Publications (Dr. Ito)

Original Papers

  1. Methylene-Bridged Bisphosphine Monoxide Ligands for Palladium-Catalyzed Copolymerization of Ethylene and Polar Monomers
    Mitsushige, Y.; Yasuda, H.; Carrow, B.; Ito, S.; Kobayashi, M.; Tayano, T.; Watanabe, Y.; Okuno, Y.; Hayashi, S.; Kuroda, J.; Okumura, Y.; Nozaki, K.
    ACS Macro Lett. 2018, 7, 305–311. 10.1021/acsmacrolett.8b00034
  2. Nickel-Catalyzed Propylene/Polar Monomer Copolymerization
    Konishi, Y.; Tao, W.; Yasuda, H.; Ito, S.; Oishi, Y.; Ohtaki, H.; Tanna, A.; Tayano, T.; Nozaki, K.
    ACS Macro Lett. 2018, 7, 213–217. 10.1021/acsmacrolett.7b00904
  3. Palladium/IzQO-Catalyzed Coordination–Insertion Copolymerization of Ethylene and 1,1-Disubstituted Ethylenes Bearing a Polar Functional Group
    Yasuda, H.; Nakano, R.; Ito, S.; Nozaki, K.
    J. Am. Chem. Soc. 2018, 140, 1876–1883. 10.1021/jacs.7b12593
  4. Synthesis of Pyrrole-Fused Corannulenes: 1,3-Dipolar Cycloaddition of Azomethine Ylides to Corannulene
    Tokimaru, Y.; Ito, S.; Nozaki, K.
    Angew. Chem. Int. Ed. 2017, 56, 15560–15564. 10.1002/anie.201707087 Highlighted in Synfacts
  5. Competing Annulene and Radialene Structures in a Single Anti-Aromatic Molecule Studied by High-Resolution Atomic Force Microscopy
    Kawai, S.; Takahashi, K.; Ito, S.; Pawlak, R.; Meier, T.; Spijker, P.; Canova, F. F.; Tracey, J.; Nozaki, K.; Foster, A. S.; Meyer, E.
    ACS Nano 2017, 11, 8122–8130. 10.1021/acsnano.7b02973
  6. Copolymerisation of Ethylene with Polar Monomers by Palladium Catalysts Bearing an N-Heterocyclic Carbene–Phosphine Oxide Bidentate Ligand
    Tao, W.; Akita, S.; Nakano, R.; Ito, S.; Hoshimoto, Y.; Ogoshi, S.; Nozaki, K.
    Chem. Commun. 2017, 53, 2630–2633. 10.1039/C7CC00002B
  7. Selective Synthesis of Unsymmetric Dibenzo[a,e]pentalenes by Rhodium-Catalysed Stitching Reaction
    Takahashi, K.; Ito, S.; Shintani, R.; Nozaki, K.
    Chem. Sci. 2017, 8, 101–107. 10.1039/C6SC04560J Featured on the back cover. Highlighted in Synfacts
  8. Elucidating the Key Role of Phosphine–Sulfonate Ligands in Palladium-Catalyzed Ethylene Polymerization: Effect of Ligand Structure on the Molecular Weight and Linearity of Polyethylene
    Nakano, R.; Chung, L. W.; Watanabe, Y.; Okuno, Y.; Okumura, Y.; Ito, S.; Morokuma, K.; Nozaki, K.
    ACS Catal. 2016, 6, 6101-6113. 10.1021/acscatal.6b00911
  9. Crystalline Isotactic Polar Polypropylene from the Palladium-Catalyzed Copolymerization of Propylene and Polar Monomers
    Ota, Y.; Ito, S.; Kobayashi, M.; Kitade, S.; Sakata, K.; Tayano, T.; Nozaki, K.
    Angew. Chem. Int. Ed. 2016, 55, 7505-7509. 10.1002/anie.201600819
  10. Copolymerization of Ethylene and Polar Monomers Using Ni/IzQO Catalysts
    Tao, W.; Nakano, R.; Ito, S.; Nozaki, K.
