発表論文 (楠本講師)
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Hydrogenative Degradation of PEG-Functionalized Lignin
S. Kusumoto, T. Higashi, Y. Matsumoto, T. Yamada, K. Nozaki
Polym. J. accepted.
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Boron Polycation Supported by Cyclic Bis(carbodiphosphorane)
K. Saito, S. Kusumoto, K. Nozaki
Chem. Eur. J. 2023, e202302060. 10.1002/chem.202302060
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A Dinuclear Rh(-I)/Rh(I) Complex Bridged by Biphilic Phosphinine Ligands
K. Masada, K. Okabe, S. Kusumoto, K. Nozaki
Chem. Sci. 2023, 14, 8524–8530. 10.1039/D3SC02292G
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Synthesis, Characterization and Trapping of a Cyclic Diborylcarbene, an Electrophilic Carbene
Y. Shibutani, S. Kusumoto, K. Nozaki
J. Am. Chem. Soc. 2023, 145, 16186–16192. 10.1021/jacs.3c04933 Featured on the cover. Highlighted in Chem-Station.
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Cyclopentadienone Vanadium(I) Complex; Synthesis, Red-Ox Activity and Application to Catalytic Transfer Hydrogenation
T. Higashi, S. Kusumoto, K. Nozaki
Organometallics 2023, 42, 865–870. 10.1021/acs.organomet.3c00135
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Structure and Reactivity of Ag(I) Complexes Bearing Tridentate Phosphinine Ligands
K. Masada, S. Kusumoto, K. Nozaki
Organometallics 2023, 42, 971–981. 10.1021/acs.organomet.3c00143
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Pincer-Supported Perfluororhodacyclopentanes: High Nucleophilicity of M–CF Bond
S. Hayashi, T. Murayama, S. Kusumoto, K. Nozaki
Angew. Chem. Int. Ed. 2022, 61, e202207760. 10.1002/anie.202207760
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Synthesis and Reactivity of PC(sp3)P-pincer Iridium Complexes Bearing Diborylmethyl Anion
M. Kishino, S. Takaoka, Y. Shibutani, S. Kusumoto, K. Nozaki
Dalton Trans. 2022, 51, 5009–5015. 10.1039/D2DT00513A
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Atom Swapping on Aromatic Rings: Conversion from Phosphinine Pincer Metal Complexes to Metallabenzenes Triggered by O2 Oxidation
K. Masada, S. Kusumoto, K. Nozaki
Angew. Chem. Int. Ed. 2022, 61, e202117096. 10.1002/anie.202117096 Featured on the cover.
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Cleavage of Si–H, Si–C Bonds by Metal–Ligand Cooperation: Formation of Silyl Anion and Silylene Equivalents from Tertiary Silanes
T. Higashi, S. Kusumoto, K. Nozaki
Organometallics 2022, 41, 659–665. 10.1021/acs.organomet.2c00037 Selected as ACS Editors' Choice. Selected as Most Read Articles in 2022.
