nozaki
    Organometallics 2018, 37, 3001–3009. 10.1021/acs.organomet.8b00377 Featured on the cover
  11. Dehydrogenation of dimethylamine-borane catalyzed by half-sandwich Ir and Rh complexes: Mechanism and the role of Cp* non-innocence
    S. Pal, S. Kusumoto, K. Nozaki
    Organometallics 2018, 37, 906–914. 10.1021/acs.organomet.7b00889
  12. Cp*Ir-catalyzed Acceptorless Dehydrogenation of Carbon–Carbon Single Bonds
    H. Ando, S. Kusumoto, W. Wu, K. Nozaki
    Organometallics 2017, 36, 2317–2322. 10.1021/acs.organomet.7b00245
  13. Facile styrene formation from ethylene and a phenylplatinum(II) complex leading to an observable platinum(II)-hydride
    S. Pal, S. Kusumoto, K. Nozaki
    Organometallics 2017, 36, 502–505. 10.1021/acs.organomet.6b00892
  14. Development of Highly Active Ir–PNP Catalysts for Hydrogenation of Carbon Dioxide with Organic Bases
    W. Aoki, N. Wattanabinin, S. Kusumoto, K. Nozaki
    Bull. Chem. Soc. Jpn. 2016, 89, 113–124. 10.1246/bcsj.20150311 highlighted as BCSJ Selected Papers
  15. The Retro-Hydroformylation Reaction
    S. Kusumoto, T. Tatsuki, K. Nozaki
    Angew. Chem. Int. Ed. 2015, 54, 8458–8461. 10.1002/anie.201503620 highlighted in Front cover and Wiley-Japan Science Cafe
  16. Direct and Selective Hydrogenolysis of Arenols and Aryl Methyl Ethers
    S. Kusumoto, K. Nozaki
    Nat. Commun. 2015, 6, 6296. 10.1038/ncomms7296 highlighted in C&E News and UTokyo Research.
  17. Acceptorless Dehydrogenation of C–C Single Bonds Adjacent to Functional Groups by Metal-Ligand Cooperation
    S. Kusumoto, M. Akiyama, K. Nozaki
    J. Am. Chem. Soc. 2013, 135, 18726–18729. 10.1021/ja409672w
  18. Direct Aldol Polymerization of Acetaldehyde with Organocatalyst/Brønsted Acid Systems
    S. Kusumoto, S. Ito, K. Nozaki
    Asian J. Org. Chem. 2013, 2, 977–982. 10.1002/ajoc.201300134 This paper will be listed in a special issue on the Mukaiyama aldol reaction.
  19. Why Did Incorporation of Acrylonitrile to a Linear Polyethylene Become Possible? Comparison of Phosphine-Sulfonate Ligand with Diphosphine and Imine-Phenolate Ligands in the Pd-Catalyzed Ethylene/Acrylonitrile Copolymerization
    K. Nozaki, S. Kusumoto, S. Noda, T. Kochi, L. W. Chung, K. Morokuma
    J. Am. Chem. Soc. 2010, 132, 16030–16042. 10.1021/ja104837h

総説・解説

  1. Metal-Ligand Cooperative Bond Cleavage/Formation and Their Catalytic Applications with Cyclopentadienone Metal Complexes
    T. Higashi, S. Kusumoto, K. Nozaki
    J. Synth. Org. Chem. Jpn. 2022, 80, 459–468. 10.5059/yukigoseikyokaishi.80.459
  2. Cleavage of Si–H, B–H and C–H Bonds by Metal-Ligand Cooperation
    T. Higashi, S. Kusumoto, K. Nozaki
    Chem. Rev. 2019, 119, 10393–10402. 10.1021/acs.chemrev.9b00262