    Angew. Chem. Int. Ed. 2016, 55, 2835-2839. 10.1002/anie.201510077
  11. Ligand-Controlled Insertion Regioselectivity Accelerates Copolymerisation of Ethylene with Methyl Acrylate by Cationic Bisphosphine Monoxide-Palladium Catalysts
    Mitsushige, Y.; Carrow, B. P.; Ito, S.; Nozaki, K.
    Chem. Sci. 2016, 7, 737-744. 10.1039/C5SC03361F
  12. Iron-Catalyzed Homo- and Copolymerization of Propylene: Steric Influence of Bis(imino)pyridine Ligands
    Kawakami, T.; Ito, S.; Nozaki, K.
    Dalton Trans. 2015, 44, 20745-20752. 10.1039/C5DT03551A
  13. Benzene-Fused Azacorannulene Bearing an Internal Nitrogen Atom
    Ito, S.; Tokimaru, Y.; Nozaki, K.
    Angew. Chem. Int. Ed. 2015, 54, 7256-7260. 10.1002/anie.201502599 highlighted in Frontispiece and Synfacts
  14. Formal Aryne/Carbon Monoxide Copolymerization to Form Aromatic Polyketones/Polyketals
    Ito, S.; Wang, W.; Nishimura, K.; Nozaki, K.
    Macromolecules 2015, 48, 1959-1962. 10.1021/acs.macromol.5b00315
  15. Formal Aryne/Ethylene Copolymerization to Form Polyethylene Containing o-Arylene Units in the Main Chain
    Ito, S.; Wang, W.; Nozaki, K.
    Polym. J. 2015, 47, 474-480. 10.1038/pj.2015.27
  16. Isoquinolino[4,3,2-de]phenanthridine: Synthesis and Its Use in 1,3-Dipolar Cycloadditions to Form Nitrogen-Containing Polyaromatic Hydrocarbons
    Ito, S.; Tokimaru, Y.; Nozaki, K.
    Chem. Commun. 2015, 51, 221-224. 10.1039/C4CC06643J
  17. Quantification of the Steric Influence of Alkylphosphine–Sulfonate Ligands on Polymerization, Leading to High-Molecular-Weight Copolymers of Ethylene and Polar Monomers
    Ota, Y.; Ito, S.; Kuroda, J.; Okumura, Y.; Nozaki, K.
    J. Am. Chem. Soc. 2014, 136, 11898-11901. 10.1021/ja505558e
  18. Formal Aryne Polymerization: Use of [2.2.1]Oxabicyclic Alkenes as Aryne Equivalents
    Ito, S.; Takahashi, K.; Nozaki, K.
    J. Am. Chem. Soc. 2014, 136, 7547–7550. 10.1021/ja502073k highlighted in Synfacts.
  19. Copolymerization of Carbon Dioxide and Butadiene via a Lactone Intermediate
    Nakano, R.; Ito, S.; Nozaki, K.
    Nature Chem. 2014, 6, 325-331. 10.1038/nchem.1882 highlighted in Nature Chemistry, Chemistry World, C&E News, Chemical Enginnering, Chem-Station, Angew. Chem. Int. Ed..
  20. Friedel-Crafts Functionalization of the Cyclopentadienyl Ligand in Buckymetallocenes
    Matsuo, Y.; Kuninobu, Y.; Ito, S.; Sawamura, M.; Nakamura, E.
    Dalton Trans. 2014, 43, 7407-7412. 10.1039/C3DT52002A
  21. Direct Aldol Polymerization of Acetaldehyde with Organocatalyst/Brønsted Acid Systems
    Kusumoto, S.; Ito, S.; Nozaki, K.
    Asian J. Org. Chem. 2013, 2, 977-982. 10.1002/ajoc.201300134 This paper will be listed in a special issue on the Mukaiyama aldol reaction.
  22. Ethylene/Allyl Monomer Cooligomerization by Nickel/Phosphine–Sulfonate Catalysts
    Ito, S.; Ota, Y.; Nozaki, K.
    Dalton Trans. 2012, 41, 13807-13809. 10.1039/C2DT31771K
  23. Ping-Pong Polymerization by Allylation and Hydroformylation for Alternating Vinyl Alcohol-Vinyl Monomer Copolymers
    Ito, S.; Noguchi, M.; Nozaki, K.