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Heterolytic Oxidative Addition of sp2 and sp3 C–H Bonds by Metal–Ligand Cooperation with an Electron-deficient Cyclopentadienone Iridium Complex
T. Higashi, S. Kusumoto, K. Nozaki
J. Am. Chem. Soc. 2021, 143, 12999–13004. 10.1021/jacs.1c06714 Featured on the cover
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Umpolung of B–H Bonds by Metal–Ligand Cooperation with Cyclopentadienone Iridium Complexes
T. Higashi, S. Kusumoto, K. Nozaki
Angew. Chem. Int. Ed. 2021, 60, 2844–2848. 10.1002/anie.202011322
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Reductive Coupling of Carbon Dioxide and an Aldehyde Mediated by a Copper(I) Complex toward the Synthesis of α-Hydroxycarboxylic Acids
K. Masada, S. Kusumoto, K. Nozaki
Org. Lett. 2020, 22, 4922–4926. 10.1021/acs.orglett.0c00995 Featured on the cover
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Cleavage of C–C and C–O bonds in β-O-4 Linkage of Lignin Model Compound by Cyclopentadienone Group 8 and 9 Metals Complexes
S. Kusumoto, M. Kishino, K. Nozaki
Chem. Lett. 2020, 49, 477–480. 10.1246/cl.200037
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Metal–Ligand Cooperative C–H Bond Formation by Cyclopentadienone Platinum Complexes
T. Higashi, H. Ando, S. Kusumoto, K. Nozaki
J. Am. Chem. Soc. 2019, 141, 2247–2250. 10.1021/jacs.8b13829
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Hydrogenation of Carbon Dioxide with Organic Base by PC(II)P-Ir Catalysts
S. Takaoka, A. Eizawa, S. Kusumoto, K. Nakajima, Y. Nishibayashi, K. Nozaki
Organometallics 2018, 37, 3001–3009. 10.1021/acs.organomet.8b00377 Featured on the cover
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Dehydrogenation of dimethylamine-borane catalyzed by half-sandwich Ir and Rh complexes: Mechanism and the role of Cp* non-innocence
S. Pal, S. Kusumoto, K. Nozaki
Organometallics 2018, 37, 906–914. 10.1021/acs.organomet.7b00889
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Cp*Ir-catalyzed Acceptorless Dehydrogenation of Carbon–Carbon Single Bonds
H. Ando, S. Kusumoto, W. Wu, K. Nozaki
Organometallics 2017, 36, 2317–2322. 10.1021/acs.organomet.7b00245
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Facile styrene formation from ethylene and a phenylplatinum(II) complex leading to an observable platinum(II)-hydride
S. Pal, S. Kusumoto, K. Nozaki
Organometallics 2017, 36, 502–505. 10.1021/acs.organomet.6b00892
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Development of Highly Active Ir–PNP Catalysts for Hydrogenation of Carbon Dioxide with Organic Bases
W. Aoki, N. Wattanabinin, S. Kusumoto, K. Nozaki
Bull. Chem. Soc. Jpn. 2016, 89, 113–124. 10.1246/bcsj.20150311 highlighted as BCSJ Selected Papers
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The Retro-Hydroformylation Reaction
S. Kusumoto, T. Tatsuki, K. Nozaki
Angew. Chem. Int. Ed. 2015, 54, 8458–8461. 10.1002/anie.201503620 highlighted in Front cover and Wiley-Japan Science Cafe
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Direct and Selective Hydrogenolysis of Arenols and Aryl Methyl Ethers
S. Kusumoto, K. Nozaki
Nat. Commun. 2015, 6, 6296. 10.1038/ncomms7296 highlighted in C&E News and UTokyo Research.
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Acceptorless Dehydrogenation of C–C Single Bonds Adjacent to Functional Groups by Metal-Ligand Cooperation
S. Kusumoto, M. Akiyama, K. Nozaki
J. Am. Chem. Soc. 2013, 135, 18726–18729. 10.1021/ja409672w
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Direct Aldol Polymerization of Acetaldehyde with Organocatalyst/Brønsted Acid Systems
S. Kusumoto, S. Ito, K. Nozaki
Asian J. Org. Chem. 2013, 2, 977–982. 10.1002/ajoc.201300134 This paper will be listed in a special issue on the Mukaiyama aldol reaction.
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Why Did Incorporation of Acrylonitrile to a Linear Polyethylene Become Possible? Comparison of Phosphine-Sulfonate Ligand with Diphosphine and Imine-Phenolate Ligands in the Pd-Catalyzed Ethylene/Acrylonitrile Copolymerization
K. Nozaki, S. Kusumoto, S. Noda, T. Kochi, L. W. Chung, K. Morokuma
J. Am. Chem. Soc. 2010, 132, 16030–16042. 10.1021/ja104837h
総説・解説
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Metal-Ligand Cooperative Bond Cleavage/Formation and Their Catalytic Applications with Cyclopentadienone Metal Complexes
T. Higashi, S. Kusumoto, K. Nozaki
J. Synth. Org. Chem. Jpn. 2022, 80, 459–468. 10.5059/yukigoseikyokaishi.80.459
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Cleavage of Si–H, B–H and C–H Bonds by Metal-Ligand Cooperation
T. Higashi, S. Kusumoto, K. Nozaki
Chem. Rev. 2019, 119, 10393–10402. 10.1021/acs.chemrev.9b00262