    Chem. Commun. 2012, 48, 10481-10483. 10.1039/C2CC34980A Featured in the front cover
  24. P-Chiral Phosphine–Sulfonate/Palladium-Catalyzed Asymmetric Copolymerization of Vinyl Acetate with Carbon Monoxide
    Nakamura, A.; Kageyama, T.; Goto, H.; Carrow, B. P.; Ito, S.; Nozaki, K.
    J. Am. Chem. Soc. 2012, 134, 12366-12369. 10.1021/ja3044344
  25. Ethylene Polymerization by Palladium/Phosphine–Sulfonate Catalysts in the Presence and Absence of Protic Solvents: Structural and Mechanistic Differences
    Kanazawa, M.; Ito, S.; Nozaki, K.
    Organometallics 2011, 30, 6049-6052. 10.1021/om2004207
  26. Pd-Catalyzed Copolymerization of Methyl Acrylate with Carbon Monoxide: Structures, Properties and Mechanistic Aspects toward Ligand Design
    Nakamura, A.; Munakata, K.; Ito, S.; Kochi, T.; Chung, L. W.; Morokuma, K.; Nozaki, K.
    J. Am. Chem. Soc. 2011, 133, 6761-6779. 10.1021/ja2003268
  27. Coordination-Insertion Copolymerization of Allyl Monomers with Ethylene
    Ito, S.; Kanazawa, M.; Munakata, K.; Kuroda, J.; Okumura, Y.; Nozaki, K.
    J. Am. Chem. Soc. 2011, 133, 1232-1235. 10.1021/ja1092216
  28. Vinylarene/CO Copolymerization and Vinylarene/Polar Vinyl Monomer/CO Terpolymerization Using Palladium/Phosphine-Sulfonate Catalysts
    Kageyama, T.; Ito, S.; Nozaki, K.
    Chem. Asian J. 2011, 6, 690-697. 10.1002/asia.201000668
  29. Diastereoselective Carbometalation of Oxa- and Azabicyclic Alkenes under Iron Catalysis
    Ito, S.; Itoh, T.; Nakamura, M.
    Angew. Chem. Int. Ed. 2011, 49, 454-457. 10.1002/anie.201006180
  30. Copolymerization of Vinyl Acetate with Ethylene by Palladium/Alkylphosphine–Sulfonate Catalysts
    Ito, S.; Munakata, K.; Nakamura, A.; Nozaki, K.
    J. Am. Chem. Soc. 2009, 131, 14606-14607. 10.1021/ja9050839
  31. Iron-Catalyzed Cross-Coupling of Alkyl Sulfonates with Arylzinc Reagents.
    Ito, S.; Fujiwara, Y.i.; Nakamura, E.; Nakamura, M.
    Org. Lett. 2009, 11, 4306-4309. 10.1021/ol901610a
  32. Iron-catalysed fluoroaromatic coupling reactions under catalytic modulation with 1,2-bis(diphenylphosphino)benzene.
    Hatakeyama, T.; Kondo, Y.; Fujiwara, Y.-i.; Takaya, H.; Ito, S.; Nakamura, E. Nakamura, M.
    Chem. Commun. 2009, 1216-1218. 10.1039/b820879d
  33. Regioselective α-Alkylation of Ketones with Alkyl Chlorides and Fluorides via Highly Nucleophilic Magnesium Enamides.
    Hatakeyama, T.; Ito, S.; Yamane, H.; Nakamura, M.; Nakamura, E.
    Tetrahedron 2007, 63, 8440–8448. 10.1016/j.tet.2007.05.087
  34. Alkylation of Magnesium Enamide with Alkyl Chlorides and Fluorides.
    Hatakeyama, T.; Ito, S.; Nakamura, M.; Nakamura, E.
    J. Am. Chem. Soc. 2005, 127, 14192–14193. 10.1021/ja055306q
  35. Iron-Catalyzed Chemoselective Cross-Coupling of Primary and Secondary Alkyl Halides with Arylzinc Reagents.
    Nakamura, M.; Ito, S.; Matsuo, K.; Nakamura, E.
    Synlett 2005, 1794-1798. 10.1055/s-2005-871541
  36. Iron-Catalyzed Cross-Coupling of Primary and Secondary Alkyl Halides with Aryl Grignard Reagents.
    Nakamura, M.; Matsuo, K.; Ito, S.; Nakamura, E.
    J. Am. Chem. Soc. 2004, 126, 3686-3687. 10.1021/ja049744t
  37. Synthesis and Reactivity of Bucky Ruthenocene "Ru(η5-C60Me5)(η5-C5H5)".
    Matsuo, Y.; Kuninobu, Y.; Ito, S.; Nakamura, E.
    Chem. Lett. 2004, 33, 68-69. 10.1246/cl.2004.68

Review Articles

  • Palladium-Catalyzed Homo- and Copolymerization of Polar Monomers: Synthesis of Aliphatic and Aromatic Polymers
    Ito, S.
    Bull. Chem. Soc. Jpn. accepted. 10.1246/bcsj.20170347
  • 配位重合(2) 極性モノマーの配位共重合反応
    Ito, S.; Nozaki, K.
    In 精密重合が拓く高分子合成:高度な制御と進む実用化(CSJカレントレビュー); The Chemical Society of Japan Ed., vol. 20, 96–103 (2016). link
  • Chain-Growth Polymerization Enabling Formation/Introduction of Arylene Groups into Polymer Main Chains
    Ito, S.
    Polym. J. 2016, 48, 667-677. 10.1038/pj.2016.18
  • Formal Aryne/Ethylene Copolymerization to Form Polyethylene Containing o-Arylene Units in the Main Chain
    Ito, S.
    高分子(Polymers), Hot Topics, 2015, 64(12), 755. link
  • アライン等価体の重合反応
    Ito, S.
    化学と工業(Chemistry & Chemical Industry) 2015, 68(7), 640–641. link
  • Iron-catalyzed cross-coupling reactions
    Nakamura, E.; Hatakeyama, T.; Ito, S.; Ishizuka, K.; Ilies, L.; Nakamura, M.
    Organic Reactions 2014, 83, 1–209. 10.1002/0471264180.or083.01
  • C-H結合活性化を伴う金属表面上での重合反応
    Ito, S.
    Organometallic News 2013, 80–80. link
  • Alkene/CO Copolymerization
    Nozaki, K.; Ito, S.
    In Polymer Science: A Comprehensive Reference; Matyjaszewski, K., Möller, M., Eds., Elsevier: Amsterdam, vol. 3, 825-842 (2012). 10.1016/B978-0-444-53349-4.00086-8
  • 後周期遷移金属触媒を用いる極性ビニルモノマーの配位ー挿入共重合反応
    Ito, S.; Nozaki, K.
    触媒(Shokubai) 2010, 52, 559-563. link
  • Coordination-Insertion Copolymerization of Polar Vinyl Monomers by Palladium Catalysts
    Ito, S.; Nozaki, K.
    Chem. Rec. 2010, 10, 315-325. 10.1002/tcr.201000032
  • Asymmetric Polymerization
    Ito, S.; Nozaki, K.
    In Catalytic Asymmetric Synthesis 3rd ed.; Ojima, I., Ed., Wiley: Hoboken, 931-985 (2010). link
  • Metal-Catalyzed Arylations of Non-Activated Alkyl (Pseudo)halides via Cross-Coupling Reactions
    Ito, S.; Nakamura, M.
    In Modern Arylation Methods; Ackermann, L., Ed., Wiley-VCH: Weinheim, 155-181 (2009). link
  • Coordination-Insertion Copolymerization of Fundamental Polar Monomers
    Nakamura, A.; Ito, S.; Nozaki, K.
    Chem. Rev. 2009, 109, 5215-5244. 10.1021/cr900079r
  • 単純アルコールを活用する炭素−炭素結合形成反応
    Ito, S.
    有機合成化学協会誌(J. Synth. Org. Chem. Jpn.) 2007, 65, 618–619. 10.5059/yukigoseikyokaishi.65.618
  • 普遍金属を活用するクロスカップリング反応
    Ito, S.; Nakamura, M.
    Organometallic News 2007, 88–93. link